TECHNICAL COMPARISON OF CANDIDATE ION EXCHANGE MEDIA FOR SMALL COLUMN ION EXCHANGE (SCIX) APPLICATIONS IN SUPPORT OF SUPPLEMENTAL LAW PRETREATMENT (open access)

TECHNICAL COMPARISON OF CANDIDATE ION EXCHANGE MEDIA FOR SMALL COLUMN ION EXCHANGE (SCIX) APPLICATIONS IN SUPPORT OF SUPPLEMENTAL LAW PRETREATMENT

At-tank supplemental pretreatment including both filtration and small column ion exchange is currently under evaluation to facilitate salt waste retrieval and processing in the Hanford tank farms. Spherical resorcinol formaldehyde (sRF) resin is the baseline ion exchange resin for use in the Waste Treatment and Immobilization Plant (WTP). This document provides background and technical rationale to assist in determining whether spherical resorcinol formaldehyde (sRF) is also the appropriate ion exchange resin for supplemental LAW pretreatment processes and compares sRF with crystalline silicotitanate (CST) as potential supplemental pretreatment ion exchange media.
Date: December 28, 2010
Creator: AA, RAMSEY & MR, THORSON
System: The UNT Digital Library
Final Report-Confirmatory Survey Results for the ABB Combustion Engineering Site, Windsor, Connecticut; Revision 1 (DCN 5158-SR-02-1) (Docket No. 030-03754; RFTA No. 12-003) (open access)

Final Report-Confirmatory Survey Results for the ABB Combustion Engineering Site, Windsor, Connecticut; Revision 1 (DCN 5158-SR-02-1) (Docket No. 030-03754; RFTA No. 12-003)

The objectives of the confirmatory activities were to provide independent contractor field data reviews and to generate independent radiological data for use by the NRC in evaluating the adequacy and accuracy of the contractor�s procedures and FSS results. ORAU reviewed ABB CE�s decommissioning plan, final status survey plan, and the applicable soil DCGLs, which were developed based on an NRC-approved radiation dose assessment. The surveys included gamma surface scans, gamma direct measurements, and soil sampling.
Date: January 28, 2013
Creator: ADAMS, WADE C
System: The UNT Digital Library
Efficient Windows Collaborative: Research Tool Dissemination to Increase Energy Efficient Fenestration Product Penetration (open access)

Efficient Windows Collaborative: Research Tool Dissemination to Increase Energy Efficient Fenestration Product Penetration

The project goals covered both the residential and commercial windows markets and involved a range of audiences such as window manufacturers, builders, homeowners, design professionals, utilities, and public agencies. Essential goals included: (1) Creation of 'Master Toolkits' of information that integrate diverse tools, rating systems, and incentive programs, customized for key audiences such as window manufacturers, design professionals, and utility programs. (2) Delivery of education and outreach programs to multiple audiences through conference presentations, publication of articles for builders and other industry professionals, and targeted dissemination of efficient window curricula to professionals and students. (3) Design and implementation of mechanisms to encourage and track sales of more efficient products through the existing Window Products Database as an incentive for manufacturers to improve products and participate in programs such as NFRC and ENERGY STAR. (4) Development of utility incentive programs to promote more efficient residential and commercial windows. Partnership with regional and local entities on the development of programs and customized information to move the market toward the highest performing products. An overarching project goal was to ensure that different audiences adopt and use the developed information, design and promotion tools and thus increase the market penetration of energy efficient fenestration …
Date: February 28, 2010
Creator: Alliance to Save Energy (U.S.)
System: The UNT Digital Library
Scotts Valley Energy Office and Human Capacity Building that will provide energy-efficiency services and develop sustainable renewable energy projects. (open access)

Scotts Valley Energy Office and Human Capacity Building that will provide energy-efficiency services and develop sustainable renewable energy projects.

The primary goal of this project is to develop a Scotts Valley Energy Development Office (SVEDO). This office will further support the mission of the Tribe's existing leadership position as the DOE Tribal Multi-County Weatherization Energy Program (TMCWEP) in creating jobs and providing tribal homes and buildings with weatherization assistance to increase energy efficiency, occupant comfort and improved indoor air quality. This office will also spearhead efforts to move the Tribe towards its further strategic energy goals of implementing renewable energy systems through specific training, resource evaluation, feasibility planning, and implementation. Human capacity building and continuing operations are two key elements of the SVEDO objectives. Therefore, the project will 1) train and employ additional Tribal members in energy efficiency, conservation and renewable resource analyses and implementation; 2) purchase materials and equipment required to implement the strategic priorities as developed by the Scotts Valley Tribe which specifically include implementing energy conservation measures and alternative energy strategies to reduce energy costs for the Tribe and its members; and 3) obtain a dedicated office and storage space for ongoing SVEDO operations.
Date: June 28, 2013
Creator: Anderson, Temashio
System: The UNT Digital Library
American Recovery and Reinvestment Act (ARRA) - FEMP Technical Assistance - Federal Aviation Administration - Project 209 - Control Tower and Support Building, Boise, Idaho (open access)

American Recovery and Reinvestment Act (ARRA) - FEMP Technical Assistance - Federal Aviation Administration - Project 209 - Control Tower and Support Building, Boise, Idaho

This report documents an energy audit performed by Pacific Northwest National Laboratory (PNNL) and Redhorse Corporation (Redhorse) conducted on the Federal Aviation Administration (FAA) control tower and base building in Boise, Idaho. This report presents findings of the energy audit team that evaluated construction documents and operating specifications (at the 100% level) followed by a site visit of the facility under construction. The focus of the review was to identify measures that could be incorporated into the final design and operating specifications that would result in additional energy savings for FAA that would not have otherwise occurred.
Date: June 28, 2010
Creator: Arends, J. & Sandusky, William F.
System: The UNT Digital Library
American Recovery and Reinvestment Act (ARRA) FEMP Technical Assistance U.S. General Services Administration – Project 195 John Seiberling Federal Office Building and U.S. Courthouse, Akron, Ohio (open access)

American Recovery and Reinvestment Act (ARRA) FEMP Technical Assistance U.S. General Services Administration – Project 195 John Seiberling Federal Office Building and U.S. Courthouse, Akron, Ohio

This report documents the findings from an onsite audit of the John Seiberling Federal building located in Akron, Ohio. The Federal landlord for this building is the General Services Administration (GSA). The focus of the audit was to identify various no-cost or low-cost energy efficiency opportunities that, once implemented, would reduce in either electrical and gas consumption and increase the operational efficiency of the building. This audit also provided an opportunity to identify potential capital cost projects that should be considered in the to acquire additional energy (electric and gas) and water savings to further increase the operational efficiency of the building.
Date: May 28, 2010
Creator: Arends, J. & Sandusky, William F.
System: The UNT Digital Library
Ocean Thermal Extractable Energy Visualization- Final Technical Report on Award DE-EE0002664. October 28, 2012 (open access)

Ocean Thermal Extractable Energy Visualization- Final Technical Report on Award DE-EE0002664. October 28, 2012

The Ocean Thermal Extractable Energy Visualization (OTEEV) project focuses on assessing the Maximum Practicably Extractable Energy (MPEE) from the world's ocean thermal resources. MPEE is defined as being sustainable and technically feasible, given today's state-of-the-art ocean energy technology. Under this project the OTEEV team developed a comprehensive Geospatial Information System (GIS) dataset and software tool, and used the tool to provide a meaningful assessment of MPEE from the global and domestic U.S. ocean thermal resources. The OTEEV project leverages existing NREL renewable energy GIS technologies and integrates extractable energy estimated from quality-controlled data and projected optimal achievable energy conversion rates. Input data are synthesized from a broad range of existing in-situ measurements and ground-truthed numerical models with temporal and spatial resolutions sufficient to reflect the local resource. Energy production rates are calculated for regions based on conversion rates estimated for current technology, local energy density of the resource, and sustainable resource extraction. Plant spacing and maximum production rates are then estimated based on a default plant size and transmission mechanisms. The resulting data are organized, displayed, and accessed using a multi-layered GIS mapping tool, http://maps.nrel.gov/mhk_atlas with a user-friendly graphical user interface.
Date: October 28, 2012
Creator: Ascari, Matthew B.; Hanson, Howard P.; Rauchenstein, Lynn; Van Zwieten, James; Bharathan, Desikan; Heimiller, Donna et al.
System: The UNT Digital Library
Numerical Calculation of Neoclassical Distribution Functions and Current Profiles in Low Collisionality, Axisymmetric Plasmas (open access)

Numerical Calculation of Neoclassical Distribution Functions and Current Profiles in Low Collisionality, Axisymmetric Plasmas

A new code, the Neoclassical Ion-Electron Solver (NIES), has been written to solve for stationary, axisymmetric distribution functions (f ) in the conventional banana regime for both ions and elec trons using a set of drift-kinetic equations (DKEs) with linearized Fokker-Planck-Landau collision operators. Solvability conditions on the DKEs determine the relevant non-adiabatic pieces of f (called h ). We work in a 4D phase space in which Ψ defines a flux surface, θ is the poloidal angle, v is the total velocity referenced to the mean flow velocity, and λ is the dimensionless magnetic moment parameter. We expand h in finite elements in both v and λ#21; . The Rosenbluth potentials, φ#8; and ψ, which define the integral part of the collision operator, are expanded in Legendre series in cos χ , where #31;χ is the pitch angle, Fourier series in cos #18;θ , and finite elements in v . At each ψ , we solve a block tridiagonal system for hi (independent of fe ), then solve another block tridiagonal system for he (dependent on fi ). We demonstrate that such a formulation can be accurately and efficiently solved. NIES is coupled to the MHD equilibrium code JSOLVER [J. …
Date: June 28, 2012
Creator: B.C. Lyons, S.C. Jardin, and J.J. Ramos
System: The UNT Digital Library
National Ignition Campaign Program Completion Report (open access)

National Ignition Campaign Program Completion Report

None
Date: May 28, 2013
Creator: Baisden, P
System: The UNT Digital Library
A New Approach in Advance Network Reservation and Provisioning for High-Performance Scientific Data Transfers (open access)

A New Approach in Advance Network Reservation and Provisioning for High-Performance Scientific Data Transfers

Scientific applications already generate many terabytes and even petabytes of data from supercomputer runs and large-scale experiments. The need for transferring data chunks of ever-increasing sizes through the network shows no sign of abating. Hence, we need high-bandwidth high speed networks such as ESnet (Energy Sciences Network). Network reservation systems, i.e. ESnet's OSCARS (On-demand Secure Circuits and Advance Reservation System) establish guaranteed bandwidth of secure virtual circuits at a certain time, for a certain bandwidth and length of time. OSCARS checks network availability and capacity for the specified period of time, and allocates requested bandwidth for that user if it is available. If the requested reservation cannot be granted, no further suggestion is returned back to the user. Further, there is no possibility from the users view-point to make an optimal choice. We report a new algorithm, where the user specifies the total volume that needs to be transferred, a maximum bandwidth that he/she can use, and a desired time period within which the transfer should be done. The algorithm can find alternate allocation possibilities, including earliest time for completion, or shortest transfer duration - leaving the choice to the user. We present a novel approach for path finding in …
Date: January 28, 2010
Creator: Balman, Mehmet; Chaniotakis, Evangelos; Shoshani, Arie & Sim, Alex
System: The UNT Digital Library
High Performance Computing Productivity Study - Evaluation of Parallel Tools Platform (PTP) Eclipse Plug-In (open access)

High Performance Computing Productivity Study - Evaluation of Parallel Tools Platform (PTP) Eclipse Plug-In

None
Date: June 28, 2012
Creator: Banks, Lawrence E. & Dube, Eveline I.
System: The UNT Digital Library
Establishing MICHCARB, a geological carbon sequestration research and education center for Michigan, implemented through the Michigan Geological Repository for Research and Education, part of the Department of Geosciences at Western Michigan University (open access)

Establishing MICHCARB, a geological carbon sequestration research and education center for Michigan, implemented through the Michigan Geological Repository for Research and Education, part of the Department of Geosciences at Western Michigan University

The Michigan Geological Repository for Research and Education (MGRRE), part of the Department of Geosciences at Western Michigan University (WMU) at Kalamazoo, Michigan, established MichCarb—a geological carbon sequestration resource center by: • Archiving and maintaining a current reference collection of carbon sequestration published literature • Developing statewide and site-specific digital research databases for Michigan’s deep geological formations relevant to CO2 storage, containment and potential for enhanced oil recovery • Producing maps and tables of physical properties as components of these databases • Compiling all information into a digital atlas • Conducting geologic and fluid flow modeling to address specific predictive uses of CO2 storage and enhanced oil recovery, including compiling data for geological and fluid flow models, formulating models, integrating data, and running the models; applying models to specific predictive uses of CO2 storage and enhanced oil recovery • Conducting technical research on CO2 sequestration and enhanced oil recovery through basic and applied research of characterizing Michigan oil and gas and saline reservoirs for CO2 storage potential volume, injectivity and containment. Based on our research, we have concluded that the Michigan Basin has excellent saline aquifer (residual entrapment) and CO2/Enhanced oil recovery related (CO2/EOR; buoyant entrapment) geological carbon sequestration potential …
Date: January 28, 2014
Creator: Barnes, David A. & Harrison, William B.
System: The UNT Digital Library
Used Fuel Disposition Campaign - Baseline Studies for Ring Compression Testing of High-Burnup Fuel Cladding (open access)

Used Fuel Disposition Campaign - Baseline Studies for Ring Compression Testing of High-Burnup Fuel Cladding

None
Date: June 28, 2013
Creator: Billone, M.C.; Burtseva, T.A.; Liu, Y.Y. (Decision and Information Sciences) & NE), (
System: The UNT Digital Library
Final Technical Report for Phase I Award DE-SC0003559 (open access)

Final Technical Report for Phase I Award DE-SC0003559

The Smart Grid opens the door to the development of many companion technologies which will in turn enable the development of a variety of devices for household electricity-consuming appliances that can communicate with it; especially, many major appliance manufacturers (such as Whirlpool and General Electric) have made public commitments to design their appliances to be Smart Grid-compatible over the next several years. Yet during that same time period, customers will purchase many millions of long-lasting appliances which are not compatible with the Smart Grid. This research project's purpose is to bring significant Smart Grid compatibility to previously-installed appliances that were not specifically designed for any Smart Grid communications, in a way that is both economical and attractive for users who want to share in the energy cost savings and reduction of peak power demand opportunities provided by the evolving Smart Grid infrastructure. The focus of this effort is to identify and research smart control solutions which take advantage of the effective strategies of demand-response (DR) communications from utilities [including time-of-day (TOD) and peak-demand pricing options] and function apart from any need for operational changes to be designed into the non-smart appliances. Our Phase I concepts promote technological advancements for enabling …
Date: September 28, 2010
Creator: Blair, Jeff L. & Glenn, Lee J.
System: The UNT Digital Library
Science & Technology Review June 2010 (open access)

Science & Technology Review June 2010

This month's issue has the following articles: (1) A Leader in High-Pressure Science--Commentary by William H. Goldstein; (2) Diamonds Put the Pressure on Materials--New experimental capabilities are helping Livermore scientists better understand how extreme pressure affects a material's structure; (3) Exploring the Unusual Behavior of Granular Materials--Livermore scientists are developing new techniques for predicting the response of granular materials under pressure; (4) A 1-Ton Device in a Briefcase--A new briefcase-sized tool for nuclear magnetic resonance is designed for onsite analysis of suspected chemical weapons; and (5) Targets Designed for Ignition--A series of experiments at the National Ignition Facility is helping scientists finalize the ignition target design.
Date: April 28, 2010
Creator: Blobaum, K. J.
System: The UNT Digital Library
Multi-Hybrid Power Vehicles with Cost Effective and Durable Polymer Electrolyte (open access)

Multi-Hybrid Power Vehicles with Cost Effective and Durable Polymer Electrolyte

Anima Bose, the principal investigator of the project, originally proposed to develop composite membranes to operate PEMFCs at much higher temperatures than 80{degrees}C and to alleviate the flooding problems often encountered in Nafion menmbrane containing fuel cells. The PI has successfully created composite membranes by blending small quantities of octasilane-poss (OSP) with Nafion. The composite membranes exhibited temperature tolerance up to 110{degrees}C without scarifying cell performance as determined by polarization curves and proton conductivity measurements. These membranes also exhibited superior water management performance as evident from the lack of flooding. Furthermore, these fuel cells performed well under reduced humidities. Structural and thermal analyses revealed that these Nafion-octasilane composite membranes are homogenous at concentrations up to 3 wt% of the OSP and that the siloxane offers additional thermal stability.
Date: February 28, 2014
Creator: Bose, Anima
System: The UNT Digital Library
Radiation leukaemogenesis at low doses DE-FG02-05 ER 63947 Final Technical Report 15 May 2005 – 14 May 2010 (open access)

Radiation leukaemogenesis at low doses DE-FG02-05 ER 63947 Final Technical Report 15 May 2005 – 14 May 2010

This report provides a complete summary of the work undertaken and results obtained under US Department of Energy grant DF-FG02-05 ER 63947, Radiation leukaemogenesis at low doses. There is ample epidemiological evidence indicating that ionizing radiation is carcinogenic in the higher dose range. This evidence, however, weakens and carries increasing uncertainties at doses below 100-200 mSv. At these low dose levels the form of the dose-response curve for radiation-induced cancer cannot be determined reliably or directly from studies of human populations. Therefore animal, cellular and other experimental systems must be employed to provide supporting evidence on which to base judgements of risk at low doses. Currently in radiological protection a linear non-threshold (LNT) extrapolation of risk estimates derived from human epidemiological studies is used to estimate risks in the dose range of interest for protection purposes. Myeloid leukaemias feature prominently among the cancers associated with human exposures to ionising radiation (eg UNSCEAR 2006; IARC 2000). Good animal models of radiation-induced acute myeloid leukaemia (AML) are available including strains such as CBA, RFM and SJL (eg Major and Mole 1978; Ullrich et al 1976; Resnitzky et al 1985). Early mechanistic studies using cytogenetic methods in these mouse models established that the …
Date: July 28, 2010
Creator: Bouffler, Simon
System: The UNT Digital Library
Connecticut State University System Initiative for Nanotechnology-Related Equipment, Faculty Development and Curriculum Development (open access)

Connecticut State University System Initiative for Nanotechnology-Related Equipment, Faculty Development and Curriculum Development

DOE grant used for partial fulfillment of necessary laboratory equipment for course enrichment and new graduate programs in nanotechnology at the four institutions of the Connecticut State University System (CSUS). Equipment in this initial phase included variable pressure scanning electron microscope with energy dispersive x-ray spectroscopy elemental analysis capability [at Southern Connecticut State University]; power x-ray diffractometer [at Central Connecticut State University]; a spectrophotometer and spectrofluorimeter [at Eastern Connecticut State University; and a Raman Spectrometer [at Western Connecticut State University]. DOE's funding was allocated for purchase and installation of this scientific equipment and instrumentation. Subsequently, DOE funding was allocated to fund the curriculum, faculty development and travel necessary to continue development and implementation of the System's Graduate Certificate in Nanotechnology (GCNT) program and the ConnSCU Nanotechnology Center (ConnSCU-NC) at Southern Connecticut State University. All of the established outcomes have been successfully achieved. The courses and structure of the GCNT program have been determined and the program will be completely implemented in the fall of 2013. The instrumentation has been purchased, installed and has been utilized at each campus for the implementation of the nanotechnology courses, CSUS GCNT and the ConnSCU-NC. Additional outcomes for this grant include curriculum development for non-majors …
Date: March 28, 2013
Creator: Broadbridge, Christine C.
System: The UNT Digital Library
Radiological Dispersal Device Shelter & Evacuation Technical Basis CalEMA RNER Framework Supplement (open access)

Radiological Dispersal Device Shelter & Evacuation Technical Basis CalEMA RNER Framework Supplement

None
Date: June 28, 2013
Creator: Buddemeier, B R & Wood-Zika, A R
System: The UNT Digital Library
Rapid Exploitation and Analysis of Documents (open access)

Rapid Exploitation and Analysis of Documents

Analysts are overwhelmed with information. They have large archives of historical data, both structured and unstructured, and continuous streams of relevant messages and documents that they need to match to current tasks, digest, and incorporate into their analysis. The purpose of the READ project is to develop technologies to make it easier to catalog, classify, and locate relevant information. We approached this task from multiple angles. First, we tackle the issue of processing large quantities of information in reasonable time. Second, we provide mechanisms that allow users to customize their queries based on latent topics exposed from corpus statistics. Third, we assist users in organizing query results, adding localized expert structure over results. Forth, we use word sense disambiguation techniques to increase the precision of matching user generated keyword lists with terms and concepts in the corpus. Fifth, we enhance co-occurrence statistics with latent topic attribution, to aid entity relationship discovery. Finally we quantitatively analyze the quality of three popular latent modeling techniques to examine under which circumstances each is useful.
Date: November 28, 2011
Creator: Buttler, D J; Andrzejewski, D; Stevens, K D; Anastasiu, D & Gao, B
System: The UNT Digital Library
West Valley Demonstration Project Annual Site Environmental Report Calendar Year 2010 (open access)

West Valley Demonstration Project Annual Site Environmental Report Calendar Year 2010

The West Valley Demonstration Project (WVDP) Annual Site Environmental Report (ASER) for Calendar Year 2010. The report, prepared for the U.S. Department of Energy West Valley Demonstration Project office (DOE-WVDP), summarizes the environmental protection program at the WVDP for calendar year (CY) 2010. Monitoring and surveillance of the facilities used by the DOE are conducted to verify protection of public health and safety and the environment. The report is a key component of DOE's effort to keep the public informed of environmental conditions at the WVDP. The quality assurance protocols applied to the environmental monitoring program ensure the validity and accuracy of the monitoring data. In addition to demonstrating compliance with environmental laws, regulations and directives, evaluation of data collected in 2010 continued to indicate that WVDP activities pose no threat to public health or safety, or to the environment.
Date: September 28, 2011
Creator: CH2MHILL • B&W West Valley, LLC
System: The UNT Digital Library
A Hybrid Forming System: Electrical-Assisted Double Side Incremental Forming (EADSIF) Process for Enhanced Formability and Geometrical Flexibility (open access)

A Hybrid Forming System: Electrical-Assisted Double Side Incremental Forming (EADSIF) Process for Enhanced Formability and Geometrical Flexibility

The objectives of this project are to establish the scientific bases, engineering technologies and energy/emission impact of a novel dieless forming process, Double side Incremental Forming (DSIF), and to explore the effectiveness of its hybrid variation, Electrical-Assisted Double Side Incremental Forming (EADSIF), on increasing the formability of metallic sheets. The scope of this project includes: (1) the analysis of environmental performance of the proposed new process as compared to conventional sheet metal forming processes; (2) the experimental investigation of the process capabilities of DSIF and EADSIF via the self-designed and newly established lab-scale EADSIF equipment; (3) the development of the essential software in executing the new proposed process, i.e., the toolpath generation algorithms; and finally (4) the exploration of the electricity effect on material deformation. The major accomplishments, findings and conclusions obtained through this one and a half years exploratory project are: (1) The first industrial medium-size-scale DSIF machine using two hexapods, capable of handling a sheet area up to 675 mm x 675 mm, was successfully completed at Ford. (2) The lab-scale of the DSIF machine was designed, fabricated and assembled to form a workpiece up to 250 mm x 250 mm. (3) Parts with arbitrary freeform double-curvatures using …
Date: April 28, 2012
Creator: Cao, Jian; Xia, Z. Cedric; Gutowski, Timothy G. & Roth, John
System: The UNT Digital Library
Amorphous Alloy Membranes Prepared by Melt-Spin methods for Long-Term use in Hydrogen Separation Applications (open access)

Amorphous Alloy Membranes Prepared by Melt-Spin methods for Long-Term use in Hydrogen Separation Applications

Amorphous Ni-based alloy membranes show great promise as inexpensive, hydrogenselective membrane materials. In this study, we developed membranes based on nonprecious Ni-Nb-Zr alloys by adjusting the alloying content and using additives. Several studies on crystallization of the amorphous ribbons, in-situ x-ray diffraction, SEM and TEM, hydrogen permeation, hydrogen solubility, hydrogen deuterium exchange, and electrochemical studies were conducted. An important part of the study was to completely eliminate Palladium coatings of the NiNbZr alloys by hydrogen heattreatment. The amorphous alloy (Ni0.6Nb0.4)80Zr20 membrane appears to be the best with high hydrogen permeability and good thermal stability.
Date: February 28, 2013
Creator: Chandra, Dhanesh; Kim, Sang-Mun; Adibhatla, Anasuya; Dolan, Michael; Paglieri, Steve; Flanagan, Ted et al.
System: The UNT Digital Library
Effect of Gaseous Impurities on Long-Term Thermal Cycling and Aging Properties of Complex Hydrides for Hydrogen Storage (open access)

Effect of Gaseous Impurities on Long-Term Thermal Cycling and Aging Properties of Complex Hydrides for Hydrogen Storage

This program was dedicated to understanding the effect of impurities on Long-Term Thermal Cycling and aging properties of Complex Hydrides for Hydrogen Storage. At the start of the program we found reversibility between Li2NH+LiH  LiH+LiNH2 (yielding ~5.8 wt.%H capacity). Then we tested the effect of impurity in H2 gas by pressure cycling at 255oC; first with industrial gas containing ppm levels of O2 and H2O as major impurities. Both these impurities had a significant impact on the reversibility and decreased the capacity by 2.65 wt.%H. Further increase in number of cycles from 500 to 1100 showed only a 0.2 wt%H more weight loss, showing some capacity is still maintained after a significant number of cycles. The loss of capacity is attributed to the formation of ~55 wt% LiH and ~30% Li2O, as major contaminant phases, along with the hydride Li2NH phase; suggesting loss of nitrogen during cycling. The effect of 100 ppm H2O in H2 also showed a decrease of ~2.5 wt.%H (after 560 cycles), and 100ppm O2 in H2; a loss of ~4.1 wt.%. Methane impurity (100 ppm, 100cycles), showed a very small capacity loss of 0.9 wt.%H under similar conditions. However, when Li3N was pressure cycled with …
Date: March 28, 2011
Creator: Chandra, Dhanesh; Lamb, Joshua; Chien, Wen-Ming; Talekar, Anjali & Pal, Narendra
System: The UNT Digital Library