Development of an experimental database and theories for prediction of thermodynamic properties of aqueous electrolytes and nonelectrolytes of geochemical significance at supercritical temperatures and pressures (open access)

Development of an experimental database and theories for prediction of thermodynamic properties of aqueous electrolytes and nonelectrolytes of geochemical significance at supercritical temperatures and pressures

Volumetric measurements have been completed for CH{sub 4}, CO{sub 2}, and H{sub 2}S at temperatures from 25{degrees}C to 380{degrees}C and 2 or 3 pressures at each temperature. The H{sub 2}S and CO{sub 2} solutions are stored in aluminized mylar bags in PVC pipes with water surrounding the bags at a pressure of several atmospheres. The methane is stored in a one liter autoclave with a sliding teflon piston engaging the sides of the autoclave which separates the standard methane solution from the pressurizing fluid. The solutions are prepared at 100 to 200 atmospheres and do not need to be re-standardized after each experiment. We also have some measurements on aqueous ammonia, boric acid, and acetic acid. Preliminary calculations of the free energy of methane in water at room temperature as a function of the model parameters for the methane have been finished. In preparation for these calculations, the theory and practice of the free energy perturbation calculations was reviewed. In molecular dynamics and Monte Carlo calculations a system does not immediately equilibrate to a change in the Hamiltonian, so that there is a time lag or a configuration number lag in the response of the system. These lags cause errors …
Date: May 2, 1991
Creator: Wood, R.H.
Object Type: Report
System: The UNT Digital Library
Optical analogs of model atoms in fields (open access)

Optical analogs of model atoms in fields

The equivalence of the paraxial wave equation to a time-dependent Schroedinger equation is exploited to construct optical analogs of model atoms in monochromatic fields. The approximation of geometrical optics provides the analog of the corresponding classical mechanics. Optical analogs of Rabi oscillations, photoionization, stabilization, and the Kramers-Henneberger transformation are discussed. One possibility for experimental realization of such optical analogs is proposed. These analogs may be useful for studies of quantum chaos'' when the ray trajectories are chaotic. 9 refs.
Date: May 2, 1991
Creator: Milonni, P.W.
Object Type: Article
System: The UNT Digital Library
An analysis of the tritium content in fish from Upper Three Runs Creek (open access)

An analysis of the tritium content in fish from Upper Three Runs Creek

In November of 1988 the F/H-area effluent treatment facility (ETF) began releasing treated waste water to Upper Three Runs Creek. Previous to that time, there has been minimal discharge of plant waste water to this tributary of the Savannah River. The ETF is designed to remove the toxic and radioactive waste materials from the effluent stream and to meet the discharge limits of the South Carolina Department of Health and Environmental Control (SCDHEC). The only radioactive nuclide not removed by the process is tritium. Tritium, an isotope of hydrogen, is chemically associated with the water molecules in the waste stream and can not be economically removed at this time. The objective of this study was to determine the relationship between the concentration of tritium in the stream water and the concentration of tritium in the fish. Fish collections were made at two locations. The most upstream location was 50 meters downstream from the SRS Road C bridge. This is immediately downstream of the effluent discharge pipe from the ETF. The other location was at the bridge of SRS Road A (SC Highway 125). The water is removed from the fish by freeze drying under vacuum. This study suggests that, on …
Date: May 2, 1991
Creator: Murphy, C. E. Jr.
Object Type: Report
System: The UNT Digital Library
An analysis of the tritium content in fish from Upper Three Runs Creek (open access)

An analysis of the tritium content in fish from Upper Three Runs Creek

In November of 1988 the F/H-area effluent treatment facility (ETF) began releasing treated waste water to Upper Three Runs Creek. Previous to that time, there has been minimal discharge of plant waste water to this tributary of the Savannah River. The ETF is designed to remove the toxic and radioactive waste materials from the effluent stream and to meet the discharge limits of the South Carolina Department of Health and Environmental Control (SCDHEC). The only radioactive nuclide not removed by the process is tritium. Tritium, an isotope of hydrogen, is chemically associated with the water molecules in the waste stream and can not be economically removed at this time. The objective of this study was to determine the relationship between the concentration of tritium in the stream water and the concentration of tritium in the fish. Fish collections were made at two locations. The most upstream location was 50 meters downstream from the SRS Road C bridge. This is immediately downstream of the effluent discharge pipe from the ETF. The other location was at the bridge of SRS Road A (SC Highway 125). The water is removed from the fish by freeze drying under vacuum. This study suggests that, on …
Date: May 2, 1991
Creator: Murphy, C. E. Jr.
Object Type: Report
System: The UNT Digital Library
Automatically processed alpha-track radon monitor (open access)

Automatically processed alpha-track radon monitor

An automatically processed alpha-track radon monitor is provided which includes a housing having an aperture allowing radon entry, and a filter that excludes the entry of radon daughters into the housing. A flexible track registration material is located within the housing that records alpha-particle emissions from the decay of radon and radon daughters inside the housing. The flexible track registration material is capable of being spliced such that the registration material from a plurality of monitors can be spliced into a single strip to facilitate automatic processing of the registration material from the plurality of monitors. A process for the automatic counting of radon registered by a radon monitor is also provided.
Date: May 2, 1991
Creator: Langner, G. H. Jr.
Object Type: Patent
System: The UNT Digital Library