The temperature of a char particle burning in an oxygen containing atmosphere is the product of a strongly coupled balance between particle size and physical properties, heat transfer from the particle, surface reactivity, CO/CO{sub 2} ratio and gas phase diffusion in the surrounding boundary layer and within the particle. CO{sub 2}/CO ratios can be strongly influenced by catalytic material in the carbon and by the char temperature. In this program we are measuring the CO{sub 2}/CO ratio for both catalyzed and uncatalyzed chars over a wide range of temperature. These results will then be used to develop predictive models for char temperature and burning rates. The electrodynamic balance has been successfully used to make such measurements for single 200{mu}m spherocarb particles. A few theoretical approaches to model a single particle oxidation have been made, but most of them assumed the infinitely thin reaction zone at the particle surface. This approach can not explain pore diffusion limitation, structural change, or reaction at low temperatures inside the particle. Too simplifying solid phase reaction may leads to wrong predictions. In this report, progress on constructing models including both solid and gas phase reaction are reported.

During this period, we focused our attention in analyzing the magnetic nature of the extensively used trimetallic catalyst system Cu-Co-Cr for the production of higher alcohols. We believe that there could be some correspondence between the catalytic and magnetic behaviors of the transition metal catalyst systems. Both the morphology and metallic charge distribution of the particles are known to govern the catalytic as well as the magnetic properties of the system.

In the design of superconducting magnet elements, such as may be required to guide and focus ions in a particle accelerator, one frequently premises some particular current distribution and then proceeds to compute the consequent magnetic field through use of the laws of Biot and Savart or of Ampere. When working in this manner one of course may need to revise frequently the postulated current distribution before arriving at a resulting magnetic field of acceptable field quality. It therefore is of interest to consider an alternative ( inverse'') procedure in which one specifies a desired character for the field required in the region interior to the winding and undertakes then to evaluate the current distribution on the specified winding surface that would provide this desired field. We may note that in undertaking such an inverse procedure we would wish, on practical grounds, to avoid the use of any double-layer'' distributions of current on the winding surface or interface but would not demand that no fields be generated in the exterior region, so that in this respect the goal would differ in detail from that discussed by other authors, in analogy to the distribution sought in electrostatics by the so-caged Green's …

The Savannah River Site is developing a facility called the E-Area Vaults which will serve as the new radioactive waste disposal facility beginning early in 1992. The facility will employ engineered below-grade concrete vaults for disposal and above-grade storage for certain long-lived mobile radionuclides. This report documents the determination of interim upper limits for radionuclide inventories and concentrations which should be allowed in the disposal structures. The work presented here will aid in the development of both waste acceptance criteria and operating limits for the E-Area Vaults. Disposal limits for forty isotopes which comprise the SRS waste streams were determined. The limits are based on total facility and vault inventories for those radionuclides which impact groundwater, and or waste package concentrations for those radionuclides which could affect intruders.

Research activity during the 1991--1992 funding period has been concerned with the following topics relevant to carbon monoxide activation. (1) Exploratory studies of water gas shift catalysts heterogenized on polystyrene based polymers. (2) Mechanistic investigation of the nucleophilic activation of CO in metal carbonyl clusters. (3) Application of fast reaction techniques to prepare and to investigate reactive organometallic intermediates relevant to the activation of hydrocarbons toward carbonylation and to the formation of carbon-carbon bonds via the migratory insertion of CO into metal alkyl bonds.

The HB-Line building vacuum instrumentation and glovebox vacuum instrumentation at the Savannah River Plant are described. The configuration and operation of the Foxboro 834 series transmitters and Moore 350 series controllers is detailed. In particular, the uncertainties in the differential pressure readings are explained.

A weekly publication, the Texas Register serves as the journal of state agency rulemaking for Texas. Information published in the Texas Register includes proposed, adopted, withdrawn and emergency rule actions, notices of state agency review of agency rules, governor's appointments, attorney general opinions, and miscellaneous documents such as requests for proposals. After adoption, these rulemaking actions are codified into the Texas Administrative Code.

A weekly publication, the Texas Register serves as the journal of state agency rulemaking for Texas. Information published in the Texas Register includes proposed, adopted, withdrawn and emergency rule actions, notices of state agency review of agency rules, governor's appointments, attorney general opinions, and miscellaneous documents such as requests for proposals. After adoption, these rulemaking actions are codified into the Texas Administrative Code.

A weekly publication, the Texas Register serves as the journal of state agency rulemaking for Texas. Information published in the Texas Register includes proposed, adopted, withdrawn and emergency rule actions, notices of state agency review of agency rules, governor's appointments, attorney general opinions, and miscellaneous documents such as requests for proposals. After adoption, these rulemaking actions are codified into the Texas Administrative Code.

A weekly publication, the Texas Register serves as the journal of state agency rulemaking for Texas. Information published in the Texas Register includes proposed, adopted, withdrawn and emergency rule actions, notices of state agency review of agency rules, governor's appointments, attorney general opinions, and miscellaneous documents such as requests for proposals. After adoption, these rulemaking actions are codified into the Texas Administrative Code.

Document issued by the Office of the Attorney General of Texas in Austin, Texas, providing an interpretation of Texas law. It provides the opinion of the Texas Attorney General, Dan Morales, regarding a legal question submitted for clarification; Whether the provisions of House Bill 799 of the 72d Legislature apply to the procurement of brokerage and investment services by state agencies (RQ-239)

The hydroxylamine nitrate (HAN) precipitate hydrolysis process produces sufficient oxidant (nitrate) such that the resulting blend of formic acid treated sludge and the aqueous product from hydrolysis (PHA) produces a melter feed of acceptable redox (i.e. Fe+2/Total Fe <0.33). With implementation of Late Washing (to reduce the nitrite content of the tetraphenyborate slurry produced during In-Tank Precipitation to 0.01M or less), HAN is no longer required during hydrolysis. As a result, the nitrate content of the melter feed will be reduced greater than an order-of-magnitude and the resulting melter feed produced will be too reducing. If formic acid treatment of the sludge is retained, it will be necessary to trim the melter feed with an oxidant to attain a proper redox. Rather than trimming the melter feed with an oxidant subsequent to the SRAT cycle in which formic acid is used to acidify the sludge, the Savannah River Technology Center (SRTC) has recommended this be accomplished by conversion to nitric acid addition to the Sludge Receipt and Adjustment Tank (SRAT) in place of formic acid (1). This memorandum specifies the stoichiometric bases for determining the nitric acid requirement for the SRAT.

The HB-Line building vacuum instrumentation and glovebox vacuum instrumentation at the Savannah River Plant are described. The configuration and operation of the Foxboro 834 series transmitters and Moore 350 series controllers is detailed. In particular, the uncertainties in the differential pressure readings are explained.

The single particle equations for the longitudinal motion in a synchrotron can be faithfully represented as a one-turn mapping of a particle`s phase space position relative to the synchronous particle. Applied to a distribution of particles, the mapping can be used to model the evolution of bunches to test beam manipulations or to extract the time dependence of quantities like the bunching factor, momentum spread, etc. which can be difficult to calculate. Such modelling requires rather few representative particles, permitting numerical experimentation and exploratory design trials. By modifying the mapping each turn to introduce the collective effects of the distribution, one can model such processes as phase feedback, space-charge effects, coupled bunch motion, etc. Calculations of this type offer quantitative performance predictions, aid diagnosis of existing accelerators, and contribute to the understanding of the underlying dynamics. This talk introduces the tools and some illustrations.

This paper addresses problems of calibration and estimation of a parameter, p{sub o}, in high level neutron coincidence counting (HLNC) measurement. The presentation begins with a deductive approach, based on the generally accepted physical equations which are satisfied by the total and coincidence count rates. A new approach for the estimation of p{sub o} via measurement and a new calibration procedure consistent with the physical theory of coincidence counting measurement are presented. The approach is compared with the existing conventional approach in which possible inconsistency with the theoretical model is shown. In addition, the original model for neutron coincidence counting in a multiplying medium was extended to simultaneously account for the possible presence of poison, as well as for the neutron detection. The equations suitable for the data analysis of measurement of waste and their criteria are given.

During this period, we focused our attention in analyzing the magnetic nature of the extensively used trimetallic catalyst system Cu-Co-Cr for the production of higher alcohols. We believe that there could be some correspondence between the catalytic and magnetic behaviors of the transition metal catalyst systems. Both the morphology and metallic charge distribution of the particles are known to govern the catalytic as well as the magnetic properties of the system.

The Savannah River Site is developing a facility called the E-Area Vaults which will serve as the new radioactive waste disposal facility beginning early in 1992. The facility will employ engineered below-grade concrete vaults for disposal and above-grade storage for certain long-lived mobile radionuclides. This report documents the determination of interim upper limits for radionuclide inventories and concentrations which should be allowed in the disposal structures. The work presented here will aid in the development of both waste acceptance criteria and operating limits for the E-Area Vaults. Disposal limits for forty isotopes which comprise the SRS waste streams were determined. The limits are based on total facility and vault inventories for those radionuclides which impact groundwater, and or waste package concentrations for those radionuclides which could affect intruders.

Our goal is to improve the scientific basis for tumor diagnosis, treatment and treatment follow-up based on the use of cyclotron produced radiotracers in oncology. The grant includes 3 interactive components: Radiochemistry/Cyclotron; Pharmacology; and Immunology. The radiochemistry group seeks to develop innovative cyclotron targetry, radiopharmaceuticals, and radiolabeled antibodies, which are then used to assess important unanswered questions in tumor pharmacology and immunology. Examples include selected positron emitting radionuclides, such as Iodine-124, and Ga-66; I-124, I-123, I-131 labeled iododeoxyuridine, C-11 colchicine, and antimetabolites, like C-11 methotrexate; and radiolabeled antibodies, 3F8, M195, A33, and MRK16 for application in the pharmacology and immunology projects. The pharmacology program studies tumor resistance to chemotherapy, particularly the phenomenon of multidrug resistance and the relationship between tumor uptake and retention and the tumor response for anti-metabolite drugs. The immunology program studies the physiology of antibody localization at the tissue level as the basis for novel approaches to improving tumor localization such as through the use of an artificial lymphatic system which mechanically reduces intratumoral pressures in tumors in vivo. Quantitative imaging approaches based on PET and SPECT in radioimmunotherapy are studied to give greater insight into the physiology of tumor localization and dosimetry.

It has been observed for a number of the Zr catalysts that the maximum MCH conversion (ca. 20 wt.%) can be obtained in 15 min. using a reaction temperature of 150{degrees}C and 1 atm. of H{sub 2}, and no further reaction occurs during 120 minutes. Typical results for these catalysts as well as catalyst which show lower activities using the 15 min. residence time are shown in Figure 2. Both catalyst formulations, a Pt/ZrO{sub 2}/SO{sub 4} and a Fe/Mn/ZrO{sub 2}/SO{sub 4} show this behavior. The 15 minute conversion and the 2 hour conversion are not due to thermodynamic limitations. A series of experiments were completed using the Pt/ZrO{sub 2}/SO{sub 4} catalyst to obtain data to explain the maximum conversions obtained. In the first set of experiments a conversion versus residence time curve (Figure 3) was generated. The data shown in Figure 3 indicated a conversion curve with reaction time that is typical of the catalysts tested. In the next set of experiments, the amount of reactor volume which was occupied by the catalyst and feedstock was varied to determine if the reaction taking place in the liquid or gas phase was limiting the conversion of MCH. The MCH/catalyst ratio was …

Document issued by the Office of the Attorney General of Texas in Austin, Texas, providing an interpretation of Texas law. It provides the opinion of the Texas Attorney General, Dan Morales, regarding a legal question submitted for clarification: Whether a city council violates the Open Meetings Act when a majority of the council signs a letter that has not been authorized in an open meeting (RQ-252).

Document issued by the Office of the Attorney General of Texas in Austin, Texas, providing an interpretation of Texas law. It provides the opinion of the Texas Attorney General, Dan Morales, regarding a legal question submitted for clarification: Whether the Dallas Independent School District may give favored treatment to bidders based on the bidders’ residence, ownership of taxable improvements to real property in the district, and related questions (RQ-40)

Document issued by the Office of the Attorney General of Texas in Austin, Texas, providing an interpretation of Texas law. It provides the opinion of the Texas Attorney General, Dan Morales, regarding a legal question submitted for clarification: Whether persons appointed to boards and commissions by the commissioners court are subject to removal by the commissioners court (RQ-72)

Document issued by the Office of the Attorney General of Texas in Austin, Texas, providing an interpretation of Texas law. It provides the opinion of the Texas Attorney General, Dan Morales, regarding a legal question submitted for clarification: Authority of the Alcoholic Beverage Commission to adopt a rule regarding the sale of alcohol to minors (RQ-264)

Document issued by the Office of the Attorney General of Texas in Austin, Texas, providing an interpretation of Texas law. It provides the opinion of the Texas Attorney General, Dan Morales, regarding a legal question submitted for clarification; Whether the Uniform Compact on Juveniles by Texas authorizes and requires Texas juvenile probation officers to supervise delinquent juveniles as defined by the compact who would not be defined as juvenile delinquents under chaoter 51 of the Texas Family Code (RQ-106)