Direct Comparison of the X-Ray Emission and Absorption of Cerium Oxide (open access)

Direct Comparison of the X-Ray Emission and Absorption of Cerium Oxide

Bremstrahlung Isochromat Spectroscopy (BIS). The XES spectra were collected using a Specs electron gun for the excitation and the XES 350 grating monochromator and channel plate system from Scienta as the photon detection. Spectra were collected in 'normal mode,' where the electron gun kinetic energy (KE) and the energy position of the center of the channel plate were both fixed and the energy distribution in the photon (hv) spectrum was derived from the intensities distributed across the channel plate detector in the energy dispersal direction. The polycrystalline Ce sample was oxidized by exposure to air at ambient pressures. After introduction to the ultra-high vacuum system, the oxidized sample was bombarded with Ar, to clean the topmost surface region and stabilize the surface and near surface regions. Although CeO{sub 2} would be the thermodynamically preferred composition in an oxygen rich environment, the combination of a vacuum environment and ion etching may have driven the near surface region into a Ce{sub 2}O{sub 3} stoichiometry. XES data collection occurred with the sample at or near room temperature. The base pressure of the system was 3 x 10{sup -10} torr, but the pressure changed depending the energy and current of the electron gun. For …
Date: November 24, 2010
Creator: Tobin, J G; Yu, S W; Chung, B W; Waddill, G D & Denlinger, J D
System: The UNT Digital Library
Energy Efficiency Design Options for Residential Water Heaters: Economic Impacts on Consumers (open access)

Energy Efficiency Design Options for Residential Water Heaters: Economic Impacts on Consumers

The U.S. Department of Energy (DOE) recently completed a rulemaking process in which it amended the existing energy efficiency standards for residential water heaters. A key factor in DOE?s consideration of new standards is the economic impacts on consumers. Determining such impacts requires a comparison of the additional first cost of energy efficiency design options with the savings in operating costs. This paper describes the method used to conduct the life-cycle cost (LCC) and payback period analysis for gas and electric storage water heaters. It presents the estimated change in LCC associated with more energy-efficient equipment, including heat pump electric water heaters and condensing gas water heaters, for a representative sample of U.S. homes. The study included a detailed accounting of installation costs for the considered design options, with a focus on approaches for accommodating the larger dimensions of more efficient water heaters. For heat pump water heaters, the study also considered airflow requirements, venting issues, and the impact of these products on the indoor environment. The results indicate that efficiency improvement relative to the baseline design reduces the LCC in the majority of homes for both gas and electric storage water heaters, and heat pump electric water heaters and …
Date: November 24, 2010
Creator: Lekov, Alex; Franco, Victor; Meyers, Steve; Thompson, Lisa & Letschert, Virginie
System: The UNT Digital Library