Undergraduate thesis psychoanalyzing the composer Don Carlo Gesualdo. It focuses on the relationship between the composer and mastery of the musical task. The author examines the life and work of Don Carlo Gesualdo, Prince of Venosa, who was commonly referred to as both musician and murderer.

Undergraduate thesis examining the moderating role of religious coping on the associations between romantic attachment and psychological symptoms among 86 heterosexual, married couples with children aged 8-11. Spouses completed a demographic questionnaire, the Brief RCOPE (Pargament et al., 1998), the Experiences in Close Relationships Scale (Brennan et al., 1998), and the Symptom Assessment-45 (Maruish, 1996, 1998). Using the Actor-Partner Interdependence Model (Kenny et al., 2006), multilevel modeling examined both within-person (actor) and dyadic (partner) influences between spouses.

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This thesis is the culminating project for my participation in the OECD NEA International School of Nuclear Law. This paper will begin by providing a historical background to current disarmament and denuclearization treaties. This paper will discuss the current legal framework based on current and historical activities related to denuclearization and nuclear disarmament. Then, it will propose paths forward for the future efforts, and describe the necessary legal considerations. Each treaty or agreement will be examined in respect to its requirements for: 1) limitations and implementation; 2) and verification and monitoring. Then, lessons learned in each of the two areas (limitations and verification) will be used to construct a proposed path forward at the end of this paper.

The research presented and discussed in this dissertation involves the synthesis of transition metal complexes of oxazolinylboranes and cyclopentadienyl-bis(oxazolinyl)borates, and their application in catalytic enantioselective olefin hydroamination and acceptorless alcohol decarbonylation. Neutral oxazolinylboranes are excellent synthetic intermediates for preparing new borate ligands and also developing organometallic complexes. Achiral and optically active bis(oxazolinyl)phenylboranes are synthesized by reaction of 2-lithio-2-oxazolide and 0.50 equiv of dichlorophenylborane. These bis(oxazolinyl)phenylboranes are oligomeric species in solid state resulting from the coordination of an oxazoline to the boron center of another borane monomer. The treatment of chiral bis(oxazolinyl)phenylboranes with sodium cyclopentadienide provide optically active cyclopentadienyl-bis(oxazolinyl)borates H[PhB(C{sub 5}H{sub 5})(Ox{sup R}){sub 2}] [Ox{sup R} = Ox{sup 4S-iPr,Me2}, Ox{sup 4R-iPr,Me2}, Ox{sup 4S-tBu]}. These optically active proligands react with an equivalent of M(NMe{sub 2}){sub 4} (M = Ti, Zr, Hf) to afford corresponding cyclopentadienyl-bis(oxazolinyl)borato group 4 complexes {PhB(C{sub 5}H{sub 4})(Ox{sup R}){sub 2}}M(NMe{sub 2}){sub 2} in high yields. These group 4 compounds catalyze cyclization of aminoalkenes at room temperature or below, providing pyrrolidine, piperidine, and azepane with enantiomeric excesses up to 99%. Our mechanistic investigations suggest a non-insertive mechanism involving concerted C−N/C−H bond formation in the turnover limiting step of the catalytic cycle. Among cyclopentadienyl-bis(oxazolinyl)borato group 4 catalysts, the zirconium complex {PhB(C{sub …

Understanding the structure of baryons in terms of the fundamental interaction of the constituent quarks and gluons is one of the primary challenges in strong interaction physics. This interaction is governed by Quantum Chromodynamics (QCD), which is a theory for understanding the dynamics of strong. QCD displays the asymptotic freedom of hadrons at very short distances and also the confinement of quarks and gluons inside hadrons. However, solutions of this QCD theory in the non-perturbative domain of the interaction are extremely difficult to achieve, mainly because confinement happens on the hadronic scale on which the coupling constant is large and prevents any perturbative approach. Thus leaving us with strategies such as lattice QCD or formulating QCD sum rules to get around this problem. In exclusive hadron production the yN interaction is recognized for being a powerful method for investigating hadrons and the mysteries that still exist within the strong interaction. From reactions with the nucleon, the strong interaction can be investigated through the transition amplitudes to the N and Delta resonances. More specifically, if an electromagnetic interaction is well known then the intermediate resonance states may be evaluated through meson photoproduction. To gain more detailed insight into this interaction, we …

Beam diagnostics is an essential constituent of any accelerator, so that it is named as "organs of sense" or "eyes of the accelerator." Beam diagnostics is a rich field. A great variety of physical effects or physical principles are made use of in this field. Some devices are based on electro-magnetic influence by moving charges, such as faraday cups, beam transformers, pick-ups; Some are related to Coulomb interaction of charged particles with matter, such as scintillators, viewing screens, ionization chambers; Nuclear or elementary particle physics interactions happen in some other devices, like beam loss monitors, polarimeters, luminosity monitors; Some measure photons emitted by moving charges, such as transition radiation, synchrotron radiation monitors and diffraction radiation-which is the topic of the first part of this thesis; Also, some make use of interaction of particles with photons, such as laser wire and Compton polarimeters-which is the second part of my thesis. Diagnostics let us perceive what properties a beam has and how it behaves in a machine, give us guideline for commissioning, controlling the machine and indispensable parameters vital to physics experiments. In the next two decades, the research highlight will be colliders (TESLA, CLIC, JLC) and fourth-generation light sources (TESLA FEL, …

This thesis consists of one major section with two subsections. The first subsection investigates the activity of Arthrobacter globiformis aspartate transcarbamylase's specific activity with increasing concentrations of the enzyme's substrate. Dihydroorotase (DHOase) activity was also measured with increasing concentrations of the substrate dihydroorotate. The second subsection collected data in order to classify the enzyme, resulting in a classification into the category of class A ATCases with bifunctional ATCase-DHOase complexes. The thesis provides evidence to broaden understanding of the ATCase and DHOase enzymes for members of the family that Arthrobacter belongs to.

The primary goal of this study was to analyze the characteristics of current registered sex offenders in Collin County, Texas, as well as to compare age and gender of the victims of these offenders in order to know who sex offenders primarily target in these crimes. The study also sought to discover geographic patterns of where the registered sex offenders reside for the purpose of keeping communities aware. Participants consisted of 175 registered sex offenders (N = 175) in Collin County, Texas, found on Collin County's and the Texas Department of Public Safety's online public registries. The findings demonstrate that there were significant trends among the sex offenders, their victims, location of residence, and housing complications as a result of progressing sex offender laws. Treatment programs and the reintegration of offenders in the community were also addressed. The meaning of the results in this study can aid in the development of safety and prevention strategies, provide an understanding about the utilization of sex offender registries, and can benefit law enforcement to predict the movement of current sex offenders, along with knowing where to find other potential offenders.

Members of Generation Y in the training and development industry will be required to assume leadership roles as Baby Boomers retire, yet little empirical research exists regarding how best to prepare them for leadership. The purpose of this study was to examine differences in leader developmental readiness between generational cohorts in the training industry, specifically Baby Boomers, Generation X, and Generation Y. Leader developmental readiness provided a definition of developmental readiness for leaders using the five constructs (learning goal orientation, developmental efficacy, self-awareness, leader complexity, and metacognitive ability). A volunteer sample was compiled from members of the ASTD National LinkedIN group (n = 636). Results were analyzed using structured means analysis with maximum likelihood (ML) estimation. Generational cohorts demonstrated differences in leader developmental readiness. Baby Boomers indicated statistically and practically higher metacognitive ability and developmental efficacy than Generation Y. Results demonstrated statistically and practically higher leader complexity in Generation Y and both Generation X and Baby Boomers. These results should inform leader development practitioners as they continue to use existing methods in preparing the different generations for leader development interventions while pointing to possible needs to increase the metacognitive ability and developmental efficacy in Generation Y and ensure accurate perception …

The present philosophical literature on philosopher Ludwig Wittgenstein tends to either stagnate by focusing upon issues particular to Wittgenstein's philosophy or expand the boundaries of Wittgenstein's thought to shed light onto other areas of study. One area that has largely been ignored is the realm of environmental philosophy. I prepare the way for a solution to this by first arguing that Wittgenstein's later philosophy of language shows 'proto-ecolinguistic' concerns, sharing much in common with the ecolinguistic thought of both Peter Mühlhäusler and Luisa Maffi. This reading, as well as the work of Mühlhäusler and Maffi, is a starting point for an opposition to a common trend in much of contemporary linguistics of adhering to a linguistic paradigm of universalizing linguistic atomism that gives an impoverished account of language. This impoverished account is argued to have potential environmental and ecological consequences which the universalizing atomistic paradigm is ill-equipped to address.

A Ni/TiC/C metal matrix composite (MMC) has been processed using the laser engineered net shaping (LENS) process from commercially available powders with a Ni-3Ti-20C (atomic %) composition. This processing route produces the in-situ formation of homogeneously distributed eutectic and primary titanium carbide and graphite precipitates throughout the Ni matrix. The composite exhibits promising tribological properties when tested in dry sliding conditions with a low steady state coefficient of friction (CoF) of ~0.1 and lower wear rates in comparison to LENS deposited pure Ni. The as deposited and tribologically worn composite has been characterized using Auger electron spectroscopy, scanning electron microscopy (SEM), X-ray diffraction, high resolution transmission electron microscopy (HRTEM) with energy dispersive spectroscopy (EDS), dual beam focused ion beam SEM (FIB/SEM) serial sectioning and Vickers micro-hardness testing. The evolution of subsurface stress states and precipitate motion during repeated sliding contact has been investigated using finite element analysis (FEA). The results of FIB/SEM serial sectioning, HRTEM, and Auger electron spectroscopy in conjunction with FEA simulations reveal that the improved tribological behavior is due to the in-situ formation of a low interfacial shear strength amorphous carbon tribofilm that is extruded to the surface via refined Ni grain boundaries.

Britain during the Labour government's administration took a major step toward developing Iraq primarily due to the decision of Ernest Bevin, the Foreign Minister, to start a new British policy toward the Iraqi regimes that would increase the British influence in the area. This led to Bevin's strategy of depending on guiding the Iraqi regime to make economic and political reforms that would lead to social justice.

The purpose of this study was to identify factors that predict quality of life (QOL) for aging adults and to examine and compare Baby Boomers', Older Adults' and Younger Adults' responses to the 2010 National Health Interview Survey/QOL Functioning and Disability. Significant findings included several significant values based on the multivariate regression to estimate a model to predict QOL. In particular, being male, four ethnicities other than white, being older than Boomer, age in 10 years, the Functional Difficulty Index, the Functional Limitation Index scores, chronic heart disease, asthma, and arthritis all had significant p values. Adults with chronic heart disease, asthma, or arthritis scored lower on the QOL index, but cancer, stroke, or diabetes were not associated with the QOL index. Two hypotheses had strong support. Lower scores on both the Functional Difficulty Index and the Functional Limitation Index yielded lower QOL scores. Further research recommendations include establishing reliability and validity of the QOL index; running additional regressions for demographics (ethnicity, marital status, etc.) to predict possible combinations of variables predicting QOL or barriers to QOL; and investigating the viability of incorporating the QOL index into an electronic medical record (EMR) dashboard parameter to serve as a screening mechanism …

The focus of the following research was to provide an optimized particle stabilized foam of Laponite and Pluronic L62 in water by understanding (1) the Laponite-Pluronic interactions and properties for improved performance in a particle stabilized foam and (2) the interfacial properties between air and the Laponite-Pluronic complex. These studies were conducted using both bulk and interfacial rheology, XRD, sessile droplet, TGA and UV-vis. Two novel and simple techniques, lamella break point and capillary breakup extensional rheometry, were used to both understand the Laponite Pluronic L62 interaction and determine a different mechanism for foaming properties. Bulk rheological properties identified an optimal Laponite concentration of 2% with Pluronic L62 ranging from 2.5% and 6.5%, due to the ease of flow for the dispersion. The Pluronic L62 was observed to enhance the Laponite bulk rheological properties in solution. Additionally TGA showed a similar trend in thermal resistance to water with both addition of Laponite and Pluronic L62. XRD demonstrated that 0.25% Pluronic intercalated into Laponite from dried 2% Laponite films. XRD demonstrated that the Laponite matrix was saturated at 1% Pluronic L62. UV-vis demonstrated that a monolayer of Pluronic L62 is observed up to 0.65% Pluronic L62 onto Laponite. Interfacial rheology showed …

This dissertation explores how nonconscious thought processing might be affected and activated in ways that influence consumer decision making. To activate nonconscious thought processes, this dissertation relies on priming—the unobtrusive activation of mental representations by stimuli in a social context, which occurs without participants' conscious awareness. Three dimensions of consumer decision making are investigated: purchase intention, product evaluation and arousal. The dissertation is based on the auto-motive model of nonconscious goal pursuit and somatic marker hypothesis. The dissertation is driven by three experiments, which respectively explore crucial areas in priming effects and addresses the following research question: can primes be shaped or controlled by marketers? Specifically, the dissertation examines whether shopping behavior can be primed. Second, the dissertation also examines how facial primes displaying basic emotions (happiness, anger, contempt, disgust, fear, sadness, and surprise) can prime emotion and arousal. Finally the dissertation examines the effect of the interaction of the buying prime with the primes of faces displaying basic emotions on the dependent variables of purchase intention, product evaluation, emotion, and arousal. Results from three experimental studies show that shopping behavior can be primed, and primed participants will exhibit higher product evaluation than those exposed to a control prime. Second …

Previous findings on the relationship between self-esteem and psychological outcomes are inconsistent. Therefore it appears that self-esteem, while related to crucial variables, does not provide a clear, direct, and comprehensive prediction of psychological symptoms. Thus, it was hypothesized that the relationship between self-esteem and symptomatology would be moderated by broader measures of how one interacts with emotional and cognitive stimuli.The purpose of this study was to examine the influence of self-esteem, psychological flexibility, and cognitive flexibility on psychological symptomatology. A sample of 82 undergraduate students at the University of North Texas completed self-report questionnaires measuring low self-esteem, psychological flexibility, measured inversely as inflexibility, cognitive flexibility, and psychological symptoms. Results of the study suggest that self-esteem (?= -0.59, p < 0.001) and flexibility (both psychological (?= 0.36, p = 0.001) and cognitive (?= 0.21, p < 0.05) are significant predictors of psychological symptoms. In other words, self-esteem is positively correlated with psychological symptoms, while psychological and cognitive flexibility are negatively correlated with psychological symptoms. Neither form of flexibility moderated the relationship between self-esteem and psychological symptoms in this sample. The findings of the current study are discussed as well as suggestions for further research related to self-esteem, psychological and cognitive flexibility, …

When the tubist is first introduced to the bass tuba, Mahler's songs can be used as effective solo material. Through transcription, practice, and performance of art songs, novice bass tubists focus primarily on fundamental musical components such as tone quality, intonation, breathing, and musicianship. By identifying deficiencies in the current solo repertoire as related to the early stages of development on the bass tuba, I intend to address the need for more solo works through the transcription and performance of Mahler's Lieder und Gesänge aus der Jugendzeit.

This study offers a partial reduplication of a 2006 study by Williams, which focused primarily on the analysis of the quality of translation produced by online software, namely Yahoo!® Babelfish, Freetranslation.com, and Google Translate. Since the data for the study by Williams were collected in 2004 and the data for present study in 2012, this gives a lapse of eight years for a diachronic analysis of the differences in quality of the translations provided by these online services. At the time of the 2006 study by Williams, all three services used a rule-based translation system, but, in October 2007, however, Google Translate switched to a system that is entirely statistical in nature. Thus, the present study is also able to examine the differences in quality between contemporary statistical and rule-based approaches to machine translation.

The focus of this research study is glycemic control in the presence of multiple morbidities and polypharmacy in homebound individuals with Type 2 diabetes aged 65 years and older. The research method is a quantitative retrospective cohort study of discharged patients of a nonprofit community-based home health agency from January 1, 2010, to December 31, 2011, using OASIS data. Glycemic control is assessed using the hA1C laboratory test following the recommendation of the American Diabetes Association. The study documents a moderate significant association between glycemic control, polypharmacy and comorbid conditions, indicating that homebound individuals with Type 2 diabetes aged 65 years and older are less likely to have optimal glycemic control in the presence of multiple morbidities and polypharmacy. There continues to be a need for scientific research in this population cohort; and the dose-response association between antidiabetic therapy interventions designed to lower blood glucose levels in the presence of chronic disease and polypharmacy.

This study investigates the effects of postmodern factors on the relationship between maternal distress and children's delinquency. It seeks to understand the factors associated with distress levels of mothers whose children exhibit delinquency in order to potentially decrease the cost associated with mental health problems especially in mothers. Another goal of this study is to contribute to the sociological analysis of mental health problems which seem to be the reserved domain of the discipline of psychology and related subfields. The data came from the third wave of the 3-city study with N = 1835. The ages of the children range from 5 to 18 years old. The analysis of the data using regression analysis suggests children's delinquency significantly affects maternal distress in mothers. The study also indicates postmodernity factors did not moderate the association between maternal distress and children's delinquency. However, postmodern factors have significant, separate, and direct effects on maternal distress. For example, employment and religion have positive influences on maternal distress. The research points toward weakness in the postmodern perspective. It also underlines the importance of a sociological approach to the assessment and treatment of distress problems among mothers with low-income. Agencies working with low-income families should integrate …

This study analyzed instructional achievement and intrinsic motivation among 21st century secondary students utilizing a video lecture incorporating both student reaction cutaway images and immediate content interaction within the lecture. Respondents (n = 155) were from multiple classes and grade levels at a suburban Texas high school. Four groups of students viewed the identical lecture with differing video and content interaction treatments. Students responded to a pretest/posttest survey to assess academic achievement in addition to an intrinsic motivation instrument to assess student interest. Group one (the control group) viewed the 12 minute lecture without enhancement. A second group viewed the identical lecture with student reaction shots inserted in the video. Another group viewed the lecture with content question intervention inserted into the video. The final group saw the lecture with the student reaction shots and content question intervention combined in the video. A repeated measures multivariate analysis of variance (MANOVA) was used to compare results from a 14 item pretest/posttest. Combined, the groups showed no significance (p = .069) indicating no associations were identified by the experiment. Although no association was identified, this may be a reflection of the generic nature of the video lecture and the lack of association …

The chakra system consists of seven energetic vortexes ascending up the spine that connect to every aspect of human existence. These vortexes become blocked and unblocked through the course of a life, these openings and closings have physiological and mental repercussions. Knowledge of these physical and mental manifestations, indicate where the chakra practitioner is in need, the practitioner can then manipulate their mind and body to create a desired outcome. These manipulations are based upon physical exercises and associative meditations for the purpose of expanding the human experience. As a poem can be thought of as the articulation of the human experience, and the chakra system can be thought of as a means to understand and enhance that experience, it is interesting and worthwhile leap to explore the how the chakras can develop and refresh the way we read and write poetry. This critical preface closely reads seven poems, one through each chakra, finding what the chakras unveil. Here, each chakra is considered for its dynamic creative capabilities and for its beneficial potentiality in the reading and writing process, finding each chakra provides tools: idea generators with the potential to free the poet from usual patterns of creativity while broadening …

This thesis describes development of low cost indoor air quality (IAQ) monitoring system for research. It describes data collection of various parameters concentration present in indoor air and sends data back to host PC for further processing. Thesis gives detailed information about hardware and software implementation of IAQ monitoring system. Also discussed are building wireless ZigBee network, creating user friendly graphical user interface (GUI) and analysis of obtained results in comparison with professional benchmark system to check system reliability. Throughputs obtained are efficient enough to use system as a reliable IAQ monitor.