This report is an overview on the subject of carbon dioxide as a starting material for organic syntheses of potential commercial interest and the utilization of carbon dioxide as a substrate for fuel production. It draws extensively on literature sources, particularly on the report of a 1999 Workshop on the subject of catalysis in carbon dioxide utilization, but with emphasis on systems of most interest to us. Atmospheric carbon dioxide is an abundant (750 billion tons in atmosphere), but dilute source of carbon (only 0.036 % by volume), so technologies for utilization at the production source are crucial for both sequestration and utilization. Sequestration--such as pumping CO{sub 2} into sea or the earth--is beyond the scope of this report, except where it overlaps utilization, for example in converting CO{sub 2} to polymers. But sequestration dominates current thinking on short term solutions to global warming, as should be clear from reports from this and other workshops. The 3500 million tons estimated to be added to the atmosphere annually at present can be compared to the 110 million tons used to produce chemicals, chiefly urea (75 million tons), salicylic acid, cyclic carbonates and polycarbonates. Increased utilization of CO{sub 2} as a starting …

This report is an overview on the subject of carbon dioxide as a starting material for organic syntheses of potential commercial interest and the utilization of carbon dioxide as a substrate for fuel production. It draws extensively on literature sources, particularly on the report of a 1999 Workshop on the subject of catalysis in carbon dioxide utilization, but with emphasis on systems of most interest to us. Atmospheric carbon dioxide is an abundant (750 billion tons in atmosphere), but dilute source of carbon (only 0.036 % by volume), so technologies for utilization at the production source are crucial for both sequestration and utilization. Sequestration--such as pumping CO{sub 2} into sea or the earth--is beyond the scope of this report, except where it overlaps utilization, for example in converting CO{sub 2} to polymers. But sequestration dominates current thinking on short term solutions to global warming, as should be clear from reports from this and other workshops. The 3500 million tons estimated to be added to the atmosphere annually at present can be compared to the 110 million tons used to produce chemicals, chiefly urea (75 million tons), salicylic acid, cyclic carbonates and polycarbonates. Increased utilization of CO{sub 2} as a starting …

A number of programs have been implemented on the Hanford Site that utilize the pumping and treatment of contaminated groundwater as part of their remediation strategy. Often the treated water is reinjected into the aquifer at injection well sites. The implementation of remedial pump and treat systems, however, results in hydraulic pressure responses, both areally and vertically (i.e., with depth) within the pumped aquifer. The area within the aquifer affected by the pump and treat system (i.e., radius of influence) is commonly estimated based on detecting associated water-level responses within surrounding monitor wells. Natural external stresses, such as barometric pressure fluctuations, however, can have a discernible impact on well water-level measurements. These temporal barometric effects may significantly mask water-level responses within more distant wells that are only slightly affected (< 0.10 m) by the test system. External stress effects, therefore, can lead to erroneous indications of the radius of influence of the imposed pump and treat system remediation activities and can greatly diminish the ability to analyze the associated well responses for hydraulic property characterization. When these extraneous influences are significant, adjustments or removal of the barometric effects from the test-response record may be required for quantitative hydrologic assessment. This …

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Appropriations are one part of a complex federal budget process that includes budget resolutions, appropriations (regular, supplemental, and continuing) bills, rescissions, and budget reconciliation bills. This report is a guide to one of the 13 regular appropriations bills that Congress passes each year. It is designed to supplement the information provided by the House and Senate Appropriations Subcommittees on Agriculture Appropriations.

Monthly newsletter discussing news and activities related to the Atmospheric Radiation Measurement Program, articles about weather and atmospheric phenomena, and other related topics.

Two previous Analysis and Modeling Reports (AMRs) Civilian Radioactive Waste Management Systems Management and Operating Contractor (CRWMS M&O 2000a and CRWMS M&O 2000b) provided abstractions of the biosphere dose conversion factors (BDCFs) for those radionuclides determined (CRWMS M&O 1999a) to be of potential importance for the initial ten thousand years after closure of the repository. To continue predictions of dose beyond ten thousand years requires abstractions of the BDCFs for those additional radionuclides defined in CRWMS M&O 1999b to be of potential importance in this time domain. The radionuclides for which BDCFs were generated (CRWMS M&O 2000c) to address the time period out to a million years are {sup 210}Pb, {sup 226}Ra, {sup 230}Th, {sup 231}Pa, and {sup 242}Pu. The abstraction to be used in this calculation for providing as input to the Total System Performance Assessment (TSPA) code is the definition of the percentile points, at intervals of 5%, of the set of stochastic BDCF data for each radionuclide generated and reported in CRWMS M&O 2000c. Being based directly on the stochastic data the approach captures the uncertainty in the BDCF distributions.

When embarking on an experimental program for purposes of discovery and understanding, it is only prudent to use appropriate analysis tools to aid in the discovery process. Due to the limited scope of experimental measurement analytical results can significantly complement the data after a reasonable validation process has occurred. In this manner the analytical results can help to explain certain measurements, suggest other measurements to take and point to possible modifications to the experimental apparatus. For these reasons it was decided to create a detailed nonlinear finite element model of the Sandia Microslip Experiment. This experiment was designed to investigate energy dissipation due to microslip in bolted joints and to identify the critical parameters involved. In an attempt to limit the microslip to a single interface a complicated system of rollers and cables was devised to clamp the two slipping members together with a prescribed normal load without using a bolt. An oscillatory tangential load is supplied via a shaker. The finite element model includes the clamping device in addition to the sequence of steps taken in setting up the experiment. The interface is modeled using Coulomb friction requiring a modest validation procedure for estimating the coefficient of friction. Analysis …

We are developing scientific software component technology to manage the complexity of modem, parallel simulation software and increase the interoperability and re-use of scientific software packages. In this paper, we describe a language interoperability tool named Babel that enables the creation and distribution of language-independent software libraries using interface definition language (IDL) techniques. We have created a scientific IDL that focuses on the unique interface description needs of scientific codes, such as complex numbers, dense multidimensional arrays, complicated data types, and parallelism. Preliminary results indicate that in addition to language interoperability, this approach provides useful tools for thinking about the design of modem object-oriented scientific software libraries. Finally, we also describe a web-based component repository called Alexandria that facilitates the distribution, documentation, and re-use of scientific components and libraries.

A letter report issued by the General Accounting Office with an abstract that begins "The Panama Canal Treaty called for the United States to transfer control over the Panama Canal to Panama and withdraw U.S. military forces and equipment from Panama. The treaty allowed the U.S. government to remove or dispose of all equipment and supplies acquired by U.S. forces. U.S. plans for withdrawal from Panama required excess property to be processed using disposal procedures that gave the military services and the federal agencies the first opportunity to receive the property. During 1998 and 1999, the Department of Defense's (DOD) Panama disposal office processed excess property valued at $136.7 million. Of this amount, $691,000 worth of property (less than one percent) was unaccounted for during this period. Disposal office records show that the property was written off as lost. DOD recognizes the need to properly manage and account for its assets and is working on a long-term strategy to provide in-transit control and visibility over excess property through information technology. DOD also has developed a new lesson segment for training its personnel on control procedures, but it has not taken adequate steps to ensure that the appropriate field personnel have …

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The Clinton Administration’s FY2001 budget proposes several tax subsidies for energy conservation and alternative fuels: 1) solar energy tax credits very similar to those that expired in 1985; 2) a new tax credit for the cost of a new home that would meet certain energy efficiency standards; 3) a tax credit for advanced energy-efficient equipment for space heating and cooling and hot water heaters; 4) more accelerated depreciation deductions for distributed power technologies, including small electrical generating systems (self-generated power), and for co-generation systems; 5) a new tax credit for the purchase of hybrid vehicles – cars, minivans, sport utility vehicles, and pickups – that run alternately on a consumable fuel (such as gasoline) and a rechargeable energy storage system (such as an electric battery); 6) extension of the present $4,000 tax credit for electric vehicles, which would otherwise terminate on 2004; and 7) a liberalization of the renewable electricity credit from such wind systems and closed-loop biomass systems.

Enzymes for Degradation of Energetic Materials and Demilitarization of Explosives Stockpiles: SERDP Final Report 9/00

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As directed by written work direction (CRWMS M and O 1999f), Performance Assessment (PA) developed a model for microbial communities in the engineered barrier system (EBS) as documented here. The purpose of this model is to assist Performance Assessment and its Engineered Barrier Performance Section in modeling the geochemical environment within a potential repository drift for TSPA-SR/LA, thus allowing PA to provide a more detailed and complete near-field geochemical model and to answer the key technical issues (KTI) raised in the NRC Issue Resolution Status Report (IRSR) for the Evolution of the Near Field Environment (NFE) Revision 2 (NRC 1999). This model and its predecessor (the in-drift microbial communities model as documented in Chapter 4 of the TSPA-VA Technical Basis Document, CRWMS M and O 1998a) was developed to respond to the applicable KTIs. Additionally, because of the previous development of the in-drift microbial communities model as documented in Chapter 4 of the TSPA-VA Technical Basis Document (CRWMS M and O 1998a), the M and O was effectively able to resolve a previous KTI concern regarding the effects of microbial processes on seepage and flow (NRC 1998). This document supercedes the in-drift microbial communities model as documented in Chapter 4 …

Correspondence issued by the General Accounting Office with an abstract that begins "This report focuses on GAO's review of the South Boston Piers Transitway Finance Plan. The Massachusetts Bay Transportation Authority (MBTA) is building a 1.5 mile underground transitway to connect its existing transit system with the South Boston Piers area, which is undergoing significant economic development. The project is experiencing cost increases and schedule delays, which have led to concerns over funding. GAO notes that although MBTA has shown that it has the financial capacity to complete the project, it has not yet clearly demonstrated to the Federal Transit Administration's financial management oversight contractor that funding the transitway project will not impair its ability to operate and maintain its overall transit system."

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Algebraic multigrid methods offer the hope that multigrid convergence can be achieved (for at least some important applications) without a great deal of effort from engineers and scientists wishing to solve linear systems. In this paper the authors consider parallelization of the smoothed aggregation multi-grid method. Smoothed aggregation is one of the most promising algebraic multigrid methods. Therefore, developing parallel variants with both good convergence and efficiency properties is of great importance. However, parallelization is nontrivial due to the somewhat sequential aggregation (or grid coarsening) phase. In this paper, they discuss three different parallel aggregation algorithms and illustrate the advantages and disadvantages of each variant in terms of parallelism and convergence. Numerical results will be shown on the Intel Teraflop computer for some large problems coming from nontrivial codes: quasi-static electric potential simulation and a fluid flow calculation.

As directed by a written development plan (CRWMS M&O 1999a), Task 1, an overall conceptualization of the physical and chemical environment (P/CE) in the emplacement drift is documented in this Analysis/Model Report (AMR). Included are the physical components of the engineered barrier system (EBS). The intended use of this descriptive conceptualization is to assist the Performance Assessment Department (PAD) in modeling the physical and chemical environment within a repository drift. It is also intended to assist PAD in providing a more integrated and complete in-drift geochemical model abstraction and to answer the key technical issues raised in the U.S. Nuclear Regulatory Commission (NRC) Issue Resolution Status Report (IRSR) for the Evolution of the Near-Field Environment (NFE) Revision 2 (NRC 1999). EBS-related features, events, and processes (FEPs) have been assembled and discussed in ''EBS FEPs/Degradation Modes Abstraction'' (CRWMS M&O 2000a). Reference AMRs listed in Section 6 address FEPs that have not been screened out. This conceptualization does not directly address those FEPs. Additional tasks described in the written development plan are recommended for future work in Section 7.3. To achieve the stated purpose, the scope of this document includes: (1) the role of in-drift physical and chemical environments in the Total …

We study the so-called {rho}{pi} puzzle of the {psi}(2S) decay by incorporating two inputs; the relative phase between the one-photon and the gluonic decay amplitude, and a possible hadronic excess in the inclusive nonelectromagnetic decay rate of {psi}(2S). We look into the possibility that the hadronic excess in {psi}(2S) originates from a decay process of long-distance origin which is absent from the J/{upsilon} decay. We propose that the amplitude of this additional process happens to nearly cancel the short-distance gluonic amplitude in the exclusive decay {psi}(2S) {yields} 1{sup -}0{sup -} and turn the sum dominantly real in contrast to the J/{psi} decay. We present general consequences of this mechanism and survey two models which might possibly explain the source of this additional amplitude.

Correspondence issued by the General Accounting Office with an abstract that begins "The National Association of Securities Dealers (NASD) subsidiary, NASD Dispute Resolution (DR), failed to update its arbitrator disclosure system in a timely manner. As a result, several parties in an arbitration did not receive timely information on their arbitrator. To reduce the potential for further errors, NASD-DRplans to: (1) introduce a form that will allow arbitrators to submit updated information electronically, and (2) centralize processing of the information in itsDepartment of Neutral Management. In 1992 and 1998, NASD-DR also used other measures to ensure that arbitrator background information was current. Because NASD-DR has made these changes and plans to make additional improvements to its procedures for updating arbitrator disclosure information, GAO is not making any further recommendations at this time."

As a technology partner with NREL, Global Solar Energy (GSE) has initiated an extensive and systematic plan to accelerate the commercialization of thin-film photovoltaics (PV) based on copper indium gallium diselenide (CIGS). The distinguishing feature of the GSE manufacturing process is the exclusive use of lightweight, flexible substrates. GSE has developed the technology to fabricate CIGS photovoltaics on both stainless-steel and polymer substrates. CIGS deposited on flexible substrates can be fabricated into either flexible or rigid modules. Low-cost, rigid PV panels for remote power, bulk/utility, telecommunication, and rooftop applications have been produced by affixing the flexible substrate to an inexpensive rigid panel by lamination or adhesive. Stainless-steel-based PV modules are fabricated by a novel interconnect method that avoids the use of wires or foils and soldered connections. In the case of polymer-based PV modules, the continuous roll is not sectioned into individual panels until the module buss and power leads are attached. Roll-to-roll vacuum deposition has several advantages that translate directly to reduced capital costs, greater productivity, improved yield, greater reliability, lower maintenance, and a larger volume of PV material. In combination with roll-to-roll processing, GSE has developed evaporation deposition operations that enable low-cost and high-efficiency CIGS modules. The CIGS …