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Reduction of U(VI) Complexes by Anthraquinone Disulfonate: Experiment and Molecular Modeling
Past studies demonstrate that complexation will limit abiotic and biotic U(VI) reduction rates and the overall extent of reduction. However, the underlying basis for this behavior is not understood and presently unpredictable across species and ligand structure. The central tenets of these investigations are: (1) reduction of U(VI) follows the electron-transfer (ET) mechanism developed by Marcus; (2) the ET rate is the rate-limiting step in U(VI) reduction and is the step that is most affected by complexation; and (3) Marcus theory can be used to unify the apparently disparate U(VI) reduction rate data and as a computational tool to construct a predictive relationship.
Date:
March 17, 2004
Creator:
Ainsworth, C. C.; Wang, Z.; Rosso, K. M.; Wagnon, K. & Fredrickson, J. K.
System:
The UNT Digital Library
Combinatorial Synthesis and Discovery of PEMFC Electrocatalysts on a Scaled Powder Production Platform
This report talks about Combinatorial Synthesis and Discovery of PEMFC Electrocatalysts on a Scaled Powder Production Platform
Date:
October 24, 2003
Creator:
Atanassova, Paolina; Bhatia, Rimple; Dericotte, David; Napolitano, Paul; Hampden-Smith, Mark & Kodas, Toivo
System:
The UNT Digital Library
Combinatorial Synthesis of Oxygen Reduction Electrocatalysts by Spray Pyrolysis
This report talks about Combinatorial Synthesis of Oxygen Reduction Electrocatalysts by Spray Pyrolysis
Date:
October 20, 2002
Creator:
Napolitano, Paul; Dericotte, David; Bhatia, Rimple; Atanassova, Paolina; Hampden-Smith, Mark & Kodas, Toivo
System:
The UNT Digital Library
Combinatorial Spray-Based Synthesis of PEM FC Electrocatalysts
This report talks about Combinatorial Spray-Based Synthesis of PEM FC Electrocatalysts
Date:
November 2, 2003
Creator:
Atanassova, Paolina; Bhatia, Rimple; Brewster, James; Dericotte, David; Gurau, Bogdan; Napolitano, Paul et al.
System:
The UNT Digital Library
A New Class of Solvents for TRU Dissolution and Separation: Ionic Liquids
This presentation was given at the DOE Office of Science-Environmental Management Science Program (EMSP) High-Level Waste Workshop held on January 19-20, 2005 at the Savannah River Site.
Date:
January 19, 2005
Creator:
Rogers, Robin D.
System:
The UNT Digital Library
Novel Fission-Product Separation Based on Room Temperature Ionic Liquids
This presentation was given at the DOE Office of Science-Environmental Management Science Program (EMSP) High-Level Waste Workshop held on January 19-20, 2005 at the Savannah River Site.
Date:
January 19, 2005
Creator:
Luo, Huimin; Dai, Sheng; Bonnesen, Peter V.; Buchanan, A.C.; Rogers, Robin D.; Holbrey, John D. et al.
System:
The UNT Digital Library
After Treatment (Emissions) Issues for Locomotives in the Future
None
Date:
January 21, 2001
Creator:
Patten, Jim
System:
The UNT Digital Library