Results of multidimensional computations of sprays in a very high pressure constant volume chamber are presented in two parts. Comparisons of computed and measured penetrations of non-vaporizing and vaporizing sprays are presented. A broad range of density ratios (0.005 to 0.243) is covered. It is shown that, provided sufficient numerical resolution is used, the model can adequately reproduce the measurements. Scaling laws for time and distance derived in a previous publication are found to apply also to the sprays over the broad range of density ratios considered. A combustion sub-model that has been used in spark-ignition engines, stratified-charge engines and Diesel engines is included in the model. The combustion sub-model represents low-temperature autoignition and high temperature heat release. Comparisons of computed and measured penetrations of combusting sprays and computed and measured chamber pressures are being made. In this report, only preliminary indicative comparisons of computed and measured chamber pressures for three cases are presented. Agreement of pressures within 5% is shown. The work is ongoing and a detailed report will be presented later.

The January 2, 1992 explosion in an electrochemistry laboratory at SRI International (SRI) resulted in the death of scientist Andrew Riley, and gained some notoriety due to its association with experimental work in the controversial field of cold fusion research. Selected components of explosion debris were subjected to forensic analyses at LLNL to elucidate potential causes of, or contributing factors to, the explosion. Interrogation of the debris by LLNL encompassed nuclear, chemical, physical, and materials investigations. Nuclear studies for the determination of tritium and neutron-activation products in stainless steel and brass were negative. No evidence of signature species indicative of orthodox nuclear events was detected. The inorganic and particulate analyses were likewise negative with respect to residues of unexpected chemical species. Such target compounds included conventional explosives, accelerants, propellants, or any exceptional industrial chemicals. The GC-MS analyses of trace organic components in the explosion debris provided perhaps the most interesting results obtained at LLNL. Although no evidence of organic explosives, oxidizers, or other unusual compounds was detected, the presence of a hydrocarbon oil in the interior of the electrochemical cell was established. It is likely that its source was lubricating fluid from the machining of the metal cell components. If …

In September 1994 the DOE Richland Operations Office (RL) approved the FY 1995 multi-year baseline that included a cost estimate of $1.9 billion for FY 1996. However, Congress only appropriated $1.3 billion for that year. The shortfall of $600 million resulted in a significant challenge to accomplish the required workscope. Therefore, RL initiated an aggressive cost savings program to eliminate the shortfall by deleting workscope that was unnecessary and performing the remaining workscope more efficiently. RL initiated baseline planning actions (including deletions, deferrals, transfers, and additions) during the FY 1996 multi-year baseline development process to match workscope and anticipated funding and identified $205 million of workscope deletions. CFR (Contract Finance and Review Division) then reviewed over 200 cost baseline change requests during FY 1996 and documented an additional $95 million of FY 1996 cost savings. This included $73 million of workscope deletions and $22 million of efficiencies. Total savings as a result of FY 1996 initiatives, including baseline planning actions and current year initiatives, were $300 million. This report contains tables which enumerate the savings realized within each program at Hanford.

Cost savings are an integral part of Hanford site operations. Congressional actions towards establishing a balanced budget have resulted in reductions to funding for all federal agencies, including the Department of Energy (DOE) Environmental Management (EM) cleanup mission. In September 1994 the DOE Richland Operations Office (RL) approved the FY 1995 multi-year baseline that included a cost estimate of $1.9 billion for FY 1996. However, Congress only appropriated $1.3 billion for that year. The shortfall of $600 million resulted in a significant challenge to accomplish the required workscope. Therefore, RL initiated an aggressive cost savings program to eliminate the shortfall by deleting workscope that was unnecessary and performing the remaining workscope more efficiently. RL initiated baseline planning actions (including deletions, deferrals, transfers, and additions) during the FY 1996 multi-year baseline development process to match workscope and anticipated funding and identified $205 million of workscope deletions. CFR (Contract Finance and Review Division) then reviewed over 200 cost baseline change requests during FY 1996 and documented an additional $95 million of FY 1996 cost savings. This included $73 million of workscope deletions and $22 million of efficiencies. Total savings as a result of FY 1996 initiatives, including baseline planning actions and current …

The DWPF Salt Cell Vent Condenser (SCVC) includes a High Efficiency Mist Eliminator (HEME) designed to remove mercury aerosols that may form in the Precipitate Reactor (PR) condenser. The Savannah River Technology Center was requested by DWPF to make a performance assesssment of a prototypic HEME element in the vent system of the Precipitate Hydrolysis Experimental Facility at TNX.[sup a]

The DWPF Salt Cell Vent Condenser (SCVC) includes a High Efficiency Mist Eliminator (HEME) designed to remove mercury aerosols that may form in the Precipitate Reactor (PR) condenser. The Savannah River Technology Center was requested by DWPF to make a performance assesssment of a prototypic HEME element in the vent system of the Precipitate Hydrolysis Experimental Facility at TNX.

The signal and background for the search of the Standard Model Higgs boson in the intermediate mass range 80 GeV < m{sub H} < 2M{sub Z} is studied based on calculations of the cross sections in next-to-leading order QCD perturbation theory for the production of the Higgs boson via gluon-gluon fusion and for the hadronic two-photon production. The method of Monte-Carlo integration allows the application of realistic cuts (p{sub T}, rapidity, photon isolation) to the cross section. Results are given for the K-factors of the signal and the background. It turns out that the NLO corrections improve the situation for a Higgs boson mass in the range of 80--120 GeV. Furthermore, the influence of a cut on the transverse momentum of the additional jet produced in the processes gg {yields} Hg, gq {yields} Hq, q{bar q} {yields} Hg is compared to a similar cut for the background.

Corrosive plutonium solutions stored in 10-L containers at the Plutonium Finishing Plant must be treated to convert the plutonium to a safe, solid form for storage and to remove the americium so that radiation exposure can be reduced. Extraction chromatographic resins will be tested for separating plutonium from these solutions in the laboratory. Separation parameters will be developed during the testing for large scale processing of the 10-L solutions and solutions of similar composition. Use of chromatographic resins will allow plutonium separation with minimum of chemical addition to the feed and without the need for plutonium valence adjustment. The separated plutonium will be calcined to plutonium oxide by direct solution calcination.

We show that the conventionally defined partonic cross section for the production of isolated prompt photons is not an infrared safe quantity. We work out the case of e{sup +}e{sup -} {yields} {gamma} + X in detail, and we discuss implications for hadron reactions such as p{bar p} {yields} {gamma} + X.

In next-to-leading order quantum chromodynamics, gluon-gluon interactions dominate the production of bottom quarks at hadron collider energies, and gluon-quark interactions control inclusive prompt photon production at large transverse momentum in pp collisions at fixed-target energies. Using such data, in conjunction with data from deep inelastic lepton scattering, we determine a new gluon density whose shape differs substantially from that derived from previous fits of data. The new set of parton densities provides a good fit to bottom quark, prompt photon, and deep inelastic data, including the most recent NMC and CCFR results.

In next-to-leading order quantum chromodynamics, gluon-gluon interactions dominate the production of bottom quarks at hadron collider energies, and gluon-quark interactions control inclusive prompt photon production at large transverse momentum in pp collisions at fixed-target energies. Using such data, in conjunction with data from deep inelastic lepton scattering, we determine a new gluon density whose shape differs substantially from that derived from previous fits of data. The new set of parton densities provides a good fit to bottom quark, prompt photon, and deep inelastic data, including the most recent NMC and CCFR results.

This report will provide the findings of the demonstration test conducted on the Double-Shell Tank (DST) 241-SY-101 HMR Pump-3 in accordance with WHC-SDWM-TP-434 ``Test plan for run-in acceptance testing of hydrogen mitigation/retrieval pump-3`` at the 400 Area Maintenance and Storage Facility (MASF) building from 7 June 1996 through 30 July 1996 per work package 4A-96-92/W. The DST 241-SY-101 hydrogen mitigation retrieval Pump-3 is a 200-HP submersible electric driven pump that has been modified for use in the DST 241-SY-101 containing mixed waste located in the 200W area. The pump has a motor driven rotation mechanism that allows the pump column to rotate through 355{degree}. Prior to operation, pre-operational checks were performed which included loop calibration grooming and alignment of instruments, learning how plumb HMR-3 assembly hung in a vertical position and bump test of the motor to determine rotation direction. The pump was tested in the MASF Large Diameter Cleaning Vessel (LDCV) with process water at controlled temperatures and levels. In addition, the water temperature of the cooling water to the motor oil heat exchanger was recorded during testing. A 480-volt source powered a Variable Frequency Drive (VFD). The VFD powered the pump at various frequencies and voltages to control …

A composite sample of groundwater from F- and H-Areas was collected by Waste Management Tech and delivered to the Savannah River Laboratory to use in preliminary experiments that would test three remediation technologies under consideration. The three technologies are pH adjustment and filtration, decontamination with a strong acid ion exchange resin, and decontamination with a chelating ion exchange resin.

A composite sample of groundwater from F- and H-Areas was collected by Waste Management Tech and delivered to the Savannah River Laboratory to use in preliminary experiments that would test three remediation technologies under consideration. The three technologies are pH adjustment and filtration, decontamination with a strong acid ion exchange resin, and decontamination with a chelating ion exchange resin.

This invention is comprised of a method for on-line accurate monitoring and precise control of molecular beam epitaxial growth of Groups III-III-V or Groups III-V-V layers in an advanced semiconductor device incorporates reflection mass spectrometry. The reflection mass spectrometry is responsive to intentional perturbations in molecular fluxes incident on a substrate by accurately measuring the molecular fluxes reflected from the substrate. The reflected flux is extremely sensitive to the state of the growing surface and the measurements obtained enable control of newly forming surfaces that are dynamically changing as a result of growth.

Progress is described in the following research areas concerned with high resolution interface nanochemistry and structure: ceramic interfaces and grain boundaries; metal/alpha (6H)-SiC(0001) interfaces; oxygen distributions in monolithic silicon carbide; SiC/nitride and metal on nitride interfaces; and interface synthesis.

Circulation in bubble columns, such as those used in fischer-tropsch synthesis, detracts from their performance in that gas is carried on average more rapidly through the column, and the residence time distribution of the gas in the column is widened. Both of these factors influence mass-transfer operations in bubble columns. Circulation prediction and measurement has been undertaken using probes, one-dimensional models, laser Doppler velocimetry, and numerical modeling. Local void fraction was measured using resistance probes and a newly developed approach to determining air/water threshold voltage for the probe. A tall column of eight inch diameter was constructed of Plexiglas and the distributor plate was manufactured to distribute air evenly through the base of the column. Data were gathered throughout the volume at three different gas throughputs. Bubble velocities proved difficult to measure using twin probes with cross-correlation because of radial bubble movement. A series of three-dimensional mean and RMS bubble and liquid velocity measurements were also obtained for a turbulent flow in a laboratory model of a bubble column. These measurements have been made using a three-component laser Doppler velocimeter (LDV), to determine velocity distributions non-intrusively. Finally, the gas-liquid flow inside a vertically situated circular isothermal column reactor was simulated …

BCR National Laboratory (BCRNL) has initiated a project aimed at evaluating the technical and economic feasibility of using a rotary kiln, suitably modified, to burn Pennsylvania anthracite wastes, co-fired with high-sulfur bituminous coal. Limestone will be injected into the kiln for sulfur control, to determine whether high sulfur capture levels can be achieved with high sorbent utilization. The principal objectives of this work are: (1) to prove the feasibility of burning anthracite refuse, with co-firing of high-sulfur bituminous coal and with limestone injection for sulfur emissions control, in a rotary kiln fitted with a Universal Energy International (UEI) air injector system; (2) to determine the emissions levels of SO{sub x} and NO{sub x} and specifically to identify the Ca/S ratios that are required to meet New Source Performance Standards; (3) to evaluate the technical and economic merits of a commercial rotary kiln combustor in comparison to fluidized bed combustors; and, (4) to ascertain the need for further work, including additional combustion tests, prior to commercial application, and to recommend accordingly a detailed program towards this end.

BCR National Laboratory (BCRNL) has initiated a project aimed at evaluating the technical and economic feasibility of using a rotary kiln, suitably modified, to burn Pennsylvania anthracite wastes, co-fired with high-sulfur bituminous coal. Limestone will be injected into the kiln for sulfur control, to determine whether high sulfur capture levels can be achieved with high sorbent utilization. The principal objectives of this work are: (1) to prove the feasibility of burning anthracite refuse, with co-firing of high-sulfur bituminous coal and with limestone injection for sulfur emissions control, in a rotary kiln fitted with a Universal Energy International (UEI) air injector system; (2) to determine the emissions levels of SO{sub x} and NO{sub x} and specifically to identify the Ca/S ratios that are required to meet New Source Performance Standards; (3) to evaluate the technical and economic merits of a commercial rotary kiln combustor in comparison to fluidized bed combustors; and, (4) to ascertain the need for further work, including additional combustion tests, prior to commercial application, and to recommend accordingly a detailed program towards this end.

The Hanford Facility Dangerous Waste Permit Application is considered to 10 be a single application organized into a General Information Portion (document 11 number DOE/RL-91-28) and a Unit-Specific Portion. The scope of the 12 Unit-Specific Portion is limited to Part B permit application documentation 13 submitted for individual, `operating` treatment, storage, and/or disposal 14 units, such as the Liquid Effluent Retention Facility and 200 Area Effluent 15 Treatment Facility (this document, DOE/RL-97-03). 16 17 Both the General Information and Unit-Specific portions of the Hanford 18 Facility Dangerous Waste Permit Application address the content of the Part B 19 permit application guidance prepared by the Washington State Department of 20 Ecology (Ecology 1987 and 1996) and the U.S. Environmental Protection Agency 21 (40 Code of Federal Regulations 270), with additional information needs 22 defined by the Hazardous and Solid Waste Amendments and revisions of 23 Washington Administrative Code 173-303. For ease of reference, the Washington 24 State Department of Ecology alpha-numeric section identifiers from the permit 25 application guidance documentation (Ecology 1996) follow, in brackets, the 26 chapter headings and subheadings. A checklist indicating where information is 27 contained in the Liquid Effluent Retention Facility and 200 Area Effluent 28 Treatment …

Two auger samples from tank 241-C-204 (C-204) were received at the 222-S Laboratories and underwent safety screening analysis, consisting of differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), and total alpha activity. The three samples submitted to energetics determination by DSC exceeded the notification limit. As required by the Tank Characterization Plan, the appropriate notifications were made within 24 hours of official confirmation that the limit was exceeded. Secondary analyses have been initiated. Results from secondary analyses will be included in a revision to this report.

This report contains a number of studies that were performed to better understand the technology of the biodegradation of petroleum hydrocarbons. Topics of investigation include the following: diesel fuel degradation by Rhodococcus erythropolis; BTEX degradation by soil isolates; aerobic degradation of diesel fuel-respirometry; aerobic degradation of diesel fuel-shake culture; aerobic toluene degradation by A3; effect of HEPES, B1, and myo-inositol addition on the growth of A3; aerobic and anaerobic toluene degradation by contaminated soils; denitrifying bacteria MPNs; sulfate-reducing bacteria MPNs; and aerobic, DNB and SRB enrichments.

Xtoys is a collection of xwindow programs for demonstrating simulations of various statistical models. Included are xising, for the two dimensional Ising model, xpotts, for the q-state Potts model, xautomalab, for a fairly general class of totalistic cellular automata, xsand, for the Bak-Tang-Wiesenfield model of self organized criticality, and xfires, a simple forest fire simulation. The programs should compile on any machine supporting xwindows.

The Diesel Emission Control-Sulfur Effects (DECSE) is a joint government/industry program to determine the impact of diesel fuel sulfur levels on emission control systems whose use could lower emissions of nitrogen oxides (NO{sub x}) and particulate matter (PM) from on-highway trucks in the 2002--2004 model years. Phase 1 of the program was developed with the following objectives in mind: (1) evaluate the effects of varying the level of sulfur content in the fuel on the emission reduction performance of four emission control technologies; and (2) measure and compare the effects of up to 250 hours of aging on selected devices for multiple levels of fuel sulfur content. This interim data report summarizes results as of August, 1999, on the status of the test programs being conducted on three technologies: lean-NO{sub x} catalysts, diesel particulate filters and diesel oxidation catalysts.