Abstract. The rate constants for the reaction of the hydrated electron eaq with a number of solutes and with radicals formed in water radiolysis are reported. Hydrated electrons were formed in the electron pulse irradiated solutions at concentrations in the range from 1 to 10 pM. Their reaction was followed by the decay of the optical absorption of eaq at 5780 A. Generally a 04 psec pulse of 15 MeV electrons was used. In the absence of eaq scavengers, second-order kinetics prevailed owing to the dominance of the reactions,eaq+eaq, eaq+H, and eaq+H202 when OH radical scavengers were present in alkaline solution. An analysis of the decay curves leads to values for keaq+eaq and keaq+H of 0.9~ 1010 and 3 x 1010 M-1 sec-1, respectively. With scavenger present in excess over [eaq], pseudo first-order kinetics were found and rate constants for a number of inorganic and organic compounds are reported. The agreement of these and other rate constants with diffusion-controlled reaction theory is discussed.

This report covers the S-I-5-B-M fuel irradiation in the GETR Maritime Loop during the final quarter of fiscal year 1962 plus the month of July 1962 to conclude the irradiation program. The data are summarized in Section II.

This technical report presents measurements of the thermal expansion of five titanium carbide type cermets from 68 to 1800F. These cermets are designated by Kennametal, Inc., as K 138A, K 150A, K 152B and K 162B. They contain from 64 to 80 weight percent titanium carbide, 10 to 30 weight percent metal binder and 6 to 10 weight percent other carbides. The metal binders are cobalt, nickel, and nickel and molybdenum. An attempt was made to calculate the thermal expansion of each type cermet from thermal expansions of the constituents. The expansion of the mixture was computed by weighting and expansions of the constituents according to (1) weight percent of the constituents, (2) volume percent of the constituents and (3) according to a value developed for mixtures by P. S. Turner. It was found that expansions computed according to volume percent and by Turner's method agreed with measured values with +- 5 percent. The values calculated by weight percent were from 5 to 11 percent higher than the observed values. The thermal expansions of these cermets are compared with the expansions of a group of metals and alloys.

A digital-to-analog converter is described which is a part of a system that converts punched-tape digital data to analog data in a series of points drawn by an x-y plotter. The converter is designed to plot accurately tapes that contain information other than coded numerical coordinates. Operation of the converter is also described along with format requirements and power supplies. (J.R.D.)

From abstract: "In this report we present data obtained with the optical simulation apparatus on image quality as a function of the parameters of neutron scattering and image detector resolution...Also included in this report is a brief description of a large area (5 inch diameter) neutron beam exposure facility being set up at the reactor for the phase three work."

"A brief examination of the post irradiation grafting of machine irradiated polyethylene film with acrylic acid monomer was made. Evidence of postgrafting was detected in samples that had been irradiated to a total dose of 10 Mrads at a dose rate of 0.01 Mrad/sec. and then exposed to a 25% purified acrylic acid solution in benzene for periods of 1 to 4 days."

Entrained solids have in the past been one of the major factors limiting solvent extraction fission product decontamination. These solids are known to be surface active, to absorb fission products, and to form interfacial films or "cruds". A major step in eliminating these cruds was taken when the Purex columns were modified to operate with the interfaces at the waste ends of the columns rather than the product ends. This type of operation tended to flush the solids out with the waste rather than the product streams.

Molecular sieves are synthetic zeolites which, when dehydrated, contain a network of empty pores and cavities that constitute almost 50% of the total volume of the crystals. They have the unique property of adsorbing within these cavities only those molecules that are small enough to pass through the pores of the crystals, Molecular sieves have a very strong affinity for water and other polar molecules. It is this selective property plus their stability and reasonable cost that make them of interest for the application described herein.

The increasing popularity of liquid-hydrogen targets in physics research has emphasized the need for containers with maximum beam transparency (i.e., thin walls and low Z) and suitable strength at cryogenic temperatures. Fabrication of a Mylar container satisfying these requirements is described here.

A need for a small vertical cylinder-type furnace arises frequently in the Chemistry Department at the Lawrence Radiation Laboratory (LRL). Adequate heat is the major requirement; close control or calibration is not usually necessary. A heating unit of this type can either be used for quickly concentrating solutions in centrifuge cones or, by the addition of a refractory pedestal--can be made into a crucible furnace for size 0 and 00 crucibles. Because much of the chemistry done at LRL is with radioisotopes, disposal of contaminated equipment is an important consideration. In general, furnaces are difficult to decontaminate, hence there was a need for a disposable type. Because nothing meeting the requirements seemed to be commercially available, the Health Chemistry Department made up a simple furnace that has proved useful.

This paper discusses a group of high-speed switching circuits using the basic current-switching mode of operation. The first part of the paper presents a dynamic analysis of the basic current-switching mode and the second part is the dynamic and steady-state analysis of a current-switching flip-flop.

From abstract: "To investigate the deviation of the internal conversion coefficients of E2 transitions from theoretical computations and their dependence on nuclear deformation, the total internal conversion coefficient of the 121.8-kev 2+-0+ transition in ellipsoidal Sm152[over]90 was measured to be 1.135 ± 0.010 with a high accuracy coincidence-sum method. The K-shell to total internal conversion ratio was determined to be 0.588 ± 0.003 with a [beta] spectrometer...The experiment revealed no deviation from theory nor indications of strong dependence on nuclear deformation; it therefore did not confirm recent beliefs in this regard. The details of the coincidence-sum method were described. The K electron to total electron capture ratio, from Eu152 to the 1.53 Mev state in Sm152 was also measured to be 0.79±0.02."

"As a part of a program to determine the p-p scattering matrix at 213 Mev, the triple scattering parameters R and A were measured at 30, 40, 50, 60, 70, 80. and 90 deg in the center-of-msss system. The results are compared with a phase shift analysis by MacGregor and Moravcsik and with the predictions of the boundary condition model of Saylor, Bryan and Marshak."

Figures 1 and 2 summarize total decay energies for the four radioactive series. The alpha-decay energy obtained by measuring the energy of the alpha particle leading to the ground state includes the energy of the recoil nucleus. The curve shown in figure 3 defines in broad outline the conditions and regions of alpha instability. A great deal more is to be learned from a more detailed examination of the region where alpha radioactivity is prominent. Of great value to the experimentalist is that he is able to predict alpha energies, and the agreement between predicted and measured values often serves as a criterion for isotopic assignment. A number of systems for correlating alpha decay energies have been employed, and that perhaps most widely used is illustrated in figure 4. Here the isotopes of each element on a mass number vs. energy plot are joined, resulting in a family of curves which over a wide region comprise a series of nearly parallel lines.

THOROBRED is an IBM-704 code for the calculation of nuclear and economic characteristics of two-region homogeneous reactors operating on a U-Th fuel cycle in the steady state. The major input variables are reactor dimensions, power level, thorium concentration, chemical and purification systems cycle times, corrosion rates, fraction of Pa loss, and nuclear and economic data. The output includes equilibrium isotope concentrations, neutron balance, and a breakdown of fuel cost. Running times are normally less than one minute per case.

It is the purpose of this report to explain the bands and uses of a digital computer program for the calculation of steady state steam-water pressure drop and critical flow in pipes. The program has been coded for the IBM 709 computer. While so attempt has been made to obtain improved models of two-phase flow, it is believed that the numerical integration technique used in the code will permit more accurate calculation where pressure drops are large compared to the upstream pressure. The technique should lend itself readily to any improved correlations which appear in the future.

A study and tests of the feasibility and best method of reaming rear face Parker fittings has been made. Flow increase of 8 percent, based on maintaining the same front header pressure, can be obtained at B, D, and F reactors by reaming the rear Parker fittings to .610 inch and using existing rear face hardware. Tests indicate mechanical strength will not be significantly reduced, high frequency vibration will not be increased, and that methods of reaming are available.

Abstract. An IBM-650 computer code for the detailed unfolding of [gamma]-ray spectra obtained from NaI scintillation counters has been developed. The procedure is set up to remove analyzer scale dependence and to largely remove energy dependences. Computer time is about 1 minute per [gamma]-ray.

Basic Studies. Sinterability studies on the isomorphous system UO2-PuO2 have continued. One-half inch diameter X 3/8'' long compacts containing physical mixtures of the two components have been heated in hydrogen. Sintered density as a function of time and temperature has been determined for times of one and eight hours up to 1600 C. In general, there seems to be minima on isothermal plots of density versus composition in the intermediate range 20-40 w/o PuO2. At concentrations greater than 40 w/o PuO2, density increases rapidly with increasing PuO2. In every case pure PuO2, (produced by decomposing plutonium oxalate at at 300 C) sintered to a greater density that ball ball milled PWR grade UO2. The data, for a one hour soak time, and tabulated in percent of the theoretical crystallographic density, can be seen below:

The following is taken from ORNL-2257, Instantaneous Velocity Profile Measurement by Photography, by R. E. Lynch, L. D. Palmer, and G. M. Winn. This report is in in preparation status; and errors, inconsistances, and omissions in he language, as well as in the technical aspects, may exist. The technique of using phosphorescent particles to enable photographic determination of qualitative and quantitative instantaneous velocity profiles is covered by AEC Patent Application No. SN-710, 371 issued to F. E. Lynch, L. D. Palmer, H. F. Poppendiek, and G. M. Winn and entitled " A Method of and Means for Visualizing Fluid Flow Patterns.

Facilities shall be provided in the 221-U Building for removing fuel elements from the casks as placed in the railroad tunnel from the transfer facility and moving the elements to modified existing 10' X 16' X 14' storage tanks in ten existing cells where they will be stored, until scheduled for processing.

A number of Pu-Al and UO2-PuO2 Zircaloy clad capsules have been fabricated for irradiation in the MTR. In addition, a four rod cluster containing Al 8 w/o Pu and Al 12 w/o Si 8 w/o Pu cores has been successfully irradiated and discharged from Loop 3 of the KER. A second four rod cluster is awaiting irradiation and design and fabrication of a seven rod cluster test element is underway.

Technical report describing the investigation undertaken to determine the necessary requirements for obtaining sound bonded joints on tantalum. Corrosion and Mass Transfer Loops LTTN 237A and 427 called for fabrication of 430 stainless steel clad tantalum tubing. Since there was little or no experience at welding this material at CANEL, specimens were welded using vacuum chambers and plastic chambers as normally used for loop fabrication. Resistance welding was performed without the use of a special atmosphere producing sound bonds.

In formulating this general diffusion theory expression which represents the neutron balance in a nuclear chain reactor the following assumptions were made : (1) the medium through which the neutrons are diffusing has a low neutron capture cross section, (2) the region in which the flux distribute is being described is two or three mean free paths from strong sources and sinks or from a boundary. Certainly, is going to the lattice cell of a receptor, both of the above conditions are violated; fuel elements have a large absorption cross section and most lattice cells are only two or three mean free paths to is over-all sites