Established uses of enriched isotopes in the environmental field were surveyed to determine future trends in isotope needs. Based on established isotope uses, on the projected increase in the pollution problem, and on the apparent social and economic pressure for pollution abatement, a significant demand for enriched isotopes appears to be developing for the assessment and control of air, water, and soil pollutants. Isotopic techniques will be used in combination with conventional methods of detection and measurement, such as gas chromatography, x-ray fluorescence, and atomic absorption. Recent advances in economical isotope separation methods, instrumentation, and methodology promise to place isotopic technology within the reach of most research and industrial institutions. Increased application of isotope techniques appears most likely to occur in areas where data are needed to characterize the movement, behavior, and fate of pollutants in the environment.

A program was conducted for the definition and demonstration of acceptable waste packages for defense transuranic waste for interim storage and terminal isolation. During FY-1977, a Contractor Questionnaire was used to gather pertinent data and to assess contractor concerns. This information was integrated into basic application data in the form of a checklist. Conceptual Container Design Specifications were developed by analyzing and evaluating the application data against Federal Regulations and interim/terminal storage constraints.

The overall objective of the Westinghouse coal gasification program is to demonstrate the viability of the Westinghouse pressurized, fluidized bed, gasification system for the production of medium-Btu fuel gas for syngas, electrical power generation, chemical feedstocks, or industrial fuels and to obtain performance and scaleup data for the process and hardware. Technical progress summaries and reports are presented for the following tasks: (1) process development unit (PDU) test operations and results (gasifier test TP-033-1 and maintenance and modifications); (2) process analysis (environmental characterization results, coal gas combustion results, and fines elutriation and consumption results); (3) cold flow scaleup (modifications and maintenance, operations, and data analysis); (4) process and component engineering and design (hot fines recycle modifications, and hot recycled fines); (5) laboratory support studies (gas-solids flow modeling and coal/ash behavior). 23 figures, 23 tables.

This report summarizes and compares the main beryllium properties included in producer, Department of Energy (formerly ERDA) facility, and government specifications. These data are tabulated in a sequence established primarily by increasing purity and secondarily by increasing tensile properties. Comments on formability and weldability are also included.

The Data Director editor is a powerful, multiuser editor that will aid in the development and modification of APT part programs, assembly-language programs, and other text. Some benefits of the editor are as follows: most of the editor is reentrant, allowing several users to share it; the user can use the editor as though the entire file being edited is in memory; editing takes place on a working file so that changes are not made to the original file until desired; the editor offers a powerful command set where most commands have the same syntax. 1 table.

A conceptual design of a D-T fusion facility for continuous production of 14-MeV neutron wall loading from 5 to 10 MW/m/sup 2/ at the plasma surface is presented. In this design, D-T neutrons are produced in a linear, two-component plasma formed by neutral beam irradiation of a fully ionized warm plasma target. The beam energy, which is deposited in the center, is transferred to the warm plasma mainly by electron drag and is conducted along the target plasma column to end regions where it is absorbed in neutral gas at high pressure. The target plasma is operated in a regime where electron thermal conduction along the column is the controlling energy-loss process. The loss rate is minimized by adjusting the diameter and length of the plasma column. A substantial gradient in T/sub e/ along the column results in recombination of the plasma to gas in the end-regions before impact on the end walls. The resultant hot gas is cooled by contact with large-area heat exchangers. In this way, the large steady-state heat load from the injected neutral beams is diffused and removed at tolerable heat flux levels. The reacting plasma is essentially an extrapolation of the 2XIIB high-..beta.. plasma to …

We analyze the solar reflectance of asphalt roofing shingles that are covered with pigmented mineral roofing granules. The reflecting surface is rough, with a total area approximately twice the nominal area. We introduce a simple analytical model that relates the 'micro-reflectance' of a small surface region to the 'macro-reflectance' of the shingle. This model uses a mean field approximation to account for multiple scattering effects. The model is then used to compute the reflectance of shingles with a mixture of different colored granules, when the reflectances of the corresponding mono-color shingles are known. Simple linear averaging works well, with small corrections to linear averaging derived for highly reflective materials. Reflective base granules and reflective surface coatings aid achievement of high solar reflectance. Other factors that influence the solar reflectance are the size distribution of the granules, coverage of the asphalt substrate, and orientation of the granules as affected by rollers during fabrication.

Density modulation of charged particle beams may occur as a consequence of deliberate action, or may occur inadvertently because of imperfections in the particle source or acceleration method. In the case of intense beams, where space charge and external focusing govern the beam dynamics, density modulation may under some circumstances be converted to velocity modulation, with a corresponding conversion of potential energy to kinetic energy. Whether this will occur depends on the properties of the beam and the initial modulation. This paper describes the evolution of discrete and continuous density modulations on intense beams, and discusses three recent experiments related to the dynamics of density-modulated electron beams.

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Morphological control of nanocrystals has becomeincreasingly important, as many of their physical and chemical propertiesare highly shape-dependent. Nanocrystal shape control for both single andmultiple material systems, however, remains fairly empirical andchallenging. New methods need to be explored for the rational syntheticdesign of heterostructures with controlled morphology. Overgrowth of adifferent material on well-faceted seeds, for example, allows for the useof the defined seed morphology to control nucleation and growth of thesecondary structure. Here, we have used highly faceted cubic Pt seeds todirect the epitaxial overgrowth of a secondary metal. We demonstrate thisconcept with lattice matched Pd to produce conformal shape-controlledcore-shell particles, and then extend it to lattice mismatched Au to giveanisotropic growth. Seeding with faceted nanocrystals may havesignificant potential towards the development of shape-controlledheterostructures with defined interfaces.

This project demonstrates a novel nanostructured solar cell architecture capable of achieving high efficiency levels that is relatively simple and inexpensive to manufacture. The high efficiency will be achieved by the novel structure that separates the path of the photons from the path of the generated charge carriers. In this way, the photon path can be long for maximum light absorption, while the path for carriers can be short for maximum electronic energy harvesting. The combination of maximum light absorption coupled with maximum carrier harvesting is the basis for the expected high efficiency. The project will develop high efficiency solar cell prototypes utilizing this unique nanostructured architecture. The project addresses the fundamental limitation inherent in all current solar cell designs, and which opens a pathway to development for high efficiency solar cells at low cost. Realizing this goal will result in a levelized cost of electricity in the range of 10¢/kWh, which would achieve the long-sought goal of making photovoltaic electricity cost competitive with fossil-fuel generated electricity without any governmental subsidies. This breakthrough would spur the already rapid growth in the photovoltaic industry to an explosive pace, with significant, widespread benefit to the national economy and the nation’s energy security. …

This project used gene expression patterns from two forest Free-Air CO2 Enrichment (FACE) experiments (Aspen FACE in northern Wisconsin and POPFACE in Italy) to examine ways to increase the aboveground carbon sequestration potential of poplars (Populus). The aim was to use patterns of global gene expression to identify candidate genes for increased carbon sequestration. Gene expression studies were linked to physiological measurements in order to elucidate bottlenecks in carbon acquisition in trees grown in elevated CO2 conditions. Delayed senescence allowing additional carbon uptake late in the growing season, was also examined, and expression of target genes was tested in elite P. deltoides x P. trichocarpa hybrids. In Populus euramericana, gene expression was sensitive to elevated CO2, but the response depended on the developmental age of the leaves. Most differentially expressed genes were upregulated in elevated CO2 in young leaves, while most were downregulated in elevated CO2 in semi-mature leaves. In P. deltoides x P. trichocarpa hybrids, leaf development and leaf quality traits, including leaf area, leaf shape, epidermal cell area, stomatal number, specific leaf area, and canopy senescence were sensitive to elevated CO2. Significant increases under elevated CO2 occurred for both above- and belowground growth in the F-2 generation. Three …

SRI International has conducted research on the upgrading of computerized thermo-hydro code calculations and the synthesis of energetic materials. This project comprised four tasks, as follows: Task A included: (1) formulating routines for inverting the P = P(T,V) and V = V(T,P) equations of state when isotherms exhibit a van der Waals' loop; (2) incorporating these routines into the TIGER code so V and T can be used as independent variables in computing thermodynamic functions of liquids exhibiting a van der Waals' loop; (3) using these routines to incorporate into TIGER the prototype equation of state for liquids formulated at LLL by Dr. E.L. Lee; and (4) modifying TIGER routines to perform thermodynamic calculations when the concentrations of the gaseous species become zero. In Task B, a homopolymer of fluorodinitroethyl vinyl ether was obtained as a white, cotton-like material by bulk cationic polymerization. Work was begun on solution polymerization of fluorodinitroethyl vinyl ether. During Task C, studies were conducted on the synthesis of energetic compounds, especially hexanitrobenzene (HNB). The following areas were investigated: (1) nitration of phloroglucinol trioxime; (2) reaction of nitroaromatics with hydroxylamine; (3) oxidation of triaminotrinitrobenzene (TATB) with nitric acid; (4) oxidations with trifluoroperacetic acid, (5) oxidations with …

An evaluation was made of the design and hydromechanical performance characteristics for three basic turbine types: axial flow (Jonval), inward radial flow (Francis) and crossflow (Banki). A single commercially available turbine representative of each type and within the appropriate power range (<5hp) was obtained for evaluation. Specific turbine selections were based on price, availability and suitability for operation at heads of 50 feet or less and flows under 2 cubic feet per second. In general, the peak operating efficiencies of each unit tended to be lower than anticipated, falling in the range of 40 to 50%. With sufficient flow, however, significant useful power outputs up to 3 hp were obtained. While the radial flow turbine (a centrifugal pump operated as a turbine) had the lowest initial unit cost, the axial and cross flow designs exhibited more stable operation, particularly under transient loadings. The crossflow turbine had the added advantage that it was essentially self-cleaning. With further developmental effort and appropriate design modifications it should be possible to bring each of these microhydro designs to their full performance potential.

This paper contains lecture notes given by Gary Feinberg on the historical aspect of the violation of P and C invariance and more recently the violation of CP invariance. (LSP) 13 refs., 2 figs., 2 tabs.

The preliminary safety assessment report analyzes the potential radiological risk of the integrated MSNPS with the launch vehicle including interface with the weapon system. Most emphasis will be placed the prime power concept design. Safety problems can occur any time during the entire life cycle of the system including contingency phases. The preliminary safety assessment report is to be delivered at the end of phase 2. This assessment will be the basis of the safety requirements which will be applied to the design of the MSNPS as it develops in subsequent phases. The assessment also focuses design activities on specific high-risk scenarios and missions that may impact safety.

The Phase 2 program objectives are to (1) demonstrate concept feasibility, (2) develop a preliminary design, and (3) complete Phase 3 engineering development and ground test plans. The approach to accomplish these objectives is to prove technical feasibility of our baseline design early in the program while maintaining flexibility to easily respond to changing requirements and advances in technology. This approach recognizes that technology is advancing rapidly while the operational phase MSNPS is 15 to 20 years in the future. This plan further recognizes that the weapons platform and Advanced Launch System (ALS) are in very early program definition stages; consequently, their requirements, interfaces, and technological basis will evolve. This document outlines the Phase 2 plan along with task scheduling of the various program aspects.

Development of a risk-analysis methodology for inclusion in the Threshold Screening Model used by the Buildings and Community Systems Division for the purpose of evaluating projects that are candidates for funding by that division is proposed. The contract includes a review of the pertinent literature, discussions with individuals in industry, development of evaluation criteria, development and test of alternative approaches, evaluation of results, and preparation of a final report. The following are described: management structure; the technical approach; the work breakdown structure; management control; government-owned property, facilities, and material; and test and security plans.

This project is a continuing multidisciplinary study of middle to Upper Cretaceous marine carbonate and clastic rocks in the Utah-Colorado-Kansas corridor of the old Cretaceous seaway that extended from the Gulf Coast to the Arctic during maximum Cretaceous transgressions. It is collaborative between in the US Geological Survey (W.E. Dean, P.I.) and University researchers led by The Pennsylvania State University(M.A. Arthur, P.I.) and funded by DOE and the USGS, in part. Research focusses on the Greenhom, Niobrara and lower Pierre Shale units and their equivalents, combining biostratigraphic/paleoecologic studies, inorganic, organic and stable isotopic geochemical studies, mineralogical investigations and high-resolution geophysical logging. This research requires unweathered samples and continuous smooth exposures'' in the form of cores from at least 4 relatively shallow reference holes (i.e. < 1000m) in transect from east to west across the basin. The major initial effort was recovery in Year 1 of the project of continuous cores from each site in the transect. This drilling provided samples and logs of strata ranging from pelagic sequences that contain organic-carbon-rich marine source rocks to nearshore coal-bearing units. This transect also will provide information on the extent of thermal maturation and migration of hydrocarbons in organic-carbon-rich strata along a burial …

A knowledge of the effect of reactor irradiation on the properties of UO{sub 2} is relevant to the design and evaluation of UO{sub 2} fuel elements for the PRTR. Of particular interest is the effect of reactor irradiation on the thermal conductivity of sintered UO{sub 2} and the type, mechanism, and extent of radiation damage in sintered UO{sub 2}. In the latter case the study of fractured surfaces of irradiated UO{sub 2} specimens is a method of determining the extent of radiation damage. It is the purpose of this report to propose an irradiation test of a number of capsules containing UO{sub 2} thermal conductivity and fractography specimens.

It is recommended that the actual intensity existing today above the liquid be measured before recommendations are made on cutting through the concrete seal. A detailed statement of work on this problem follows. The calculations have been filed. In the study of the feasibility of cutting through the concrete seal on the center riser of the waste storage tank the radiation intensity that would be encountered is critical because director operator contact would be required. The question of the radiation intensity to be expected was approached from two standpoints: (a) a study of previous measurements of sludge level and activities in the storage tanks; and (b) direct calculation.

The Notre Dame Radiation Laboratory is a facility of the Department of Energy operated for the DOE by the University of Notre Dame under contract No. DE-AC02-76ER00038. This quarterly report summarizes the progress on the programs within the Laboratory for the period of October 1, 193 through December 31, 1993. The activities of the staff during this period are noted. A list of publications is presented. A listing and a brief description of each of the reports issued during this quarter are provided.

In June 28, 1997, the Low Level Waste (LLW) glovebox was tested using glovebox acceptance test procedure 13031A-85. The primary focus of the glovebox acceptance test was to examine control system interlocks, display menus, alarms, and operator messages. Limited mechanical testing involving the drum ports, hoists, drum lifter, compacted drum lifter, drum tipper, transfer car, conveyors, lidder/delidder device and the supercompactor were also conducted. As of November 24, 1997, 2 of the 131 test exceptions that affect the LLW glovebox remain open. These items will be tracked and closed via the WRAP Master Test Exception Database. As part of Test Exception resolution/closure the responsible individual closing the Test Exception performs a retest of the affected item(s) to ensure the identified deficiency is corrected, and, or to test items not previously available to support testing. Test Exceptions are provided as appendices to this report.

The Nijmegen YN potential models are reviewed. Differences with the models constructed by the Juelich group are highlighted. A mini- review is given of the status of the scalar mesons and their relevance for the NN and YN interactions. Finally, the reactions {bar N}N {yields} {bar Y}Y are discussed.