Estimating Filtering Errors Using the Peano Kernel Theorem (open access)

Estimating Filtering Errors Using the Peano Kernel Theorem

The Peano Kernel Theorem is introduced and a frequency domain derivation is given. It is demonstrated that the application of this theorem yields simple and accurate formulas for estimating the error introduced into a signal by filtering it to reduce noise.
Date: February 20, 2009
Creator: Blair, Jerome
Object Type: Article
System: The UNT Digital Library
Documentation Package for the RFID Temperature Monitoring System (Of Model 9977 Packages at NTS). (open access)

Documentation Package for the RFID Temperature Monitoring System (Of Model 9977 Packages at NTS).

The technical basis for extending the Model 9977 shipping package periodic maintenance beyond the one-year interval to a maximum of five years is based on the performance of the O-ring seals and the environmental conditions. The DOE Packaging Certification Program (PCP) has tasked Argonne National Laboratory to develop a Radio-Frequency Identification (RFID) temperature monitoring system for use by the facility personnel at DAF/NTS. The RFID temperature monitoring system, depicted in the figure below, consists of the Mk-1 RFId tags, a reader, and a control computer mounted on a mobile platform that can operate as a stand-alone system, or it can be connected to the local IT network. As part of the Conditions of Approval of the CoC, the user must complete the prescribed training to become qualified and be certified for operation of the RFID temperature monitoring system. The training course will be administered by Argonne National Laboratory on behalf of the Headquarters Certifying Official. This is a complete documentation package for the RFID temperature monitoring system of the Model 9977 packagings at NTS. The documentation package will be used for training and certification. The table of contents are: Acceptance Testing Procedure of MK-1 RFID Tags for DOE/EM Nuclear Materials …
Date: February 20, 2009
Creator: Chen, K.; Tsai, H. & Sciences, Decision and Information
Object Type: Report
System: The UNT Digital Library
Innovative Protocols for in SITU MTBE Degradation by Using Molecular Probes-An Enhanced Chemical-Bio Oxidation Technique (open access)

Innovative Protocols for in SITU MTBE Degradation by Using Molecular Probes-An Enhanced Chemical-Bio Oxidation Technique

In situ chemical oxidation (ISCO) is a common technology to cleanup petroleum hydrocarbon-contaminated soils and groundwater. Sodium percarbonate (SPC) is an oxidant which is activated by iron (Fe) to produce Fenton-like reactions. Western Research Institute, in conjunction with Regenesis and the U.S. Department of Energy, conducted a study that investigated the performance of a 'safe' oxidant, SPC, to cleanup groundwater and soils contaminated with petroleum hydrocarbons and associated contaminants (e.g., MTBE). Results from a field pilot test in Frenchglen, Oregon showed VOC concentrations in groundwater decreased substantially within 2 weeks after injecting activated SPC (RegenOx). A protocol was established for determining RegenOx TOD in soils and groundwater. Total oxidant demand tests were necessary to determine the correct dosage of RegenOx to apply in the field and sufficiently degrade the contaminants of concern. Bench studies with RegenOx showed this technology was effective in degrading diesel fuel and 1,4-dioxane. The Fe-silica activator (RegenOx Part B) was tested with another oxidant, sodium persulfate. Bench tests results showed the combination of sodium persulfate and RegenOx Part B was effective in reducing PCE, MTBE, benzene, and n-heptane concentrations in water. Overall, the results of this project indicated that most petroleum contaminants in soil and groundwater …
Date: February 20, 2009
Creator: Fallgren, Paul
Object Type: Report
System: The UNT Digital Library
Caustic Recycle from Hanford Tank Waste Using NaSICON Ceramic Membrane Salt Splitting Process (open access)

Caustic Recycle from Hanford Tank Waste Using NaSICON Ceramic Membrane Salt Splitting Process

A family of inorganic ceramic materials, called sodium (Na) Super Ion Conductors (NaSICON), has been studied at Pacific Northwest National Laboratory (PNNL) to investigate their ability to separate sodium from radioactively contaminated sodium salt solutions for treating U.S. Department of Energy (DOE) tank wastes. Ceramatec Inc. developed and fabricated a membrane containing a proprietary NAS-GY material formulation that was electrochemically tested in a bench-scale apparatus with both a simulant and a radioactive tank-waste solution to determine the membrane performance when removing sodium from DOE tank wastes. Implementing this sodium separation process can result in significant cost savings by reducing the disposal volume of low-activity wastes and by producing a NaOH feedstock product for recycle into waste treatment processes such as sludge leaching, regenerating ion exchange resins, inhibiting corrosion in carbon-steel tanks, or retrieving tank wastes.
Date: February 20, 2009
Creator: Fountain, Matthew S.; Kurath, Dean E.; Sevigny, Gary J.; Poloski, Adam P.; Pendleton, J.; Balagopal, S. et al.
Object Type: Report
System: The UNT Digital Library
Noise-Sustained Convective Instability in a Magnetized Taylor-Couette Flow (open access)

Noise-Sustained Convective Instability in a Magnetized Taylor-Couette Flow

The helical magnetorotational instability of the magnetized Taylor-Couette flow is studied numerically in a finite cylinder. A distant upstream insulating boundary is shown to stabilize the convective instability entirely while reducing the growth rate of the absolute instability. The reduction is less severe with larger height. After modeling the boundary conditions properly, the wave patterns observed in the experiment turn out to be a noise-sustained convective instability. After the source of the noise resulted from unstable Ekman and Stewartson layers is switched off, a slowly-decaying inertial oscillation is observed in the simulation. We reach the conclusion that the experiments completed to date have not yet reached the regime of absolute instability.
Date: February 20, 2009
Creator: Liu, W.
Object Type: Report
System: The UNT Digital Library
Response functions for Logarithnically Spaced Interference Filters Manufactured for Dark Energy Missions (open access)

Response functions for Logarithnically Spaced Interference Filters Manufactured for Dark Energy Missions

Report of filters produced by JDSU for the SNAP experiment
Date: February 20, 2009
Creator: Mufson, Stuart L.
Object Type: Report
System: The UNT Digital Library
DOE Award No. DE-FC36-03GO13108 Novel Non-Precious Metal Catalysts for PEMFC: Catalyst Selection Through Molecular Modeling and Durability Studies Final Report (September 2003 – October 2008) (open access)

DOE Award No. DE-FC36-03GO13108 Novel Non-Precious Metal Catalysts for PEMFC: Catalyst Selection Through Molecular Modeling and Durability Studies Final Report (September 2003 – October 2008)

The objective of this project is to develop novel non-precious metal electrocatalysts for oxygen reduction reaction (ORR), and demonstrate the potential of the catalysts to perform at least as good as conventional Pt catalysts currently in use in polymer electrolyte membrane fuel cell (PEMFC) with a cost at least 50 % less than a target of 0.2 g (Pt loading)/peak kW and with durability > 2,000 h operation with less than 10 % power degradation. A novel nitrogen-modified carbon-based catalyst was obtained by modifying carbon black with nitrogen-containing organic precursor in the absence of transition metal precursor. The catalyst shows the onset potential of approximately 0.76 V (NHE) for ORR and the amount of H2O2 of approximately 3% at 0.5 V (NHE). Furthermore, a carbon composite catalyst was achieved through the high-temperature pyrolysis of the precursors of transition metal (Co and Fe) and nitrogen supported on the nitrogen-modified carbon-based catalyst, followed by chemical post-treatment. This catalyst showed an onset potential for ORR as high as 0.87 V (NHE), and generated less than 1 % of H2O2. The PEM fuel cell exhibited a current density of 2.3 A cm-2 at 0.2 V for a catalyst loading of 6.0 mg cm-2. No …
Date: February 20, 2009
Creator: Popov, Branko N.
Object Type: Report
System: The UNT Digital Library
Duck Valley Reservoirs Fish Stocking and O&M, Annual Progress Report 2007-2008. (open access)

Duck Valley Reservoirs Fish Stocking and O&M, Annual Progress Report 2007-2008.

The Duck Valley Reservoirs Fish Stocking and Operations and Maintenance Project (DV Fisheries) is an ongoing resident fish program that serves to partially mitigate the loss of anadromous fish that resulted from downstream construction of the federal hydropower system. The project's goals are to enhance subsistence fishing and educational opportunities for Tribal members of the Shoshone-Paiute Tribes and provide fishing opportunities for non-Tribal members. In addition to stocking rainbow trout (Oncorhynchus mykiss) in Mountain View (MVR), Lake Billy Shaw (LBS), and Sheep Creek Reservoirs (SCR), the program is also designed to: maintain healthy aquatic conditions for fish growth and survival, provide superior facilities with wilderness qualities to attract non-Tribal angler use, and offer clear, consistent communication with the Tribal community about this project as well as outreach and education within the region and the local community. Tasks for this performance period fall into three categories: operations and maintenance, monitoring and evaluation, and public outreach. Operation and maintenance of the three reservoirs include maintaining fences, roads, dams and all reservoir structures, feeder canals, water troughs, stock ponds, educational signs, vehicles, equipment, and restroom facilities. Monitoring and evaluation activities include creel, gillnet, wildlife, and bird surveys, water quality and reservoir structures monitoring, …
Date: February 20, 2009
Creator: Sellman, Jake & Perugini, Carol
Object Type: Report
System: The UNT Digital Library
Filtration and Leach Testing for REDOX Sludge and S-Saltcake Actual Waste Sample Composites (open access)

Filtration and Leach Testing for REDOX Sludge and S-Saltcake Actual Waste Sample Composites

A testing program evaluating actual tank waste was developed in response to Task 4 from the M-12 External Flowsheet Review Team (EFRT) issue response plan.( ) The test program was subdivided into logical increments. The bulk water-insoluble solid wastes that are anticipated to be delivered to the Waste Treatment and Immobilization Plant (WTP) were identified according to type such that the actual waste testing could be targeted to the relevant categories. Under test plan TP-RPP-WTP-467, eight broad waste groupings were defined. Samples available from the 222S archive were identified and obtained for testing. Under this test plan, a waste-testing program was implemented that included: • Homogenizing the archive samples by group as defined in the test plan • Characterizing the homogenized sample groups • Performing parametric leaching testing on each group for compounds of interest • Performing bench-top filtration/leaching tests in the hot cell for each group to simulate filtration and leaching activities if they occurred in the UFP2 vessel of the WTP Pretreatment Facility. This report focuses on filtration/leaching tests performed on two of the eight waste composite samples and follow-on parametric tests to support aluminum leaching results from those tests.
Date: February 20, 2009
Creator: Shimskey, Rick W.; Billing, Justin M.; Buck, Edgar C.; Daniel, Richard C.; Draper, Kathryn E.; Edwards, Matthew K. et al.
Object Type: Report
System: The UNT Digital Library
Sub-10ps monolithic and low-power photodetector readout (open access)

Sub-10ps monolithic and low-power photodetector readout

Recent advances in photon detectors have resulted in high-density imaging arrays that offer many performance and cost advantages. In particular, the excellent transit time spread of certain devices show promise to provide tangible benefits in applications such as Positron Emission Tomography (PET). Meanwhile, high-density, high-performance readout techniques have not kept on pace for exploiting these developments. Photodetector readout for next generation high event rate particle identification and time-resolved PET requires a highly-integrated, low-power, and cost-effective readout technique. We propose fast waveform sampling as a method that meets these criteria and demonstrate that sub-10ps resolution can be obtained for an existing device.
Date: February 20, 2009
Creator: Varner, Gary S. & Ruckman, Larry L.
Object Type: Report
System: The UNT Digital Library