This report documents progress made on the subject project during the period of September 1, 2003 through February 28, 2004. The TERESA Study is designed to investigate the role played by specific emissions sources and components in the induction of adverse health effects by examining the relative toxicity of coal combustion and mobile source (gasoline and/or diesel engine) emissions and their oxidative products. The study involves on-site sampling, dilution, and aging of coal combustion emissions at three coal-fired power plants, as well as mobile source emissions, followed by animal exposures incorporating a number of toxicological endpoints. The DOE-EPRI Cooperative Agreement (henceforth referred to as ''the Agreement'') for which this technical progress report has been prepared covers the analysis and interpretation of the field data collected at the first power plant (located in the Upper Midwest), followed by the performance and analysis of similar field experiments at two additional coal-fired power plants utilizing different coal types and with different plant configurations. Modifications to the original study design, which will improve the atmospheric aging component of the project and ensure that emissions are as realistic as possible, have resulted in project delays, and, at the time of report preparation, fieldwork at the …

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This report describes the approach to estimating the benefits and analysis results for the Heavy Vehicle Technologies activities of the FreedomCar and Vehicle Technologies (FCVT) Program of EERE. The scope of the effort includes: (1) Characterizing baseline and advanced technology vehicles for Class 3-6 and Class 7 and 8 trucks, (2) Identifying technology goals associated with the DOE EERE programs, (3) Estimating the market potential of technologies that improve fuel efficiency and/or use alternative fuels, (4) Determining the petroleum and greenhouse gas emissions reductions associated with the advanced technologies. In FY 05 the Heavy Vehicles program activity expanded its technical involvement to more broadly address various sources of energy loss as compared to focusing more narrowly on engine efficiency and alternative fuels. This broadening of focus has continued in subsequent activities. These changes are the result of a planning effort that occurred during FY 04 and 05. (Ref. 1) This narrative describes characteristics of the heavy truck market as they relate to the analysis, a description of the analysis methodology (including a discussion of the models used to estimate market potential and benefits), and a presentation of the benefits estimated as a result of the adoption of the advanced technologies. …

Mercury continuous emissions monitoring systems (CEMS) are being implemented in over 800 coal-fired power plant stacks. The power industry desires to conduct at least a full year of monitoring before the formal monitoring and reporting requirement begins on January 1, 2009. It is important for the industry to have available reliable, turnkey equipment from CEM vendors. Western Research Institute (WRI) is working closely with the Electric Power Research Institute (EPRI), the National Institute of Standards and Technology (NIST), and the Environmental Protection Agency (EPA) to facilitate the development of the experimental criteria for a NIST traceability protocol for dynamic elemental mercury vapor generators. The generators are used to calibrate mercury CEMs at power plant sites. The Clean Air Mercury Rule (CAMR) which was published in the Federal Register on May 18, 2005 requires that calibration be performed with NIST-traceable standards (Federal Register 2007). Traceability procedures will be defined by EPA. An initial draft traceability protocol was issued by EPA in May 2007 for comment. In August 2007, EPA issued an interim traceability protocol for elemental mercury generators (EPA 2007). The protocol is based on the actual analysis of the output of each calibration unit at several concentration levels ranging initially …

Severe plastic deformation in an eutectic tin-lead alloy is studied by imposing fast bending at room temperature, in an attempt to examine the microstructural response in the absence of thermally activated diffusion processes. A change in microstructure due to this purely mechanically imposed load is observed: the tin-rich matrix phase appears to be extruded out of the narrow region between neighboring layers of the lead-rich phase and alterations in the colony structure occur. A micromechanism is proposed to rationalize the experimental observations.

This program is part of the US Department of Energy (DOE) Energy Related Inventions Program (ERIP). The purpose of ERIP is to promote and facilitate the development of energy saving technologies that may not otherwise be developed solely by commercial enterprises. The program has been highly successful in achieving its mission. The aim of this project is to determine and provide technical and economic data to a commercial end user of the alloy so that a full-scale alloy qualification program can be defined and implemented. The object of this project is to define the compositional range for a new alloy that is suitable for evaluation and qualification by a commercial enterprise. Alloy properties that will need to be determined include weldability, oxidation resistance, creep strength, resistance to thermo-mechanical fatigue, microstructure stability, and cost. Test results will be used to finalize the compositional range of an alloy that will undergo a rigorous qualification process.

This report describes the approach to estimating the benefits and analysis results for the Heavy Vehicle Technologies activities of the Vehicle Technologies (VT) Program of EERE. The scope of the effort includes: (1) Characterizing baseline and advanced technology vehicles for Class 3-6 and Class 7 and 8 trucks, (2) Identifying technology goals associated with the DOE EERE programs, (3) Estimating the market potential of technologies that improve fuel efficiency and/or use alternative fuels, and (4) Determining the petroleum and greenhouse gas emissions reductions associated with the advanced technologies. In FY 08 the Heavy Vehicles program continued its involvement with various sources of energy loss as compared to focusing more narrowly on engine efficiency and alternative fuels. These changes are the result of a planning effort that first occurred during FY 04 and was updated in the past year. (Ref. 1) This narrative describes characteristics of the heavy truck market as they relate to the analysis, a description of the analysis methodology (including a discussion of the models used to estimate market potential and benefits), and a presentation of the benefits estimated as a result of the adoption of the advanced technologies. The market penetrations are used as part of the …

We have fabricated a novel GMR ML flux sensor that is designed to operate in the CPP mode. The GMR sensor is a 0.4 {mu}m diameter, 0.09 {mu}m high Cu-Co ML pedestal. The sensors are patterned using electron beam lithography. The Al{sub 2}O{sub 3}-TiC substrate is coated with a sputter deposited Al{sub 2}O{sub 3} film that is polished to <0.2 nm RMS roughness. Contact to the bottom of the GMR sensor is made by depositing the Cu-Co multilayers onto a smooth 0.45 {mu}m thick Mo-Si ML stack. The top contact is self-aligned to the GMR sensor. This is accomplished, in part, by CMP. The top and bottom contact layers are electrically isolated by a PECVD Si{sub 3}N{sub 4} film. The configuration of the contacts allows four point probe resistance measurements. The GMR response of these 0.4 {mu}m diameter sensors is 12%.

Fluid mechanics research related to fire is reviewed with focus on canonical flows, multiphysics coupling aspects, experimental and numerical techniques. Fire is a low-speed, chemically-reacting, flow in which buoyancy plans an important role. Fire research has focused on two canonical flows, the reacting boundary-layer and the reacting free plume. There is rich, multi-lateral, bi-directional, coupling among fluid mechanics and scalar transport, combustion, and radiation. There is only a limited experimental fluid-mechanics database for fire due to measurement difficulties in the harsh environment, and the focus within the fire community on thermal/chemical consequences. Increasingly, computational fluid dynamics techniques are being used to provide engineering guidance on thermal/chemical consequences and to study fire phenomenology.

Powerspan's multipollutant control process called electrocatalytic oxidation (ECO) technology is designed to simultaneously remove SO{sub 2}, NO{sub x}, PM{sub 2.5}, acid gases (such as hydrogen fluoride [HF], hydrochloric acid [HCl], and sulfur trioxide [SO{sub 3}]), Hg, and other metals from the flue gas of coal-fired power plants. The core of this technology is a dielectric barrier discharge reactor composed of cylindrical quartz electrodes residing in metal tubes. Electrical discharge through the flue gas, passing between the electrode and the tube, produces reactive O and OH radicals. The O and OH radicals react with flue gas components to oxidize NO to NO{sub 2} and HNO{sub 3} and a small portion of the SO{sub 2} to SO{sub 3} and H{sub 2}SO{sub 4}. The oxidized compounds are subsequently removed in a downstream scrubber and wet electrostatic precipitator. A challenging characteristic of selected North Dakota lignites is their high sodium content. During high-sodium lignite combustion and gas cooling, the sodium vaporizes and condenses to produce sodium- and sulfur-rich aerosols. Based on past work, it was hypothesized that the sodium aerosols would deposit on and react with the silica electrodes and react with the silica electrodes, resulting in the formation of sodium silicate. The deposit …

The 5s-5p electric-dipole resonance transitions in highly ionized promethiumlike ions have been studied applying relativistic multi-reference Moeller-Plesset second-order perturbation theory. The transition wavelengths are determined to within 0.2 {angstrom} in the more highly charged ions, where the level degeneracies are small. For somewhat lighter ions a very large reference space was used in order to account for the many degeneracies. In order to calculate transition probabilities and lifetimes, correlation corrections have been added to the transition operator in the next order. The contributions from the higher orders of the theory, that is, frequency-dependent Breit correction, Lamb shift, and mass shifts, have been estimated. The results are used to re-assess spectroscopic data from beam-foil, electron beam ion trap, and tokamak observations.

Further studies are reported on the analytical behavior and experimental testing of Cs/sup 137/ plaque irradiator designs. Low-level sources used for the initial experiments consisted of about 7 mc of Cs/sup 137/ aqueous solution in brass trays 20 by 20 by 1/2 in. high having wall thicknesses of 1/16 in. Calibration tests were made preliminary to radiation field mapping. (T.R. H.)

This report summarizes work carried out by the Ultrascale Visualization Climate Data Analysis Tools (UV-CDAT) Team for the period of July 1, 2011 through December 31, 2011. It discusses highlights, overall progress, period goals, and collaborations and lists papers and presentations. The UV-CDAT team is positioned to address the following high-level visualization requirements: (1) Alternative parallel streaming statistics and analysis pipelines - Data parallelism, Task parallelism, Visualization parallelism; (2) Optimized parallel input/output (I/O); (3) Remote interactive execution; (4) Advanced intercomparison visualization; (5) Data provenance processing and capture; and (6) Interfaces for scientists - Workflow data analysis and visualization construction tools, Visualization interfaces.

A new generation of specialized scientific instruments called synchrotron light sources allow the imaging of materials at very fine scales. However, in contrast to a traditional microscope, interactive use has not previously been possible because of the large amounts of data generated and the considerable computation required translating this data into a useful image. The authors describe a new software architecture that uses high-speed networks and supercomputers to enable quasi-real-time and hence interactive analysis of synchrotron light source data. This architecture uses technologies provided by the Globus computational grid toolkit to allow dynamic creation of a reconstruction pipeline that transfers data from a synchrotron source beamline to a preprocessing station, next to a parallel reconstruction system, and then to multiple visualization stations. Collaborative analysis tools allow multiple users to control data visualization. As a result, local and remote scientists can see and discuss preliminary results just minutes after data collection starts. The implications for more efficient use of this scarce resource and for more effective science appear tremendous.

The report contains three appendices from the Phase 1 final report. Appendix A contains wet scrubber sampling and analysis schedules, DBA/lime chemical analysis, and limestone forced oxidation chemical analysis. Appendix B consists of data on air toxic benchmarking baghouse conditions, ESP conditions, and wet scrubber conditions. Appendix C contains the quality assurance results. The primary objective of this project is to develop practical, cost-effective strategies for reducing the emissions of air toxics from coal-fired boilers. Phase 1 was aimed at providing a reliable test facility for conducting air toxic emissions control development work and is described more fully in the main report (OCDO--96013945).

The primary objective of the Advanced Emissions Control Development Program (AECDP) is to develop practical, cost-effective strategies for reducing the emissions of air toxics from coal-fired boilers. Ideally, the project aim is to effectively control air toxic emissions through the use of conventional flue gas cleanup equipment such as electrostatic precipitators (ESP`s), fabric filters (baghouse), and wet flue gas desulfurization. B&W`s Clean Environment Development Facility (CEDF) and the AECDP equipment combined to form a state-of-the-art facility for integrated evaluation of combustion and post-combustion emissions control options. Phase 1 activities were primarily aimed at providing a reliable, representative test facility for conducting air toxic emissions control development work later in the project. This report summarizes the AECDP Phase I activities which consisted of the design, installation, shakedown, verification, and air toxics benchmarking of the AECDP facility. All verification and air toxic tests were conducted with a high sulfur, bituminous Ohio coal.

In preparation for fulfilling our responsibilities under the Government Management Reform Act of 1994, we planned to conduct an audit of the Department of Energy`s FY 1995 Consolidated Statement of Financial Position. As discussed in the accompanying reports, the Office of Inspector General (OIG) could not express an opinion on the reasonableness of the value of assets and liabilities of the Department because of matters outside the control of the auditors that restricted the scope of their work. Although the OIG could not express an opinion, the audit disclosed reportable conditions in the Department`s internal control structure that adversely affected its ability to manage and account for its assets and liabilities. Corrective management actions on these reportable conditions should help the Department in preparing its Fiscal Year (FY) 1996 Statement of Financial Position.

This volume presents the results of the first phase of the Station Keeping Subsystem (SKSS) design study for 40 MW/sub e/ capacity Modular Experiment OTEC Platforms. The objectives of the study were: (1) establishment of basic design requirements; (2) verification of technical feasibility of SKSS designs; (3) identification of merits and demerits; (4) estimates of sizes for major components; (5) estimates of life cycle costs; (6) deployment scenarios and time/cost/risk assessments; (7) maintenance/repair and replacement scenarios; (8) identifications of interface with other OTEC subsystems; (9) recommendations for and major problems in preliminary design; and (10) applicability of concepts to commercial plant SKSS designs. A brief site suitability study was performed with the objective of determining the best possible location at the Punta Tuna (Puerto Rico) site from the standpoint of anchoring. This involved studying the vicinity of the initial location in relation to the prevailing bottom slopes and distances from shore. All subsequent studies were performed for the final selected site. The two baseline OTEC platforms were the APL BARGE and the G and C SPAR. The results of the study are presented in detail. The overall objective of developing two conceptual designs for each of the two baseline OTEC …

The objective of the small-scale group of tests is to demonstrate that sodium will drain from the surface of the fire suppression deck into the catch pan without interference during a spill event, and to demonstrate that burning is terminated following the spill event by the accumulation of combustion products inside the drain pipes. The results of this series of tests will be used to validate the catch pan fire suppression deck design concept based on the criteria that sodium will drain freely from the surface of the fire suppression deck and that burning is terminated in an acceptably short time (less than or equal to 36 h). The objective of the large-scale group of tests is to provide experimental data on the consequences of sodium spills using prototypic leak rates and to demonstrate the effectiveness of a large-scale fire suppression Q-deck assembly.

The purpose of the ARC78 forecasts and the ways in which they differ from those in the ARC77 are discussed. In a preliminary overview of the projection process, the relationship between energy prices, supply, and demand is addressed. Topics treated in detail include a description of energy-economic interactions, assumptions regarding world oil prices, and energy modeling in the long term beyond 1995. Subsequent sections present the general approach and methodology underlying the forecasts, and define and describe the alternative projection series and their associated assumptions. Short-term forecasting, midterm forecasting, long-term forecasting of petroleum, coal, and gas supplies are included. The role of nuclear power as an energy source is also discussed.

One of the possible options for generating electrical energy from ocean thermal gradients requires the use of a floating offshore platform. The platform would contain all OTEC (Ocean Thermal Energy Conversion) systems and power cycle components and consist of the hull, seawater, station-keeping, platform service, and mission support subsystems. It would be stationed at one of the designated OTEC sites, and would transmit the generated electricity to the shore power networks by means of an electrical transmission cable. The objective of the present study is to investigate the station-keeping subsystem (SKSS) requirements and develop preliminary SKSS designs for the two Modular Experiment Plant (MEP) candidates of 10/40 MW/sub e/ capacity for deployment at a specific site. The two MEP hull candidates are a Barge type platform and a Spar shaped hull with external heat exchangers. The specific site assigned for this study is Puerto Rico. The preliminary SKSS designs are developed for both platforms as follows: (1) an 8-leg spread catenary mooring system for the Spar, and (2) a 12-leg spread catenary mooring system for the Barge. Applicability of these designs to larger capacity commercial OTEC platforms is also investigated.

This volume contains appendices to the Station Keeping Subsystem design study for the 40 MeW Modular Experiment OTEC platforms. Appendices presented include: detailed drag calculations; sample CALMS computer printouts for SPAR and BARGE static analyses; sample time domain computer printouts (Hydromechanics, Inc.) program; extreme value and fatigue load calculations; anchor design calculations; deployment calculations; bottom slope plots; time domain analysis report by Hydromechanics Inc.; detailed cost analysis; control systems study report by Sperry Systems Management; cost estimates for model basin tests; and hydrodynamic loading on the mooring cables. (WHK)

This volume of the report presents the results of the third through the sixth tasks of the Station Keeping Subsystem (SKSS) design studies for 10/40 MW/sub e/ capacity OTEC Modular Experiment platforms (MEP). Tasks 3 through 6 are: (3) complete preliminary designs for one SKSS for each of the two platforms (SPAR and BARGE); (4) development and testing recommendations for the MEP SKSS; (5) cost-time analysis; and (6) commercial plant recommendations. The overall conclusions and recommendations for the modular, as well as the commercial, OTEC platform station keeping subsystems are delineated. The basic design assumptions made during the process, the technical approach followed, and the results of design iterations, reliability and performance analyses are given. A complete description of the preliminary design SKSS concept is presented. The summary cost estimates for each of the alternative SKSS concepts considered are presented and a time schedule for the recommended concept is provided. The effects of varying some of the important parameters used in SKSS design on the performance and cost of the mooring system are investigated and results presented. The tests required and other developmental recommendations in order to verify and confirm the basic design assumptions are discussed. Finally, the experience gained …

The hydrodyraruios code BOCH and the physics code PUREE' were used in the anaiysis of specific VMR cores. Eight core designs of different geometries were selected for initial evaluation. Extensive analysis of the first of these cores was completed. aid more general analysis of the other cores is in progress. The analog representation of the VMR kinetics was completed and applied to the aaalysis of the VMR over a large range of parameters for curves of positive void versus reactivity. Funiner checks of the first three energy groups of PUREE' against experinnental data were completed. The P/sub 3/-POP method of computing the thermal group constants was used in conjunction with the first three groups to analyze the reference core designs and the critical experiment. The more complex blackness method of computing the PUREE' thermal group constants appeared to be functioning properly and is being checked on very tight lattices to determine the magnitude of the change in fuel-pin blackness due to incident neutron distortion by neighboring fuel pins. Mechanical and system design of selected cores was started. Corrosion rate of the moderator systems was computed. and preliminary analysis of a clean-up system was started. (For preceding period see ATL-A-103.) (W.D.M.)