Quarterly report discussing fuel cell research and development work at Argonne National Laboratory (ANL). This report describes studies directed toward seeking alternative cathode materials to NiO for molten carbonate fuel cells.

From Introduction: "This bulletin updates and summarizes research recovering tungsten from Searles Lake brines, the largest known single domestic tungsten deposit."

Report on studies of advanced batteries, aqueous batteries, advanced fuel cells, coal utilization, methodologies for recovery of energy from municipal waste, solid and liquid desiccants, nuclear technology related to waste management, and physical chemistry of selected materials in environments simulating those of fission, fusion, and other energy systems.

Report on research in carcinogenesis, human radiobiology, low-level radiation, molecular biology, and toxicology.

Report of the activities of the physics division at Argonne including the successful completion of Argonne Tandem-Linac Accelerator System.

Annual report of the Argonne National Laboratory Radiological and Environmental Research Division regarding activities related to molecular physics and chemistry.

Current status of epidemiological studies of the late effects of internal radium in humans, and mechanistic investigations of those effects.

The Nevada Nuclear Waste Storage Investigations (NNWSI) project is investigating the volcanic tuff beds of Yucca Mountain, Nevada, as a potential location for a high-level radioactive waste repository. This report describes a test method (Phase II) that has been developed to measure the release of radionuclides from the waste package under simulated repository conditions, and provides information on materials interactions that may occur in the repository. The results of 13 weeks of testing using the method are presented, and an analog test is described that investigates the relationship between the test method and expected repository conditions.

This document contains the Proceedings of the Sixth NBS/NCSBCS Joint Conference on Research and Innovation in the Building Regulatory Process, held on September 11, 1984, in Denver, CO. This conference addressed streamlined administrative procedures, computers in construction, and fire safety technology. These Proceedings contain the 10 papers selected for presentation at the conference.

Report describing an effort to determine the state-of-the-art in tunnel and shaft construction technology, as part of the overall feasibility study to construct a facility for the ICBM Deep Basing Deployment Concept.

Section I introduces the material contained in the rest of the report. Section II presents the origin and characteristics of humic materials as we understand them today and outlines the methods that have been used to separate and analyze these substances. Section III focuses on the general problem of metal-organic interactions and treats some of the factors that are important in chelating and complexing of metal ions by humic substances. Section IV deals specifically with the complexing of radionuclides by organic substances, treated from the standpoint of both empirical and experimental studies.

Measurements are described for determining average values of fission rates in uranium-235, uranium-238 and plutonium-239 and capture rates in uranium-238 for heterogeneous cells used to construct fast critical assemblies. The measurements are based on irradiations of foils of uranium-238, uranium-235 and plutonium-239 with counting of fission and capture products using gamma-ray spectroscopy. Both plate and pin cells are considered. Procedures are described for inferring cell-average reaction rate values from a single foil location based on a cell using a quantity called a cell factor. Cell factors are determined from special measurements in which several foils are irradiated within a cell. Comparisons are presented between cell factors determined by measurements and by Monte Carlo calculations which lend credibility to the measurement procedures.

This report provides a summary of theoretical and experimental studies of actinide spectra in condensed phases. Much of the work was accomplished at Argonne National Laboratory, but references to related investigations by others are included. Spectroscopic studies of the trivlent actinides are emphasized, as is the use of energy level parameters, evaluated from experimental data, to investigate systematic trends in electronic structure and other properties. Some reference is made to correlations with atomic spectra, as well as with spectra of the (II), (IV), and higher valence states.

A data bank of field experiences with heat exchanger tube vibration reveals numerous cases of tube failures at, or near, the baffle. The objective of this study is to provide qualitative impact/fretting wear information for heat exchanger tubes through the performance of a series of tests involving the pertinent parameters: impact force level, between the tube and its support; tube to support plate hole clearance; tube support plate thickness; and tube vibration frequency. The characteristics of impact/fretting wear relative to tube motion pattern, material combination and surrounding fluid were also investigated. The test apparatus consists of a cantilevered tube with a simulated tube support plate at the ''free end''. Tube vibration is induced by an electromagnetic exciter to simulate the flow-induced tube motion occurring in a real heat exchanger at the tube/tube support plate interface. Tests are conducted in air, water, and oil, all at room temperature. Wear rate increases significantly with the magnitude of the impact force between the tube and its support plate; the degree and trend of the wear rates are highly dependent on the mechanical and metallurgical properties of the tube/support material combination; the rate of impact/fretting wear decreases with increasing frequency. An empirical formula is …

This report summarizes the flow-induced vibration of circular cylinders in quiescent fluid, axial flow, and crossflow, and applications of the analytical methods and experimental data in design evaluation of various system components consisting of circular cylinders.

A general theory of fluid-elastic instability for a tube array in crossflow is presented for application to the space shuttle main engine liquid oxygen (SSME LOX) posts. Various techniques to obtain the motion-dependent fluid-force coefficients are discussed and the general instability characteristics are summarized. The theory is also used to evaluate the results of other mathematical models for crossflow-induced instability.

Fluid forces are important in the assessment of vibration of the Space Shuttle Main Engine liquid oxygen posts. This report summarizes the available data on fluid excitation forces acting on tube arrays in turbulent crossflow, and test results for an array of tubes subject to turbulent flow. The fluctuating drag and lift forces are measured as a function of Reynolds number, incoming flow conditions, and tube location in an array.

Abstract: Results of a research program to develop fitness-for-service criteria for assessing the significance of fatigue cracks in offshore structures are presented in five papers. Each paper describes the goals and approaches to a specific task and details the results of the study.

From foreword: "This report represents the most current methodology available for wetland classification and culminates a long-term effort involving many wetland scientists."

From introduction: In this report the following will he discussed: (1) design consideration of the broadband magnetic field sensor, (2) overall design of the magnetic field meter, (3) performance of the meter, (4) calibration and operating procedures, (5) alignment and adjustment procedures, and (6) summary and conclusions.

Abstract: This report identifies experimental and analytical research needed to advance the state-of-the-art and improve safety and economy in the design, fabrication and construction of steel buildings. A five year plan for a coordinated research program is included. Recommendations for research projects dealing with the following topics are presented: total building systems, connections and members, frames, seismic design, load and resistance factor design, fire protection, and design loads. The recommendations were developed at a workshop involving participation by steel industry representatives, design professionals, Federal agency representatives and university researchers.

From Abstract: "This report presents results of Bureau of Mines research, conducted from 1965 to 1983, on separating on and recovering useful materials from the scrapped hulks, using old and new metallurgical techniques combined with standard scrapyard methods."

A set of programs, gathered from major Argonne computer users, was run on the current generation of supercomputers: the CRAY X-MP-4, Fujitsu VP-200, and Hitachi S-810/20. The results show that a single processor of a CRAY X-MP-4 is a consistently strong performer over a wide range of problems. The Fujitsu and Hitachi excel on highly vectorized programs and offer an attractive opportunity to sites with IBM-compatible computers.

This report describes logic programming approaches to two graph theoretical problems relevant to reactor and logic circuit analysis: those of cut-set verification and subsystem detection.