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1,2-HOIQO--A highly versatile 1,2-HOPO analog
A cyclic, bidentate hydroxamic acid binding unit based on an isoquinoline scaffold has been utilized for the synthesis of a hexadentate tripodal ligand based on the TREN backbone. This prototype for a new class of multidentate chelators forms mononuclear iron(III) complexes and one-dimensional coordination polymers with lanthanide(III) cations. The latter has been determined by single crystal X-ray analysis of the cerium species. The solid state structure in the monoclinic space group P2{sub 1}/c (C{sub 36}H{sub 34}CeN{sub 7}O{sub 11}, a = 12.341(2){angstrom}, b = 26.649(4){angstrom}, c = 10.621(2){angstrom}, {alpha} = {gamma} = 90{sup o}, {beta} = 96.753(3){sup o}, V = 3468.6(9) {angstrom}{sup 3}, Z = 4) exhibits a trigonal-dodecahedral environment around the cerium cation. The proof of concept for the versatility of the new scaffold has been shown by the modification of the crucial precursor 3-carboxyiso-coumarin through electrophilic aromatic substitutions to yield the corresponding chlorosulfonated and nitrated analogs.
Date:
August 7, 2006
Creator:
Seitz, Michael; Pluth, Michael D. & Raymond, Kenneth N.
Object Type:
Article
System:
The UNT Digital Library
1,2- Hydroxypyridonates as Contrast Agents for Magnetic ResonanceImaging: TREN-1,2-HOPO
1,2-Hydroxypyridinones (1,2-HOPO) form very stable lanthanide complexes that may be useful as contrast agents for Magnetic Resonance Imaging (MRI). X-ray diffraction of single crystals established that the solid state structures of the Eu(III) and the previously reported [Inorg. Chem. 2004, 43, 5452] Gd(III) complex are identical. The recently discovered sensitizing properties of 1,2-HOPO chelates for Eu(III) luminescence allow direct measurement of the number if water molecules in the metal complex. Fluorescence measurements of the Eu(III) complex corroborate that in solution two water molecules coordinate the lanthanide (q = 2) as proposed from the analysis of NMRD profiles. In addition, fluorescence measurements have verified the anion binding interactions of lanthanide TREN-1,2-HOPO complexes in solution, studied by relaxivity, revealing only very weak oxalate binding (K{sub A} = 82.7 {+-} 6.5 M{sup -1}). Solution thermodynamic studies of the metal complex and free ligand have been carried out using potentiometry, spectrophotometry and fluorescence spectroscopy. The metal ion selectivity of TREN-1,2-HOPO supports the feasibility of using 1,2-HOPO ligands for selective lanthanide binding [pGd = 19.3 (2); pZn = 15.2 (2), pCa = 8.8 (3)].
Date:
May 8, 2007
Creator:
Jocher, Christoph J.; Moore, Evan G.; Xu, Jide; Avedano, Stefano; Botta, Mauro; Aime, Silvio et al.
Object Type:
Article
System:
The UNT Digital Library
$1.2 Million in Savings Identified in Akzo Nobel Assessment: Plant-Wide Assessment Summary--Chemicals (Fact Sheet)
Summary of Akzo Nobel's plant-wide assessment to identify energy and cost saving opportunities at the corporation's Surface Chemistry plant in Morris, Illinois.
Date:
August 1, 2003
Creator:
unknown
Object Type:
Text
System:
The UNT Digital Library
$1.2 Million in Savings Identified in Caraustar Assessment: Plant-Wide Assessment Summary--Forest Products (Fact Sheet)
Summary of Caraustars plant-wide assessment to identify energy and cost saving opportunities at the corporations recycled paperboard mill in Rittman, Ohio.
Date:
August 1, 2003
Creator:
unknown
Object Type:
Text
System:
The UNT Digital Library
1.2 MW klystron for Asymmetric Storage Ring B Factory
A cw klystron operating at 476 MHz has been developed jointly by SLAC and Varian Associates. The unique set of characteristics of this tube were strongly guided by requirements of the fast feedback necessary to prevent oscillations of the storage ring beams caused by the detuned accelerating cavity. This requires a combination of bandwidth and short group delay within the klystron. The RF feedback stabilization scheme also requires amplitude modulation making it necessary to operate the klystron about 10% below saturation. Performance specifications and initial operating results are presented.
Date:
March 1995
Creator:
Fowkes, W. R.; Caryotakis, G. & Doyle, E.
Object Type:
Article
System:
The UNT Digital Library
1/2 Sintering of Mullite-Containing Materials: I. Effect of Composition
Sintering behavior of mullite-containing powders was studied over a range of chemical compositions (Al{sub 2}O{sub 3}/SiO{sub 2} ratio). Densification measurements were made for both liquid phase-containing and solid state systems. Small amounts of liquid phase were observed to have a significant effect on densification rate. A linear relationship was obtained between the percent of theoretical density and the logarithm of time for compositions in the range 73-75 wt% Al{sub 2}O{sub 3}. Currently available models for intermediate stage sintering kinetics were considered to be inadequate for these systems. Grain boundary transport 0r diffusion appeared to be the primary mechanism of densification.
Date:
December 1, 1981
Creator:
Sacks, Michael D. & Pask, Joseph A.
Object Type:
Article
System:
The UNT Digital Library
1/2/Sup +/. -->. 1/2/Sup -/ Beta Decay of /Sup 19/Ne and the Parity Nonconserving Nn Force
A branching ratio of (1.20 +- 0.20) x 10/sup -4/ is obtained for the ..beta../sup +/ decay of /sup 19/Ne to the 110 keV 1/2/sup -/ level of /sup 19/F. This transition (presumably dominated by the ..delta..J/sup ..pi../ = 0/sup -/ axial charge operator) provides a crucial test of wavefunctions used in interpreting the parity mixing of the ground and 110 keV levels of /sup 19/F. These wavefunctions, which yield a parity mixing larger than that observed experimentally, also predict too large a ..beta../sup +/ decay rate.
Date:
1978~
Creator:
Adelberger, E. G.; Hindi, M. M.; Hoyle, C. D.; Swanson, H. E. & Von Lintig, R. D.
Object Type:
Report
System:
The UNT Digital Library
1,3,5-trichlorobenzene progress report, July--September 1976
Research progress is reported on the following topics: (1) conversion of 2, 4, 6-trichloroaniline to 2, 4, 6-trichloronitrobenzene; (2) nitration of 1, 2, 4-trichlorobenzene; (3) exploration of the route to 1, 3, 5-trichlorobenzene via aniline; and (4) direct nitration of trichloroaniline. (TFD)
Date:
September 1, 1976
Creator:
Estes, Z. L.
Object Type:
Report
System:
The UNT Digital Library
1.3 GHz superconducting RF cavity program at Fermilab
At Fermilab, 9-cell 1.3 GHz superconducting RF (SRF) cavities are prepared, qualified, and assembled into cryomodules (CMs) for Project X, an International Linear Collider (ILC), or other future projects. The 1.3 GHz SRF cavity program includes targeted R&D on 1-cell 1.3 GHz cavities for cavity performance improvement. Production cavity qualification includes cavity inspection, surface processing, clean assembly, and one or more cryogenic low-power CW qualification tests which typically include performance diagnostics. Qualified cavities are welded into helium vessels and are cryogenically tested with pulsed high-power. Well performing cavities are assembled into cryomodules for pulsed high-power testing in a cryomodule test facility, and possible installation into a beamline. The overall goals of the 1.3 GHz SRF cavity program, supporting facilities, and accomplishments are described.
Date:
March 1, 2011
Creator:
Ginsburg, C. M.; Arkan, T.; Barbanotti, S.; Carter, H.; Champion, M.; Cooley, L. et al.
Object Type:
Article
System:
The UNT Digital Library
1,3-Propanediol Made From Fermentation-Derived Malonic Acid: Office of Industrial Technologies (OIT) Agriculture Project Fact Sheet
1,3-Propanediol is one of two ingredients used in producing polytrimethylene terephthalate (PTT), a polymer which can be used in polyester and nylon applications. Researchers are developing a process to ferment biomass feedstock to malonic acid using filamentous fungi and then catalytically convert malonic acid to 1,3-propanediol.
Date:
September 12, 2001
Creator:
Carde, T.
Object Type:
Book
System:
The UNT Digital Library
1,4-diphenylbutadiyne as a potential tritium getter
Research on the acetylene compound 1,4-diphenylbutadiyne is an effort to develop an air-operative tritium gas scavenger. T/sub 2/ adds to the acetylene bond of the organic in the presence of a metal catalyst. The catalyst also stimulates the oxidation reaction as well. The butadiyne compound has shown good reaction efficiency at 300 ppM T/sub 2/ in static dry air. At this concentration 75% of the scavenged tritium was in the organic. This work has expanded to the investigation of liquid acetylenes, metal acetylene complexes, organometallics and acetylene based alcohols. The best of these compounds has gettered 100% of 10 to 500 ppM T/sub 2/ for both static and dynamic air flow conditions.
Date:
October 1, 1980
Creator:
Miller, H. H.; Bissell, E. E.; Tsugawa, R. T. & Souers, P. C.
Object Type:
Article
System:
The UNT Digital Library
A 1. 5--4 Kelvin detachable cold-sample transfer system: Application to inertially confined fusion with spin-polarized hydrogens fuels
A compact cold-transfer apparatus for engaging and retrieving samples at liquid helium temperatures (1.5--4K), maintaining the samples at such temperatures for periods of hours, and subsequently inserting them in diverse apparatuses followed by disengagement, is described. The properties of several thermal radiation-insulating shrouds, necessary for very low sample temperatures, are presented. The immediate intended application is transportable target-shells containing highly spin-polarized deuterons in solid HD or D{sub 2} for inertially confined fusion (ICF) experiments. The system is also valuable for unpolarized high-density fusion fuels, as well as for other applications which are discussed. 9 refs., 6 figs.
Date:
January 1, 1990
Creator:
Alexander, N.; Barden, J.; Fan, Q. & Honig, A.
Object Type:
Report
System:
The UNT Digital Library
1.5% boron, stainless steel
A test report on the brittleness of borated steel to be used in the KIWI B-5 shield capsules.
Date:
September 19, 1962
Creator:
Schreiber, J.J.
Object Type:
Report
System:
The UNT Digital Library
1. 5 GeV/c multiturn shaving extraction and its transport line for the Brookhaven AGS
A system for fast shaving extraction at 1.5 GeV/c is implemented to extract the circulating beam in five turns. A numerical simulation is first carried out to determine the emittance and the rf structure of the extracted beam. This is followed by several machine study sessions which establish the optimal extraction configuration, confirm the emittance, and modify the transport line for low energy beam. Finally, a one-week run for the Neutrino Oscillation experiment demonstrates that the system is very stable and capable of delivering 7.5 x 10/sup 12/ p/sec with 70% extraction efficiency and 95% transport efficiency.
Date:
January 1, 1979
Creator:
Weng, W. T.; Blumberg, L. N.; Gill, E.; Soukas, A.; Witkover, R. L.; Egleman, E. et al.
Object Type:
Article
System:
The UNT Digital Library
A 1.5 GeV compact light source with superconducting bending magnets
This paper describes the design of a compact electron synchrotron light source for producing X-rays for medical imaging, protein crystallography, nano-machining and other uses up to 35 keV. The source will provide synchrotron light from six 6.9 tesla superconducting 60{degree} bending magnet stations. In addition the ring, contains conventional quadrupoles and sextupoles. The light source has a circumference of 26 meters, which permits it to be located in a variety of industrial and medical facilities.
Date:
May 1995
Creator:
Garren, A. A.; Cline, D. B.; Kolonko, J. J.; Green, M. A.; Johnson, D. E.; Leung, E. M. et al.
Object Type:
Article
System:
The UNT Digital Library
1.5-GEV FFAG ACCELERATOR AS INJECTOR TO THE BNL-AGS.
A 1.5-GeV Fixed-Field Alternating-Gradient (FFAG) proton Accelerator is being studied as a new injector to the Alternating-Gradient Synchrotron (AGS) of Brookhaven National Laboratory (BNL). The major benefit is that it would considerably shorten the overall AGS acceleration cycle, and, consequently, may yield to an improvement of beam stability, intensity and size. The AGS-FFAG will also facilitate the proposed upgrade of the AGS facility toward a 1-MW average proton beam power at the top energy of 28 GeV. This paper describes the FFAG design for acceleration of protons from 400 MeV to 1.5 GeV, with the same circumference of the AGS, and entirely housed in the AGS tunnel.
Date:
July 5, 2004
Creator:
Ruggiero, A. G.; Blaskiewicz, M.; Trbojevic, D.; Tsoupas, N. & Zhang, W.
Object Type:
Article
System:
The UNT Digital Library
1.5-GeV FFAG Accelerator for the AGS Facility
N/A
Date:
February 1, 2004
Creator:
Ruggiero, A. G.; Blaskiewicz, M.; Courant, E.; Trbojevic, D.; Tsoupas, N. & Zhang, W.
Object Type:
Report
System:
The UNT Digital Library
1.5 megawatt dc chopper power supplies for plasma shape control on Doublet III
The Doublet III device is designed to study noncircular plasmas, including doublet and dee-shaped cross-sections. The plasma shape is determined by a system of 24 field-shaping coils which surround the vacuum vessel. Control of the magnetic flux linking these coils allows the plasma shape to be varied and controlled. This paper describes the high-speed dc chopper which is a major component of the field-shaping coil power system. The high-speed dc choppers, with a frequency response of up to 5 kHz and a switching power capability of 1.5 megawatts are used for fine tuning and feedback control of the plasma position and shape. The design and operation of two 1.5 megawatt, 3 kHz choppers used on closed loop plasma control experiments will be presented.
Date:
November 1979
Creator:
Rock, P. J. & Wesley, J. C.
Object Type:
Article
System:
The UNT Digital Library
A 1.5 Mwe Thermionic Reactor Space Power System
None
Date:
October 31, 1966
Creator:
Smith, C. K. & Parkinson, R. Y.
Object Type:
Report
System:
The UNT Digital Library
1/5-scale experiment of a Mark I boiling-water reactor pressure-suppression system under hypothetical LOCA conditions
Experimental results show the sensitivity of hydrodynamically generated vertical loads to changes in the drywell pressurization rate, downcomer submergence, and vent-line loss coefficient. Insignificant effects on peak vertical loads were observed when the vent-line loss was varied. Peak vertical loads can be reduced by adding initial drywell overpressure so that the downcomers are partly cleared of water. Spatial variation of pressure at about the time of vent clearing is seen in comparisons of data from locations along the axis of the toroidal wetwell.
Date:
July 8, 1977
Creator:
Pitts, J. H. & McCauley, E. W.
Object Type:
Article
System:
The UNT Digital Library
1.06 μm 150 psec laser damage study of diamond turned, diamond turned/ polished and polished metal mirrors
Using a well characterized 1.06 μm 150 ps glass laser pulse the damage characteristics for diamond turned, diamond turned/ polished, and polished copper and silver mirrors less than 5 cm diameter were studied. Although most samples were tested with a normal angle of incidence, some were tested at 45$sup 0$ with different linear polarization showing an increase in damage threshold for S polarization. Different damage mechanisms observed will be discussed. Laser damage is related to residual surface influences of the fabrication process. First attempts to polish diamond turned surfaces resulted in a significant decrease in laser damage threshold. The importance of including the heat of fusion in the one dimensional heat analysis of the theoretical damage threshold and how close the samples came to the theoretical damage threshold is discussed. (auth)
Date:
July 24, 1975
Creator:
Saito, T. T.; Milam, D.; Baker, P. & Murphy, G.
Object Type:
Article
System:
The UNT Digital Library
$1.6 Million in Savings Identified in Anchor Assessment: Plant-Wide Assessment Summary--Glass (Fact Sheet)
Summary of Anchor Glass' plant-wide assessment to identify energy and cost saving opportunities at the corporation's facilities in Warner Robins, GA and Jacksonville, FL.
Date:
August 1, 2003
Creator:
unknown
Object Type:
Text
System:
The UNT Digital Library
$1.6 Million in Savings Identified in Augusta Newsprint Assessment: Plant-Wide Assessment Summary--Forest Products (Fact Sheet)
Augusta Newsprint and its partners conducted a systematic plant-wide assessment (PWA) to identify energy- and cost-saving opportunities at the company's plant in Augusta, Georgia. The assessment team identified$1.6 million in potential annual savings.
Date:
August 1, 2003
Creator:
unknown
Object Type:
Text
System:
The UNT Digital Library
1.8.2.1.2 Site system engineering implementation Fiscal Year 1998 multi-year work plan
Manage the Site Systems Engineering process to provide a traceable, integrated, requirements-driven, and technically defensible baseline., Through the Site Integration Group, Systems Engineering ensures integration of technical activities across all site projects. Systems Engineering`s primary interfaces are with the Project Direction Office and with the projects, as well as with the Planning organization.
Date:
October 3, 1997
Creator:
Ferguson, J. E.
Object Type:
Report
System:
The UNT Digital Library