None

None

None

None

The leachabilities of /sup 90/Sr, /sup 239/Pu, and /sup 137/Cs from solids in Tank 108-SX were determined. Through 21 leach cycles covering a 3.5 day period, 63 volumes of leachate removed 1.4, 4.6, and 19.2% of the /sup 239/Pu, /sup 90/Sr, and /sup 137/Cs, respectively, from the 108-SX solids. With the exception of the first few leachates, the /sup 239/Pu concentrations in the leachates were less than maximum permissible concentration in drinking water for 168-h/wk exposure. A composite of the TK-108-SX leachate was passed through a column containing typical Hanford soil. Column distribution coefficients with 108-SX leachate of 14, 24, and 20 were obtained for /sup 239/Pu, /sup 90/Sr, and /sup 137/Cs, respectively, indicating appreciable sorption of all these radionuclides by the soil. The radionuclides were not readily removed from the loaded soil columns with 12 column volumes of dilute leachate solution. Laboratory results with the 108-SX sludge were carefully evaluated to determine their significance to the overall analysis of the safety of long-term storage of Redox sludge in existing underground tanks. The primary deterrent to movement of the radionuclides from such solids to the water table is the absence of moving water in the storage zone. Incident precipitation does …

This paper reports on a laboratory study of erosion-corrosion on aluminum surfaces in high temperature water. It is essentially a continuation of a similar previous study with refinement in testing procedure and the addition of electrochemical measurements to study the phenomenon. The electrochemical procedures are of intrinsic worth, because such measurements have never before been conducted with such an unusual cell geometry as imposed by the erosion-corrosion testing apparatus.

The Quality Plan for the SNAP-27 Follow-On Program describes the manner in which the Isotope Power Systems Operation of the General Electric Space Division will control product quality. NASA NHB5300.4 (1B) and AEC QASL-SNAP-1 and 2 have been used as guides in the development of this plan and, upon approval by the AEC, this plan will serve as a policy document to be utilized in implementing the SNAP-27 Follow-On Quality Program.

None

None

None

This report contains a compilation of unclassified plutonium programs underway in FY 1970 in the field of materials science. It includes work in ceramics, metallurgy, solid state physics and physical chemistry. Information on each of the programs is given in five sub-headings: scope of the work; technical effort in manyears; primary class of materials studied; person(s) to contact for further information; and reports and publications. All the work listed is restricted to either research or long range development and not applied or hardware-type projects.

None

None

Thermal analysis of the LOFT containment vessel penetration S-6A was conducted for steady-state operation and blowdown transients. Penetration S-6A is a 20-inch pipe through which passes a 10-inch pipe from the steam generator containing 600/sup 0/F steam. Recommendations for penetration S-5E were based on the analysis of penetration S-6A. Penetration S-5E is an 18-inch pipe through which pass a 4-inch pipe containing the steam generator feedwater at 430/sup 0/F and a 0.5-inch pipe containing sample water at 600/sup 0/F. The thermal analysis is necessary to determine the maximum temperature gradient in the containment vessel around the penetrations. The outside of the penetrations protrude into a room adjacent to the containment vessel which will be maintained at a minimum temperature of 50/sup 0/F. The steady-state temperature inside the containment vessel was assumed to be 100/sup 0/F. Table I of LOFT Containment Vessel Specification S-1 was used for inside transient temperatures.

Relationships necessary for ring stability are derived between the self-focusing forces of an electron ring and the magnetic field gradient defocusing forces present near and just subsequent to the start of ring acceleration.

Di-tertiarybutylnitroxide (DTBN), which they have tried to use as a trapping agent to identify the species giving rise to the photo-induced EPR signals in photosynthetic materials, functions as a Hill reagent with spinach chloroplasts. Evidence is presented which indicates that the reduction of DTBN is affected by photosystem II of the electron transport system of spinach chloroplasts. The reduced form of DTBN, the hydroxylamine, undergoes a photo-oxidation with spinach chloroplasts. Possible explanations of this apparent inconsistency are presented. A product which could be ascribed to a chemical coupling reaction between the nitroxide and the radical species giving rise to the photo-induced EPR signals in spinach chloroplasts was not detected, even using radioactive tracer methods.

The influence upon axial stability in an electron ring of the diffraction radiation reaction force, generated by a ring moving in an acceleration column, is calculated theoretically. A stability criterion is obtained, and numerical examples show that the criterion is not an important constraint upon the choice of parameters or the operation of an electron ring accelerator.

Static quadrupole moments of the first excited states of {sup 28}Si, {sup 32}S, and {sup 40}Ar have been measured using the reorientation effect in projectile Coulomb excitation. The results obtained are Q({sup 28}Si,2{sup +}) = +0.11 {+-} 0.05 b, Q({sup 32}S,2{sup +}) = -0.20 {+-} 0.06 b, and Q({sup 40}Ar, 2{sup +}) = +0.01 {+-} 0.04 b.

Semiconductors with a sufficiently large energy gap, in contact with an electrolyte, can be used as electrodes for the study of electrochemical reactions of excited molecules. The behavior of excited chlorophyll molecules at single crystal ZnO-electrodes has been investigated. These molecules inject electrons from excited levels into the conduction band of the electrode, thus giving rise to an anodic photocurrent. The influence of various agents on this electron transfer has been studied. In the presence of suitable electron donors (e.g., hydroquinone, phenylhydrazine) in the electrolyte chlorophyll molecules, absorbing quanta, mediate the pumping of electrons from levels of the reducing agents into the conduction band of the semiconductor-electron acceptor. The electron capture by the semiconductor electrode is irreversible, when an adequate electrochemical gradient is provided in the electrode surface. An experimental technique for the study of the kinetics of photoelectrochemical reactions of chlorophyll molecules is introduced and a theoretical approach for its calculation is given. Some properties of excited chlorophyll at semiconductor electrodes (unidirectional electron transfer, highly efficient charge separation, chlorophyll as electron pump and able to convert electronic excitation into electric energy) show similarity to the behavior of chlorophyll in photosynthetic reaction centers.

Early in 1968 a research group was set up at the Lawrence Radiation Laboratory to investigate the exciting new concept of accelerating ions by means of relativistic electron rings, which had been introduced and developed by Veksler, Sarantsev, and other workers at Dubna. The initial work of our group was reported at the first USSR National Conference on Particle Accelerators in 1968. In this report the author review the subsequent progress and the present program.

Branched alkanes from blue-green algae were separated on a 750 feet high resolution capillary gas chromatographic column. The mixture was found to be 90% of 1:1 ratio 7-methyl, and 8-methyl-heptadecane, and 10% of 6-methylheptadecane. An optical rotation of +2.5 {+-} 0.5 was obtained on a 5 mg of mixture.

The authors have measured the asymmetry in the cross section for the reaction {gamma}p {yields} {pi}{sup +}n between the two stages of polarization of the initial proton normal to the plane of scattering. The initial laboratory photon energies, k, were 5 GeV and 16 GeV, and the regions of momentum transfer, t, covered were 0.14 {le} {radical}-t {le} 1.01 GeV/c and 0.14 {le} {radical}-t {le} 0.78 GeV/c respectively. A butanol polarized target was used with the SLAC 20 GeV/c magnetic spectrometer. The data show a sizeable asymmetry at both 5 GeV and 16 GeV. The 16 GeV data peak at {radical}-t {approx} 0.30 GeV/c with an asymmetry of about -0.70, and the 5 GeV data pak at {radical}-t {approx} 0.80 GeV/c with an asymmetry of about -0.70. The direction of our normal to the scattering plane is along (photon in) x (pion out).

An equilibrium theory of the length of intense electron bunches circulating in a storage ring is presented. The consequence of electrical interaction with various resonant structures is expressed in terms of quadratures over the impedance of the structures, and impedance functions for a variety of elements are evaluated. It is shown that elements having resonances at high frequency can, above transition, cause bunches to increase in length with increasing current. The parametric dependence of the bunch lengthening is found to be in good agreement with observations, and numerical estimates, which are in substantial agreement with experiment, are presented.

In order to build a thin particle detector with 10 micron spatial resolution and automatic readout, the avalanche of ionization electrons in high electric fields in liquid argon and liquid xenon has been studied. We present a scheme using an array of points that could be used to make a reliable liquid argon filled detector. The avalanche pulses in liquid xenon have a rise time more than three orders of magnitude faster than that in liquid argon, suggesting that the positive charge carriers are holes, and making possible a detector with a time resolution of better than 100 nanoseconds. A direct observation of hole conduction is described.