This report supersedes ORNL CF-57-2-1, which was an extension and revision of ORNL CF-54-6-72. Details concerning a recommended system of flow-plan symbols and drawing are given. The system is designed to identify the function of all major instrument components and to show schematically the operation of the instrument relative to the particular process. The system is used for identification and designation. The system is a modification of the Instrument Society of American Recommended Practice (RP 5.1).

A series of two-group calculations has been made on the Oracle for the purpose of obtaining critical-mass and flux distribution data for various ORR core configurations. The 3G3R code of Bate, Einstein, and Kinney was used, together with the RSP code developed by Nelson. This made it possible to obtain results for the three-dimensional case. The results, which are presented graphically, are intended to serve as a guide for the design of experiments until such time as actual measurements are available. The calculations were performed for the "clean cold" case, and it should be realized that the presence in the core of experiments and of fission products built up during operation will materially alter the flux patterns found. It is believed that the critical-mass data are accurate to within 10%. Within the fuel region it is believed that the thermal-flux patterns are the also accurate to this degree. Comparison of the results with MTR critical experiments, however, indicates that the thermal flux in the reflector in the vicinity of the fuel-reflector interface may have been underestimated by a factor of as much as 1.3. It should also be recalled that in a two-group calculation the "fast flux" is often a …

This report is presented in order to provide a satisfactory system of symbols and identifications for process-instrumentation equipment and to promote a uniformity of practice that will simplify and expedite instrumentation work. It is intended that the systems presented here should be capable of designating and identifying the multitude of instrumentation items which are used for control and operation of conventional processes, as well as for specialized work peculiar to ORNL. Instrument Society of America standards have been adhered to whenever practical.

A general program has been written to plot curves on the Oracle curve plotter. The supplement includes changes to slow down some of the loops and minimize the possibility of read-around errors and changes to handle special cases.

An annual report is given on the operation and costs of waste-disposal facilities at ORNL laboratories and operating buildings in the Bethel Valley area. The operations of the hot-chemical and metal-waste systems, the process-waste system, and the radioactive-gas-disposal system which utilized the 250-ft stack located in the Radioisotope area are discussed. The miscellaneous operations which include the SS (source and special nuclear) material control, SS material recovery, off-shift service for research divisions, water demineralization plant operations, and hydrogen liquefaction are included. However, the disposal of cooling water from LITR, off-gases from the Hot Pilot Plant, and the ORNL Graphite Reactor building are not covered by the report.

Section 9.0 is the "Chemical Processes for Fission Product Concentration, Removal or Fixation" section of the Status Report on the Disposal of Radioactive Wastes. The report is divided into four areas: (1) Introduction; (2) Summary of waste processes; (3) Concept of a multipurpose waste processing facility; and (4) Details of some of the waste processes.

Tests have been completed on a combination heater-cooler unit for use in in-pile loops designed to operate in beam hole HN-1 of the ORR facility. The unit is designed to use air-water mixtures as the coolant. the coolant flows through a spiral of 3/8-inc. diameter tubing cast in aluminum around the 3/8-in. IPS loop pipe. four 1000-w calrod-type electric heating elements are cast into the aluminum, along with the cooling coils to provide loop heating.

The new and as yet unsolved problems introduced by the production of large quantities of fission products and radioactive isotopes from fission or neutron capture present mankind a most complex technical, economic, and political problem. On one hand, the possibility of using the fission process to produce energy from an unexploited and abundant natural source is emerging from large programs of research and development. We are also beginning to see the promise of use of particulate and electromagnetic radiation for the good of man. On the other hand, we are presented with the problem of controlling the dangerous products of fission for periods of time measured in terms of many hundreds of years, periods longer than the effective tenure of any political state in history. We must not only devise ways of protecting ourselves in the present and for our lifetime but, in addition, we must establish the basic technical, social, and administrative control of vast quantities of artificial radioactivity that must remain effective for at least ten to twenty lifetimes.

A new and rapid method for the liquid-liquid extraction of uranium and plutonium from hydrochloric acid solution is based on the use of tri(iso-octyl)amine dissolved in xylene or methylisobutylketone. Uranium and/or plutonium are separated from thorium, alkalis, alkaline earths, rare earths, zirconium, niobium, ruthenium and other elements which do not form anionic species under the conditions described. The technique may be used for either tracer or macro quantities of uranium. Several practical applications of the method for the separations chemist are proposed.

The HRT mockup was shut down February 16, 1957 after operating for 576 hours on high concentration uranyl sulfate. At this time, all corrosion samples in the system were removed and replaced, and the wire extending thought the letdown hear exchanger was removed of examination.

A spectrophotometric method for the determination of cerium with Tiron (disodium-1,2-dihydroxybenzene-3,5disulfonate) was applied to the determination of cerium in samples which contain uranium and zirconium. The cerium-Tiron complex in solutions of pH 8 or greater exhibits an absorption maximum of 500 mu . This reagent does not react with any other lanthanide element. The interference of iron, uranium, and zirconium was eliminated by extracting these interfering elements with a solution of trioctylphosphine oxide in cyclohexane. (auth)

For various reasons it is not possible to leave the uranium or other nuclear fuel in a power reactor until all of it has been "burned up" by fission. In the case of liquid fuel (homogeneous) reactors a small part is continuously bled out, purified and returned. In the case of solid fuel reactors, fuel elements are periodically removed, reprocessed and the "unburned" fuel put back into service. In both cases the purification produces wastes which contain radioactive fission products and transuranic elements, and it is with the disposal of these wastes that we are concerned. For technical reasons, we will limit our consideration to the wastes from the processing of solid fuel elements, and from the processing of the very similar solid "blanket" elements in which fissionable fuel is made from non-fissionable isotopes of uranium and thorium by interaction with neutrons in the outer regions of the nuclear reactor.

A slurry addition system, a venturi in the circulation loop, and two types of sampling systems were tested with 500 and 800 g Th/kg H2O slurries in the 200 gpm loop at 250 C and 1000 psig. The addition system worked satisfactorily while the venturi gave erratic readings during part of the run. Both the capillary and in-line sampling systems proved satisfactory with the capillary sampler being much easier and more convenient to operate. The addition of uranium to the slurry had no appreciable effect on the handling characteristics, the attack rate on 347 SS, the particle size and crystallite size of the thorium oxide. The attack rate was found to be 1 mpy during the first 100 hours of circulation and decreased to 0.4 mpy at the end of the run.

This technical report summarizes some preliminary calculations of fuel exposures attainable in heterogeneous reactors, fueled with a mixture of thorium and U233, moderated with D2O and operated with no net loss in fissionable fuel.

Loop L-2-10 was the eighth completed in-pile loop experiment and the first in the HB-2 beam hole at the LITR. The loop was inserted on July 2, 1956 and removed on September 3, 1956. The installation, operation, removal, and general performance of the HRP in-pile solution corrosion loop in the HB-2 beam hole at the LITR are described.

The OCUSOL-A program (ORNL-CF-57-6-4) for Univac is a modification of the Eyewash (ORNL-1925) multi-group, multi-region reactor code. The group=energy-lethargy-temperature relationship are given in Table A. The element code numbers are given in Table B. The cross sections now on the sigma-tape are given in tables in the Appendix numbered with the element code number. This technical report explains the bases for choosing the cross sections.

An investigation of the causes of observed explosive reaction of zirconium-coated uranium dioxide on dissolution in nitric acid was conducted. It was concluded that such a reaction is to be expected. Possible but unconfirmed methods of alleviating the problem are suggested.

Design calculations were made for a system consisting of a pump, one hundred feet of pipe, and a heat exchanger to remove 1 Mw of heat from various aqueous thorium oxide slurries. The rheological properties of the slurries were varied over a range of yield stresses from 0 to 1.5 lb/sq ft and of coefficients of rigidity from 1/2 to 2 centipoise. Two different cases were studied: a heat exchanger having fixed axial and radial delta T in which the tube length was allowed to vary and a heat exchanger having fixed tube length in which the axial and radial delta T were allowed to vary. It was shown that the pump power must be increased by a factor of 15 to 30 in order to maintain satisfactory operation of the heat exchanger as the slurry yield stress is increased form 0 to 1.5 lb/sq ft. However the pump power is essentially independent of heat exchanger tube diameter for any given slurry. The rated capacity of a slurry heat exchange is essentially independent of slurry yield stress and coefficient of rigidity, provided that the tube velocity can be suitably increased as the slurry yield stress in increased.

Specifications are presented for cleanliness during installation of piping and equipment in the High Level Volatility Laboratory, Bldg. 4507.

A 10% phosphoric acid solution contain 0.2% "Rodine 45" inhibitor is recommended to be used for the chemical cleaning of the HRT seam and closed colling water systems. Wet storage is recommended for both of these systems. The steam system is to be stored with steam condensate containing 100 ppm hydrazine, and closed cooling water system is to be stored with steam condensate containing 1000 ppm potassium chromate.

To supply information about the several letdown valves which have been in HRT service, a typical valve plug examined by the Metallurgy Section confirms the belief that chemical attack on the Stellite #6 was occurring. It appears that most of the corrosion was due to rinse solutions, since this phenomenon has not been noted on letdown valves in the HRT Mockup where over 90% of the operating time has been with UO2SO4 solutions.

The Eyewash program, written by James H. Alexander and Nancy D. Given, provides solutions of reactor criticality problems in spherical geometry by means of the group diffusion method. It employs thirty lethargy groups (plus one thermal group) in nine regions. The input consists principally of specifying the geometrical scaling factor, boundaries and compositions of the various regions, and temperature level. The output includes the value of vc that would render the system critical, the relative fission density distribution, fissions, absorptions, and leakages in each lethargy group in each region, and, if desired, an edit of the flux at each space point, each lethargy, and an edit of the macroscopic cross sections for each lethargy, each region. OCUSOL-A is a minor modification and extension of Eyewash. It provides for the computation and editing, on the supervisory control typewriter, of the total absorptions in selected nuclides in the various regions. This information is useful in the computation of breeding ratios and the preparation of detailed neutron balances, and in the estimation of flux-averaged cross sections for use in estimating the rate of change of concentration of the various nuclides with burn-up. The program also provides for saving and transferring the final fission …

Radiation level measurements of various HRE fuel system components, made in September, 1956, after 27 moths of storage, are compared with the June, 1954, readings before storage. Measurements were made with a standard cutie pie and results tabulated.

An estimate has been obtained of the heat that should be generated in the HRT core in order to hold the system at operating temperature under no-load conditions. This estimate was made by measuring the feed-water rate to the package boiler during an oxygenated water rung. Results are summarized.