Thermoelectric material development. Quarterly technical progress report, January 1, 1995--March 31, 1995 (open access)

Thermoelectric material development. Quarterly technical progress report, January 1, 1995--March 31, 1995

We have found that there is a limited range of solid solutions between the skutterudite compounds CoSb{sub 3} and RuSb{sub 2}Te (about 5% on each side). For the system (RuSb{sub 2}Te){sub x}(CoSb{sub 3}){sub 1-x}, preliminary results obtained on one n-type sample on the CoSb{sub 3}-rich side show that these alloys have good thermoelectric properties and a maximum ZT of about 0.89 was obtained at about 600 C. More experiments will be started to investigate the possibility of a broader range of miscibility in this system which would allow an even further decrease in the lattice thermal conductivity, resulting in better thermoelectric properties. IrSb{sub 3} and RuSb{sub 2}Te form a complete range of solid solutions. Hot-pressed samples in this system have shown p-type conductivity. The thermoelectric properties of these p-type alloys have been measured and results have shown that their potential for thermoelectric applications is limited mainly because of the relatively low Seebeck coefficient values for p-type materials. Efforts will be directed on preparing n-type samples of the same alloys by doping with various dopants such as Ni and Pd.
Date: July 1, 1995
Creator: Vandersande, J.W. & Caillat, T.
System: The UNT Digital Library
High-Temperature Cyanide Leaching of Platinum-Group Metals from Automobile Catalysts--Pilot Plant Study (open access)

High-Temperature Cyanide Leaching of Platinum-Group Metals from Automobile Catalysts--Pilot Plant Study

From abstract: The U.S. Bureau of Mines Reno Research Center investigated, developed, and patented a high temperature cyanide leaching process for recovering platinum-group metals (PGM) from automobile catalysts. A batch pilot plant was constructed at the center and operated to demonstrate this technology to industry.
Date: 1995
Creator: Kuczynski, R. J.; Atkinson, G. B. & Dolinar, W. J.
System: The UNT Digital Library