Small Size Pressurized Water Reactor Conceptual Design: April 11, 1960 (open access)

Small Size Pressurized Water Reactor Conceptual Design: April 11, 1960

From foreword: The purpose of this conceptual design is to outline criteria for the selection and development of a reactor plant with a fossil fuel fired superheater, a conventional generator plant and auxilary systems constituting a complete operating unit capable of producing a gross electrical power output of 22,000 kw.
Date: April 11, 1960
Creator: unknown
System: The UNT Digital Library
gem-Bis(disubstitutedphosphinyl)alkanes. II. Extraction Properties of Bis(di-n-hexlphosphinyl)methane (open access)

gem-Bis(disubstitutedphosphinyl)alkanes. II. Extraction Properties of Bis(di-n-hexlphosphinyl)methane

From abstract: "Bis(di-n-hexylphosphinyl)methane, HDPM, [(C6H13)2P(O)]2CH2, has been studied as an extractant for a variety of metals. HDPM was evaluated as an extractant for uranium(VI) and compared with tri-n-octylphosphine oxide, TOPO, (C8H13)3PO. In nonpolar solvents, HDPM forms a polymeric-like substance with compounds of uranium(VI). Viscosity measurements indicate that the molecular weight of this polymeric-like substance is about 100 times greater than the corresponding complex with TOPO. Polymer formation occurs only when nonpolar solvents are used as diluents for HDPM and is easily avoided by using polar solvents such as 1,2-aichlorobenzene. HDPM forms 1:1 and 2:1 complexes with uranium(VI) nitrate. Equilibrium constants for these complexes as well as that for the 2:1 TOPO complex were calculated and it was shown that the over-all constant is at least ten times larger for the HDPM complex than for the TOPO complex. The effect of concentration of various mineral acids, extractant concentration, temperature, and diluents on the extraction of uranium are discussed."
Date: April 11, 1961
Creator: Burke, Keith E.; Sakurai, Hiroshi; O'Laughlin, Jerome W. & Banks, Charles V.
System: The UNT Digital Library
Grüneisen's Law and the Fusion Curve at High Pressure (open access)

Grüneisen's Law and the Fusion Curve at High Pressure

A method to determine the correction to Grüneisen's law corresponding to the effect of the electrons at high pressure. It is assumed that the lattice contribution to the pressure is small and that the equation of state of the solid can be approximated by results of the statistical Thomas-Fermi atom model for the electron pressure.
Date: April 11, 1955
Creator: Gilvarry, J. J. (John James), 1917-
System: The UNT Digital Library