We subjected the Meteorological Data Acquisition (MEDA) remote station hardware to temperature, vibration, and road tests. The MEDA equipment was designed at the Lawrence Livermore Laboratory (LLL) for the Air Resources Laboratory (ARL). ARL supplied all MEDA sensors. The prototype system passed these tests.

Erbium hydride thin films are grown onto polished, a-axis {alpha} Al{sub 2}O{sub 3} (sapphire) substrates by reactive ion beam sputtering and analyzed to determine composition, phase and microstructure. Erbium is sputtered while maintaining a H{sub 2} partial pressure of 1.4 x 10{sup {minus}4} Torr. Growth is conducted at several substrate temperatures between 30 and 500 C. Rutherford backscattering spectrometry (RBS) and elastic recoil detection analyses after deposition show that the H/Er areal density ratio is approximately 3:1 for growth temperatures of 30, 150 and 275 C, while for growth above {approximately}430 C, the ratio of hydrogen to metal is closer to 2:1. However, x-ray diffraction shows that all films have a cubic metal sublattice structure corresponding to that of ErH{sub 2}. RBS and Auger electron that sputtered erbium hydride thin films are relatively free of impurities.

The Antiproton (Pbar) Source at Fermi National Accelerator Laboratory is a facility comprised of a target station, two rings called the Debuncher and Accumulator and the transport lines between those rings and the remainder of the particle accelerator complex. Water is by far the most common medium for carrying excess heat away from components, primarily electromagnets, in this facility. The largest of the water systems found in Pbar is the 95 degree Fahrenheit Low Conductivity Water (LCW) system. LCW is water which has had free ions removed, increasing its resistance to electrical current. This water circuit is used to cool magnets, power supplies, and stochastic cooling components and typically has a resistivity of 11--18 megaohms-cm. For more than ten years the Antiproton rings were plagued with overheating magnets due to plugged water-cooling channels. Various repairs have been tried over the years with no permanent success. Throughout all of this time, water samples have indicated copper oxide, CuO, as the source of the contamination. Matters came to a head in early 1997 following a major underground LCW leak between the Central Utilities Building and the Antiproton Rings enclosures. Over a span of several weeks following system turn-on, some twenty magnets overheated …

Glycolic acid (GA) is being studied as an alternate reductant in the Defense Waste Processing Facility (DWPF) feed preparation process. It will either be a total or partial replacement for the formic acid that is currently used. A literature review has been conducted on the impact of glycolate on two post-DWPF downstream systems - the 2H Evaporator system and the Effluent Treatment Facility (ETF). The DWPF recycle stream serves as a portion of the feed to the 2H Evaporator. Glycolate enters the evaporator system from the glycolate in the recycle stream. The overhead (i.e., condensed phase) from the 2H Evaporator serves as a portion of the feed to the ETF. The literature search revealed that virtually no impact is anticipated for the 2H Evaporator. Glycolate may help reduce scale formation in the evaporator due to its high complexing ability. The drawback of the solubilizing ability is the potential impact on the criticality analysis of the 2H Evaporator system. It is recommended that at least a theoretical evaluation to confirm the finding that no self-propagating violent reactions with nitrate/nitrites will occur should be performed. Similarly, identification of sources of ignition relevant to glycolate and/or update of the composite flammability analysis to …

The US Heavy Ion Fusion Virtual National Laboratory is continuing research into ion sources and injectors that simultaneously provide high current (0.5-1.0 Amps) and high brightness (normalized emittance better than 1.0 {pi}-mm-mr). The central issue of focus is whether to carry on the traditional approach of large surface ionization sources or to adopt a multi-aperture approach that transports many smaller ''beamlets'' separately at low energies before allowing them to merge. For the large surface source, the recent commissioning of the 2-MeV injector for the High Current experiment has increased our understanding of the beam quality limitations for these sources. We have also improved our techniques for fabricating large diameter aluminosilicate sources to improve lifetime and emission uniformity. For the multi-aperture approach we are continuing to study the feasibility of small surface sources and a RF induced plasma source in preparation for beamlet merging experiments, while continuing to run computer simulations for better understanding of this alternate concept. Experiments into both architectures will be performed on a newly commissioned ion source test stand at LLNL called the STS-500. This stand test provides a platform for testing a variety of ion sources and accelerating structures with 500 kV, 17-microsecond pulses. Recent progress …

A major problem with cavitation in pumps and other hydraulic devices is that there is no effective method for detecting or predicting its inception. The traditional approach is to declare the pump in cavitation when the total head pressure drops by some arbitrary value (typically 3o/0) in response to a reduction in pump inlet pressure. However, the pump is already cavitating at this point. A method is needed in which cavitation events are captured as they occur and characterized by their process dynamics. The object of this research was to identify specific features of cavitation that could be used as a model-based descriptor in a context-dependent condition-based maintenance (CD-CBM) anticipatory prognostic and health assessment model. This descriptor was based on the physics of the phenomena, capturing the salient features of the process dynamics. An important element of this concept is the development and formulation of the extended process feature vector @) or model vector. Thk model-based descriptor encodes the specific information that describes the phenomena and its dynamics and is formulated as a data structure consisting of several elements. The first is a descriptive model abstracting the phenomena. The second is the parameter list associated with the functional model. The …

The overall objective of the bioremediation project is to provide a cost effective bioremediation demonstration of petroleum contaminated soil at the Czechowice Oil Refinery. Additional objectives include training of personnel, and transfer of this technology by example to Poland, and the Risk Abatement Center for Central and Eastern Europe (RACE). The goal of the remediation is to reduce the risk of PAH compounds in soil and provide a green zone (grassy area) adjacent to the site boundary. Initial project discussions with the Czechowice Oil Refinery resulted in helping the refinery find an immediate cost effective solution for the dense organic sludge in the lagoons. They found that when mixed with other waste materials, the sludge could be sold as a fuel source to local cement kilns. Thus the waste was incinerated and provided a revenue stream for the refinery to cleanup the lagoon. This allowed the bioremediation project to focus on remediation of contaminated soil that unusable as fuel, less recalcitrant and easier to handle and remediate. The assessment identified 19 compounds at the refinery that represented significant risk and would require remediation. These compounds consisted of metals, PAH`s, and BTEX. The contaminated soil to be remediated in the bioremediation …

Kinetic data for elimination of silylene supports formation of a ``tighter`` transition state, indicating a silacyclopropene intermediate. This extends the silacyclopropene mechanism to the cyclicdialkyne system and validates the consistency of the mechanism for silylakynes, in general. Investigation into the other possible silacyclopropene product established the instability of the product. The work with silylketenes proved that an inherent difference exists between reactivity of monosilyl-substituted ketenes and polysilyl-substituted ketenes. Although the mechanism for thermal decomposition of bis(silyl)ketenes can be modified to account for the unexpected silylene elimination products, reasons for the difference are limited to speculation. The photochemistry of silylketenes has not been previously studied, so a model system does not exist for comparison with our polysilylketene work. The photochemical experimentation suggests that the photochemistry and thermochemistry of polysilylketenes is not the same. A more extensive study of the mechanism of the systems covered in this research as well as with monosilyl-substituted systems is needed.

Time-dependent ion charge state measurements for Pb and Bicathodic arc plasmas revealed unexpectedly strong differences: the meanBi ion charge state dropped much stronger and with a longer time constantthan the mean Pb ion charge state. It is shown that the difference inthermal conductivity led to much higher vapor pressure for Bi, which inturn much more effectively caused charge exchange collisions. The resultshave implications beyond Pb and Bi plasmas, most importantly that the"true" charge states as emitted from the cathode spot are higher thanwhat is generally measured and published.

The spatial distribution of copper ions and atoms in high power impulse magnetron sputtering (HIPIMS) discharges was determined by (i) measuring the ion current to electrostatic probes and (ii) measuring the film thickness by profilometry. A set of electrostatic and collection probes were placed at different angular positions and distances from the target surface. The angular distribution of the deposition rate and the average charge state of the copper species (including ions and neutrals) were deduced.The discharge showed a distinct transition to a high current mode dominated by copper self-sputtering when the applied voltage exceeded the threshold of 535 V. For a lower voltage, the deposition rate was very low and the average charge state was found to be less than 0.4. For higher voltage (and average power), the absolute deposition rates were much higher, but they were smaller than the corresponding direct current (DC) rates if normalized to the same average power. At the high voltage level, the spatial distribution of the average charge state showed some similarities with the distribution of the magnetic field, suggesting that the generation and motion of copper ions is affected by magnetized electrons. At higher voltage, the average charge state increases with the …

Using ORNL information on the characterization of the tank waste sludges, SRTC performed extensive bench-scale vitrification studies using simulants. Several glass systems were tested to ensure the optimum glass composition (based on the glass liquidus temperature, viscosity and durability) is determined. This optimum composition will balance waste loading, melt temperature, waste form performance and disposal requirements. By optimizing the glass composition, a cost savings can be realized during vitrification of the waste. The preferred glass formulation was selected from the bench-scale studies and recommended to ORNL for further testing with samples of actual OR waste tank sludges.

The following are proposed activities for quarter 3 (12/15/00-3/14/01): (1) Conduct TGA and fuel characterization studies - Task 1; (2) Continue to perform re-burn experiments. - Task 2; (3) Design fixed bed combustor. - Task 3; and (4) Modify the PCGC2 code to include moisture evaporation model - Task 4. The following were achieved During Quarter 3 (12/15/0-3/14/01): (1) Conducted TGA and Fuel Characterization studies (Appendix I). A comparison of -fuel properties, TGA traces etc is given in Appendix I. Litter has 3 and 6 times more N compared to coal on mass and heat basis. The P of litter is almost 2 % (Task 1). Both litter biomass (LB) and feedlot biomass (FB) have been pulverized. The size distributions are similar for both litter and FB in that 75 % pass through 150 {micro}m sieve while for coal 75 % pass through 60 {micro}m sieve. Rosin Rammler curve parameters are given. The TGA characteristics of FB and LB are similar and pyrolysis starts at 100 C below that of coal; (2) Reburn experiments with litter and with FB have been performed (Appendix II) -Task 2. Litter is almost twice effective (almost 70--90 % reduction) compared to coal in reducing …

Paper presented at the International Conference on Ultra-Relativistic Nucleus-Nucleus Collisions (1999) reporting on the progress of the STAR experiment, a complex system of many detector sub-systems which have been installed in a large solenoidal magnet at the Relativistic Heavy Ion Collider (RHIC).

This paper reports the results in the effort to destabilize lithium borohydride for reversible hydrogen storage. A number of metals, metal hydrides, metal chlorides and complex hydrides were selected and evaluated as the destabilization agents for reducing dehydriding temperature and generating dehydriding-rehydriding reversibility. It is found that some additives are effective. The Raman spectroscopic analysis shows the change of B-H binding nature.

The authors present a search for the rare B-meson decay B{sup 0} {yields} {alpha}{sub 1}{sup {+-}}{rho}{sup {-+}} with {alpha}{sub 1}{sup {+-}} {yields} {pi}{sup +}{pi}{sup -}{pi}{sup {+-}}. We use (110 {+-} 1.2) x 10{sup 6} {Upsilon}(4S) {yields} B{bar B} decays collected with the BABAR detector at the PEp-II asymmetric-energy B Factory at SLAC. They obtain an upper limit of 30 x 10{sup -6} (90% C.L.) for the branching fraction product {Beta}(B{sup 0} {yields} {alpha}{sub 1}{sup {+-}}{rho}{sup {-+}}) {Beta}({alpha}{sub 1}{sup {+-}} {yields} {pi}{sup +}{pi}{sup -}{pi}{sup {+-}}), where they assume that the {alpha}{sub 1}{sup {+-}} decays exclusively to {rho}{sup 0}{pi}{sup {+-}}.

SRTC performed small-scale tests to determine the behavior associated with blending streams in the High-level Waste (HLW) Lag Storage and Feed Blending Process System for the Hanford Waste Treatment and Immobilization Plant (WTP). The work reported here was planned and designed in response to the test specification. The Office of River Protection Hanford Waste Treatment and Immobilization Plant consists of three primary facilities: a Pretreatment Facility and two facilities for low-activity and high-level waste vitrification. The Pretreatment Facility contains unit operations which receive waste feed from the Hanford Tank Farms and separate it into two treated waste streams: a low-activity, liquid waste stream stripped of most solids and radioisotopes (processed through the Low-Activity Waste Vitrification Facility) and a high-level waste slurry containing most of the solids and radioisotopes (processed through the High-Level Waste Vitrification Facility). Blending of the later solids a nd radioisotopes streams and their resulting properties is the subject of this report. These mixtures are shown to be unreactive and pumpable by using statistically designed combinations of nonradioactive simulants for the process streams. Properties of the mixtures are also predicted numerically (with the Environmental Simulation Program) and compared with the experimental results. The results did not reveal any …

A high energy beam absorber has been built for the Advanced Superconducting Test Accelerator (ASTA) at Fermilab. In the facility's initial configuration, an electron beam will be accelerated through 3 TTF-type or ILC-type SRF cryomodules to an energy of 750MeV. The electron beam will be directed to one of multiple downstream experimental and diagnostic beam lines and then deposited in one of two beam absorbers. The facility is designed to accommodate up to 6 cryomodules, which would produce a 75kW beam at 1.5GeV; this is the driving design condition for the beam absorbers. The beam absorbers consist of water-cooled graphite, aluminum and copper layers contained in a helium-filled enclosure. This paper describes the mechanical implementation of the beam absorbers, with a focus on thermal design and analysis. The potential for radiation-induced degradation of the graphite is discussed.

The increasing gap between processor performance and memory access time warrants the re-examination of data movement in iterative linear solver algorithms. For this reason, we explore and establish the feasibility of modifying a standard iterative linear solver algorithm in a manner that reduces the movement of data through memory. In particular, we present an alternative to the restarted GMRES algorithm for solving a single right-hand side linear system Ax = b based on solving the block linear system AX = B. Algorithm performance, i.e. time to solution, is improved by using the matrix A in operations on groups of vectors. Experimental results demonstrate the importance of implementation choices on data movement as well as the effectiveness of the new method on a variety of problems from different application areas.

Some recent theoretical results on coherent electromagnetic processes in ultrarelativistic heavy ion reactions are surveyed. In ultrarelativistic heavy ion collisions, Coulomb induced cross sections are huge, much larger than geometric. For the RHIC case of 100 GeV x 100 GeV colliding gold ions the predicted cross section for bound-electron positron pairs is about 110 barns. The corresponding cross section for continuum electron-positron pairs has recently been recalculated to be 34,000 barns, consistent with the result of the classic formula of Landau and Lifshitz. The cross section for Coulomb dissociation of the nucleus is about 95 barns, and the cross section for ionization of a single electron on one of the ions is about 100,000 barns.

In March 1998, the 324 Building Fire Hazards Analysis (FHA) (Reference 1) was approved by the U S. Department of Energy, Richland Operations Office (DOE-RL) for implementation by B and W Hanford Company (BWHC). The purpose of the FHA was to identify gaps in compliance with DOE Order 5480.7A (Reference 2) and Richland Operations Office Implementation Directive (RLID) 5480.7 (Reference 3), especially in regard to loss limitation. The FHA identified compliance gaps in six areas and provided 20 recommendations to bring the 324 Building into compliance with DOE Order 5480 7A. Additionally, one observation was provided. A status is provided for each recommendation in this document. The actions for recommendations associated with the safety related part of the 324 Building and operation of the cells and support areas were evaluated using the Unreviewed Safety Question (USQ) process BWHC will use this Implementation Plan to bring the 324 Building and its operation into compliance with DOE Order 5480 7A and RLID 5480.7.

In March 1998, the 327 Building Fire Hazards Analysis (FHA) (Reference 1) was approved by the U.S. Department of Energy, Richland Operations Office (DOE-E) for implementation by B and W Hanford Company (BWC). The purpose of the FHA was to identify gaps in compliance with DOE Order 5480.7A (Reference 2) and Richland Operations Office Implementation Directive (RLID) 5480.7 (Reference 3), especially in regard to loss limitation. The FHA identified compliance gaps in five areas and provided nine recommendations (11 items) to bring the 327 Building into compliance. A status is provided for each recommendation in this document. BWHC will use this Implementation Plan to bring the 327 Building and its operation into compliance with DOE Order 5480.7A and IUD 5480.7.

The primary goals of this report are to (1) understand experimental radiography better (radiograph known static targets); and (2) to better understand the sources and effects of short wavelength perturbations on the long wavelength RT growth. Some secondary goals are to initiate Richtmyer-Meshkov mix targets; test beryllium cylinder implosions (if available); and observe emission spectroscopy from chlorinated foam to study implosions. To achieve these goals the authors: (1) shot mix targets with late backlighter and confirmed set up of radiography, begin static targets; (2) did a sequence of unperturbed and perturbed targets of different smoothness and thickness, fill in static, beryllium, and chlorinated foam targets; and (3) repeated step number 2 at a different backlighter time.

This report provides a qualitative and semiquantitative description of the chemical reaction that decomposed the excess sodium tetraphenylborate in Tank 48H during November and December 1995.

The Advanced Light Source (ALS) will soon be upgraded to enable top-off operations [1], in which electrons are quasi-continuously injected to produce constant stored beam current. The upgrade is structured in two phases. First, we will upgrade our injector from 1.5 GeV to 1.9 GeV to allow full energy injection and will start top-off operations. In the second phase, we will upgrade the Booster Ring (BR) with a bunch cleaning system to allow high bunch purity top-off injection. A diagnostics upgrade will be crucial for success in both phases of the top-off project, and our plan for it is described in this paper. New booster ring diagnostics will include updated beam position monitor (BPM) electronics, a tune monitoring system, and a new scraper. Two new synchrotron light monitors and a beam stop will be added to the booster-to-storage ring transfer line (BTS), and all the existing beam current monitors along the accelerator chain will be integrated into a single injection efficiency monitoring application. A dedicated bunch purity monitor will be installed in the storage ring (SR). Together, these diagnostic upgrades will enable smooth commissioning of the full energy injector and a quick transition to high quality top-off operation at the …