Report on results of research on the catalytic macrocyclization reactions of thietane and thiolactones by metal carbonyl complexes.

The diverse set of organizations and software components involved in a typical collaboratory make providing a seamless security solution difficult. In addition, the users need support for a broad range of frequency and locations for access to the collaboratory. A collaboratory security solution needs to be robust enough to ensure that valid participants are not denied access because of its failure. There are many tools that can be applied to the task of securing collaborative environments and these include public key infrastructure, secure sockets layer, Kerberos, virtual and real private networks, grid security infrastructure, and username/password. A combination of these mechanisms can provide effective secure collaboration capabilities. In this paper, we discuss the requirements of typical collaboratories and some proposals for applying various security mechanisms to collaborative environments.

Copper ions for the 2005 run [1] of the Relativistic Heavy Ion Collider (RHIC) at Brookhaven National Laboratory (BNL) are accelerated in the Tandem, Booster and AGS prior to injection into RHIC. The setup and performance of these accelerators with copper are reviewed in this paper.

Soil CO{sub 2} flux surveys have been conducted over known CO{sub 2} reservoirs at Farnham Dome, Utah, Crystal Geyser-Ten Mile Graben in Utah and Springerville-St. Johns, Arizona. No anomalous CO{sub 2} flux was detected at the Farnham Dome and Springerville-St. Johns. At Crystal Geyser-Ten Mile Graben, localized areas of anomalously high CO{sub 2} flux ({approx}100 g m{sup -2} day{sup -1}) occur along a fault zone near visibly degassing features. Isotopic measurements on CO{sub 2} collected from nearby springs indicate that it originated at depth. Evidence of widespread vein calcite at the surface (Farnham Dome) and travertine deposits at the other two areas suggests that discharge of CO{sub 2}-rich fluids has occurred in the past. Despite the lack of evidence for significant present day leakage of CO{sub 2} to the atmosphere at Springerville-St. Johns and Crystal Geyser-Ten Mile Graben, there are significant outflows of high-bicarbonate water in both areas suggesting continuous migration of CO{sub 2} in the aqueous phase from depth. The very localized nature of the CO{sub 2} flux anomalies, and the outflow of ground water containing dissolved CO{sub 2} present challenges for effective, long term monitoring of CO{sub 2} leakage.

This report presents the results from the Columbia River Recreation Survey conducted in the summer of 2001. The survey combined on-site personal interviews with parties engaged in river recreation with on-site field observations to develop a picture of summer river recreation on the Columbia. The study area stretched from just below Priest Rapids Dam in the north to McNary Dam in the south, and was divided into four "Areas" that correspond to the river areas used by the Groundwater/Vadose Zone Integration Project. This study is part of the Groundwater/Vadose Zone Integration Project and was commissioned specifically to document the current recreation use levels in these areas of the river, and to elicit recreation-related expenditure information from visitors. This information informs economic and environmental models used to measure the economic risk posed by possible, but unlikely, releases of contaminants from the Hanford site into the Columbia River. During the study period, researchers collected 256 survey responses and 396 field observations from recreation sites up and down both shores of the river in the study area. Results presented include analysis of trip duration by river activity, trip frequency, and visitor place of origin. Economics-related results include trip expenditure profiles by activity and …

None

Recent recoil polarization measurements in Hall A at Jefferson Lab show that the ratio of the electric to magnetic form factors for the proton decreases significantly with increasing Q{sup 2}. This contradicts previous Rosenbluth measurements which indicate approximate scaling of the form factors ({micro}{sub p} G{sub E}{sup p}(Q{sup 2})/G{sub M}{sup p} (Q{sup 2}) {approx} 1). The cross section measurements were reanalyzed to try and understand the source of this discrepancy. They find that the Rosenbluth measurements are consistent when normalization uncertainties are taken into account, and that the discrepancy cannot come from errors in one or two data sets. If there is a problem in the Rosenbluth data, it must be a systematic, {epsilon}-dependent uncertainty affecting several experiments.

We present an independent calculation of that part of the O({alpha}{sub s}{sup 2}) contribution to dipole operator {Omicron}{sub 7}. Using a different method, we find complete agreement mass ambiguity appearing at NLL accuracy. the complete NNLL prediction of {Lambda}({bar B} {yields} X{sub s}{gamma}) which will resolve the charm quark the decay width {Lambda}({bar B} {yields} X{sub s}{gamma}) which arises from the self-interference term of the electromagnetic with a previous calculation. This NNLL contribution is an important ingredient for

We perform an amplitude analysis of B{sup {+-}} {yields} {var_phi}(1020)K*(892){sup {+-}} decay with a sample of about 384 million B{bar B} pairs recorded with the BABAR detector. Overall, twelve parameters are measured, including the fractions of longitudinal f{sub L} and parity-odd transverse f{sub {perpendicular}} amplitudes, branching fraction, strong phases, and six parameters sensitive to CP-violation. We use the dependence on the K{pi} invariant mass of the interference between the J{sup P} = 1{sup -} and 0{sup +} K{pi} components to resolve the discrete ambiguity in the determination of the strong and weak phases. Our measurements of f{sub L} = 0.49 {+-} 0.05 {+-} 0.03, f{sub {perpendicular}} = 0.21 {+-} 0.05 {+-} 0.02, and the strong phases point to the presence of a substantial helicity-plus amplitude from a presently unknown source.

The authors report a study of the processes e{sup +}e{sup -} {yields} {eta}{gamma} and e{sup +}e{sup -} {yields} {eta}'{gamma} at a center-of-mass energy of 10.58 GeV, using a 232 fb{sup -1} data sample collected with the BABAR detector at the PEP-II collider at SLAC.

The authors present results from an analysis of B{sup 0} {yields} {rho}{sup +}{rho}{sup -} decays using (383.6 {+-} 4.2) x 10{sup 6} B{bar B} pairs collected by the BABAR detector at the PEP-II asymmetric-energy B Factory at SLAC. The measurements of the B{sup 0} {yields} {rho}{sup +}{rho}{sup -} branching fraction, longitudinal polarization fraction f{sub L}, and the CP-violating parameters S{sub long} and C{sub long} are: {Beta}(B{sup 0} {yields} {rho}{sup +}{rho}{sup -}) = (25.5 {+-} 2.1(stat){sub -3.9}{sup +3.6}(syst)) x 10{sup -6}, f{sub L} = 0.992 {+-} 0.024(stat){sub -0.013}{sup +0.026}(syst), S{sub long} = -0.17 {+-} 0.20(stat){sub -0.06}{sup +0.05}(syst), C{sub long} = 0.01 {+-} 0.15(stat) {+-} 0.06(syst). The authors determine the unitarity triangle angle {alpha}, using an isospin analysis of B {yields} {rho}{rho} decays. One of the two solutions, {alpha} = [73.1, 117.0]{sup o} at 68% CL is compatible with standard model-based fits of existing data. Constraints on the unitarity triangle are also evaluated using an SU(3) symmetry based approach.

We present branching fraction measurements of twelve B meson decays of the form B {yields} D{sup (*)} D{sub s(J)}{sup (*)}. The results are based on {Upsilon}(4S) decays in B{bar B} pairs. One of the B mesons is fully reconstructed and the other decays to two charm mesons, of which one is reconstructed, and the mass and momentum of the other is inferred by kinematics. Combining these results with previous exclusive branching fraction measurements, we determine {Beta}(D{sub s}{sup -} {yields} {phi}{pi}{sup -}) = (4.62 {+-} 0.36{sub stat.} {+-} 0.51{sub syst.})%, {Beta}(D{sub sJ}(2460){sup -} {yields} D*{sub s}{sup -} {pi}{sup 0}) = (56 {+-} 13{sub stat.} {+-} 9{sub syst.})% and {Beta}(D{sub sJ}(2460){sup -} {yields} D{sub s}{sup -}{gamma}) = (16 {+-} 4{sub stat.} {+-} 3{sub syst.})%.

The purpose of this technical evaluation is to determine whether the secondary hoses are to be categorized as Commercial Grade Items (CGI) or Engineered Equipment. This determination will identify whether or not use of the CGI Dedication process is appropriate.

Nuclear structure data pertaining to {sup 225}Fr have been evaluated, and incorporated into the ENSDF data file. This evaluation includes literature available by 16 May 2005 and supersedes the previous publication for {sup 225}Fr (Y.A. Akovali, ''Nuclear Data Sheets 60, 617 (1990)'', literature cutoff date 1 June 1989). Data have been incorporated from the following references: 1987Co19, 1997BuO3 and 2003AuO3.

The Relativistic Heavy Ion Collider provides not only collisions of ions but also collisions of polarized protons. In a circular accelerator, the polarization of polarized proton beam can be partially or fully lost when a spin depolarizing resonance is encountered. To preserve the beam polarization during acceleration, two full Siberian snakes were employed in RHIC. In 2002, polarized proton beams were first accelerated to 100 GeV and collided in RHIC. Beams were brought into collisions with longitudinal polarization at the experiments STAR and PHENIX by using spin rotators. Optimizing polarization transmission efficiency and improving luminosity performance are significant challenges. Currently, the luminosity lifetime in RHIC is limited by the beam-beam effect. The current state of RHIC polarized proton program, including its dedicated physics run in 2005 and efforts to optimize luminosity production in beam-beam limited conditions are reported.

Siberian snakes now become essential in the polarized proton acceleration. With proper configuration of Siberian snakes, the spin precession tune of the beam becomes 1/2 which avoids all the spin depolarizing resonance. However, the enhancement of the perturbations on the spin motion can still occur when the spin precession tune is near some low order fractional numbers, called snake resonances, and. the beam can be depolarized when passing through the resonance. The snake resonances have been confirmed in the spin tracking calculations, and observed in RHIC with polarized proton beam. Equipped with two full Siberian snakes in each ring, RHIC provides us a perfect facility for snake resonance studies. This paper presents latest experimental results. New insights are also discussed.

The losses of charged particles from a detector aperture, due to multiple scattering of the particles in thin layers of material preceding the detector, are calculated with the aid of a high-speed digitai computer. The rootmean-square multiple-scattering angle is computed after the method of Moliere, and graphs are presented for protons and alpha particles scattering in nitrogen, aluminum, argon, copper, silver, and gold, and for deuterons and tritons scattering in aluminum and copper. The range of particle energy covered is from 5 to 100 Mev. A second program is used to construct a map from which losses, as a function of the root-mean-square multiple-scattering angle and the scattering configuration, may be directly read. The FORTRAN listings for both programs are given. (auth)

A systematic methodology is presented and applied for the identification of requirements and issues pertaining to the planning for, and transition to, long term stewardship (LTS). The method has been applied to three of the twelve identified LTS functions. The results of the application of the methodology to contaminated and uncontaminated federal real property in those three functions are presented. The issues that could be seen as impediments to the implementation of LTS are also identified for the three areas under consideration. The identified requirements are significant and in some cases complex to implement. It is clear that early and careful planning is required in all circumstances.

Concerns about global climate change have substantially increased the likelihood that future policy will seek to minimize carbon dioxide emissions. Assuch, even today, electric utilities are making resource planning and investment decisions that consider the possible implications of these future carbon regulations. In this article, we examine the manner in which utilities assess the financial risks associated with future carbon regulations within their long-term resource plans. We base our analysis on a review of the most recent resource plans filed by fifteen electric utilities in the Western United States. Virtually all of these utilities made some effort to quantitatively evaluate the potential cost of future carbon regulations when analyzing alternate supply- and demand-side resource options for meeting customer load. Even without Federal climate regulation in the U.S., the prospect of that regulation is already having an impact on utility decision-making and resource choices. That said, the methods and assumptions used by utilities to analyze carbon regulatory risk, and the impact of that analysis on their choice of a particular resource strategy, vary considerably, revealing a number of opportunities for analytic improvement. Though our review focuses on a subset of U.S. electric utilities, this work holds implications for all electric utilities …

Coupling correction is essential for the operational performance of RHIC. The independence of the transverse degrees of freedom makes diagnostics and tune control easier, and it is advantageous to operate an accelerator close to the coupling resonance to minimize nearby nonlinear sidebands. An automated coupling correction application iDQmini has been developed for RHIC routine operations. The application decouples RHIC globally by minimizing the tune separation through finding the optimal settings of two orthogonal skew quadrupole families. The program iDQmini provides options of automatic, semi-automatic and manual decoupling operations. It accesses tune information from all RHIC tune measurement systems: the PLL (phase lock loop), the high frequency Schottky system and the tune meter. It also supplies tune and skew quadrupole scans, finding the minimum tune separation, display the real time results and interface with the RHIC control system. We summarize the capabilities of the coupling correction application iDQmini, and discuss the operational protections incorporated in the program.

The electron-ion collider eRHIC [1] currently under study at BNL consists of an electron storage ring added to the existing RHIC complex. The interaction region of this facility has to provide the required low-beta focusing while accommodating the synchrotron radiation generated by beam separation close to the interaction point. In the current design, the synchrotron radiation caused by 10GeV electrons bent by separator dipole magnets will be guided through the interaction region and dumped 5m downstream. However, it is unavoidable to stop a fraction of the photons at the septum where the electron and ion vacuum systems are separated. In order to protect the septum and minimize the backward synchrotron radiation, an absorber and collimation system will be employed. In this paper, we fist present the overview of the current design of the eRHIC interaction region with special emphasis on the synchrotron radiation. Then the initial design of the absorber, including its geometrical and physical property, will be described. Finally, our initial investigation of synchrotron radiation in the eRHIC interaction region, especially a simulation of the backward scattering from the absorber, will be presented.

This Phase I SBIR project focused on developing flexible scintillating liquid core optical fibers, with potential uses in high-energy calorimetry, tracking, preradiators, active targets or other fast detectors. Progress on the six tasks of the project is summarized. The technical developments involve three technology components: (1) highly flexible capillaries or tubes of relatively low n (index of refraction) to serve as cladding and liquid core containment; (2) scintillator (and clear) fluids of relatively high n to serve as a core-- these fluids must have a high light transmission and, for some applications, radiation hardness; (3) optical end plugs, plug insertion, and plug-cladding tube sealing technology to contain the core fluids in the tubes, and to transmit the light.

Thermodynamic studies have been performed for the beam target and focusing horn system to be used in a very long baseline neutrino oscillation experiment [1]. A 2mm rms beam spot with power deposition of over 18 KW presents challenging material and engineering solutions to this project. Given that the amount of heat transferred by radiation alone from the target to the horn is quite small, the primary mechanism is heat removal by forced convection in the annular space between the target and the horn. The key elements are the operating temperature of the target, the temperature of the cooling fluid and the heat generation rate in the volume of the target that needs to be removed. These working parameters establish the mass flow rate and velocity of the coolant necessary to remove the generated heat. Several cooling options were explored using a carbon-carbon target and aluminum horn. Detailed analysis, trade studies and simulations were performed for cooling the horn and target with gaseous helium as well as water.

Next generation ERL light-sources, high-energy electron coolers, high-power Free-Electron Lasers, powerful Compton X-ray sources and many other accelerators were made possible by the emerging technology of high-power, high-brightness electron beams. In order to get the anticipated performance level of ampere-class currents, many technological barriers are yet to be broken. BNL's Collider-Accelerator Department is pursuing some of these technologies for its electron cooling of RHIC application, as well as a possible future electron-hadron collider. We will describe work on CW, high-current and high-brightness electron beams. This will include a description of a superconducting, laser-photocathode RF gun and an accelerator cavity capable of producing low emittance (about 1 micron rms normalized) one nano-Coulomb bunches at currents of the order of one ampere average.