Restricted Hartree-Fock calculations for the ground electronic states of BrH/sup +/, KrH/sup +/, and RbH/sup +/ have been carried out using carefully selected nominal atomic basis sets for the heavy atoms, supplemented with an additional orbital designed to allow for a better description of atomic distortion at intermediate internuclear separations. A flexible four-function basis set was used on the hydrogen atom. Molecular optimization was carried out for the heavy-atom distortion orbital and also for the hydrogen 2p orbital. The interatomic potentials obtained for the X /sup 2/PI state of BrH/sup +/ and the X /sup 1/..sigma../sup +/ state of KrH/sup +/ show strong molecular binding (i.e., 3-4 eV) relative to the neutral heavy atoms plus a proton. The RbH/sup +/ X /sup 2/..sigma../sup +/ calculations give a repulsive interatomic potential with dissociation to Rb/sup +/ and a neutral hydrogen atom.

In the course of the Cascade Improvement Program, many component equipment parts will be electroplated with nickel for corrosion protection. The maximum hardness which will be acceptable in the electroplated deposit is specified in Union Carbide's Job Specification JS-1396, Revision 3, entitled Electroplated Nickel Coatings on Steel Parts. The hardness specification is intended primarily as a control over both organic and inorganic impurities in the deposit. This report covers a study evaluating several of the numerous controllable variables which influence the hardness of the nickel plate deposited from a Watts-type bath. The variables tested were: 1) bath composition, 2) pH, 3) current density, 4) anode-cathode area ratio, and 5) bath temperature. Within the tested ranges of the variables studied, the pH and current density had the most influence on the plate hardness. The softest deposit was obtained with a bath pH of 1.5, a current density of 30 to 40 amperes/square foot, and with the anode-cathode area ratio in the range of 3:1 to 1:1. (auth)