Prediction of Corrosion of Alloys in Mixed-Solvent Environments (open access)

Prediction of Corrosion of Alloys in Mixed-Solvent Environments

Corrosion is much less predictable in organic or mixed-solvent environments than in aqueous process environments. As a result, US chemical companies face greater uncertainty when selecting process equipment materials to manufacture chemical products using organic or mixed solvents than when the process environments are only aqueous. Chemical companies handle this uncertainty by overdesigning the equipment (wasting money and energy), rather than by accepting increased risks of corrosion failure (personnel hazards and environmental releases). Therefore, it is important to develop simulation tools that would help the chemical process industries to understand and predict corrosion and to develop mitigation measures. To create such tools, we have developed models that predict (1) the chemical composition, speciation, phase equilibria, component activities and transport properties of the bulk (aqueous, nonaqueous or mixed) phase that is in contact with the metal; (2) the phase equilibria and component activities of the alloy phase(s) that may be subject to corrosion and (3) the interfacial phenomena that are responsible for corrosion at the metal/solution or passive film/solution interface. During the course of this project, we have completed the following: (1) Development of thermodynamic modules for calculating the activities of alloy components; (2) Development of software that generates stability diagrams …
Date: June 5, 2003
Creator: A. Anderko, P. Wang, R. D. Young, D. P. Riemer, P. McKenzie and M. M. Lencka (OLI Systems Inc.) & Laboratory), S. S. Babu and P. Angelini (Oak Ridge National
Object Type: Report
System: The UNT Digital Library
Electricity: The Road Toward Restructuring (open access)

Electricity: The Road Toward Restructuring

The Public Utility Holding Company Act of 1935 (PUHCA) and the Federal Power Act (FPA) were enacted to eliminate unfair practices and other abuses by electricity and gas holding companies by requiring federal control and regulation of interstate public utility holding companies. Comprehensive energy legislation has passed the House and Senate. The House passed H.R. 6 on April 11, 2003. On July 31, 2003, the Senate suspended debate on S. 14, inserted the text of H.R. 4 (107th Congress) as a substitute, and passed H.R. 6. A conference agreement was reached November 17, 2003, and passed by the House the next day. H.R. 6 includes an electricity title that would, in part, repeal PUHCA, would prospectively repeal the mandatory purchase requirement under PURPA, and would create an electric reliability organization. On June 15, 2004, H.R. 4503, a comprehensive energy policy bill, passed the House.
Date: June 5, 2002
Creator: Abel, Amy & Parker, Larry
Object Type: Report
System: The UNT Digital Library
DEVELOPMENT OF THE H1700 SHIPPING PACKAGE (open access)

DEVELOPMENT OF THE H1700 SHIPPING PACKAGE

The H1700 Package is based on the DOE-EM Certified 9977 Packaging. The H1700 will be certified by the Packaging Certification Division of the National Nuclear Security Administration for the shipment of plutonium by air by the United Stated Military both within the United States and internationally. The H1700 is designed to ship radioactive contents in assemblies of Radioisotope Thermoelectric Generators (RTGs) or arrangements of nested food-pack cans. The RTG containers are designed and tested to remain leaktight during transport, handling, and storage; however, their ability to remain leaktight during transport in the H1700 is not credited. This paper discusses the design and special operation of the H1700.
Date: June 5, 2009
Creator: Abramczyk, G.; Loftin, B. & Mann, P.
Object Type: Article
System: The UNT Digital Library
Plasma Diagnostic Calibration and Characterizations with High Energy X-rays (open access)

Plasma Diagnostic Calibration and Characterizations with High Energy X-rays

National Security Technologies’ High Energy X-ray (HEX) Facility is unique in the U.S. Department of Energy complex. The HEX provides fluorescent X-rays of 5 keV to 100 keV with fluence of 10^5–10^6 photons/cm^2/second at the desired line energy. Low energy lines can be filtered, and both filters and fluorescers can be changed rapidly. We present results of calibrating image plates (sensitivity and modulation transfer function), a Bremsstrahlung spectrometer (stacked filters and image plates), and the National Ignition Facility’s Filter- Fluorescer Experiment (FFLEX) high energy X-ray spectrometer. We also show results of a scintillator light yield and alignment study for a neutron imaging system.
Date: June 5, 2009
Creator: Ali, Zaheer
Object Type: Article
System: The UNT Digital Library
Radiation-induced segregation and the relationship to physical properties in irradiated austenitic alloys. (open access)

Radiation-induced segregation and the relationship to physical properties in irradiated austenitic alloys.

Radiation-induced changes in composition are studied because these changes can degrade failure of materials irradiated in nuclear reactors. In this work, the effect of alloy composition on radiation-induced segregation, hardening, and void swelling is presented. Five alloys, Fe-18Cr-8Ni, Fe-16Cr-13Ni, Fe-18Cr-40Ni, Fe-16Cr-13Ni+Mo, and Fe-16Cr-13Ni+Mo+P (all compositions in wt. %), were irradiated with 3.2 MeV protons at 400 C to a dose of 0.5 displacements per atom. The change in grain boundary composition was measured using field emission gun scanning transmission electron microscopy and the hardening was measured using Vickers indentation. Void swelling is calculated from the void size distribution measured using transmission electron microscopy. After irradiation, Cr depletes and Ni enriches at grain boundaries. Increasing bulk Ni concentration causes greater Cr depletion and Ni enrichment at grain boundaries. For alloys with 16 Cr, the addition of P reduces the Cr depletion and Ni enrichment. Hardening does not directly correlate with composition, but a framework for isolating the effect of hardening and segregation on cracking is suggested. The amount of void swelling in the irradiated material is shown to correspond inversely with segregation. Those alloys with greater segregation tend to swell less.
Date: June 5, 2002
Creator: Allen, T. R.; Cole, J. I.; Was, G. S. & Kenik, E. A.
Object Type: Article
System: The UNT Digital Library
Properties of 20% cold-worked 316 stainless steel irradiated at low dose rate. (open access)

Properties of 20% cold-worked 316 stainless steel irradiated at low dose rate.

To assess the effects of long-term, low-dose-rate neutron exposure, tensile, hardness, and fracture properties were measured and microstructural characterization performed on irradiated 20% cold-worked Type 316 stainless steel. Samples were prepared from reactor core components retrieved from the EBR-II reactor following final shutdown. Sample locations were chosen to cover a dose range of 1-56 dpa at temperatures from 371-390 C and dose rates from 0.8-3.3 x 10{sup -7} dpa/s. Irradiation caused hardening, with the ultimate tensile strength (UTS) reaching about 800 MPa near 20 dpa and appearing to saturate at higher doses. The yield strength (YS) follows approximately the same trend as the ultimate tensile strength. At higher dose, the difference between the UTS and YS decreases, suggesting the work-hardening capability of the material is decreasing with increasing dose. The hardness and yield strength increases occur roughly over the same range of dose. While the material retained respectable ductility at 20 dpa, the uniform and total elongation decreased to <1 and <3%, respectively, at 47 dpa. Fracture in the 30 dpa specimen is mainly ductile but with local regions of mixed-mode failure, consisting mainly of dimples and microvoids. The fracture surface of the higher-exposure 47 dpa specimen displays more brittle …
Date: June 5, 2002
Creator: Allen, T. R.; Tsai, H.; Cole, J. I.; Ohta, J.; Dohi, K. & Kusanagi, H.
Object Type: Article
System: The UNT Digital Library
Insulated Concrete Homes Increase Durability and Energy Efficiency (open access)

Insulated Concrete Homes Increase Durability and Energy Efficiency

New houses designed by Mercedes Homes in Melbourne, Florida, with technical support from the U.S. Department of Energy's Building America Program, save their homeowners money by using energy efficient features such as a high performance heat pump and solar control glazing to reduce cooling costs.
Date: June 5, 2001
Creator: America, Building; Hendron, B. & Poole, L.
Object Type: Book
System: The UNT Digital Library
A korarchaeal genome reveals insights into the evolution of the Archaea (open access)

A korarchaeal genome reveals insights into the evolution of the Archaea

The candidate division Korarchaeota comprises a group of uncultivated microorganisms that, by their small subunit rRNA phylogeny, may have diverged early from the major archaeal phyla Crenarchaeota and Euryarchaeota. Here, we report the initial characterization of a member of the Korarchaeota with the proposed name,"Candidatus Korarchaeum cryptofilum," which exhibits an ultrathin filamentous morphology. To investigate possible ancestral relationships between deep-branching Korarchaeota and other phyla, we used whole-genome shotgun sequencing to construct a complete composite korarchaeal genome from enriched cells. The genome was assembled into a single contig 1.59 Mb in length with a G + C content of 49percent. Of the 1,617 predicted protein-coding genes, 1,382 (85percent) could be assigned to a revised set of archaeal Clusters of Orthologous Groups (COGs). The predicted gene functions suggest that the organism relies on a simple mode of peptide fermentation for carbon and energy and lacks the ability to synthesize de novo purines, CoA, and several other cofactors. Phylogenetic analyses based on conserved single genes and concatenated protein sequences positioned the korarchaeote as a deep archaeal lineage with an apparent affinity to the Crenarchaeota. However, the predicted gene content revealed that several conserved cellular systems, such as cell division, DNA replication, and tRNA …
Date: June 5, 2008
Creator: Anderson, Iain J; Elkins, James G.; Podar, Mircea; Graham, David E.; Makarova, Kira S.; Wolf, Yuri et al.
Object Type: Article
System: The UNT Digital Library
Letter of intent to build an off-axis detector to study nu(mu) ---> nu(e) oscillations with the NuMI neutrino beam (open access)

Letter of intent to build an off-axis detector to study nu(mu) ---> nu(e) oscillations with the NuMI neutrino beam

None
Date: June 5, 2006
Creator: Ayres, D.; Drake, G.; Goodman, M.; Guarino, V.; Joffe-Minor, T.; Reyna, D. et al.
Object Type: Report
System: The UNT Digital Library
DUAL ION EXPOSURE VS. SPLIT-DOSE EXPOSURES IN HUMAN CELL NEOPLASTIC TRANSFORMATION. (open access)

DUAL ION EXPOSURE VS. SPLIT-DOSE EXPOSURES IN HUMAN CELL NEOPLASTIC TRANSFORMATION.

Since radiation fields of space contain many-fold more protons than high atomic number, high energy (HZE) particles, cells in astronaut crews will experience on average several proton hits before an HZE hit. Thus radiation regimes of proton exposure before HZE particle exposure simulate space radiation exposure, and measurement of the frequency of neoplastic transformation of human primary cells to anchorage-independent growth simulates in initial step in cancer induction. Previously our group found that exposure to 20 cGy 1 GeV/n protons followed within about 1 hr by a HZE ion (20 cGy 1 GeV/n Fe or Ti ions) hit gave about a 3-fold increase in transformation frequency ([1]). To provide insight into the H-HZE induced increased transformation frequencies, we asked if split doses of the same ion gave similar increased transformation frequencies. However, the data show that the split dose of 20 cGy plus 20 cGy of either H or HZE ions gave about the same effect as the 40 cGy uninterrupted dose, quite different from the effect of the mixed ion H + HZE irradiation. We also asked if lower proton doses than 20 cGy followed 15 minutes later by 20 cGy of HZE ions gave greater than additive transformation …
Date: June 5, 2006
Creator: BENNETT, P.V.; CUTTER, N.C. & SUTHERLAND, B.M.
Object Type: Article
System: The UNT Digital Library
A process model of natural attenuation in drainage from a historic mining district (open access)

A process model of natural attenuation in drainage from a historic mining district

A process model was used to better understand the controls on the chemical evolution of drainage in a historic mining district. At the Pecos Mine Operable Unit, New Mexico, drainage near the waste rock pile is acidic (pH varies from 3.0--5.0) and carries high concentrations of Zn, Al, Cu and Pb. As drainage flows toward the Pecos River, pH increases to greater than 7 and heavy metal content decreases. A process model of natural attenuation in this drainage shows the main controls on pH are reaction with a local bedrock that contains limestone, and concurrent mixing with tributary streams. Models that account for both calcite dissolution and mixing reproduce the observed decrease in aqueous metal concentrations with increasing pH. Contaminant concentrations attenuate primarily via two distinct pathways: Al, Cu, Fe and Pb precipitate directly from solution, whereas Zn, Mg, Mn and SO{sub 4} concentrations decrease primarily through dilution. Additionally, Pb adsorbs to precipitating hydroxide surfaces.
Date: June 5, 2000
Creator: BERGER,AMY C.; BETHKE,CRAIG M. & KRUMHANSL,JAMES L.
Object Type: Article
System: The UNT Digital Library
Distributed Energy Resources at Naval Base Ventura County Building 1512: A Sensitivity Analysis (open access)

Distributed Energy Resources at Naval Base Ventura County Building 1512: A Sensitivity Analysis

This report is the second of a two-part study by BerkeleyLab of a DER (distributed energy resources) system at Navy Base VenturaCounty (NBVC). First, a preliminary assessment ofthe cost effectivenessof distributed energy resources at Naval Base Ventura County (NBVC)Building 1512 was conducted in response to the base s request for designassistance to the Federal Energy Management Program (Bailey and Marnay,2004). That report contains a detailed description of the site and theDER-CAM (Consumer Adoption Model) parameters used. This second reportcontains sensitivity analyses of key parameters in the DER system modelof Building 1512 at NBVC and additionally considers the potential forabsorption-powered refrigeration.The prior analysis found that under thecurrent tariffs, and given assumptions about the performance andstructure of building energy loads and available generating technologycharacteristics, installing a 600 kW DER system with absorption coolingand recovery heat capabilities could deliver cost savings of about 14percent, worth $55,000 per year. However, under current conditions, thisstudy also suggested that significant savings could be obtained ifBuilding 1512 changed from its current direct access contract to a SCETOU-8 (Southern California Edison time of use tariff number 8) ratewithout installing a DER system. Evaluated on this tariff, the potentialsavings from installation of a DER system would be about 4 …
Date: June 5, 2005
Creator: Bailey, Owen C. & Marnay, Chris
Object Type: Report
System: The UNT Digital Library
The Mean and Scatter of the Velocity Dispersion-Optical Richness Relation for MaxBCG Galaxy Clusters (open access)

The Mean and Scatter of the Velocity Dispersion-Optical Richness Relation for MaxBCG Galaxy Clusters

The distribution of galaxies in position and velocity around the centers of galaxy clusters encodes important information about cluster mass and structure. Using the maxBCG galaxy cluster catalog identified from imaging data obtained in the Sloan Digital Sky Survey, we study the BCG--galaxy velocity correlation function. By modeling its non-Gaussianity, we measure the mean and scatter in velocity dispersion at fixed richness. The mean velocity dispersion increases from 202 {+-} 10 km s{sup -1} for small groups to more than 854 {+-} 102 km s{sup -1} for large clusters. We show the scatter to be at most 40.5{+-}3.5%, declining to 14.9{+-}9.4% in the richest bins. We test our methods in the C4 cluster catalog, a spectroscopic cluster catalog produced from the Sloan Digital Sky Survey DR2 spectroscopic sample, and in mock galaxy catalogs constructed from N-body simulations. Our methods are robust, measuring the scatter to well within one-sigma of the true value, and the mean to within 10%, in the mock catalogs. By convolving the scatter in velocity dispersion at fixed richness with the observed richness space density function, we measure the velocity dispersion function of the maxBCG galaxy clusters. Although velocity dispersion and richness do not form a true …
Date: June 5, 2007
Creator: Becker, M. R.; McKay, T. A.; Koester, B.; Wechsler, R. H.; Rozo, E.; Evrard, A. et al.
Object Type: Article
System: The UNT Digital Library
Simulation of Enhanced-Explosive Devices in Chambers and Tunnels (open access)

Simulation of Enhanced-Explosive Devices in Chambers and Tunnels

Introduction: Shock-dispersed fuel (SDF) explosives use a small chemical charge to disperse a combustible fuel that burns in the post-detonation environment. The energy released in the combustion process has the potential for generating higher pressures and temperatures than conventional explosives. However, the development of these types of novel explosive systems requires a detailed understanding of all of the modes of energy release. Objective: The objective of this project is develop a simulation capability for predicting explosion and combustion phase of SDF charges and apply that capability to quantifying the behavior of these types of explosives. Methodology: We approximate the dynamics of an SDF charge using high Reynolds number, fast chemistry model that effectively captures the thermodynamic behavior of SDF charges and accurately models the key modes of energy release. The overall computational model is combined with Adaptive Mesh Refinement (AMR) , implemented in a parallel adaptive framework suited to the massively parallel computer systems. Results: We have developed a multiphase version of the model and used it to simulate an SDF charge in which the dispersed fuel is aluminum flakes. Flow visualizations show that the combustion field is turbulent for the chamber and tunnel cases studied. During the 3 milli-seconds …
Date: June 5, 2007
Creator: Bell, J B; Kuhl, A L & Beckner, V E
Object Type: Article
System: The UNT Digital Library
Use of Antineutrino Detectors for Nuclear Reactor Safeguards Effectiveness Assessment (open access)

Use of Antineutrino Detectors for Nuclear Reactor Safeguards Effectiveness Assessment

As described in an earlier article [1], important information regarding reactor power and the amount and type of fissile material in reactor cores can be determined by measuring the antineutrino rate and energy spectrum, using a cubic meter scale antineutrino detector at tens of meters standoff from the core. Current International Atomic Energy Agency (IAEA) safeguards techniques do not provide such real-time quantitative information regarding core power levels and isotopic composition. The possible benefits of this approach are several and have been discussed in the earlier article. One key advantage is that the method gives the inspecting agency completely independent access to real-time information on the operational status and fissile content of the core. Furthermore, the unattended and non-intrusive nature of the technology may reduce the monitoring burden on the plant operator, even though more information is being provided than is available within the current IAEA safeguards regime. Here we present a detailed analytical framework for measuring the impact that such a detector might have on IAEA safeguards, if implemented. To perform the analysis, we will use initial data from our operating detector and a standard analysis technique for safeguards regimes, developed at Lawrence Livermore National Laboratory. Because characterization of …
Date: June 5, 2006
Creator: Bernstein, A; Lambert, H E; Elayat, H A; O'Connell, W J; Rexroth, P; Baldwin, G et al.
Object Type: Article
System: The UNT Digital Library
Supreme Court Nominations: Senate Floor Procedure and Practice, 1789-2009 (open access)

Supreme Court Nominations: Senate Floor Procedure and Practice, 1789-2009

This report discusses Senate procedure relating to Supreme Court nominations from 1789 to the present, but excluding the June 1, 2009 nomination of Sonia Sotomayor.
Date: June 5, 2009
Creator: Beth, Richard S. & Palmer, Betsy
Object Type: Report
System: The UNT Digital Library
High Performance, Three-Dimensional Bilateral Filtering (open access)

High Performance, Three-Dimensional Bilateral Filtering

Image smoothing is a fundamental operation in computer vision and image processing. This work has two main thrusts: (1) implementation of a bilateral filter suitable for use in smoothing, or denoising, 3D volumetric data; (2) implementation of the 3D bilateral filter in three different parallelization models, along with parallel performance studies on two modern HPC architectures. Our bilateral filter formulation is based upon the work of Tomasi [11], but extended to 3D for use on volumetric data. Our three parallel implementations use POSIX threads, the Message Passing Interface (MPI), and Unified Parallel C (UPC), a Partitioned Global Address Space (PGAS) language. Our parallel performance studies, which were conducted on a Cray XT4 supercomputer and aquad-socket, quad-core Opteron workstation, show our algorithm to have near-perfect scalability up to 120 processors. Parallel algorithms, such as the one we present here, will have an increasingly important role for use in production visual analysis systems as the underlying computational platforms transition from single- to multi-core architectures in the future.
Date: June 5, 2008
Creator: Bethel, E. Wes
Object Type: Report
System: The UNT Digital Library
The United Nations Human Rights Council: Issues for Congress (open access)

The United Nations Human Rights Council: Issues for Congress

This report provides historical background of the Council, including the role of the previous Commission. It discusses the Council's current mandate and structure, as well as U.S. policy and congressional actions.
Date: June 5, 2008
Creator: Blanchfield, Luisa
Object Type: Report
System: The UNT Digital Library
The United Nations Human Rights Council: Issues for Congress (open access)

The United Nations Human Rights Council: Issues for Congress

This report provides historical background of the Council, including the role of the previous Commission. It discusses the Council's current mandate and structure, as well as U.S. policy and congressional actions.
Date: June 5, 2008
Creator: Blanchfield, Luisa
Object Type: Report
System: The UNT Digital Library
Air Force Aerial Refueling Methods: Flying Boom versus Hose-and-Drogue (open access)

Air Force Aerial Refueling Methods: Flying Boom versus Hose-and-Drogue

Decisions on the composition of the Air Force aerial refueling fleet were made decades ago, when the primary mission was to refuel long-range strategic bombers. Modifications have been made to many of these tanker aircraft (KC-135s and KC-10s) to make them more effective in refueling fighter aircraft. This report examines the balance between two different refueling methods in today's refueling fleet -- "flying boom" and "hose-and-drogue."
Date: June 5, 2006
Creator: Bolkcom, Christopher
Object Type: Report
System: The UNT Digital Library
Air Force Aerial Refueling Methods: Flying Boom Versus Hose-and-Drogue (open access)

Air Force Aerial Refueling Methods: Flying Boom Versus Hose-and-Drogue

This report considers the refueling fleet for the Air Force. The report examines two different refueling methods.
Date: June 5, 2006
Creator: Bolkcom, Christopher
Object Type: Report
System: The UNT Digital Library
Air Force FB-22 Bomber Concept (open access)

Air Force FB-22 Bomber Concept

The Air Force has expressed interest in developing a bomber variant of the F-22A Raptor to "bridge the gap" between today's bombers and a follow-on bomber in 2037. Questions exist regarding the FB-22's feasibility, cost, and combat potential.
Date: June 5, 2006
Creator: Bolkcom, Christopher
Object Type: Report
System: The UNT Digital Library
Military Suppression of Enemy Air Defenses (SEAD): Assessing Future Needs (open access)

Military Suppression of Enemy Air Defenses (SEAD): Assessing Future Needs

Suppressing enemy air defenses (SEAD) has been a central element of projecting military air power for over 50 years. However, several developments suggest that this mission is of growing importance to the Department of Defense (DOD). Some say that the emergence of new technologies and air defenses will increasingly challenge U.S. SEAD efforts. Making budgetary judgments on SEAD programs and processes requires the assessment of complex factors.
Date: June 5, 2006
Creator: Bolkcom, Christopher
Object Type: Report
System: The UNT Digital Library
Non-Axisymmetric Shaping of Tokamaks Preserving Quasi-Axisymmetry (open access)

Non-Axisymmetric Shaping of Tokamaks Preserving Quasi-Axisymmetry

If quasi-axisymmetry is preserved, non-axisymmetric shaping can be used to design tokamaks that do not require current drive, are resilient to disruptions, and have robust plasma stability without feedback. Suggestions for addressing the critical issues of tokamaks can only be validated when presented with sufficient specificity that validating experiments can be designed. The purpose of this paper is provide that specificity for non-axisymmetric shaping. To our knowledge, no other suggestions for the solution of a number of tokamak issues, such as disruptions, have reached this level of specificity. Sequences of three-field-period quasi-axisymmetric plasmas are studied. These sequences address the questions: (1) What can be achieved at various levels of non-axisymmetric shaping? (2) What simplifications to the coils can be achieved by going to a larger aspect ratio? (3) What range of shaping can be achieved in a single experimental facility? The sequences of plasmas found in this study provide a set of interesting and potentially important configurations.
Date: June 5, 2009
Creator: Boozer, Long-Poe Ku and Allen H.
Object Type: Report
System: The UNT Digital Library