Equations describing coherent and partially coherent multilevel molecular excitation induced by pulsed Raman transitions: III (open access)

Equations describing coherent and partially coherent multilevel molecular excitation induced by pulsed Raman transitions: III

This memo discusses the equations of motion used to describe multilevel molecular excitation induced by Raman transitions. These equations are based upon the time-dependent Schroedinger equation expressed in a basis of molecular energy states. A partition of these states is made into two sets, those that are far from resonance (and hence unpopulated) and those that are close to resonance, either by one-photon transition or two-photon (Raman) processes. By adiabatic elimination an effective Schroedinger equation is obtained for the resonance states alone. The effective Hamiltonian is expressible in terms of a polarizibility operator.
Date: February 18, 1987
Creator: Shore, B. W.; Sacks, R. & Karr, T.
System: The UNT Digital Library