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Re-examination of the N2O+O reaction (open access)

Re-examination of the N2O+O reaction

This article is about how the reaction of N20 with O is a key step in consumption of nitrous oxide in thermal processes. In the present work ,the authors re-examined a wide range of experiments relevant for the N2O+O reaction through kinetic modeling, paying attention to the impact of artifacts such as impurities and surface reactions.
Date: July 27, 2023
Creator: Glarborg, Peter; Allingham, Johanne S.; Skov, Alexander B.; Hashemi, Hamid & Marshall, Paul
System: The UNT Digital Library
Reactions of hydrazine with the amidogen radical and atomic hydrogen (open access)

Reactions of hydrazine with the amidogen radical and atomic hydrogen

Article describes how the rate coefficient k1 for NH2 + N2H4 was measured to be (5.4 ± 0.4) × 10−14 cm3 molecule−1 s−1 at 296 K. The authors then describe how a combination of experiment and theory leads to a recommended rate coefficient for hydrogen abstraction of k1 = 6.3 × 10−23 T3.44 exp(+289 K/T) cm3 molecule−1 s−1.
Date: June 7, 2023
Creator: Gao, Yide; Alecu, I. M.; Hashemi, Hamid; Glarborg, Peter & Marshall, Paul
System: The UNT Digital Library
Probing High-Temperature Amine Chemistry: Is the Reaction NH3 + NH2 ⇄ N2H3 + H2 Important? (open access)

Probing High-Temperature Amine Chemistry: Is the Reaction NH3 + NH2 ⇄ N2H3 + H2 Important?

Article describes how the reaction NH3 + NH2 ⇄ N2H3 + H2 (R1) has been identified as a key step to explain experimental results for pyrolysis and oxidation of ammonia. In the present work, the reaction was studied by ab initio theory and by reinterpretation of experimental data.
Date: March 14, 2023
Creator: Marshall, Paul & Glarborg, Peter
System: The UNT Digital Library
Re-evaluation of rate constants for the reaction N2H4 (+ M) ⇄ NH2 + NH2 (+ M) (open access)

Re-evaluation of rate constants for the reaction N2H4 (+ M) ⇄ NH2 + NH2 (+ M)

Article describes how rate constants for the dissociation/recombination reaction N2H4 (+ M) ⇄ NH2 + NH2 (+ M) are determined by a combination of quantum-chemical calculations and statistical unimolecular rate theory. Implications of the present re-evaluated rate constants for the modeling of high temperature ammonia oxidation kinetics are discussed, showing an only small influence of their precise values on the overall properties of the process.
Date: October 4, 2023
Creator: Cobos, Carlos J.; Glarborg, Peter; Marshall, Paul & Troe, Jürgen
System: The UNT Digital Library
Measurement of the Intramolecular Hydrogen-Shift Rate Coefficient for the CH3SCH2OO Radical Between 314 and 433 K (open access)

Measurement of the Intramolecular Hydrogen-Shift Rate Coefficient for the CH3SCH2OO Radical Between 314 and 433 K

Article describes how the intramolecular hydrogen-shift rate coefficient of the CH3SCH2O2 (methylthiomethylperoxy, MSP) radical, a product formed in the oxidation of dimethyl sulfide (DMS), was measured using a pulsed laser photolysis flow tube reactor coupled to a high-resolution time-of-flight chemical ionization mass spectrometer that measured the formation of the DMS degradation end product HOOCH2SCHO. Measurements performed over the temperature range of 314–433 K yielded a hydrogen-shift rate coefficient of k1(T) = (2.39 ± 0.7) × 109 exp(−(7278 ± 99)/T) s–1 Arrhenius expression and a value extrapolated to 298 K of 0.06 s–1.
Date: March 2, 2023
Creator: Assaf, Emmanuel; Finewax, Zachary; Marshall, Paul; Veres, Patrick R.; Neuman, Andrew & Burkholder, James B. (James Bart), 1954-
System: The UNT Digital Library
Dublin Core Metadata Created by Kuwaiti Students: Exploration of Quality in Context (open access)

Dublin Core Metadata Created by Kuwaiti Students: Exploration of Quality in Context

Conference paper reporting results of the examination of metadata records for Arabic-language eBooks to support ongoing metadata education in the Arabian Gulf region. The results are presented in-context, after introducing the metadata teaching practices at this undergraduate program, and the major Dublin Core skill-building assignment. This is a manuscript version of a published work. Citation information is available for the published version of the work.
Date: March 10, 2023
Creator: Aljalahmah, Saleh & Zavalina, Oksana
System: The UNT Digital Library
Exploration of Accuracy, Completeness and Consistency in Metadata for Physical Objects in Museum Collections (open access)

Exploration of Accuracy, Completeness and Consistency in Metadata for Physical Objects in Museum Collections

Conference paper for an exploratory study that examined student-created metadata for physical non-text resources. The authors applied in-depth qualitative and quantitative content analysis to the Dublin Core (DCTERMS) metadata created by the graduate students in two sections of an introductory digital library metadata course. Finding of comparative analysis for the asynchronous course section and the section with synchronous class meetings are also presented. Implications are discussed, along with future directions for research. This is a manuscript version of a published work. Citation information is available for the published version of the
Date: March 10, 2023
Creator: Zavalin, Vyacheslav & Zavalina, Oksana
System: The UNT Digital Library
Empirically-Based Best Estimates of After-Death Communication (ADC) Phenomena: A Systematic Review of Research (open access)

Empirically-Based Best Estimates of After-Death Communication (ADC) Phenomena: A Systematic Review of Research

Article discussing and ranking 35 studies on after-death communication (ADC) related phenomena.
Date: Autumn 2022
Creator: Streit-Horn, Jenny; Holden, Janice Miner & Smith, Julia E.
System: The UNT Digital Library
Why Near-Death Experiences (NDEs) Matter to Psychology: An Exploration of Aotearoa New Zealand Psychologists' Knowledge off NDEs and Implications for Professional Practice (open access)

Why Near-Death Experiences (NDEs) Matter to Psychology: An Exploration of Aotearoa New Zealand Psychologists' Knowledge off NDEs and Implications for Professional Practice

Study on how NDEs are perceived and understood within psychology.
Date: Autumn 2022
Creator: Tassell-Matamua, Natasha A.; Lindsay, Nicole & Winterbottom, Johnathon P.
System: The UNT Digital Library
Differential effects of soil conservation practices on arthropods and crop yields (open access)

Differential effects of soil conservation practices on arthropods and crop yields

Article describes how many agricultural management tactics, such as reduced tillage, aim to promote biodiversity and ecosystem services. Authors assessed how soil tillage and landscape context affected arthropod biodiversity and crop yield in canola crop fields.
Date: October 31, 2023
Creator: Lichtenberg, Elinor M.; Milosavljević, Ivan; Campbell, Alistair J. & Crowder, David W.
System: The UNT Digital Library
Detergent-Based Decellularization for Anisotropic Cardiac-Specific Extracellular Matrix Scaffold Generation (open access)

Detergent-Based Decellularization for Anisotropic Cardiac-Specific Extracellular Matrix Scaffold Generation

Article describes how cell-derived extracellular matrix has become increasingly popular in tissue engineering applications due to its ability to provide tailored signals for desirable cellular responses. The objective of this study was to assess the efficacy of two detergent-based decellularization methods: a combination of ethylenediaminetetraacetic acid and sodium dodecyl sulfate and a combination of sodium deoxycholate and deoxyribonuclease.
Date: November 17, 2023
Creator: Chen, Te-An; Sharma, Dhavan; Jia, Wenkai; Ha, Donggi; Man, Kun; Zhang, Jianhua et al.
System: The UNT Digital Library
Pareto Optimization of CNN Models via Hardware-Aware Neural Architecture Search for Drainage Crossing Classification on Resource-Limited Devices (open access)

Pareto Optimization of CNN Models via Hardware-Aware Neural Architecture Search for Drainage Crossing Classification on Resource-Limited Devices

Article describes how embedded devices, constrained by limited memory and processors, require deep learning models to be tailored to their specifications. This research explores customized model architectures for classifying drainage crossing images.
Date: November 12, 2023
Creator: Li, Yuke; Baik, Jiwon; Rahman, Md Marufi; Anagnostopoulos, Iraklis; Li, Ruopu & Shu, Tong
System: The UNT Digital Library
Dry blood spot samples to monitor immune-associated mRNA expression in intervention studies: Impact of Baker's yeast beta glucan (open access)

Dry blood spot samples to monitor immune-associated mRNA expression in intervention studies: Impact of Baker's yeast beta glucan

Article describes how monitoring immunological response to physical stressors in a field setting is challenging because existing methods require a laboratory visit and traditional blood collection via venipuncture. The purpose of this study was to determine if our optimized dry blood spot (DBS) methodology yields sufficient total RNA to quantify the effect of Baker's Yeast Beta Glucan supplementation on post-exercise mRNA expression.
Date: September 22, 2023
Creator: McFarlin, Brian K.; Bridgeman, Elizabeth A.; Vingren, Jakob L. & Will, David W.
System: The UNT Digital Library
Construction and characterization of superhydrophobic wood coatings using one-step technique (open access)

Construction and characterization of superhydrophobic wood coatings using one-step technique

Article describes how this study was aiming at enhancing the stain resistance and durability of varnish on wood surfaces, a super hydrophobic solution was created by blending the synthetic ZIF-8/paraffin with Hexadecyltrimethoxysilane at a specified mass ratio. This superhydrophobic mixture was then directly applied onto the wood varnish coating using a one-step method.
Date: November 22, 2023
Creator: Cao, Shuai; Cheng, Shuai; Wang, Pengyu; Ge, Shengbo; Cai, Liping & Cai, Jiabin
System: The UNT Digital Library
Neonatal per- and polyfluoroalkyl substance exposure in relation to retinoblastoma (open access)

Neonatal per- and polyfluoroalkyl substance exposure in relation to retinoblastoma

Article describes how neonatal per- and polyfluoroalkyl substance exposure can disrupt hormonal homeostasis and induce neuro- and immunotoxicity in children. In this exploratory study, we investigated associations between PFAS levels in neonatal dried blood spots and retinoblastoma risk.
Date: October 31, 2023
Creator: Chen, Yixin; Paul, Kimberly C.; Walker, Douglas I.; Jones, Dean P.; Wang, Xuexia; Ritz, Beate R. et al.
System: The UNT Digital Library
The exact consistency strength of the generic absoluteness for the universally Baire sets (open access)

The exact consistency strength of the generic absoluteness for the universally Baire sets

Article describes how a set of reals is universally Baire if all of its continuous preimages in topological spaces have the Baire property. The authors show that over some mild large cardinal theory, sealing is equiconsistent with LSA-over-uB.
Date: January 18, 2023
Creator: Sargsyan, Grigor & Trang, Nam
System: The UNT Digital Library
Work-Family Conflict and its Sustainability Implications among Married Immigrants Working in the USA (open access)

Work-Family Conflict and its Sustainability Implications among Married Immigrants Working in the USA

Article describes how there is a paucity of research on the work and family dynamics of immigrants who arrive in the U.S. on visas. This study examined work-family conflicts and work-life support among married immigrants born abroad but currently holding permanent resident status in the U.S.
Date: October 8, 2023
Creator: Gopalan, Neena; Beutell, Nicholas J.; Grzywacz, Joseph G.; Middlemiss, Wendy; Manchiraju, Srikant & Srivastava, Sapna
System: The UNT Digital Library
The formation channels of multiphase gas in nearby early-type galaxies (open access)

The formation channels of multiphase gas in nearby early-type galaxies

Article describes how the processes responsible for the assembly of cold and warm gas in early-type galaxies (ETGs) are not well understood. The authors report on the multiwavelength properties of 15 non-central, nearby ETGs primary through Multi-Unit Spectroscopic Explorer (MUSE) and Chandra X-ray observations, to address the origin of their multiphase gas.
Date: October 21, 2023
Creator: Eskenasy, Ryan; Olivares, Valeria; Su, Yuanyuan & Li, Yuan
System: The UNT Digital Library
ARKENSTONE – I. A novel method for robustly capturing high specific energy outflows in cosmological simulations (open access)

ARKENSTONE – I. A novel method for robustly capturing high specific energy outflows in cosmological simulations

Article describes how ARKENSTONE is a new model for multiphase, stellar feedback-driven galactic winds designed for inclusion in coarse resolution cosmological simulations. In this first paper of a series, the authors describe the features that allow ARKENSTONE to properly treat high specific energy wind components and demonstrate them using idealized non-cosmological simulations of a galaxy with a realistic circumgalactic medium (CGM) using the AREPO code.
Date: October 17, 2023
Creator: Smith, Matthew C.; Fielding, Drummond B.; Bryan, Greg L.; Kim, Chang-Goo; Ostriker, Eve C.; Somerville, Rachel S. et al.
System: The UNT Digital Library
Aberrant Salience Inventory: A meta-analysis to investigate its psychometric properties and identify screening cutoff scores (open access)

Aberrant Salience Inventory: A meta-analysis to investigate its psychometric properties and identify screening cutoff scores

Article describes how the Aberrant Salience Inventory (ASI) is a useful tool to measure salience abnormalities among the general population. The authors claim that there is strong clinical and scientific evidence that salience alteration is linked to psychosis.
Date: May 26, 2023
Creator: Merola, Giuseppe Pierpaolo; Boy, Ottone Baccaredda; Fascina, Isotta; Pecoraro, Vincenzo; Falone, Andrea; Patti, Andrea et al.
System: The UNT Digital Library
Influence of Tools and Cutting Strategy on Milling Conditions and Quality of Horizontal Thin-Wall Structures of Titanium Alloy Ti6Al4V (open access)

Influence of Tools and Cutting Strategy on Milling Conditions and Quality of Horizontal Thin-Wall Structures of Titanium Alloy Ti6Al4V

Article describes how titanium and nickel alloys are used in the creation of components exposed to harsh and variable operating conditions. The authors state that a search is underway for cutting parameters that will minimize the vibration while meeting the quality requirements.
Date: December 18, 2023
Creator: Kurpiel, Szymon; Cudok, Bartosz; Zagórski, Krzysztof; Cieślik, Jacek; Skrzypkowski, Krzysztof & Brostow, Witold, 1934-
System: The UNT Digital Library
Securing Industrial Control Systems: Components, Cyber Threats, and Machine Learning-Driven Defense Strategies (open access)

Securing Industrial Control Systems: Components, Cyber Threats, and Machine Learning-Driven Defense Strategies

Article describes how Industrial Control Systems (ICS), which include Supervisory Control and Data Acquisition (SCADA) systems, Distributed Control Systems (DCS), and Programmable Logic Controllers (PLC), play a crucial role in managing and regulating industrial processes. This article presents an overview of ICS security, covering its components, protocols, industrial applications, and performance aspects.
Date: October 30, 2023
Creator: Nankya, Mary; Chataut, Robin & Akl, Robert
System: The UNT Digital Library
Ideal plasticity and shape memory of nanolamellar high-entropy alloys (open access)

Ideal plasticity and shape memory of nanolamellar high-entropy alloys

Article describes how understanding the relationship among elemental compositions, nanolamellar microstructures, and mechanical properties enables the rational design of high-entropy alloys (HEAs). In this article the authors construct nanolamellar Alx-CoCuFeNi HEAs with alternating high- and low-Al concentration layers and explore their mechanical properties using a combination of molecular dynamic simulation and density functional theory calculation.
Date: October 13, 2023
Creator: Chen, Shuai; Liu, Ping; Pei, Qingxiang; Yu, Zhi Gen; Aitken, Zachary H.; Li, Wanghui et al.
System: The UNT Digital Library
A multiscale approach reveals elaborate circulatory system and intermittent heartbeat in velvet worms (Onychophora) (open access)

A multiscale approach reveals elaborate circulatory system and intermittent heartbeat in velvet worms (Onychophora)

Article describes how an antagonistic hemolymph-muscular system is essential for soft-bodied invertebrates. The authors analyzed the entire circulatory system of the peripatopsid Euperipatoides rowelli and claimed they discovered a surprisingly elaborate organization.
Date: April 28, 2023
Creator: Jahn, Henry; Hammel, Jörg U.; Göpel, Torben; Wirkner, Christian S. & Mayer, Georg
System: The UNT Digital Library