The stability of fluorothene (polytrifluorochloroethylene, Kel-F) to gamma radiation has been investigated to estimate the probable life expectancy of fluorothene equipment exposed to Purex process solutions. Samples of fluorothene were exposed to total gamma radiation dosages up to 10 degree R. The results of these tests substantiate the findings reported by Sisman and Bopp in their compilation of data on the affects of radiation on plastics.

Fractional absorption of gamma photons from a source by uranium or plutonium in solution is measured to determine concentration of these elements.

Thesis discussing the relative yield of neutral pions from elements in a reaction "as a function of the quantum-limit energy (the maximum energy of the quanta in the bremsstrahlung beam) of the Berkeley synchrotron." Interpretation of the results leads to values for the mean free path for absorption of the neutral pions in nuclear matter.

The following report discusses the data of the Z-field pick-up loop, an effective diagnostic tool introduced to help experiments with the linear pinch.

Calculated data and graphs describing the effects of batch thermal-neutron irradiations on the buildup of fission products in natural uranium, enriched uranium, and thorium are presented together with empirical equations and plots correlating total fission product activities and/or decontamination factors. Fluxes of 1012-1015 are considered.

Activity and ionic impurity specifications are presented for Thorex thorium nitrate products. Two sets of specifications are given, one set for direct handling during refabrication of production reactor thorium metal slugs and the second for refabrication of future power reactor thorium metal elements by semi-remote technics. Consideration was given to the health hazard problems associated with each process step between the Thorex process and final refabricated source material in order to arrive at these specifications.

The determination of various parameters such as thermal utilization, resonance escape probability, control rod calibrations and etc. is often accomplished by the measurement of the pile period due to some given perturbation. With the present thoughts being directed towards plutonium fueled reactors, it was felt worthwhile to discuss a few of the basic differences in pile neutron behavior due to the smaller fraction of delayed neutrons per fission of Pu239 and the larger fraction of delayed neutrons per fast fission of U238 than occurs from fission of U235 alone.

Calculations are presented regarding the effect of delayed neutrons in reactors fueled with mixtures of Pu²³⁹ and U²³⁵. Results are plotted to illustrate the change in thermal flux as a function of time for various positive or negative step changes in reactivity.

A preliminary report has shown the potential importance of organic reactor coolants to Hanford technology. The salient points are complete avoidance of corrosion problems and accomplishment of DPR performance with low pressure technique. The recommendation of the report that loop tests be made at Hanford is to be acted upon by Recirculation Technology Unit as soon as organic coolant material is received. To insure starting this experimental work fully abreast of the information available, a trip to sites working with organic coolants was made. Specifically, data were sought on practical details of design for handling organic coolants, heat transfer and fouling characteristics, corrosion of materials, and hazards of handling organics.

There is a continuing high interest in the development of organic coolant technology for application to future Hanford reactors. In addition to the HAPO organic program, two other programs are being sponsored by the Atomic Energy Commission. These include the Naval Reactor program, aimed at a reactor for ship propulsion, and the Civilian Power Reactor program. Because of the similarity of the technical efforts in the three programs, an attempt is being made to establish effective liaison among the programs. To this end, a visit was made to several sites actively engaged in organic development work. These sites and their primary functions are detailed in this report.

A monthly report summarizing work perform by Babcock & Wilcox personnel for the U.S. Atomic Energy Commission. Preliminary design studies for nuclear reactor development and its components were reported.

This is the first quarterly report which summarizes the project work on the Liquid Metal Fuel Reactor Experiment. As the initial contract was not signed until November, 1956, progress within this reporting period has been limited to establishing objectives, determining what research and development will be required, and selecting preliminary design parameters.

A method of determining enclosure pressure in the event of a reactor rupture is presented and a sample calculation is shown. This method was used in calculating the design pressure of the Dresden Nuclear Power Station enclosure.

From abstract: Absolute cross sections for the production of charged secondary particles is the bombardments of aluminum, nickel, silver, and gold by 332-Mev protons, 187-deuterons, and 380-Mev alpha particles have been determined.

A fifth in-pile loop experiment, L-4-8, was completed. The loop operated in-pile for a total of 1637 hr, during which time the LITR energy output was 4377 Mwhr. The average fission power in the loop based o cesium analyses was 622 w when the LITR was at full power (3 Mw). Based on oxygen data, the generalized corrosion rate for the first 300 hr was 4.0 mpy; the rate for the remaining 1357 hr was 0.7 mpy. The nickel data gave parallel results. The corrosion of the type 347 stainless steel, Zircaloy-2, and Ti-55AX [unintelligible] exposed in the core and in in-line holders was generally consistent with that observed in previous in-pile loop experiments. Some differences with steel were attributed to the fact that this was the first loop containing steel specimens operated with 0.04 m H2SO4 present in the uranyl sulfate charge solution (0.17 m UO2SO4, 0.03 m CuSO4). Stress specimens, made from the alloys Zircaloy-2, type 17-4 PH stainless steel, and Ti-C-130-AM, were exposed in care, in-line, and pressurizer locations. Microscopic examination and average weight loss gave no indication of effects attributable to the stressed condition of the specimens.

Abstract: "The elastic double scattering of deuterons by complex nuclei has been investigated experimentally. Measurements were made on carbon, aluminum, and copper at around 157 Mev; on lithium, beryllium, and carbon at around 125 Mev; and on carbon and aluminum at 94 Mev. The expected tensor components of the deuteron polarization have not been observed. Measurements have been made of the differential cross section and vector-type polarization as a function of angle for the scattering of deuterons from the above elements, at the above energies. The observed polarizations were larger than would be expected on the basis of the individual nucleon-nucleus interactions. In a second experiment we measured the 169-Mev proton-proton polarization at 10, 15, 22.5, 30, and 35 in the laboratory system. The results indicate that partial waves up to and including L = 3 are important at this energy."

This technical report reports progress in the following areas: (1) Effect of scaling time; (2) Influence of specimen shape; (3) Effect of pretreatment; (4) Possible mechanism of growth; and (5) Future work.

The use of a reactor charged with silver nitrate coated packing for removal of radio-iodine from the waste gases of Hanford chemical processing plants has been successful in removing approximately 99.5 percent of this activity. Studies by the Radiological Sciences Department indicated the desirability of further reducing the amount of radio-iodine released to the atmosphere. Therefore, this study was undertaken with the objectives of better understanding the inherent limitations to iodine removal by reaction with silver nitrate, and improving the efficiency of removal of iodine.

Abstract: "The quantities of interest in a confined plasma include the electric and magnetic fields, current density, diffusion velocity, temperature, pressure, and particle density. Equations governing the distribution of these seven variables are given in this report and special cases of a one-dimensional steady-state plasma are examined in detail. The solutions are given in graphical form."

Abstract: "A process for the extraction and depoisoning of uranium in strong phosphoric acid solution with tributyl phostphate (TBP) is described. The formation of a complex between uranyl and phosphate ions necessities the use of a salting agent which is capable of destroying this complex and releasing the uranyl ion into an organic extractable species. Of various salting agents tried, ferric nitrate was the most successful. It not only provides nitrate ion for the formation of uranyl nitrate but also forms a very stable ferric-phosphate complex, thus completely tying up the phosphate ion when added in equi-molar quantities. Stripping of the enriched solvent is accomplished with phosphoric acid."

From abstract: "Sample holders and monitoring equipment were designed and fabricated for use in the irradiation of experimental shapes of fuel and target materials in the beryllium reflector of the Materials Testing Reactor. The samples were held in aluminum cases designed to replace certain beryllium blocks of the reflector. Sample holders of alternate designs were made to permit irradiation of samples in the reflector at locations where the shape or position of the reflector blocks would not permit the use of the original design."

Summary: By controlling certain elements within a vacuum chamber from an external station, a charged particle experiment is performed without opening the chamber, thereby saving considerable time and labor. By pre-programming the experimental sequence on the external controls, the experiment can be performed from beginning to end with a minimum of operator attention. The data collected can be read out automatically on a punched paper tape for subsequent transmission to a digital computer.

An analytical procedure for 0.04 to 1.6 percent ruthenium in plutonium metal was developed. Determination of ruthenium in metallic plutonium was investigated as part of a program for securing analytical procedures for various metals in plutonium. However, results of the investigation are given in this report with emphasis on the determination of ruthenium in plutonium chloride solutions. Specifically, this report is primarily concerned with the separation and determination of 40 to 400 micrograms of ruthenium in a hydrochloric acid solution of 25 to 100 milligrams of plutonium.

In order that fairly accurate thermal stress calculations can be made on the ART, it is necessary to have a reasonable picture of the temperature distribution in the reactor. To get the temperature distributions, and to determine cooling requirements in various parts of the reactor, one must know the heat deposition rates due to alpha particles, beta rays, gamma rays, and neutrons in all parts of the reactor. The present report contains only the basic physical data necessary to determine the heat deposition rates due to gamma rays. Neutron fluxes in the core and reflector regions of the ART are to be obtained from two-dimensional multigroup calculations (performed by the Curtiss-Wright Corporation). These fluxes, in conjunction with the neutron absorption cross sections, determine the neutron capture and inelastic scattering rates in the core and in the reflector. The data in this report permit the calculation of the number of gamma rays originating at various energies at every point in the core and reflector.