The progress made during the current grant period (1 January 1988--1 April 1990) in three different areas of research is summarized. The research areas are: (1) oxidatively-induced double carbonylation reactions to form {alpha}-ketoacyl complexes and studies of the reactivity of the resulting compounds, (2) mechanistic studies of the carbonylation of nitroaromatics to form isocyanates, carbamates, and ureas, and (3) studies of the formation and reactivity of unusual metallacycles and alkylidene ligands supported on binuclear iron carbonyl fragments. 18 refs., 5 figs., 1 tab.

This document summarizes progress made on the research of high beta and second region transport and stability. In the area second stability region studies we report on an investigation of the possibility of second region access in the center of TFTR supershots.'' The instabilities found may coincide with experimental observation. Significant progress has been made on the resistive stability properties of high beta poloidal supershot'' discharges. For these studies profiles were taken from the TRANSP transport analysis code which analyzes experimental data. Invoking flattening of the pressure profile on mode rational surfaces causes tearing modes to persist into the experimental range of interest. Further, the experimental observation of the modes seems to be consistent with the predictions of the MHD model. In addition, code development in several areas has proceeded.

Nitrate and nitrite have been almost completely removed from the synthetic effluent steam with good efficiency by affecting a separation across a pair of ion exchange membranes. In addition to recovering acid and base in this process, the volume of the remaining effluent is reduced considerably by transport of water across the membrane. One of the problems that remains with this process, however, is the stability of the membranes and particularly the stability of the anion exchange membrane. This membrane is exposed to both nitric acid and strongly alkaline solutions in the cell and to date long term stability has been a problem with the membranes tested. It is recommended that further work should evaluate other newly available membranes as well as study the effects of radiation on the performance of the membranes. The direct reduction of nitrate and nitrite has been studied at several different electrode materials and it has been demonstrated that cathode material has a large effect on both the efficiency and the gas product distribution. Highest current efficiencies for the reduction process are seen at those electrode materials that are known to show high hydrogen overpotentials. Flow cell studies have demonstrated that temperature and current density …

The objectives of the project are to discover and evaluate novel catalytic systems for the conversion of methane or by-product light hydrocarbon gases either indirectly (through intermediate light gases rich in C{sub 2}'s) or directly to liquid hydrocarbon fuels, and to evaluate, from an engineering perspective, different conceptualized schemes. The approach is to carry out catalyst testing on several specific classes of potential catalysts for the conversion of methane selectively to C{sub 2} products. The behavior of alkaline earth/metal oxide/halide catalysts containing strontium was found to be different from the behavior of catalysts containing barium. Two approaches were pursued to avoid the heterogeneous/homogeneous mechanism in order to achieve higher C{sub 2} selectivity/methane conversion combinations. One approach was to eliminate or minimize the typical gas phase combustion chemistry and make more of the reaction occur on the surface of the catalyst by using silver. Another approach was to change the gas phase chemistry to depart from the typical combustion reaction network by using vapor-phase catalysts. The layered perovskite K{sub 2}La{sub 2}Ti{sub 3}O{sub 10} was further studied. Modifications of process and catalyst variables for LaCaMnCoO{sub 6} catalysts resulted in catalysts with superior performance. Results obtained with a literature catalyst Na{sub 2}CO{sub 3}/Pr{sub …

Technology developed by the late Dr. Felix Sebba of the VPI Chemical Engineering Department by which an oil phase can be broken up into small droplets and encapsulated in a continuous water phase led to research on the possible merits of a fuel prepared by this procedure. The resulting mixture is called a polyaphron. Part 1 of this report describes the testing of polyaphronated gasoline in an automobile engine. Nitrogen oxides (NO{sub x}) emissions, total hydrocarbon (HC) emissions, and exhaust temperature were determined for various load and RPM combinations. Difficulties with viscosity and separation of the water phase have prevented complete testing at road load conditions. Rather than continue with engine testing, some bench tests of polyaphrons were performed to see the effect of various filtering processes on fuel stability as well as measuring viscosity and density. These results are reported in Part 2 of this paper. 6 figs., 4 tabs.

The purpose of this project was to provide team members with practical experience in application of Civil Engineering 555, Solid Waste Management principles. Team members chose to evaluate the functional elements of the Oak Ridge Y-12 Plant's (Y-12's) solid waste management system. The following factors contributed to selection of Y-12'system for evaluation: team members' familiarity with the Y-12 system; knowledge that the Y-12 Centralized Sanitary Landfill II was nearing capacity; and presence of the unique issues posed by special national security and potential radioactive contamination considerations. This report was limited to evaluation of the solid waste management system for conventional solid waste; hazardous radioactive, and radioactive mixed waste were not addressed. The report: (1) describes each functional element including waste generation, storage, collection, transport, processing, recovery, and disposal; (2) identifies and evaluates alternatives for each element and (3) identifies system strengths and recommends opportunities for improvement. 34 figs.

The production of top at the Fermilab Tevatron D0 detector was investigated using full Monte Carlo and event reconstruction packages. In total, 480 events were generated for m{sub T} = 150 GeV/c{sup 2} in the specific t({bar t}) {yields} b({bar b}) + W{sup {plus minus}}, with at least one W decaying to leptons. These events were then analyzed in an attempt to find characteristic signals for top production at D0. 21 figs.

The Electric Power Monthly (EPM) is prepared by the Electric Power Division; Office of Coal, Nuclear, Electric and Alternate Fuels, Energy Information Administration (EIA), Department of Energy. This publication provides monthly statistics at the national, Census division, and State levels for net generation, fuel consumption, fuel stocks, quantity and quality of fuel, cost of fuel, electricity sales, and average revenue per kilowatthour of electricity sold. Data on net generation are also displayed at the North American Electric Reliability Council (NERC) region level. Additionally, company and plant level information are published in the EPM on capability of new plants, net generation, fuel consumption, fuel stocks, quantity and quality of fuel, and cost in fuel. Quantity, quality, and cost of fuel data lag the net generation, fuel consumption, fuel stocks, electricity sales, and average revenue per kilowatthour data by 1 month. This difference in reporting appears in the national, Census division, and State level tables. However, at the plant level, all statistics presented are for the earlier month for the purpose of comparison. 12 refs., 4 figs., 48 tabs.

This report discusses the following basic research accomplishments: new x-ray structure determination methods were developed and applied to biomembrane lipid phases; a novel mechanism for general anesthesia was proposed; the elastic properties of membranes were investigated, both theoretically and experimentally; the effects of high pressures on membranes were studied; neutron diffraction was used to probe mesophase structure; and novel lipid and surfactant systems are characterized. Also discussed are instrumentation accomplishments.

This report discusses the following topics on the ARIES tokamak: systems; plasma power balance; impurity control and fusion ash removal; fusion product ripple loss; energy conversion; reactor fueling; first wall design; shield design; reactor safety; and fuel cost and resources. (LSP)

The primary objective of the collaborative studies with EITU was to study curium bismuthide using energy dispersive X-ray diffraction to monitor its structure as a function of pressure. This objective was accomplished and the material was investigated up to 0.48 megabars of pressure. These studies were a continuation of established and productive collaborations between ORNL and EITU. The study of this curium compound is significant in that it is the first 5f-element bismuthide to be studied under pressure. Bismuth has the highest Z and the largest radius of the pnictogen group of elements (important for Hill Plot assessments) and has the greatest potential to form f-p type bonding with actinides under pressure. From a preliminary assessment of our experimental data it has been determined that two structural transitions occurred in the curium bismuthide sample as a result of the applied pressure.

The countercurrent flow (CCF) performance in the fuel element region of the HFIR is examined experimentally and theoretically. The fuel element consists of two concentric annuli filled with aluminum clad fuel plates of 1.27 mm thickness separated by 1.27 mm flow channels. The plates are curved as they go radially outward to accomplish constant flow channel width and constant metal-to-coolant ratio. A full-scale HFIR fuel element mock-up is studied in an adiabatic air-water CCF experiment. A review of CCF models for narrow channels is presented along with the treatment of CCFs in system of parallel channels. The experimental results are related to the existing models and a mechanistic model for the annular'' CCF in a narrow channel is developed that captures the data trends well. The results of the experiment are used to calculate the CCFL heat flux of the HFIR fuel assembly. It was determined that the HFIR fuel assembly can reject 0.62 Mw of thermal power in the CCFL situation. 31 refs., 17 figs.

The traveler participated in a conference on environmental technology in Paris, sponsored by the US Embassy-Paris, US Environmental Protection Agency (EPA), the French Environmental Ministry, and others. The traveler sat on a panel for environmental aspects of energy technology and made a presentation on the potential contributions of Oak Ridge National Laboratory (ORNL) to a planned French-American Environmental Technologies Institute in Chattanooga, Tennessee, and Evry, France. This institute would provide opportunities for international cooperation on environmental issues and technology transfer related to environmental protection, monitoring, and restoration at US Department of Energy (DOE) facilities. The traveler also attended the Fourth International Conference on Environmental Contamination in Barcelona. Conference topics included environmental chemistry, land disposal of wastes, treatment of toxic wastes, micropollutants, trace organics, artificial radionuclides in the environment, and the use biomonitoring and biosystems for environmental assessment. The traveler presented a paper on The Fate of Radionuclides in Sewage Sludge Applied to Land.'' Those findings corresponded well with results from studies addressing the fate of fallout radionuclides from the Chernobyl nuclear accident. There was an exchange of new information on a number of topics of interest to DOE waste management and environmental restoration needs.

The objective of this travel was to advance provisional planning of an activity to coordinate research and development (R D) activities on fusion materials among the existing fusion materials R D programs of the ITER parties. This objective was accomplished in discussions with the Executive Committee for the IEA Implementing Agreement on Fusion Materials in Karlsruhe, Germany, and with the ITER management and staff of Garching, Germany. The IEA Executive Committee deferred substantive consideration of the topic at the insistence of the Ex-Officio member from European Community (EC), Brussels. Discussions with ITER management and staff were positive. It was noted the the draft ITER Long-Term Technology Research and Development Plan contains recommendations for major program effort in materials R D and includes recommendations for coordination among the existing programs of the parties to meet those materials R D needs. ITER management discussions were in the context that decisions on specific activities for the ITER engineering design activity (EDA) must await formal action by the parties on the ITER EDA.

Physicists in HEP have been forced to organize large scientific projects without a well defined organizational or sociological model to guide them. In the absence of such models, what structures do experimentalists use to develop social structures in HEP In this paper, I claim that physicists organize around what they know best, the physics problems they study and the detectors and devices they study them with. After describing the advent of management'' in HEP, I use a case study of 4 Fermilab experiments as the base upon which to propose a physics and detector driven model of social structure for experiments. In addition, I show how this model can be extended to describe strings'' of experiments, where continuities of physics interests, spectrometer design, and a core group of physicists become a definable sociological unit that can exist for over 15 years. A dominate theme that emerges from my analysis is the conscious attempt on the part of experimenters to remove the uncertainties that are part of the practice of HEP.

This report includes: MgCl{sub 2} purification and molten salt preparation facilities have been completed at both the University of Tennessee, Knoxville, and Oak Ridge National Laboratory. The purification of MgCl{sub 2} is being studied. Initial Raman spectral results have been obtained at both facilities. Two analytical spectral techniques involving near-infrared (NIR) and IR reflectance spectral measurements show promise for identifying and quantifying OH species in solid salts of interest. A sealed IR reflectance cell has been developed for use in the project. An electrochemical cell for use in voltammetric studies concerned with the project has been designed and fabricated. 5 refs., 2 figs.

Experiments in high energy physics require high density and high speed mass storage. Mass storage is needed for data logging during the online data acquisition, data retrieval and storage during the event reconstruction and data manipulation during the physics analysis. This paper examines the storage and speed requirements at the first two stages of the experiments and suggests a possible starting point to deal with the problem. 3 refs., 3 figs.

In order to help answer questions about the magnitude of heat flux to the liquid argon in a liquid argon calorimeter which could cause boiling (bubbles), calculations estimating the heat flux which can be removed by free convection were made in February, 1988. These calculations are intended to be an estimate of the heat flux above which boiling would occur. No formal writeup was made of these calculations, although the graph dated 3 Feb 88 and revised (adding low-velocity forced convection lines) 19 Feb 88 was presented in several meetings and widely distributed. With this description of the calculations, copies of the original graph and calculations are being added to the D0 Engineering Note files. The liquid argon surface is in equilibrium with argon vapor at a pressure of 1.3 bar, so the surface is at 89.70 K. The liquid is entirely at this surface temperature throughout the bulk of the volume, except locally where it is warmed by a solid surface at a higher temperature than the bulk liquid. This surface temperature is taken to be the boiling temperature of argon at the pressure corresponding to 1.3 bar plus the liquid head; hence it is a function of depth …

Nitrate and nitrite have been almost completely removed from the synthetic effluent steam with good efficiency by affecting a separation across a pair of ion exchange membranes. In addition to recovering acid and base in this process, the volume of the remaining effluent is reduced considerably by transport of water across the membrane. One of the problems that remains with this process, however, is the stability of the membranes and particularly the stability of the anion exchange membrane. This membrane is exposed to both nitric acid and strongly alkaline solutions in the cell and to date long term stability has been a problem with the membranes tested. It is recommended that further work should evaluate other newly available membranes as well as study the effects of radiation on the performance of the membranes. The direct reduction of nitrate and nitrite has been studied at several different electrode materials and it has been demonstrated that cathode material has a large effect on both the efficiency and the gas product distribution. Highest current efficiencies for the reduction process are seen at those electrode materials that are known to show high hydrogen overpotentials. Flow cell studies have demonstrated that temperature and current density …

Research programs from NIPER are briefly summarized. Topics include: Development of Analytical Methodology for Analysis of Heavy Crudes, and Thermochemistry and Thermophysical Properties of Organic Nitrogen- and Diheteroatom-Containing Compounds. 1 ref.

Microprocessor farms have been successfully employed in high energy physics for both offline analysis and online triggers. As the experiments continue to grow in size, so do the demands for processing power. The preliminary indications are that the large collider experiments will require at least a million VAX-11/780 equivalents of processing power for online trigger decisions and offline event reconstruction. This paper examines the current technology trends and projects the processing power that may be expected with the current farm architectures. 3 refs., 6 figs.

One of the goals of biomedical research is the development of imaging techniques capable of producing high resolution ({approximately}300{Angstrom}) three dimensional images of structures within live cells. Recent developments in zone plate lenses at LBL and in x-ray lasers at LLNL indicate that flash three dimensional x-ray microscopy of live biological objects can be achieved in the near term. This concept for a microscope utilizes an x-ray laser to backlit immunogold labeled biological objects. These backlit objects are then imaged with low f-number, high resolution zone plate lenses. Backlighting and imaging along several different directions allows a three dimensional image to be obtained using tomographic techniques.

The Fifth International Conference on the Physics of Highly Charged Ions drew more than 200 participants, providing an excellent overview of this growing field. Important technical developments and experimental results in electron-ion collisions were reported. The merging of fast ion beams from accelerators or storage rings with advanced high-intensity electron-beam targets has yielded data of unprecedented quality on radiative and dielectronic recombination, providing stringent tests of theory. Long-awaited technical innovations in electron-impact excitation measurements were also reported. The level of activity in multicharged ion-surface interactions has increased. More sophisticated experimental studies of the neutralization process have shown the inadequacy of previously accepted mechanisms, and theoretical activity in this area is just being initiated. The IAEA meetings addressed atomic and molecular data needs for fusion research, with ITER providing a key focus. Such data are especially critical to modeling and diagnostics of the edge plasma. The ALADDIN data base system has been universally accepted and has streamlined the exchange of numerical data among data centers and the fusion community. The IAEA continues to play a pivotal role in the identification of data needs, and in the coordination of data compilation and research activities for fusion applications.

The inner vessel heads including bypass and beam tubes had just been welded into place and dye penetrant checked. The vacuum heads were not on at this time but the vacuum shell was on covering the piping penetrating into the inner vessel. Signal boxes with all feed through boards, the instrumentation box, and high voltage boxes were all installed with their pump outs capped. All 1/4-inch instrumentation lines were terminated at their respective shutoff valves. All vacuum piping used for pumping down the inner vessel was isolated using o-ring sealed blind flanges. PV215A (VAT Series 12), the 4-inch VRC gate valve isolating the cyropump, and the rupture disk had to be removed and replaced with blind flanges before pressurizing due to their pressure limitations. Stresses in plates used as blind flanges were checked using Code calcualtions. Before the CC test, vacuum style blanks and clamps were hydrostatically pressure tested to 150% of the maximum test pressure, 60 psig. The Code inspector and Research Division Safety had all given their approval to the test pressure and procedure prior to filling the vessel with argon. The test was a major success. Based on the lack of any distinguishable pressure drop indicated on …