The environmental transport pathway of soil-borne radioisotopes to vegetation surfaces via raindrop splash was studied. The data show that soil can significantly contribute to the contamination found on plants. Further detailed study is needed to calculate the rate constant for the raindrop splash and retention pathways. 8 references, 1 figure. (ACR)

Contamination in groundwater at Canada, Kansas, was discovered in 1997, during limited private well sampling near former grain storage facilities of the Commodity Credit Corporation, U.S. Department of Agriculture (CCC/USDA). Subsequent investigations by the Kansas Department of Health and Environment (KDHE) confirmed carbon tetrachloride and nitrate concentrations in groundwater above the respective maximum contaminant levels (MCLs) of 5.0 {micro}g/L and 10.0 mg/L. The KDHE investigations identified both the former CCC/USDA grain storage facility and a private grain storage facility as likely sources for the carbon tetrachloride contamination. The CCC/USDA funded extension of a rural water district line to provide a permanent alternate water supply, and the KDHE has conducted long-term monitoring under the State Water Plan. This document presents an analysis of the available information for the Canada site, acquired in previous investigations and the long-term KDHE monitoring. This analysis forms the technical justification for a request to reclassify the former CCC/USDA grain storage facility at Canada as a site requiring no further action under the Intergovernmental Agreement (IGA) between the KDHE and the USDA's Farm Service Agency. The KDHE's long-term water level monitoring results indicate a consistent groundwater flow direction to the east-southeast. Consequently, the wells with the highest …

As part of a small scale sequestration test (about 1500 tonsof CO2) in a saline aquifer, time-lapse borehole seismic surveys wereconducted to aid in characterization of subsurface CO2 distribution andmaterial property changes induced by the injected CO2. A VSP surveydemonstrated a large increase (about 75 percent) in seismic reflectivitydue to CO2 injection and allowed estimation of the spatial extent of CO2induced changes. A crosswell survey imaged a large seismic velocitydecrease (up to 500 m/s) within the injection interval and provided ahigh resolution image of this velocity change which maps the subsurfacedistribution of CO2 between two wells. Numerical modeling of the seismicresponse uses the crosswell measurements to show that this small CO2volume causes a large response in the seismic reflectivity. This resultdemonstrates that seismic detection of small CO2 volumes in salineaquifers is feasible and realistic.

The Commodity Credit Corporation of the U.S. Department of Agriculture (CCC/USDA) began its environmental investigations at Everest, Kansas, in 2000. The work at Everest is implemented on behalf of the CCC/USDA by Argonne National Laboratory, under the oversight of the Kansas Department of Health and Environment (KDHE). The results of the environmental investigations have been reported in detail (Argonne 2001, 2003, 2006a,b). The lateral extent of the carbon tetrachloride in groundwater over the years of investigation has been interpreted as shown in Figure 1.1 (2001-2002 data), Figure 1.2 (2006 data), Figure 1.3 (2008 data), and Figure 1.4 (2009 data). The pattern of groundwater flow and inferred contaminant migration has consistently been to the north-northwest from the former CCC/USDA facility toward the Nigh property, and then west-southwest from the Nigh property (e.g., Figure 1.5 [2008 data] and Figure 1.6 [2009 data]). Both the monitoring data for carbon tetrachloride and the low groundwater flow rates estimated for the Everest aquifer unit (Argonne 2003, 2006a,b, 2008) indicate slow contaminant migration. On the basis of the accumulated findings, in March 2009 the CCC/USDA developed a plan for annual monitoring of the groundwater and surface water. This current monitoring plan (Appendix A in the report …

This report describes the main features of the results obtained in the course of this project. A new approach to the systematic development of closure relations for the averaged equations of disperse multiphase flow is outlined. The focus of the project is on spatially non-uniform systems and several aspects in which such systems differ from uniform ones are described. Then, the procedure used in deriving the closure relations is given and some explicit results shown. The report also contains a list of publications supported by this grant and a list of the persons involved in the work.

A phase II study has been initiated to investigate surfactant-assisted coal liquefaction, with the objective of quantifying the enhancement in liquid yields and product quality. This report covers the sixth quarter of work. The major accomplishments were (1) Completion of the distillation of the liquid product from coal liquefaction autoclave reactor runs with Illinois No. 6 coal at 400{degree}C, with and without surfactant and/or catalyst at pressures of 1700 psig, (2) Batch autoclave runs at 375 and 400{degree}C with 1 wt % lignin to Illinois No. 6 coal to further define the surfactant effect of sodium lignosulfonate, and (3) a preliminary economic evaluation of the application of the lignosulfonate surfactant in an industrial liquefaction process and a proposed conceptual plant design.