The stability of fluorothene (polytrifluorochloroethylene, Kel-F) to gamma radiation has been investigated to estimate the probable life expectancy of fluorothene equipment exposed to Purex process solutions. Samples of fluorothene were exposed to total gamma radiation dosages up to 10 degree R. The results of these tests substantiate the findings reported by Sisman and Bopp in their compilation of data on the affects of radiation on plastics.

Removal of particles from air is discussed in terms of three classes of filtering media--air-sampling, respirator, and air-cleaning. Plots of efficiency versus filtering velocity are presented. The pressure drop characteristics of the filters are discussed in terms of initial pressure drops of the clean filters, variations in pressure drop of the individual filters, and comparison of loading rates.

The following documents are progress reports that follow chemical research studies in subjects such as ruthenium tetroxile distillations, extraction-scrub studies of zirconium and niobium, and oxidation of plutonium and stabilization of plutonium(VI) during extraction of IAF solutions.

The following report describes two rapid, micro methods for the determination of UNH in Redox waste samples that had been developed fir the concentration range 0.2 to 100 g/l.

The following report describes polarographic methods that determine saturated aliphatic carbonyl compounds.

Calcination of liquid radioactive wastes, the process of converting metal nitrates and sulfates to oxides by heat, is under development at Hanford as a means of reducing these liquids to a dry powder or solid which can be stored safely. Radiant-heat spray calcination, one of the methods under study, was first investigated at the Oak Ridge K-25 Plant (1) as a possible method of calcining uranyl nitrate to uranium trioxide. The process has also been under extensive development at the Pulp and Paper Research Institute of Canada (2) and is designated by them as the Atomized Suspension Technique.

From introduction: "This report presents the apparent viscosities of supernate-sludge slurries prepared synthetically to simulate the conditions known to exist in the waste storage tanks, but with fission products and plutonium absent."

From statement of objectives: The purposes of the work described in this report are to provide data useful for designing and operating the dissolver solution clarification equipment to be installed in the Redox production plant.

Report describing how the neutralized aqueous waste from the TBP Metal Recovery Process will be concentrated by evaporation to minimize the requirements for underground storage tank capacity.

This document will be concerned with the design, operation and maintenance of an automatic fuel element stamping machine. In order to take advantage of automatic unloading and length checking at the Acme-Gridley lathes in the 313 Building, automatic stamping of fuel elements is desirable. This, along with the need for a permanent canning line identification, resulted in a request for a machine to automatically stamp HAPO fuel elements on a production basis.

It is desirable that a reactor exhibit a self-regulating effect. If this were not true any disturbance to the reactor would result in a continual increase in the magnitude of the disturbance and the reactor would be unstable. In this investigation the reactor is considered to have two reactivity feed-backs: metal temperature and water temperature reactivity effects. These two variables through a metal temperature coefficient and water temperature coefficient determine not only the reactor stability but also determine many operational characteristics.

The results of this investigation indicate that maximum electric power generation can be obtained by selecting the turbine steam temperature within a range of plus/minus 30 degrees C. from an "idealized" steam temperature. This "idealized" steam temperature is shown to depend primarily on the maximum permissible uranium temperature. The minimum available condenser temperature and the temperature rise of the coolant in the pile effect the selection of the turbine steam temperature to lesser extent.

The work described was undertaken to provide data for nuclear safety studies concerning NPF reprocessing equipment. The original objective was to determine the uranium density and water (hydrogen) content of UO2-H2O mixtures ranging from compact centrifuge cakes to dilute slurries. The scope was later expanded to include mixtures of UO2 with hydrocarbon oil and mixtures of UO3-H2O.

Zirflex cladding waste is to be neutralized to pH 10 before transfer to waste storage tanks. This treatment causes the precipitation of zirconium oxide or hydroxide, which may lead to flow difficulties during transfer. The purpose of this investigation was to determine the physical properties and flow characteristics of the neutralized slurry to assist in the selectin of satisfactory transfer equipment and storage conditions.

This report describes the work carried out in 321 Building semiworks equipment, to define the factors contributing to high corrosion-product contamination and presents recommendations for reducing the impurity level to meet current specifications (maximum of 200 parts total metals per million parts U).

The purpose of the Analytical Laboratory Manual is to assemble the basic procedures to be used for the analyses of materials employed within the Fuels Preparation Department. The methods appear in detailed steps suitable for laboratory use. This document replaces the "Essential Material Analytical Manual, " HW-25375 and "Metal Preparation Analytical Manual," HW-30862.

This document describes required laboratory space and lists major equipment items necessary for a routine water quality laboratory in the P. R. T. R. Building. During discussions with R. D. Widrig and V. L. Rooney about the analytical sample program for the Plutonium Recycle Test Reactor, the author was asked to summarize equipment and space needs for a water control laboratory to provide routine analytical coverage on some of the water systems. Based upon 1706-KE-KER experience, some operating personnel may be used to provide analytical coverage on those routine analyses that are needed on around-the-clock basis with a savings of both time and money.

From abstract: "The purpose of this investigation was to establish basic rates of formation of chemical films deposited on aluminum surfaces from water flowing over such surfaces. It was desired to obtain specific information, within certain ranges, as to the influence of temperature, water velocity, and type of aluminum on the rate of film formation."

This document is a sequel to HW-30226, "Steady State Temperature Distribution in a Solid Slug." A primary feature of the present as well as the former paper is a treatment of the stand heat flow equation in a manner which accounts accurately for the dependence of the thermal conductivity, K, on temperature, v.

Various non-linear calculations for heat conduction in an istropic, homogeneous medium are presented.

One of the UO2 fuel element designs proposed for use in the PTRT is the nested tubular concepts. This configuration compromises a central fuel todo surrounded by two concentric tubes of fuel (see sketch, appenx I.) . These UO2 shapes are to be jacketed in the Zircaloy and must be separated from each other and the procuresses tyvm vt annular spaces for the passage of coolant. The annuli are established and and maintained by the longitudinal ribs on the outer surface of all three jacketed fuel elements.

aluminum has been considered as a material for cladding fuel elements to be used in reactors cooled by high-temperature recirculating water. Aluminum is abundant, chap, has a relatively low cross section for thermal neutrons, and is readily fabricated into complex shapes. For these reasons, it appears that the use of aluminum rather than steel, Zircaloy or other candidate materials for fuel element cladding, would result in considerable savings in operating expense. The actual economics will of course depend on specific factors such as core materials and design of the reactor/. Aluminum appears particularly attractive for cladding the cores of aluminum-plutonium alloy proposed for the Plutonium Recycle Test Reactor since, in this case, the physical characteristics of the core and cladding would be practically identical.

A report which describes a number of experiments conducted to compare the effects of different methods of surface preparation on x-ray diffraction patterns of uranium obtained by the spectrometer technique.

Space has been reserved near the southeast corner of the 100-N Area for the 122-N Decontamination Facility. Previous correspondence between Burns and Roe, Inc and General Electric bae discussed various facilities which might be needed in the building. The concepts of the decontamination processes are under active development by research groups at Hanford. At present, there are several workable processes known; each one has one or more fairly serious drawbacks.