The objective of this project is to evaluate and demonstrate a cost effective emission control technology for acid rain precursors, oxides of nitrogen (NO{sub x}) and sulfur (SO{sub x}), on two coal fired utility boilers in Illinois. The units selected are representative of pre-NSPS design practices: tangential and cyclone fired. A third unit, wall fired, is on hold'' because of funding limitations. The specific objectives are to demonstrate reductions of 60 percent in NO{sub x} and 50 percent in SO{sub x} emissions, by a combination of two developed technologies, gas reburning (GR) and sorbent injection (SI). With GR, about 80--85 percent of the coal fuel is fired in the primary combustion zone. The balance of this fuel is added downstream as natural gas to create a slightly fuel rich environment in which NO{sub x} is converted to N{sub 2}. The combustion process is completed by overfire air addition. SO{sub x} emissions are reduced by injecting dry sorbents (usually calcium based) into the upper furnace. The sorbents trap SO{sub x} as solid sulfates that are collected in the particulate control device.

This project revolves around understanding the fundamental processes involved in the catalytic removal of harmful oxygenated organics present in coal liquids. We will model the complex type of sulfided Mo catalyst proposed for these reactions with a simple single crystal surfaces that display a controlled range and number of reaction sites and can be extensively characterized by surface science techniques.

The objective of proposed research is development of catalysts with enhanced slurry phase activity and better selectivity to fuel range products, through a more detailed understanding and systematic studies of the effects of pretreatment procedures and promoters/binders (silica) on catalyst performance.

This project is designed to develop methods for pre-combustion coal remediation by implementing recent advances in enzyme biochemistry. The novel approach of this study is incorporation of hydrophilic oxidative enzymes in reverse micelles in an organic solvent. Enzymes from commercial sources or microbial extracts are being investigated for their capacity to remove organic sulfur from coal by oxidation of the sulfur groups, splitting of C-S bonds and loss of sulfur as sulfuric acid. Dibenzothiophene (DBT) and ethylphenylsulfide (EPS) are serving as models of organic sulfur-containing components of coal in initial studies.

We present several software implementations of the elementary functions sin and cos designed to fit a large class of machines. Implementation details are provided. We also provide a detailed error analysis that bounds the errors of these implementations, over the full range of input arguments, from 0.721 to 0.912 units in the last place. Tests performed on these codes give results that are consistent with the error bounds.

The results of the environmental monitoring program conducted at Site A/Plot M in the Palos Park Forest Preserve area for CY 1989 are presented. The monitoring program is the ongoing remedial action that resulted from the 1976-1978 radiological characterization of the site. That study had determined that very low levels of hydrogen-3 (as tritiated water) migrated from the burial ground and was present in two nearby hand-pumped picnic wells. The current program consists of sample collection and analysis of air, surface and subsurface water, and bottom sediment.

This report discusses the results of the environmental monitoring program at Argonne National Laboratory (ANL) for 1989. To evaluate the effects of ANL operations on the environment, samples of environmental media collected on the site, at the site boundary, and off the ANL site were analyzed and compared. A variety of radionuclides were measured in air, surface water, groundwater, soil, grass, bottom sediment, and milk samples.

In FY 1987, a program was initiated to demonstrate technology for recovering transuranic (TRU) elements from defense wastes. This hot demonstration was to be carried out with solution from the dissolution of irradiated fuels. This recovery would be accomplished with both PUREX and TRUEX solvent extraction processes. Work planned for this program included preparation of a shielded-cell facility for the receipt and storage of spent fuel from commercial power reactors, dissolution of this fuel, operation of a PUREX process to produce specific feeds for the TRUEX process, operation of a TRUEX process to remove residual actinide elements from PUREX process raffinates, and processing and disposal of waste and product streams. This report documents the work completed in planning and starting up this program. It is meant to serve as a guide for anyone planning similar demonstrations of TRUEX or other solvent extraction processing in a shielded-cell facility.

The mission of the Analytical Services Group (ASG) is to provide analytical support for Savannah River Laboratory Research and Development Programs using onsite and offsite analytical labs as resources. A second mission is to provide Savannah River Site (SRS) operations with analytical support for nonroutine material characterization or special chemical analyses. The ASG provides backup support for the SRS process control labs as necessary.

This Report, the first of the neuroscience series, discusses the risks posed by neurotoxic substances—substances that can adversely affect the nervous system—and evaluates the Federal research and regulatory programs now in place to address these risks.

This is the second of two OTA assessments on the subject of high-temperature superconductivity (HTS). As the title suggests, this study attempts to put HTS in perspective, both in terms of competing technologies (e.g., the more mature low-temperature superconductors), and in terms of the many technical and economic problems that must be overcome before HTS can be widely used.

This report is the final, summarizing report in a series of products from a broad assessment of space transportation technologies undertaken by OTA for the Senate Committee on Commerce, Science, and Transportation, and the House Committee on Science, Space, and Technology.

The House Committee on Government Operations, Subcommittee on Human Resources and Intergovernmental Relations asked the Office of Technology Assessment (OTA) to document the extent to which federally funded research on AIDS/HIV has contributed to advances in other fields including biomedical and behavior research, prevention, patient care, and health care financing. In response to this request OTA conducted a survey of distinguished biomedical and social scientists. This Staff Paper reports on the results of that survey.

A master plan for the Yakima/Klickitat Production Project (YKPP) was developed by the Northwest Power Planning Council (Council) on October 15, 1987, as a reasonable basis upon which the Bonneville Power Administration (BPA) could proceed to fund predesign work on the project. The Council approved the predesign work on the condition that eight preliminary tasks were completed. These tasks are: Task 1. Agreement on a refined statement of project goals. Task 2. Completion of a technical analysis of water supplies. Task 3. Completion of an experimental design plan. Task 4. Development of a harvest management plan. Task 5. Assessment of potential genetic risks. Task 6. Project coordination with all other affected parties. Task 7. Submission of a preliminary design report to the Council. Task 8. Develop a project management structure. The preliminary design report summarizes the work completed on these tasks. It provides a description of the preliminary design, engineering, and construction phases of project development, and gives an estimate of project costs. Also included is a description of other studies that were conducted to support YKPP planning. The results of studies conducted during the last 30 months indicate that hatchery facilities can be built in the Yakima and Klickitat …

The major accomplishments of our initial research period (August 1, 1987, to March 1, 1990) are as follows; we completed construction of the experimental facility. Originally, it had been our intent to modify an existing facility in our laboratory. When this became impractical we constructed a new stand-alone facility. Modified an existing three-dimensional numerical code developed in our laboratory, SEAFLOS1, by incorporating a salinity transport equation. Developed experimental and analytical techniques, and performed both physical and numerical experiments for a wide range of initial and boundary conditions. Focused our overall research effort to answer the following four questions pertaining to the formation of convective intrusions due to lateral temperature gradients established by sidewall heating. (1) What is the internal structure of the convective intrusions as a function of the initial stratification and sidewall heating rates (2) What is the correct scaling for the initial vertical dimension of the intrusions (3) How does the merging process vary as a function of initial stratification and sidewall heating rate (4) Is the sidewall heating critical for continued propagation of the intrusions, or is it merely a trigger which releases the internal instability in the fluid

A 7-Day Full Series Chronic Toxicity test was conducted April 13--20, 1990, for the Savannah River Site to assess the chronic toxicity of Simulated defense waste processing facility (DWPF) effluent to Ceriodaphnia dubia. The simulated effluented consisted of Sodium Nitrate, Sodium Oxalate, Sodium Formate, and Corros. Inib.

The objective of the program was to develop an advanced coal combustion system for firing beneficiated coal fuels (BCFs) capable of being retrofitted to industrial boilers originally designed for firing natural gas. The High Efficiency Advanced Coal Combustor system is capable of firing microfine coal-water fuel (MCWF), MCWF with alkali sorbent (for SO{sub 2} reduction), and dry microfine coal. Design priorities for the system were that it be simple to operate and offer significant reductions in NO{sub x}, SO{sub x}, and particulate emissions as compared with current coal-fired combustor technology. (VC)

Much work has been devoted to methods for reasoning about the specifications of operating system specifications, the goal being to develop specifications for an operating system that are verified to be secure. Before the verification should be attempted, the specifications should be tested. This paper presents tools that can assist in the security testing of specifications. The first tool is based on the final Algebra Specification and Execution (FASE) system, and would be used to test specifications with real input values. FASE is an executable specification language which is operational in style, in which entities are represented in terms of their observable behavior. To facilitate the testing of an operating system (and its specification), use FASE we have specified a Secure Resource Manager (SRM), a generic template of an operating system. The SRM specification can be specialized to a specification of a particular operating system; the SRM is quite general and handles most features of modern nondistributed operating systems. The second tool, called the PLANNER, is used to derive a sequence of operations that exhibits a security flaw, most often a covert channel for information flow. The PLANNER is based on classical methods of AI planning, specialized to achieve goals …

One of the early tasks of the Atmospheric Radiation Measurements (ARM) Program is to provide climatic guides for site selection purposes including possible continental, regional, local and on-site locations. The first guide A Preliminary ARM Guide for Climatic Evaluations'' provided some climate data on a continental scale; this one is an attempt to show the variability that exists over a region. Kansas was chosen for this particular guide because it satisfies most of the requirements given in the ARM Program Plan, i.e., climatic significance, potential for synergism with other programs and scientific and logistical viability. Kansas has extreme climatic variations, is centrally located, is compatible with other large scale programs (Fife), has good airfields and accommodations to minimize time and effort in planning and operating an ARM site for continuous use and special campaigns.

This is the final report of the High Burnup Effects Program (HBEP). It has been prepared to present a summary, with conclusions, of the HBEP. The HBEP was an international, group-sponsored research program managed by Battelle, Pacific Northwest Laboratories (BNW). The principal objective of the HBEP was to obtain well-characterized data related to fission gas release (FGR) for light water reactor (LWR) fuel irradiated to high burnup levels. The HBEP was organized into three tasks as follows: Task 1 -- high burnup effects evaluations; Task 2 -- fission gas sampling; and Task 3 -- parameter effects study. During the course of the HBEP, a program that extended over 10 years, 82 fuel rods from a variety of sources were characterized, irradiated, and then examined in detail after irradiation. The study of fission gas release at high burnup levels was the principal objective of the program and it may be concluded that no significant enhancement of fission gas release at high burnup levels was observed for the examined rods. The rim effect, an as yet unquantified contributor to athermal fission gas release, was concluded to be the one truly high-burnup effect. Though burnup enhancement of fission gas release was observed to …

The specific objectives of the bituminous coal program were to explore and evaluate the application of advanced agglomeration technology for: (1)desulphurization of bituminous coals to sulphur content acceptable within the current EPA SO{sub 2} emission guidelines; (2) deashing of bituminous coals to ash content of less than 10 percent; and (3)increasing the calorific value of bituminous coals to above 13,000 Btu/lb. (VC)

In the second year of the current funding period, we continued the study of the following reactions: C({sup 1}D) + H{sub 2} {yields} CH(X{sup 2}{Omicron}) + H, {Delta}H = {minus}6.0 kcal.mol{sup {minus}1}; C({sup 1}D) + HCl {yields} CH(X{sup 2}{Omicron}) + Cl, {Delta}H = 7.0 kcal.mol{sup {minus}1}; and C({sup 1}D) + HCl {yields} CCl(X{sup 2}{Omicron}) + H, {Delta}H = {minus}5.8 kcal.mol{sup {minus}1}. In particular, we concentrated on three issues: the use of two-photon photolysis of C{sub 3}O{sub 2} as a source of C({sup 1}D); the mechanisms of the above reactions and conditions for reliable LIF diagnostics for the CH radical. These studies involved solving several problems both in the generation of C({sup 1}D) and the determination of rotational, spin-orbit and {Lambda}-doublet populations in CH, but they are now nearing completion, and will be written up for publication in the summer. In the third year, we plan to concentrate on three topics: (1) the construction of an efficient laser ablation source for C({sup 3}P); (2) the study of the reaction of C({sup 3}P) with N{sub 2}O and detection of CN and NO products, and (3) a new direction in our lab: enhancement of endoergic reactions of C({sup 3}P) via vibrational excitation of …

The overall objectives of this project is to use Molecular Genetics to develop strains of bacteria (esp. Rhodococcus) with enhanced ability to remove sulfur from coal, and to obtain data that will allow the performance and economics of a coal biodesulfurization process to be predicted. 5 figs.

During the second quarter of work on this new project, critical review of the literature continued. Several new references related to gravity separation were identified and evaluated. A synopsis was assembled to summarize techniques developed by various researchers for the float/sink separation of ultrafine coal. In the reviewed literature, it was commonly concluded that substantial improvements in washability results for ultrafine coals can be obtained only through the application of dynamic (centrifugal) procedures, and through the use of dispersing aids such as ultrasound and surfactants. These results suggest the presence of physicochemical phenomena, typical of colloidal systems. In theoretical studies this quarter, the effects of Brownian motion on fine particle sedimentation have been identified and theoretically quantitated. The interaction between Brownian and gravitational forces was calculated, and a model was prepared to permit estimation of critical particle size in float/sink separations. In laboratory studies this quarter, aliquots of Upper Freeport coal were prepared and subjected to laboratory float/sink separations to investigate the relative effectiveness of static and centrifugal techniques for fine and ultrafine coal. This series will verify results of earlier work and provide a basis for comparing the effects which may result from further modifications to the separation techniques …