The objective of this program is to develop a synthesis gas conversion catalyst with higher selectivity to liquid fuels, while maintaining catalytic activity and stability at least equivalent relative to state-of-the-art precipitated iron catalysts. Hydrocarbon cutoff hypothesis and developmental needs for a ruthenium catalyst with low light ends selectivity were investigated during this quarter. Hydrocarbon product distribution was Anderson-Schulz-Flory up to a carbon number of 250 and cutoff did not occur with a titania-supported catalyst containing ruthenium particles smaller than 20{Angstrom}. It was found that an alumina-supported catalyst with 1% (by weight) ruthenium in the form of 50{Angstrom} to 100{Angstrom} metal particles was initially about half as active (by catalyst volume) and made one quarter of the amount of C{sub 1}{minus}C{sub 4} light end products relative to the Sasol precipitated iron catalyst.

Yucca Mountain, in southern Nevada, is being studied by the Nevada Nuclear Waste Storage Investigations (NNWSI) Project as a potential site for an underground high-level nuclear waste repository. The site is within Miocene volcanic rocks that are 1.5 to 4 km thick and range in age from 12.5 to 14 MY. Several holes have been drilled in Yucca Mountain for geologic and hydrologic studies. Drill hole USW G-4, the most recently cored hole within the potential repository block, was chosen for detailed study of fracture-filling minerals because it is closest to the planned NNWSI exploratory shaft. Drill hole USW G-4 was drilled to 914.7 m (3001 ft) and continuously cored from 6.7 m (22 ft) to total depth (TD). The drilling history, lithology of the core, and geophysical logs of the well were published earlier. Because manganese oxides in fractures may act as a natural barrier to radionuclide migration, it is important to determine exactly which manganese minerals are present, in what intervals they occur, and how extensive these fracture coatings are.

The Department of Energy is currently supporting a program that will aid in the development of cross flow filtration technology as applied to combined cycle power generation with coal gasification. The stated overall goal is to gain information on both the operational and economic feasibility of the implementation of cross flow filtration in various gasifier options. Westinghouse has prepared a comprehensive program that will lead directly to these program goals in an efficient manner.

This report provides the reaction rate measurements and analyses and the basic data for reaction rate measurements for ZPPR-13C in: The high [sup 240]Pu zone of ZPPR-13C; The high-heavy-metal-volume- fraction zone;The pin zone; The [sup 235]U fuel zone; and the enriched uranium zone. In-cell reaction rate measurements and cell factors for the zone studies in ZPPR Assembly 13C are provided.

Accomplishments to date are described for the four projects which make up this investigation. The project titles are: (1) photochemistry of phosphine as studied by FTIR spectroscopy; (2) photolytic studies with radioactive tracers; (3) heterogeneous atmospheric reactions; and (4) reactions of tritium, {sup 38}Cl and {sup 18}F from nuclear recoil. Details of the study and results are presented for the first two projects.

This project deals with the seasonal snow on Alaska`s Arctic Slope. It is concentrated on snow of the R{sub 4}D project area. However, an important aspect of this study is to relate the snow cover of this area with the rest of the Arctic Slope. The goals include determination of the amount of precipitation which comes as snow, the wind transport of this snow and its depositional pattern as influenced by drifting, the physical properties of the snow, the physical processes which operate in it, the proportions of it which go into evaporation, infiltration and runoff, and the biological role of the snow cover.

This document contains primarily reproductions of slides presented at the 1986 Annual Doe Remedial Action Programs Meeting, Oak Ridge, Tennessee.

Repository-oriented leaching experiments involving Savannah River Laboratory (SRL) 165 type glass under a {gamma}-radiation field (1 = 0.2 x 10{sup 4} R/h) have been performed by the Nevada Nuclear Waste Storage Investigations (NNWSI) project. In this communication, we discuss glass surface analyses obtained by SEM, nuclear resonance profiling, and SIMS together with leachate solution data in relation to a mechanism that couples diffusion, hydrolysis (etching and gelation), and precipitation to qualitatively describe the release of different glass components to the leachant solutions. The release of mobile (e.g., Li) and partly mobile (e.g., B) species is controlled primarily by interdiffusion with water species across the interdiffusion zone. Glass components that are immobile in the interdiffusion zone are released to the solution by etching. For prediction of long-term steady-state concentrations of glass components with low solubility, the relative rates of release from the glass and secondary mineral precipitation must be taken into account.

This paper describes the distribution and chemistry of zeolites in tuffs and in fractures at Yucca Mountain. Samples used in this study were collected from continuously-cored exploratory drill holes. A variety of analytical techniques, including optical petrography, x-ray powder diffraction, electron microanalysis, and x-ray fluorescence, were used to characterize the distribution and chemistry of zeolites in these samples.

A model has been constructed in which a small droplet is exploded by the absorption of energy from a high energy laser beam. The beam flux is so high that it is assumed that a plasma is formed. A single-fluid model of a plasma droplet interacting with laser radiation is used. Selfsimilarity is invoked to reduce the spherically symmetric problem involving hydrodynamics and Maxwell's equations to quadrature. It is shown analytically that the model reproduces in qualitative manner certain features observed experimentally.

Shock waves amplify pre-existing turbulence. Shock tube and shock wave boundary layer interaction experiments provide qualitative confirmation. However, shock pressure, temperature, and rapid transit complicate direct measurement. Computational simulations supplement the experimental data base and help isolate the mechanisms responsible. Simulations and experiments, particularly under reflected shock wave conditions, significantly influence material mixing. In these pseudospectral Navier-Stokes simulations the shock wave is treated as either a moving (tracked or fitted) domain boundary. The simulations assist development of code mix models. Shock Mach number and pre-existing turbulence intensity initially emerge as key parameters. 20 refs., 8 figs.

Recent developments in high reliability components for linear induction accelerators (LIA) make possible the use of these devices as economical power drives for very high gradient linear colliders. A particularly attractive realization of this ''two-beam accelerator'' approach is to configure the LIA as a monolithic relativistic klystron operating at 10 to 12 GHz with induction cells providing periodic reacceleration of the high current beam. Based upon a recent engineering design of a state-of-the-art, 10- to 20-MeV LIA at Lawrence Livermore National Laboratory, this paper presents an algorithm for scaling the cost of the relativistic klystron to the parameter regime of interest for the next generation high energy physics machines. The algorithm allows optimization of the collider luminosity with respect to cost by varying the characteristics (pulse length, drive current, repetition rate, etc.) of the klystron. It also allows us to explore cost sensitivities as a guide to research strategies for developing advanced accelerator technologies.

This paper discusses calculations related to hydraulics in a loss of coolant reactor accident. Earlier calculations ignored the effect of emergency coolant injection. Present results show that if the ECS flow is considered, reactor coolant flow is maintained for much longer periods. A computer program used to carry out the calculations is included in this report. (JDH)

This paper reviews the status of the LLNL Free Electron Laser Program. Rather than using the output of an rf linac, the electron pulse from an induction linac enters the wiggler magnet without being bunched into small packets. The laser beam makes a single pass through the FEL amplifier. Wavelengths from several millimeters to less than 10/sup -6/m can be amplified. (JDH)

The paper discusses geothermal resources, what it is, where it is, and how to extract energy from it. The materials research activities at Brookhaven National Laboratory related to geothermal energy extraction are discussed. These include high-temperature, light-weight polymer cements, elastomers, biochemical waste processing techniques, and non-metallic heat exchanger tubing. The economics of geothermal energy is also discussed. (ACR)

This report discusses the progress made on laser particle acceleration. First a brief discussion of the collaboration with the University of California at Santa Barbara to examine the technical trade-offs involved in the choice of an inverse Cerenkov (IC) demonstration experiment. The goals of the IC demonstration experiment are to show the applicability of the IC mechanism to electron beam focusing and acceleration. The second part of this report covers glancing incidence measurements of mirrors. The work being performed centers around the issue of dielectric overcoats on metal mirrors. In any type of laser particle accelerator careful consideration of the timing, phasing, and alignment between laser and particle beams must be incorporated in a complete system study. Analysis of these problems has been initiated and a survey of preliminary results are covered in the last part of this report. During this year, Spectra Technology Inc. (STI) has collaborated with Prof. Jorge Fontana, of the University of California, Santa Barbara (UCSB), to examine the technical trade-offs involved in the choice of an inverse Cerenkov (IC) demonstration experiment. Prof. Fontana`s responsibilities have been to address the rationale and requirements for the demonstration experiment, including an evaluation and selection of the most attractive …

Laboratory results of a comprehensive, regulatory performance test program, utilizing an extruded bitumen and a surrogate, sodium nitrate-based waste, have been compiled at the Oak Ridge National Laboratory (ORNL). Using a 53 millimeter, Werner and Pfleiderer extruder, operated by personnel of WasteChem Corporation of Paramus, New Jersey, laboratory-scale, molded samples of type three, air blown bitumen were prepared for laboratory performance testing. A surrogate, low-level, mixed liquid waste, formulated to represent an actual on-site waste at ORNL, containing about 30 wt % sodium nitrate, in addition to eight heavy metals, cold cesium and strontium was utilized. Samples tested contained three levels of waste loading: that is, forty, fifty and sixty wt % salt. Performance test results include the ninety day ANS 16.1 leach test, with leach indices reported for all cations and anions, in addition to the EP Toxicity test, at all levels of waste loading. Additionally, test results presented also include the unconfined compressive strength and surface morphology utilizing scanning electron microscopy. Data presented include correlations between waste form loading and test results, in addition to their relationship to regulatory performance requirements.

We present predictions for the rapidity and transverse momentum distributions for inclusive production of bottom quarks at SSC energies, pp ..-->.. bX. Our computations are based on the simplest, lowest-order QCD mechanisms. To estimate uncertainties, we use three different choices for structure functions, G(x,Q), as well as different choices for the evolution scale Q.

Assembly power limits are prescribed for each reactor charge so that the Emergency Cooling System (ECS) will prevent core damage from exceeding specified damage limits during a postulated loss-of-coolant (LOCA) or loss-of-pumping (LOPA) accident. Generic assembly power limits which include a 10% uncertainty factor have been determined for the Mark 16B-31 charge. However, future power limits will not be based on the values, because a new damage model is being developed. These limits can be determined at present if the minimum assembly flows during a LOCA are known.

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This research concerns the strong resistance, or even immunity, against a specific virus that is exhibited by one or a few lines of a plant species, in contrast to the general susceptibility of most lines of that species. The contrast between the reactions to virus inoculation of different lines of one species implies that a single gene or a very few genes may mediate the resistance or immunity. The prospects for isolating, studying and transferring such a gene should be good for a system with these characteristics. Seedlings of a line Arlington of the cowpea (Vigna unguiculata) fail to support the replication of cowpea mosaic virus strain SB (CPMV-SB). Genetic crosses of Arlington cowpea to the systemic host Blackeye 5 cowpea show that the immunity is inherited as a simple dominant gene. In contrast to the seedlings, the protoplasts of the Arlington cowpea support CPMV-SB replication, but only to a very low level compared to protoplasts of Blackeye 5 cowpeas. From evidence reported earlier we concluded that Arlington cowpea protoplasts restrict the production of CPMV-SB proteins. We postulated, and obtained evidence for, a proteinase inhibitor that is specific for a CPMV-SB proteinase. This proteinase inhibitor is our prime candidate for …

This research concerns the strong resistance, or even immunity, against a specific virus that is exhibited by one or a few lines of a plant species, in contrast to the general susceptibility of most lines of that species. The contrast between the reactions to virus inoculation of different lines of one species implies that a single gene or a very few genes may mediate the resistance or immunity. The prospects for isolating, studying and transferring such a gene should be good for a system with these characteristics. Seedlings of a line Arlington of the cowpea (Vigna unguiculata) fail to support the replication of cowpea mosaic virus strain SB (CPMV-SB). Genetic crosses of Arlington cowpea to the systemic host Blackeye 5 cowpea show that the immunity is inherited as a simple dominant gene. In contrast to the seedlings, the protoplasts of the Arlington cowpea support CPMV-SB replication, but only to a very low level compared to protoplasts of Blackeye 5 cowpeas. From evidence reported earlier we concluded that Arlington cowpea protoplasts restrict the production of CPMV-SB proteins. We postulated, and obtained evidence for, a proteinase inhibitor that is specific for a CPMV-SB proteinase. This proteinase inhibitor is our prime candidate for …

The purpose of this work is to find the stresses and deflections in the major structural components of a proposed inner hadronic (IH) module. The module uses a small diameter (nominally 3 inch i.d.) inner tube with 1/8 in wall thickness which supports 38 tons of calorimetric instrumentation both when the module is lifted by one endplate, as required for installation into the EC cryostat, and when the module is in its operational orientation. In addition to this loading, the assembly procedure includes an axial preloading which will produce a force equivalent to a uniform pressure of 20 psi on the module endplates. It is important to understand the module stresses under these loads. This work is primarily to establish the feasibility of the proposed design, and does not consider weld design, tolerances, and other important design details.

We study the response of a turbulent boundary layer to an outer-flow disturbance in the form of a small-amplitude wave travelling along the bottom of a smooth channel. In a previous paper we proposed a model for the viscous attenuation of a wave propagating along the interface between two superposed fluids inside a laminar boundary layer attached to the bottom wall. We obtained precise estimates on the amount of attenuation suffered by the oscillatory component of the motion as a result of viscous dissipation. This was accomplished by means of a representation of the solution as the asymptotic sum of a Blasius boundary layer profile and a modified Stokes layer profile. The present paper contains a similar asymptotic decomposition of the solution of the appropriate turbulent Prandtl equations when the outer flow is a small-amplitude travelling wave, and so it may be considered an extension of our previous work to the more realistic case of turbulent flow. 4 refs.