Charge transport in composites of inorganic nanorods and aconjugated polymer is investigated using a photovoltaic device structure.We show that the current-voltage (I-V) curves in the dark can be modelledusing the Shockley equation modified to include series and shuntresistance at low current levels, and using an improved model thatincorporates both the Shockley equation and the presence of a spacecharge limited region at high currents. Under illumination, theefficiency of photocurrent generation is found to be dependent on appliedbias. Furthermore, the photocurrent-light intensity dependence was foundto be sublinear. An analysis of the shunt resistance as a function oflight intensity suggests that the photocurrent as well as the fill factoris diminished as a result of increased photoconductivity of the activelayer at high light intensity. By studying the intensity dependence ofthe open circuit voltage for nanocrystals with different diameters andthus ! band gaps, it was inferred that Fermi-level pinning occurs at theinterface between the aluminum electrode and the nanocrystal.

During the past decades there has been a continuous growth in the number of physical and societal problems that have been successfully studied and solved by means of computational modeling and simulation. Distinctively, a number of these are important scientific problems ranging in scale from the atomic to the cosmic. For example, ionization is a phenomenon as ubiquitous in modern society as the glow of fluorescent lights and the etching on silicon computer chips; but it was not until 1999 that researchers finally achieved a complete numerical solution to the simplest example of ionization, the collision of a hydrogen atom with an electron. On the opposite scale, cosmologists have long wondered whether the expansion of the Universe, which began with the Big Bang, would ever reverse itself, ending the Universe in a Big Crunch. In 2000, analysis of new measurements of the cosmic microwave background radiation showed that the geometry of the Universe is flat, and thus the Universe will continue expanding forever. Both of these discoveries depended on high performance computer simulations that utilized computational tools included in the Advanced Computational Testing and Simulation (ACTS) Toolkit. The ACTS Toolkit is an umbrella project that brought together a number of …

This report summarizes results of a research program investigating the fundamental principles underlying the phenomenon of topological disordering in a radiation environment. This phenomenon is known popularly as amorphization, but is more formally described as a process of radiation-induced structural arrangement that leads in crystals to loss of long-range translational and orientational correlations and in glasses to analogous alteration of connectivity topologies. The program focus has been on a set compound ceramic solids with directed bonding exhibiting structures that can be described as networks. Such solids include SiO2, Si3N4, SiC, which are of interest to applications in fusion energy production, nuclear waste storage, and device manufacture involving ion implantation or use in radiation fields. The principal investigative tools comprise a combination of experimental diffraction-based techniques, topological modeling, and molecular-dynamics simulations that have proven a rich source of information in the preceding support period. The results from the present support period fall into three task areas. The first comprises enumeration of the rigidity constraints applying to (1) more complex ceramic structures (such as rutile, corundum, spinel and olivine structures) that exhibit multiply polytopic coordination units or multiple modes of connecting such units, (2) elemental solids (such as graphite, silicon and diamond) …

Context and Objective: Vigorous exercise, alcohol and weight loss are all known to increase HDL-cholesterol, however, it is not known whether these interventions raise low HDL as effectively as has been demonstrated for normal HDL. Design: Physician-supplied medical data from 7,288 male and 2,359 female runners were divided into five strata according to their self-reported usual running distance, reported alcohol intake, body mass index (BMI) or waist circumference. Within each stratum, the 5th, 10th, 25th, 50th, 75th, 90th, and 95th percentiles for HDL-cholesterol were then determined. Bootstrap resampling of least-squares regression was applied to determine the cross-sectional relationships between these factors and each percentile of the HDL-cholesterol distribution. Results: In both sexes, the rise in HDL-cholesterol per unit of vigorous exercise or alcohol intake was at least twice as great at the 95th percentile as at the 5th percentile of the HDL-distribution. There was also a significant graded increase in the slopes relating exercise (km run) and alcohol intake to HDL between the 5th and the 95th percentile. Men's HDL-cholesterol decreased in association with fatness (BMI and waist circumference) more sharply at the 95th than at the 5th percentile of the HDL-distribution. Conclusions: Although exercise, alcohol and adiposity were all …

Laboratory-size LiNi0.8Co0.15Al0.05O2/graphite lithium-ion pouch cells were cycled over 100 percent DOD at room temperature and 60 degrees C in order to investigate high-temperature degradation mechanisms of this important technology. Capacity fade for the cell was correlated with that for the individual components, using electrochemical analysis of the electrodes and other diagnostic techniques. The high-temperature cell lost 65 percent of its initial capacity after 140 cycles at 60 degrees C compared to only 4 percent loss for the cell cycled at room temperature. Cell ohmic impedance increased significantly with the elevated temperature cycling, resulting in some of loss of capacity at the C/2 rate. However, as determined with slow rate testing of the individual electrodes, the anode retained most of its original capacity, while the cathode lost 65 percent, even when cycled with a fresh source of lithium. Diagnostic evaluation of cell components including XRD, Raman, CSAFM and suggest capacity loss occurs primarily due to a rise in the impedance of the cathode, especially at the end-of-charge. The impedance rise may be caused in part by a loss of the conductive carbon at the surface of the cathode and/or by an organic film on the surface of the cathode that becomes …

The Gordon Research Conference (GRC)on PHOTOSYNTHESIS was held at Roger Williams University, Bristol, RI. Emphasis was placed on current unpublished research and discussion of the future target areas in this field.

Flow through a pipeline-cavity system can give rise to pronounced flow tones, even when the inflow boundary layer is fully turbulent. Such tones arise from the coupling between the inherent instability of the shear flow past the cavity and a resonant acoustic mode of the system. A technique of high-image-density particle image velocimetry is employed in conjunction with a special test section, which allows effective laser illumination and digital acquisition of patterns of particle images. This approach leads to patterns of velocity, vorticity, streamline topology and hydrodynamic contributions to the acoustic power integral. Comparison of global, instantaneous images with time- and phase-averaged representations provides insight into the small-scale and large-scale concentrations of vorticity, and their consequences on the topological features of Streamline patterns, as well as the streamwise and transverse projections of the hydrodynamic contribution to the acoustic power integral. Furthermore, these global approaches allow the definition of effective wavelengths and phase speeds of the vortical structures, which can lead to guidance for physical models of the dimensionless frequency of oscillation.

The measurement of the cosmological parameters from Type Ia supernovae hinges on our ability to compare nearby and distant supernovae accurately. Here we present an advance on a method for performing generalized K-corrections for Type Ia supernovae which allows us to compare these objects from the UV to near-IR over the redshift range 0 < z < 2. We discuss the errors currently associated with this method and how future data can improve upon it significantly. We also examine the effects of reddening on the K-corrections and the light curves of Type Ia supernovae. Finally, we provide a few examples of how these techniques affect our current understanding of a sample of both nearby and distant supernovae.

This report gives results of efforts to determine electrofacies from logs; measure permeability in outcrop to study very fine-scale trends; find the correlation between permeability measured by the minipermeameter and in core plugs, define porosity-permeability flow units; and run the BOAST III reservoir simulator using the flow units defined for the Gordon reservoir.

Objectives of this project was to understand asphaltene precipitation in General and carbon dioxide induced precipitation in particular. To this effect, thermodynamic and kinetic experiments with the Rangely crude oil were conducted and thermodynamic and reservoir models were developed.

This report describes the present status of the five low-energy Linac 200-MHz RF stations with regard to availability and reliability of major components. An attempt has been made to describe possible solutions (or non-solutions) and to indicate some of the complexity and interplay between those solutions. For the problem at hand, the discontinuance of this one particular tube, an acceptable solution plan must be identified and designed in detail in the near future. As explained herein, the time scale for implementing a solution is five years; beyond that time there is considerable risk of finding ourselves with a non-maintainable Linac and no High Energy Physics program at Fermilab.

The United States Postal Service (USPS) has ordered 500 light-duty electric carrier route vehicles (ECRV) mostly for their delivery carriers to use in several California locations. The 500 ECRVs have been defined as a demonstration fleet to support a decision of potentially ordering 5,500 additional ECRVs. Several different test methods are being used by the USPS to evaluate the 500-vehicle deployment. One of these test methods is the ECRV Customer Acceptance Test Program at Fountain Valley, California. Two newly manufactured ECRVs were delivered to the Fountain Valley Post Office and eighteen mail carriers primarily drove the ECRVs on ''park and loop'' mail delivery routes for a period of 2 days each. This ECRV testing consisted of 36 route tests, 18 tests per vehicle. The 18 mail carriers testing the ECRVs were surveyed for the opinions on the performance of the ECRVs. The U.S. Department of Energy, through its Field Operations Program, is supporting the USPS's ECRV testing activities both financially and with technical expertise. As part of this support, Field Operations Program personnel at the Idaho National Engineering and Environmental Laboratory have compiled this report based on the data generated by the USPS and its testing contractor (Ryerson, Master and …

These tests indicated that: (1) duration of exposure to bacterial strain CL0145A of Pseudomonas fluorescens is a key variable in obtaining zebra mussel mortality; (2) that given a choice of exposure periods up to 96 hr, the longer the exposure period, the higher the mean mortality that will be achieved; (3) that the first few hours that the mussels are exposed to the bacteria are the most important in achieving kill; (4) that the mortality achieved by exposure periods {>=}72 hr may be somewhat amplified by the degraded water quality conditions which can develop in recirculating water systems over such extended time periods.

An existing argon atmosphere glovebox enclosure was to be refurbished for contaminated operations with a large, high temperature induction furnace. Thermal modeling indicated that glovebox temperatures would be high but acceptable without active cooling, but there were significant concerns that the analysis was inadequate and active cooling would be required. In particular, radiant heating of the glovebox walls by the furnace and pressure control system performance were concerns the thermal model had not addressed. Consequently, a thermal load test with a simulated furnace was designed to answer these questions. The purpose of the test was to determine if active cooling would be required to maintain containment integrity and, if not required, would it still be desirable for improved operations?

Heavy-ion accelerators for HIF will operate at high aperture-fill factors with high beam current and long pulses. This will lead to beam ions impacting walls: liberating gas molecules and secondary electrons. Without special preparation a large fractional electron population ({approx}&gt;1%) is predicted in the High-Current Experiment (HCX), but wall conditioning and other mitigation techniques should result in substantial reduction. Theory and particle-in-cell simulations suggest that electrons, from ionization of residual and desorbed gas and secondary electrons from vacuum walls, will be radially trapped in the {approx}4 kV ion beam potential. Trapped electrons can modify the beam space charge, vacuum pressure, ion transport dynamics, and halo generation, and can potentially cause ion-electron instabilities. Within quadrupole (and dipole) magnets, the longitudinal electron flow is limited to drift velocities (E x B and {del}B) and the electron density can vary azimuthally, radially, and longitudinally. These variations can cause centroid misalignment, emittance growth and halo growth. Diagnostics are being developed to measure the energy and flux of electrons and gas evolved from walls, and the net charge and gas density within magnetic quadrupoles, as well as the their effect on the ion beam.

The thermoelastic properties of bcc tantalum have been investigated over a broad range of temperatures (up to 12000 K) and pressures (up to 10 Mbar) using first-principles methods that account for cold, electron-thermal, and ion-thermal contributions. Specifically, we have combined ab initio all electron electronic-structure calculations for the cold and electron-thermal contributions to the elastic moduli with phonon contributions for the ion-thermal part calculated using model generalized pseudopotential theory (MGPT). For the latter, a summation of terms over the Brillouin zone is performed within the quasi-harmonic approximation, where each term is composed of a strain derivative of the phonon frequency at a particular k-point. At ambient pressure, the resulting temperature dependence of the elastic moduli is in excellent agreement with ultrasonic measurements. The experimentally observed anomalous behavior of C44 at low temperatures is shown to originate from the electron-thermal contribution. At higher temperatures, the dominant contribution to the temperature dependence of the elastic moduli comes from thermal expansion. Also, the pressure dependence of the moduli compares well with recent diamond and cell measurements up to 105 GPa. The calculated longitudinal and bulk sound velocities at higher pressure and temperature agree well with data obtained from shock experiments. Additionally, the temperature …

A Linac Afterburner is proposed to raise the energy of the beam injected into the Femrilab Booster from 400 MeV to about 600 MeV, thereby alleviating the longitudinal and transverse space-charge effects at low energy that currently limit its performance. The primary motivation is to increase the integrated luminosity of the Tevatron Collider in Run II, but other future programs would also recap substantial benefits. The estimated cost is $23M.

The structural transformations that occur in diamondlike carbon coatings with increasing hydrogen content have been investigated by Raman spectroscopy, transmission electron microscopy, electron diffraction, and electron-energy-loss spectroscopy. Friction tests were performed with uncoated steel balls against coated substrates at contact stresses of 1 GPa in ambient air (relative humidity = 30 - 40%), dry air (relative humidity &lt; 1%), and dry nitrogen (&lt; 1%). The lowest friction coefficient (f &lt; 0.02) was obtained for the most hydrogenated sample in dry nitrogen, where the formation of a third-body layer was observed on the steel surface. Raman spectra obtained from the counterfaces after sliding in humid and dry air revealed a remarkable increase and narrowing of the ''D'' and ''G'' peaks with decreasing humidity. Analysis of peak positions and I(D)/I(G) ratios pointed to an increasing order and an enlargement of the sp{sup 2} clusters under friction. The shape and position of the carbon K-edge spectra for the transfer layer are affected the same way, although evidence of extended graphite layer formation was not observed. Development of these differing trends was correlated with the hydrogen-to-carbon ratio of the gas precursor used during the synthesis and with the type of surrounding atmosphere.

Puzzles awaiting better experiments and better theory include: (1) the contradiction between good and bad SU(3) baryon wave functions in fitting Cabibbo theory for hyperon decays, strangeness suppression in the sea and the violation of the Gottfried Sum rule--no model fits all; (2) Anomalously enhanced Cabibbo-suppressed D{sup +} {yields} K*{sup +} (s{bar d}) decays; (3) anomalously enhanced and suppressed B {yields} {eta}{prime} X decays; (4) the OZI rule in weak decays; (5) Vector dominance (W {yields} {pi}, {rho}, a{sub 1}, D{sub s}, D*{sub s}) in weak decays; (6) puzzles in doubly-cabibbo-suppressed charm decays; and (7) problems in obtaining {Lambda} spin structure from polarization measurements of produced {Lambda}'s.

In young forest plantations, trees planted at high densities frequently show more rapid height and diameter growth than those plants at lower densities. This positive growth response to density (the ''density effect'') often manifests long before seedlings are tall enough to shade one another, so it is not a simple response to shade. The mechanism(s) which trigger and sustain this growth enhancement are unknown. Our objectives were to document the temporal dynamics of positive growth response to increasing density in Douglas-fir plantations and to test two hypotheses as potential mechanisms for this response. The hypotheses are (1) a canopy boundary layer effect, and (2) alterations in the quality of light reflected from neighboring trees. The ''boundary layer'' hypotheses proposes that changes in atmospheric mixing occur in high-density plantations, promoting increased concentrations of CO{sub 2} and H{sub 2}O vapor during early morning hours, which in turn would enhance carbon assimilation. The ''light quality'' hypothesis proposes that the presence of neighbors alters the ratio of red to far red light in the canopy environment. Plant sensors detect this change in light quality, and growth and development is altered in response. We found that boundary layer conductance was higher, as we predicted, in …

Measurements of oxidation. These spectra are to the best of our knowledge the first reported in situ spectroscopic observation of homogeneous aqueous redox chemistry at temperatures beyond the critical temperature of waste. We also observed a time-dependence for the growth of the Cr(VI) XANES peak and have therefore obtained both kinetic information as well as structural information on the reactants and products at the reaction temperature. We feel that these new techniques, when employed on actual waste components will elucidate the underlying chemistry.

STREAM II, an aqueous transport module of the Savannah River Site emergency response Weather INformation Display (WIND) system, accounts for the effects of dilution, advection and dispersion. Although the model has the capability to account for nuclear decay, due to the short time interval of interest for emergency response, the effect of nuclear decay is very small and so it is not employed. The interactions between the sediment and radionuclides are controlled by the flow conditions and physical and chemical characteristics of the radionuclides and the sediment constituents. The STREAM II-V2 used in emergency response does not model the effects of sediment deposition/resuspension to minimize computing time. The effects of sedimentation on cesium and plutonium transport in the Fourmile Branch were studied recently and the results from these studies indicated that the downstream cesium and plutonium peak concentrations were significantly reduced due to the effects of sedimentations. The STREAM II-V2 was upgraded to account for the effect of sedimentation on aqueous transport of cesium and plutonium released from H-Area.

We investigate how well a coupled biosphere-atmosphere model, CCM3-IBIS, can simulate the functioning of the terrestrial biosphere and the carbon cycling through it. The simulated climate is compared to observations, while the vegetation cover and the carbon cycle are compared to an offline version of the biosphere model IBIS forced with observed climatic variables. The simulated climate presents some local biases that strongly affect the vegetation (e.g., a misrepresentation of the African monsoon). Compared to the offline model, the coupled model simulates well the globally averaged carbon fluxes and vegetation pools. The zonal mean carbon fluxes and the zonal mean seasonal cycle are also well represented except between 0{sup o} and 20{sup o}N due to the misrepresentation of the African monsoon. These results suggest that, despite regional biases in climate and ecosystem simulations, this coupled atmosphere-biosphere model can be used to explore geographic and temporal variations in the global carbon cycle.

The National Renewable Energy Laboratory's Thermal Test Facility in Golden, Colorado, was designed using a whole-building approach--looking at the way the building's systems worked together most efficiently. Researchers monitor the performance of the 11,000-square-foot building, which boasts an energy cost savings of 63% for heating, cooling, and lighting. The basic plan of the building can be adapted to many needs, including retail and warehouse space. The Thermal Test Facility contains office and laboratory space; research focuses on the development of energy-efficiency and renewable energy technologies that are cost-effective and environmentally friendly.