Technical report. From Abstract : "Irradiation of 'Dowex' 1, 'Permutit' S-1, and 'Permutit' SK anion exchange resins with alpha particles results in losses in ion exchange capacity and in 'apparent per cent crosslinkage'. The order of decreasing radiolytic stability for these properties in 'Permutit" SX > 'Permutit' S-1 > 'Dowex' 1."

Introduction: This is a final report on the evaluation of Kanigen electroless nickel plating for surfaces in contact with water and steam i a sodium heated AISI Type 316 stainless steel steam generator. The purpose of the coasting was to afford protection from stress corrosion cracking originating on the water-steam side of the unit. It has been concluded that the kanigen coating does not afford adequate protection for the services condition intended. This work was performed as part of the research and development program for the United States Atomic Energy Commission sodium Components Design Project.

"A broad range nuclear spectrograph of the Buechner-Bainbridge type, which characteristic radius R-50 cm. has been constructed and installed for use in conjunction with the Rochester 27" variable energy cyclotron. For a given magnetic field, particles are focused over an energy range 0.63o‹E‹1.3Eo, where Eo is the energy of particles focused with orbit radius Q-R-50 cm. The resolution of the spectrograph ∆E/E is less than 0.2%. Particles may be recorded either in nuclear emulsions or in an array of solid state counters. Results of calibration measurements and typical nuclear data taken with the spectrograph are presented."

"The previously found maximum in the cosmic radiation energy spectrum is discussed, and the possibility that it arises in part from a misinterpretation of the data due to oversimplifying assumptions about the composition of the beam is examined. The importance that lack of recognition of isotopic composition may have is pointed out, and it is clear that this importance is strongly dependent on the measurements made and on the cut-off rigidity."

Abstract: The acid hydrolysis of [Pt(NH3)3Cl] has been shown to occur to a measurable extent. for this reaction: [APt(NH3)cCl]+ + H2O [chemical equilibrium symbol with rate constant k-1 above and k1 below] [Pt(NH3)c(H2O)]++ + Cl-, the equilibrium quotient was measured at 25 degree C and 35 degree C. At 25 degree C this quotient was 8.4 x 10-5 at [Mu] (ionic strength) = 0 and 25 x 10-5 at [mu] = .318 M. This variation is consistent with the expected changes in activity coefficients. [Delta]H for the reaction was found to be approximately 0. The rate constant, k1 was 2.3 x 10-5 sec.-1 at 25 degree C and it was nearly independent of ionic strength. The acid hydrolysis provides a mechanism for the exchange of the chloride ligand and Cl-. Exchange experiments with Cl36 showed that in addition to the acid hydrolysis, a process, first order in both, [Pt(NH3)3Cl] and Cl- with a rate constant of 6. 10-5 sec.-1M.-1 contributes to the exchange. The behavior of the entire series of chloro-ammines of platinum(II) toward acid hydrolysis and chloride exchange has been summarized, and a likely mechanism for the process has been discussed.

The development of swaging and vibratory compaction process for fabrication of clad UO2 fuel rods is described. The cost is less than 50% of that for an equivalent core fabricated from pellets. The irradiation testing of vibratory filled and swaged UO2 rods is reported for burn-ups from 2,000 to 12,000 Mwd/t UO2; the results indicate that the rods are capable of excellent performance power reactors.

"The quantum theory problem of constructing explicitly a local Lorentz invariant model field theory which has an asymptotic particle interpretation and gives rise to an S matrix different from unity is discussed. It is proved that if a local covariant field H(x) has a complete current, the S matrix associated with this field is identically equal to unity. Results show that in order to get an interaction, the current is not allowed to have a terminating expansion in terms of a free field. The absence of a finite connection between a free field and an interacting field tended to confirm the belief that in local quantum field theories with particle interpretation the requirement of the existence of scattering forces in the physical states are such that it is not pos sible to identify them with a linear space spanned by ""free'' particle states."

Technical report describing and evaluating the the three experimental methods for obtaining equation of state data at low temperatures; (1) approximate measurement of the PVT relationship by a piston-displacement technique, (2) the measurement of a heat capacity at constant volume as a function of molar volume and temperature, and (3) direct measurement of the pressure variation of the elastic constants using ultrasonic techniques. X-ray methods also might be applicable.

"The problem of explaining the lack of radiative muon decay in an intermediate charged vector meson theory is discussed. A possible way of introducing the charged vector meson to the theory of weak interactions is outlined in which renormalization is retained. However, if this way is used, the anomalous magnetic moment is calculated to be large, which is in contradiction with expectation."

Abstract; SM-1 Reactor Core I Rearranged and Spiked, and Core II with Special Components were analyzed under various off-design conditions to induce nucleate boiling. The steady state code, STDY-3, written for the thermal analysis of pressurized water cores, was employed for the analysis. The code performs a complete steady state parallel channel thermal analysis for both nominal and hot channels. Thermal characteristics of individual elements were investigated while changing the parameters of primary pressure or inlet temperature to introduce the phenomenon of nucleate boiling in the the core. Reduction of system pressures to 1000, 800, and 600 psia and increasing core inlet temperatures to 465 and 500 degree F were studied as the means to induce boiling in the core. This analysis indicates that SM-1 Core I Rearranged and Spiked can be safely operated at the reduced pressure of 910 psia without introducing extensive boiling in the core. SM-1 Core II with Special Components can be operated at 800 psia or at an inlet temperature of 500 degree F at 1200 psia.

From abstract: "Bis(di-n-hexylphosphinyl)methane, HDPM, [(C6H13)2P(O)]2CH2, has been studied as an extractant for a variety of metals. HDPM was evaluated as an extractant for uranium(VI) and compared with tri-n-octylphosphine oxide, TOPO, (C8H13)3PO. In nonpolar solvents, HDPM forms a polymeric-like substance with compounds of uranium(VI). Viscosity measurements indicate that the molecular weight of this polymeric-like substance is about 100 times greater than the corresponding complex with TOPO. Polymer formation occurs only when nonpolar solvents are used as diluents for HDPM and is easily avoided by using polar solvents such as 1,2-aichlorobenzene. HDPM forms 1:1 and 2:1 complexes with uranium(VI) nitrate. Equilibrium constants for these complexes as well as that for the 2:1 TOPO complex were calculated and it was shown that the over-all constant is at least ten times larger for the HDPM complex than for the TOPO complex. The effect of concentration of various mineral acids, extractant concentration, temperature, and diluents on the extraction of uranium are discussed."

Technical report. From Abstract : "Optimum conditions were determined for the precipitation of neptunium (IV) peroxide from nitric acid solutions. The results indicate that the precipitation could be applied successfully on a plant scale. ... Two crystalline modifications of the peroxide were prepared; these two crystalline structures were similar to structures previously reported for plutonium peroxide."

Technical report. From Abstract : "Curium-242 was experimentally identified as a minor product of the irradiation of neptunium-237 in a nuclear reactor." From Introduction : "Determinations of the half-life, alpha energy, and daughter product of the purified curium nuclide were made in this study to confirm the identity as curium-242."

From summary: "A proposed metallurgical procedure for reporocessing Th-U233 fuel has been outlined. Some basic experimental data pertinent to the proposed process which has been published elsewhere has been reviewed and some new data presented. In the dissolution of thorium-uranium alloy in magnesium the data show that protactinium precipitates with the uranium and cerium remains in the magnesium-rich solution. It is expected that yttrium, other light rare earth elements, the alkali and alkaline earth metals will also concentrate in the magnesium-rich solution while iron, chromium, zirconium, molybdenum, niobium and the more noble metals will concentrate in the uranium-rich phase."

Abstract: Hydrodynamic flow studies were conducted on a full scale model of the SM-2 reactor vessel and core. Test fluid was water at 200 psi and 200 degree F. Test facilities, model, and instrumentation design are discussed. Flow distribution in the stationary fuel elements, lattices, and control rods of the second pass was investigated. Pressure losses through the various core components were measured and are compared with calculated values. Observed over-all pressure drop was 71 feet of water at 200 degree F, 31% higher than predicted, part of which was due to presence of instrument leads. Element to element flow distribution varied approximately +-8% from pass average. Channel-to-channel stationary element flow distribution varied approximately +-10% from element average and control rod flow distribution varied from +-8.9% to +-6.4 and -11.6% depending upon rod locations. These variations exceed the original goals of a +-10% and +-12% combined deviation for stationary and control rod elements respectively, but are satisfactory in relation to thermal design. There was no indication of unsatisfactory structural performance of any components under hydrodynamic loadings up to 130% of design values. The test program was terminated after determining flow distribution in the reference core design, omitting any work on …

"This approach to the problem of radiation damage was reported. A comparison of haploid males and diploid females with respect to their radio-sensitivity was made at various stages of embryonic and post-embryonic development. Differences in sensitivity were observed and taken to indicate that genetic damage is involved in the effects of x-rays upon development in Habrobracon juglandis."

"The present work describes some computer-oriented techniques for the application of the laws of quantum mechanics to the problems of determining basic structure of diatomic molecules. At times, calculations of the type described here yield results which can be compared directly with experiment to check the validity of the hypotheses and technique used they may predict the results of unobserved experimental phenomena; and, in many instances, they provide quantities which are necessary for the interpretation of experimental data but which cannot be directly measured."

Abstract; This technical report describes the changes in the SM-1 incurred by the experiment, Core Temperature and Flow Instrumentation (Task XIV), and evaluates the possible hazard involved in these changes. Temperature and flow measurements will be taken on a Task XIV instrumented stationary fuel element, instrumented control rod fuel element and other selected points in the SM-1 core to provide data on the core steady state and transient performance. The hazards evaluation consists of a nuclear evaluation, thermal and hydraulic analysis, description of tests to be performed, and discussion of containment integrity and maximum accident considerations.

Abstract: This technical report describes the as-constructed SM-1 penetrated gasket designed for SM-1 Core and Flow Instrumentation (Task XIV). This report supplements APAE No. 79, The Summary Hazards Report for Task XIV, and evaluates the effects of a postulated failure of this gasket. The effects of failure on the Maximum Credible Accident are determined and conclusions and recommendations for the use of this gasket are made.

Abstract: The removal of both SM-1 Core I high burnup elements from SM-1 Core II and the insertion of the PM-1-M-2 element and the SM-1 Core I spare element in SM-1 Core II is discussed. Nuclear and thermal characteristics of Core II with these changes are presented and conclusions related to the changes in the hazard potential are made. If the core change indicated by this report is made, local peaking factors will be decreased and burnout ratios will be increased. This, of course, in itself leads to a more conservative estimate of core safety. There is no conceivable reason why the perturbation may not be safely made in the SM-1 Core II.

Abstract: The removal of both SM-1 Core I high burnup elements from the SM-1 Core II and the insertion of two SM-1 Core I spare elements i their places are discussed. Nuclear and thermal characteristics of Core II with the change are presented and conclusion related to the change in hazard potential are made. If the core change indicated by this report is made, local peaking factors will be decreased and burnout ratios will be increased. This, of course, in itself leads to a more conservative estimate of core safety. There is no conceivable reason why this perturbation may not be safely made in the SM-1 Core II.

Abstract: This technical report describes the Martin Co. PM-1-M-2 test element and analyzes the potential hazard incurred by its inclusion in the SM-1 Core II. A nuclear analysis develops power distributions and reactivity effects. Hydraulic and thermal analyses develop anticipated burnout heat flux ratios. An evaluation of the risk involved with the inclusion of this element is presented. In view of the narrow margin by which the PM-1-M-2 test element meets the minimum burnout ratios as defined by Alco Products, Inc., it is recommended that if time permits that critical facility design verification be accomplished. The PM-1-M-2 test element meets the minimum requirements for insertion in SM-1 Core II and in view of the importance of this element to the PM-1 and PM-3A program, should be considered for insertion.

Abstract: This technical report describes the changes incurred in the SM-1 by the insertion of the SM-1 Core II and special components. The special components consist of impact specimens, a boron gradient rod, SM-2 elements, a PM-1-M element, and high burnup SM-1 Core I elements. The change in hazards, due to operation of SM-1 with Core II and the special components is evaluated. The analysis indicates there is no change in hazards.

This report provides a detailed discussion of the analytical chemistry of cobalt, including an introduction, the properties of cobalt, the sampling of cobalt-bearing materials, the separation and isolation of cobalt, the detection and identification of cobalt, the determination of cobalt, and the specific methods for determining cobalt.