Due to analytical limitations for the determination of fluoride (F) and chloride (Cl) in a previous anion exchange study, an additional study of the decontamination of Pu from F and Cl by oxalate precipitation, filtration and calcination was performed. Anion product solution from the previous impurity study was precipitated as an oxalate, filtered, and calcined to produce an oxide for analysis by pyrohydrolysis for total Cl and F. Analysis of samples from this experiment achieved the purity specification for Cl and F for the proposed AFS-2 process. Decontamination factors (DF's) for the overall process (including anion exchange) achieved a DF of {approx}5000 for F and a DF of {approx}100 for Cl. Similar experiments where both HF and HCl were spiked into the anion product solution to a {approx}5000 {micro}g /g Pu concentration showed a DF of 5 for F and a DF of 35 for Cl across the combined precipitation-filtration-calcination process steps.

Non-radioactive cerium (Ce) and radioactive plutonium (Pu) anion exchange column experiments using scaled HB-Line designs were performed to investigate the feasibility of using either gadolinium nitrate (Gd) or boric acid (B as H{sub 3}BO{sub 3}) as a neutron poison in the H-Canyon dissolution process. Expected typical concentrations of probable impurities were tested and the removal of these impurities by a decontamination wash was measured. Impurity concentrations are compared to two specifications - designated as Column A or Column B (most restrictive) - proposed for plutonium oxide (PuO{sub 2}) product shipped to the Mixed Oxide (MOX) Fuel Fabrication Facility (MFFF). Use of Gd as a neutron poison requires a larger volume of wash for the proposed Column A specification. Since boron (B) has a higher proposed specification and is more easily removed by washing, it appears to be the better candidate for use in the H-Canyon dissolution process. Some difficulty was observed in achieving the Column A specification due to the limited effectiveness that the wash step has in removing the residual B after {approx}4 BV's wash. However a combination of the experimental 10 BV's wash results and a calculated DF from the oxalate precipitation process yields an overall DF sufficient …

Recently, the CSNI directed WGRisk to set up a task group called DIGREL to initiate a new task on developing a taxonomy of failure modes of digital components for the purposes of PSA. It is an important step towards standardized digital I&C reliability assessment techniques for PSA. The objective of this paper is to provide a comparison of the failure mode taxonomies provided by the participants. The failure modes are classified in terms of their levels of detail. Software and hardware failure modes are discussed separately.

Advanced Research Projects Agency-Energy project sheet summarizing general information about the Innovative Materials and Processes for Advanced Carbon Capture Technologies (IMPACCT) program including critical needs, innovation and advantages, impacts, and contact information. This sheet discusses frameworks for carbon capture as part of the "High Throughput Discovery of Robust Metal Organic Framework for CO2 Capture" project.

Advanced Research Projects Agency-Energy project sheet summarizing general information about the Innovative Materials and Processes for Advanced Carbon Capture Technologies (IMPACCT) program including critical needs, innovation and advantages, impacts, and contact information. This sheet discusses the development of synthetic catalysts as part of the "Catalytic Improvement of Solvent Capture Systems" project.

This is a revision to a previously released report. This revision contains additional analytical results for the sample with HEIS number B2H4X7. Between November 4, 2010 and October 26, 2011 sediment samples were received from 100-HR-3 Operable Unit for geochemical studies. The analyses for this project were performed at the 331 building located in the 300 Area of the Hanford Site. The analyses were performed according to Pacific Northwest National Laboratory (PNNL) approved procedures and/or nationally recognized test procedures. The data sets include the sample identification numbers, analytical results, estimated quantification limits (EQL), and quality control data. The preparatory and analytical quality control requirements, calibration requirements, acceptance criteria, and failure actions are defined in the on-line QA plan 'Conducting Analytical Work in Support of Regulatory Programs' (CAW). This QA plan implements the Hanford Analytical Services Quality Assurance Requirements Documents (HASQARD) for PNNL. Samples were received with a chain of custody (COC) and were analyzed according to the sample identification numbers supplied by the client. All Samples were refrigerated upon receipt until prepared for analysis. All samples were received with custody seals intact unless noted in the Case Narrative. Holding time is defined as the time from sample preparation to the …

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Congress has broad authority to place conditions on the purchases made by the federal government or with federal dollars. One of many conditions that it has placed on direct government purchases is a requirement that they be produced in the United States. The most well-known of these requirements is the Buy American Act, which is the major domestic preference statute governing procurement by the federal government. This report summarizes (1) the Buy American Act, what it does and does not cover; (2) the Little Buy American Acts found in permanent law, emphasizing what they govern, major exceptions and why Congress felt them necessary in light of the requirements of the Buy American Act; and (3) the temporary Little Buy American provision found in the American Recovery and Reinvestment Act.

Report that examines the constitutional provisions that might be implicated by retroactive tax legislation, including legislation that seems intended to punish past behavior.

Report breaking down billing rates for legal services based on salaries and operating costs documented during fiscal year 2011, for the purpose of developing rates to charge state agencies for legal services during 2012.

Report breaking down billing rates for legal services based on salaries and operating costs budgeted for the fiscal year, for the purpose of developing rates to charge state agencies for legal services during 2013.

A set of steady state diffusion flow equations, for the hydrogen diffusion from one bag to the next bag (or one plastic waste container to another), within a set of nested waste bags (or nested waste containers), are developed and presented. The input data is then presented and justified. Inputting the data for each volume and solving these equations yields the steady state hydrogen concentration in each volume. The input data (permeability of the bag surface and closure, dimensions and hydrogen generation rate) and equations are analyzed to obtain the hydrogen concentrations in the innermost container for a set of containers which are analyzed for the TRUCON code for the general waste containers and the TRUCON code for the Pencil Tank Overpacks (PTO) in a Standard Waste Box (SWB).

Advanced Research Projects Agency-Energy project sheet summarizing general information about the High Energy Advanced Thermal Storage (HEATS) program including critical needs, innovation and advantages, impacts, and contact information. This sheet discusses an advanced thermo-adsorptive battery as part of the "New Generation of the Advanced Thermo-Adsorptive Battery Climate Control System" project.

Advanced Research Projects Agency-Energy project sheet summarizing general information about the Innovative Materials and Processes for Advanced Carbon Capture Technologies (IMPACCT) program including critical needs, innovation and advantages, impacts, and contact information. This sheet discusses the development of a process to separate and store carbon dioxide as part of the"Electrochemically Mediated Separation for Carbon Capture and Mitigation" project.

Advanced Research Projects Agency-Energy project sheet summarizing general information about the High Energy Advanced Thermal Storage (HEATS) program including critical needs, innovation and advantages, impacts, and contact information. This sheet discusses the development of new materials to store heat in solar and nuclear power plants as part of the "Metallic Composites Phase-Change Materials for High-Temperature Thermal Energy Storage" project.

This report discusses how the Arecibo Ionospheric Observatory gathers funding for future endeavors.

This report examines 40 major or controversial regulatory actions taken by or under development at EPA since January 2009, providing details on the regulatory action itself, presenting an estimated timeline for completion of the rule and provides the EPA's estimates of costs and benefits where available. It provides background information on recent EPA regulatory activity to help address issues raised by this activity, as well as factors that will affect the timeframe in which these regulations will take place.

This report looks at Congress's FY2013 budget allocations for the Transportation, Housing and Urban Development, and Related Agencies (THUD) appropriations subcommittee.

The work described in the present report had the original goal to produce large, entangled, ring polymers that were uncontaminated by linear chains and to characterize by rheological methods the dynamics of these rings. While the work fell short of this specific goal, the outcomes of the research performed under support from this grant provided novel macromolecular synthesis methods, new separation methods for ring and linear chains, and novel rheological data on bottle brush polymers, wedge polymers and dendron-based ring molecules. The grant funded a total of 8 archival manuscripts and one patent, all of which are attached to the present report.

In order to simultaneously achieve both high spatial resolution and high sensitivity in small Positron Emission Tomography (PET) systems, scintillation detectors must be long in the radial direction as well as able to provide depth-of-interaction (DOI) information. DOI information is typically provided by constructing detectors from two or more layers of scintillators that are identifiable due to their different decay times. This approach has worked well in tomographs such as the High Resolution Research Tomograph (HRRT, CTI PET Systems, Inc.) in which the emission and excitation bands of the scintillator layers do not overlap each other. However, many potentially important pairs of scintillator crystals exist in which the emission of one crystal is, in fact, absorbed and re-emitted by the second crystal, thus impacting the pulse shape discrimination process used to identify the scintillator layers. These potentially useful pairs of scintillators are unlikely to be implemented in phoswich detectors without a comprehensive understanding of the complex emission that results when the light of one crystal is absorbed by the second crystal and then reemitted. Our objective is to develop a fundamental understanding of the optical phenomena that occur in phoswich detectors and to exploit these phenomena to achieve improved spatial …

Report that surveys existing law for legal issues that have arisen, or may arise in the future, on account of climate change and government responses thereto.

This report examines current political and economic conditions in Honduras as well as issues in Honduran-U.S. relations.

This report examines current conditions in Honduras as well as issues in U.S-Honduran relations, including human rights, poverty, inequality, international support, democracy, security challenges, and international trade.

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