ABS> The removal rates of iron, nickel, and chromium from synthetic stainless steel waste solutions during electrolysis over a mercury cathode were studied. The loading capacity of the mercury for the stainless steel metals was estimated on the basis of laboratory experiments to be about two% by weight. The laboratory data indicated that, at an electrode potential of --1.80 voits vs S.C.E., 85 ampere-hours per liter of waste removed essentially all of the stainless steel ions from a sulfuric acid solution containing 0.13M metal ions at 35 deg C. (auth)

This plan outlines the procedures and operations used at LLNL's Site 300 for the management of the hazardous waste generated. This waste consists primarily of depleted uranium (a by-product of U-235 enrichment), beryllium, small quantities of analytical chemicals, industrial type waste such as solvents, cleaning acids, photographic chemicals, etc., and explosives. This plan details the operations generating this waste, the proper handling of this material and the procedures used to treat or dispose of the hazardous waste. A considerable amount of information found in this plan was extracted from the Site 300 Safety and Operational Manual written by Site 300 Facility personnel and the Hazards Control Department.

The multiple hydroclone system removed l83 grams of corrosion product solids in l814 hours of operation during reactor run 2l. The low removal rate was attributed to plugging of multiclone feed ports that presumably occurred during the latter part of run 20. After modifications to the reactor core and removal of the multiclone unit at the end of run 21, the reactor core was backflushed with the flow direction in the core loop reversed. During this period, the single hydroclone removed 205 grams of solids in 10.5 hours of operation. (auth)

The quest for fusion power and understanding of plasma physics has resulted in planning, design, and construction of several major fusion power test facilities, based largely on magnetic and inertial confinement concepts. We have considered radiological design aspects of the Joint European Torus (JET), Livermore Mirror and Inertial Fusion projects, and Princeton Tokamak. Our analyses on radiological design criteria cover acceptable exposure levels at the site boundary, man-rem doses for plant personnel and population at large, based upon experience gained for the fission reactors, and on considerations of cost-benefit analyses.

Recommendations to ERDA of four solar heating and cooling demonstration projects are presented. Recommendations include (1) the Westchester Work Center Building owned by Bell Telephone Company of Pennsylvania, (2) the Scottsdale County Courts Building in Scottsdale, Arizona, (3) Howard Johnson's Inc. Hotel in North Miami, Florida, and (4) a combination warehouse, manufacturing facility offered by Mr. John I. Ladd of Ladd Brothers, Pueblo, Colorado. A conceptual diagram and a fact sheet is included for each proposed demonstration site. The combined estimated cost for the four projects is $334,586. (WHK)

The Lawrence Livermore National Laboratory is involved in many facets of research ranging from nuclear weapons research to advanced Biomedical studies. Approximately 80% of all programs at LLNL generate hazardous waste in one form or another. Aside from producing waste from industrial type operations (oils, solvents, bottom sludges, etc.) many unique and toxic wastes are generated such as phosgene, dioxin (TCDD), radioactive wastes and high explosives. One key to any successful waste management program must address the following: proper identification of the waste, safe handling procedures and proper storage containers and areas. This section of the Waste Management Plan will address methodologies used for the Analysis of Hazardous Waste. In addition to the wastes defined in 40 CFR 261, LLNL and Site 300 also generate radioactive waste not specifically covered by RCRA. However, for completeness, the Waste Analysis Plan will address all hazardous waste.

Tensile tests and metallographic examinations were done on electron beam welds on six different chemistries of vanadium. The welds were found to maintain base metal strengths even though large grains were present in the fusion zone. Nitrogen and oxygen were found to be the most effective strengtheners. The weld and surrounding area in material containing high nitrogen and oxygen exhibited higher hardness than the base metal.

Gas hydrates are a vast energy resource with global distribution in the permafrost and in the oceans. Even if conservative estimates are considered and only a small fraction is recoverable, the sheer size of the resource is so large that it demands evaluation as a potential energy source. In this review paper, we discuss the distribution of natural gas hydrate accumulations, the status of the primary international R&D programs, and the remaining science and technological challenges facing commercialization of production. After a brief examination of gas hydrate accumulations that are well characterized and appear to be models for future development and gas production, we analyze the role of numerical simulation in the assessment of the hydrate production potential, identify the data needs for reliable predictions, evaluate the status of knowledge with regard to these needs, discuss knowledge gaps and their impact, and reach the conclusion that the numerical simulation capabilities are quite advanced and that the related gaps are either not significant or are being addressed. We review the current body of literature relevant to potential productivity from different types of gas hydrate deposits, and determine that there are consistent indications of a large production potential at high rates over …

As part of a study to characterize the detailed coordination behavior of Pu(IV), single crystal X-ray diffraction structures have been determined for Pu(IV) and Ce(IV) complexes with the naturally-occurring ligand maltol (3-hydroxy-2-methyl-pyran-4-one) and its derivative bromomaltol (5-bromo-3-hydroxy-2-methyl-pyran-4-one). Although Ce(IV) is generally accepted as a structural analog for Pu(IV), and the maltol complexes of these two metals are isostructural, the corresponding bromomaltol complexes are strikingly different with respect to ligand orientation about the metal ion: All complexes exhibit trigonal dodecahedral coordination geometry but the Ce(IV)-bromomaltol complex displays an uncommon ligand arrangement not mirrored in the Pu(IV) complex, although the two metal species are generally accepted to be structural analogs.

The authors present updated measurements of time-dependent Cp asymmetries in fully reconstructed neutral B decays containing a charmonium meson. The measurements reported here use a data sample of (465 {+-} 5) x 10{sup 6} {Upsilon}(4S) {yields} B{bar B} decays collected with the BABAR detector at the PEP-II asymmetric energy e{sup +}e{sup -} storage rings operating at the SLAC National Accelerator Laboratory. The time-dependent CP asymmetry parameters measured from J/{psi} K{sub S}{sup 0}, J/{psi}K{sub L}{sup 0}, {psi}(2S)K{sub S}{sup 0}, {eta}{sub c}K{sub S}{sup 0}, {chi}{sub c1}K{sub S}{sup 0} and J/{psi} K*(892){sup 0} decays are: C{sub f} = 0.024 {+-} 0.020(stat) {+-} 0.016(syst) and -{eta}{sub f}S{sub f} = 0.687 {+-} 0.028(stat) {+-} 0.012(syst).

It is apparent to anyone who thinks about it that, to a large degree, the basic concepts of Newtonian physics are quite intuitive, but quantum mechanics is not. My purpose in this talk is to introduce you to a new, much more intuitive way to understand how quantum mechanics works. I begin with an incredibly easy way to derive the time evolution of a Gaussian wave-packet for the case free and harmonic motion without any need to know the eigenstates of the Hamiltonian. This discussion is completely analytic and I will later use it to relate the solution for the behavior of the Gaussian packet to the Feynman path-integral and stationary phase approximation. It will be clear that using the information about the evolution of the Gaussian in this way goes far beyond what the stationary phase approximation tells us. Next, I introduce the concept of the bucket brigade approach to dealing with problems that cannot be handled totally analytically. This approach combines the intuition obtained in the initial discussion, as well as the intuition obtained from the path-integral, with simple numerical tools. My goal is to show that, for any specific process, there is a simple Hilbert space interpretation …

The cosmic microwave background power spectra are studied for different families of single field new and chaotic inflation models in the effective field theory approach to inflation. We implement a systematic expansion in 1/N(e), where N(e)~;;50 is the number of e-folds before the end of inflation. We study the dependence of the observables (n(s), r and dn(s)/dlnk) on the degree of the potential (2n) and confront them to the WMAP3 and large scale structure data: This shows in general that fourth degree potentials (n=2) provide the best fit to the data; the window of consistency with the WMAP3 and LSS data narrows for growing n. New inflation yields a good fit to the r and n(s) data in a wide range of field and parameter space. Small field inflation yields r<0.16 while large field inflation yields r>0.16 (for N(e)=50). All members of the new inflation family predict a small but negative running -4(n+1) x 10-4<=dn(s)/dlnk<=-2 x 10-4. (The values of r, n(s), dn(s)/dlnk for arbitrary N(e) follow by a simple rescaling from the N(e)=50 values.) A reconstruction program is carried out suggesting quite generally that for n(s) consistent with the WMAP3 and LSS data and r<0.1 the symmetry breaking scale …

We discuss images of the central {approx} 10 kpc (in projection) of the galaxy merger NGC 6240 at H and K{prime} bands, taken with the NIRC2 narrow camera on Keck II using natural guide star adaptive optics. We detect 28 star clusters in the NIRC2 images, of which only 7 can be seen in the similar-spatial-resolution, archival WFPC2 Planetary Camera data at either B or I bands. Combining the NIRC2 narrow camera pointings with wider NICMOS NIC2 images taken with the F110W, F160W, and F222M filters, we identify a total of 32 clusters that are detected in at least one of these 5 infrared ({lambda}{sub c} > 1 {micro}m) bandpasses. By comparing to instantaneous burst, stellar population synthesis models (Bruzual & Charlot 2003), we estimate that most of the clusters are consistent with being {approx} 15 Myr old and have photometric masses ranging from 7 x 10{sup 5} M{sub {circle_dot}} to 4 x 10{sup 7}M{sub {circle_dot}}. The total contribution to the star formation rate (SFR) from these clusters is approximately 10M{sub {circle_dot}} yr{sup -1}, or {approx} 10% of the total SFR in the nuclear region. We use these newly discovered clusters to estimate the extinction toward NGC 6240's double nuclei, …

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Hydrocarbon oxygenate synthesis from photocatalytic reactions of CO{sub 2} and H{sub 2}O over various catalysts is a very attractive process. However, the formation rate of the hydrocarbons and oxygenates is significantly lower than conventional catalysis. One possible reason for the low rate of product formation is the presence of oxidation sites which reoxidize the products back to CO{sub 2} and H{sub 2}O. For further improvement of catalytic activity for the reduction process, it is essential to understand the oxidation reaction process. We have studied photocatalytic oxidation of methylene blue and found the oxidation rate is significantly higher than the reduction rate.

Various model equations are available for representing the excess Gibbs energy properties (osmotic and activity coefficients) of aqueous and other liquid mixed-electrolyte solutions. Scatchard's neutral-electrolyte model is among the simplest of these equations for ternary systems and contains terms that represent both symmetrical and asymmetric deviations from ideal mixing behavior when two single-electrolyte solutions are mixed in different proportions at constant ionic strengths. The usual form of this model allows from zero to six mixing parameters. In this report we present an analytical method for transforming the mixing parameters of neutral-electrolyte-type models with larger numbers of mixing parameters directly to those of models with fewer mixing parameters, without recourse to the source data used for evaluation of the original model parameters. The equations for this parameter conversion are based on an extension to ternary systems of the methodology of Rard and Wijesinghe [J. Chem. Thermodyn. 35, 439-473 (2003)] and Wijesinghe and Rard [J. Chem. Thermodyn. 37, 1196-1218 (2005)] that was applied by them to binary systems. It was found that the use of this approach with a constant ionic-strength cutoff of I {le} 6.2 mol {center_dot} kg{sup -1} (the NaCl solubility limit) yielded parameters for the NaCl + SrCl{sub 2} …

We present new measurements of time-dependent CP asymmetries for B{sup 0} {yields} D{sup (*)+}d{sup (*)-} decays using (467 {+-} 5) x 10{sup 6} B{bar B} pairs collected with the BABAR detector located at the PEP-II B Factory at the Stanford Linear Accelerator Center. We determine the CP-odd fraction of the B{sup 0} {yields} D*{sup +}D*{sup -} decays to be R{perpendicular} = 0.158 {+-} 0.028 {+-} 0.006 and find CP asymmetry parameters for the CP-even component of the decay S{sub +} = -0.76 {+-} 0.16 {+-} 0.04 and C{sub +} = 0.00 {+-} 0.12 {+-} 0.02. We measure S = -0.63{+-}0.36{+-}0.05 and C = -0.07{+-}0.23{+-}0.03 for B{sup 0} {yields} D{sup +}D{sup -}, S = -0.62{+-}0.21{+-}0.03 and C = 0.08 {+-} 0.17 {+-} 0.04 for B{sup 0} {yields} D*{sup +}D{sup -}, and S = -0.73 {+-} 0.23 {+-} 0.05 and C = 0.00 {+-} 0.17 {+-} 0.03 for B{sup 0} {yields} D{sup +}D*{sup -}. For the B{sup 0} {yields} D*{sup {+-}}D{sup {-+}} decays, we also determine the CP-violating asymmetry A = 0.008 {+-} 0.048 {+-} 0.013. In each case, the first uncertainty is statistical and the second is systematic. The measured values for the asymmetries are all consistent with the Standard Model.

The High Exposure Facility is a collimated high-level gamma irradiator that is located in the basement of the 318 building. It was custom developed by PNNL back in 1982 to meet the needs for high range radiological instrument calibrations and dosimeter irradiations. At the time no commercially available product existed that could create exposure rates up to 20,000 R/h. This document is intended to pass on the design criteria that was employed to create this unique facility, while maintaining compliance with ANSI N543-1974, "General Safety Standard for Installations Using Non-Medical X-Ray and Sealed Gamma-Ray Sources, Energies up to 10 MeV."

The four diffusion coefficients D{sub ij} of the ternary system NaCl-MgCl{sub 2}-H{sub 2}O at the simplified seawater composition 0.48877 mol {center_dot} dm{sup -3} NaCl and 0.05110 mol {center_dot} dm{sup -3} MgCl{sub 2} have been remeasured at 25 C. The diffusion coefficients were obtained using both Gouy and Rayleigh interferometry with the highly precise Gosting diffusiometer. The results, which should be identical in principle, are essentially the same within or very close to their combined 'realistic' errors. This system has a cross-term D{sub 12} that is larger than the D{sub 22} main-term, where subscript 1 denotes NaCl and 2 denotes MgCl{sub 2}. The results are compared with earlier, less-precise measurements. Recommended values for this system are (D{sub 11}){sub V} = 1.432 x 10{sup -9} m{sup 2} {center_dot} sec{sup -1}, (D{sub 12}){sub V} = 0.750 x 10{sup -9} m{sup 2} {center_dot} sec{sup -1}, (D{sub 21}){sub V} = 0.0185 x 10{sup -9} m{sup 2} {center_dot} sec{sup -1}, and (D{sub 22}){sub V} = 0.728 x 10{sup -9} m{sup 2} {center_dot} sec{sup -1}.

As an alternative to the traditional recovery systems, it was proposed in a previous publication that the n-butanol/acetone/ethanol fermentation products could be recovered as a power grade fuel blend and used directly as a fuel. This would affect a savings in process energy requirements because each chemical component would not have to be processed individually to technical grade purity. Further, some residual water could be tolerated in the fuel blend. To develop such a power grade fuel recovery scheme beyond the conceptual stage, the Energy Research and Resource Division of the Kansas Energy Office undertook a two-fold program to demonstrate and test a power grade butanol/acetone/ethanol fuel recovery system, and further to demonstrate the feasibility of using the fuel blend in a standard type engine. A development program was initiated to accomplish the following objectives: design and test an operational power grade butanol recovery plant that would operate at one liter per hour output; and test and assess the performance of power grade butanol in a spark ignition automotive engine. This project has demonstrated that recovery of a power grade butanol fuel blend is simple and can be accomplished at a considered energy advantage over ethanol. It was further demonstrated …

Statistical analyses provide a valuable method for establishing initially the existence (or lack of existence) of a relationship between diverse data sets. Statistical methods also allow one to make quantitative assessments of the strengths of observed relationships. This paper reviews the essential techniques and underlying statistical bases for the use of correlative methods in solar wind-magnetosphere coupling studies. Techniques of visual correlation and time-lagged linear cross-correlation analysis are emphasized, but methods of multiple regression, superposed epoch analysis, and linear prediction filtering are also described briefly. The long history of correlation analysis in the area of solar wind-magnetosphere coupling is reviewed with the assessments organized according to data averaging time scales (minutes to years). It is concluded that these statistical methods can be very useful first steps, but that case studies and various advanced analysis methods should be employed to understand fully the average response of the magnetosphere to solar wind input. It is clear that many workers have not always recognized underlying assumptions of statistical methods and thus the significance of correlation results can be in doubt. Long-term averages (greater than or equal to 1 hour) can reveal gross relationships, but only when dealing with high-resolution data (1 to 10 …

Mixtures of hydrogen isotopes, primarily deuterium (D/sub 2/), protium-deuterium (HD), and protium (H/sub 2/) must be pumped by the vacuum system in the Mirror Fusion Test Facility at Lawrence Livermore National Laboratory. In this study, we used argon as an adsorbent for cryopumping these isotopes at 4.2 K and found that deuterium will displace already adsorbed protium. Thus, when we pump mixtures of the two, sufficient argon must be supplied to adsorb both species. We also found that without argon, deuterium will cryptrap protium in accord with Raoult's law.

Flux is conserved during mechanical compression of magnetic fields for both nonrelativistic and relativistic compressors. However, the relativistic compressor generates radiation, which can carry up to twice the energy content of the magnetic field compressed adiabatically. The radiation may be either confined or allowed to escape.

The research completed and in progress for the first period of this grant is reviewed. Specific scattering scenarios for TFTR and JET and ITER were studied. The Lodestar scattering code, SKATR, was upgraded to include anisotropic energetic ion distributions and an analytic diffraction formulation was completed. Research continues on JET studies and upgrading the code for JET and ITER relevant conditions.