100 Area Excavation Treatability Test Plan. Revision 1 (open access)

100 Area Excavation Treatability Test Plan. Revision 1

This test plan documents the requirements for a treatability study on field radionuclide analysis and dust control techniques. These systems will be used during remedial actions involving excavation. The data from this treatability study will be used to support the feasibility study (FS) process. Excavation is one of the high-priority, near-term, treatability study needs identified in the program plan (DOE-RL 1992f). Excavation of contaminated soils and buried solid wastes is included in several of the alternatives identified in the 100 Area FS. Although a common activity, excavation has only been used occasionally at the Hanford Site for waste removal applications. The most recent applications are excavation of the 618-9 burial ground and partial remediation of the 316-5 process trenches (DOE-RL 1992a, 1992b). Both projects included excavation of soil and dust control (using water sprays). Excavation is a well-developed technology and equipment is readily available; however, certain aspects of the excavation process require testing before use in full-scale operations. These include the following: Measurement and control of excavation-generated dust and airborne contamination; verification of field analytical system capabilities; demonstration of soil removal techniques specific to the 100 Area waste site types and configurations. The execution of this treatability test may produce …
Date: August 1, 1993
Creator: unknown
Object Type: Report
System: The UNT Digital Library
100-N Area underground storage tank closures (open access)

100-N Area underground storage tank closures

This report describes the removal/characterization actions concerning underground storage tanks (UST) at the 100-N Area. Included are 105-N-LFT, 182-N-1-DT, 182-N-2-DT, 182-N-3-DT, 100-N-SS-27, and 100-N-SS-28. The text of this report gives a summary of remedial activities. In addition, correspondence relating to UST closures can be found in Appendix B. Appendix C contains copies of Unusual Occurrence Reports, and validated sampling data results comprise Appendix D.
Date: August 1, 1993
Creator: Rowley, C. A.
Object Type: Report
System: The UNT Digital Library
The 1992 Pacific Northwest Residential Energy Survey: Phase 1 : Book 1 : Getting Started. (open access)

The 1992 Pacific Northwest Residential Energy Survey: Phase 1 : Book 1 : Getting Started.

This Executive Summary outlines the general processes employed in and the major findings from the conduct of Phase I of the Pacific Northwest Residential Energy Survey (PNWRES92-I) during the last quarter of 1992. This study was Bonneville`s third comprehensive residential survey of the region, conducted to provide data on energy usage, conservation awareness and behaviors, and associated consumer characteristics for use in forecasting and planning. The summary is divided into four sections: Background sets the stage with respect to the need for the survey, relates it to previous work, outlines the implementation processes, and summarizes the data products. Profiling the respondents summarizes the survey results under these six categories: Demographics; Housing Units; Room Inventory; Appliance Inventory; Air-Conditioning/Heating; Water-Heating; and Opinion. Reports and cross-tabulations describes the various individual documents. Bonneville Power Plus provides a short description of an Excel-spreadsheet-based software program that contains all of the tabulated material in a format that encourages browsing among the tables and charts, with special feature that they can be copied directly into other Windows-based documents.
Date: August 1, 1993
Creator: Applied Management & Planning Group
Object Type: Report
System: The UNT Digital Library
The 1992 Pacific Northwest Residential Energy Survey - Phase 1.  Book 2: Item-by-Item Crosstabulations, Volume C: Pacific Northwest Region (open access)

The 1992 Pacific Northwest Residential Energy Survey - Phase 1. Book 2: Item-by-Item Crosstabulations, Volume C: Pacific Northwest Region

This book constitutes a portion of the primary documentation for the 1992 Pacific Northwest Residential Energy Survey, Phase I. The complete 33-volume set of primary documentation provides information needed by energy analysts and interpreters with respect to planning, execution, data collection, and data management of the PNWRES92-I process. Thirty of these volumes are devoted to different ``views`` of the data themselves, with each view having a special purpose or interest as its focus. Analyses and interpretations of these data will be the subjects of forthcoming publications. Conducted during the late summer and fall months of 1992, PNWRES92-I had the over-arching goal of satisfying basic requirements for a variety of information about the stock of residential units in Bonneville`s service region. Surveys with a similar goal were conducted in 1979 and 1983. This volume discerns the information by region. ``Selected crosstabulations`` refers to a set of nine survey items of wide interest (Dwelling Type, Ownership Type, Year-of-Construction, Dwelling Size, Primary Space-Heating Fuel, Primary Water-Heating Fuel, Household Income for 1991, Utility Type, and Space-Heating Fuels: Systems and Equipment) that were crosstabulated among themselves.
Date: August 1, 1993
Creator: United States. Bonneville Power Administration. End-Use Research Section.
Object Type: Report
System: The UNT Digital Library
The 1992 Pacific Northwest Residential Energy Survey - Phase 1.  Book 7: Selected Crosstabulations for Publicly-Owned Non-Generating Utilities, Volumes J-O (open access)

The 1992 Pacific Northwest Residential Energy Survey - Phase 1. Book 7: Selected Crosstabulations for Publicly-Owned Non-Generating Utilities, Volumes J-O

This book constitutes a portion of the primary documentation for the 1992 Pacific Northwest Residential Energy Survey, Phase I. The complete 33-volume set of primary documentation provides information needed by energy analysts and interpreters with respect to planning, execution, data collection, and data management of the PNWRES92-I process. Thirty of these volumes are devoted to different ``views`` of the data themselves, with each view having a special purpose or interest as its focus. Analyses and interpretations of these data will be the subjects of forthcoming publications. Conducted during the late summer and fall months of 1992, PNWRES92-I had the over-arching goal of satisfying basic requirements for a variety of information about the stock of residential units in Bonneville`s service region. Surveys with a similar goal were conducted in 1979 and 1983. This volume is comprised of selected crosstabulations for publicly-owned non-generating utilities in Montana, Idaho, Washington, and Oregon. ``Selected crosstabulations`` refers to a set of nine survey items of wide interest (Dwelling Type, Ownership Type, Year-of-Construction, Dwelling Size, Primary Space-Heating Fuel, Primary Water-Heating Fuel, Household Income for 1991, Utility Type, and Space-Heating Fuels: Systems and Equipment) that were crosstabulated among themselves.
Date: August 1, 1993
Creator: United States. Bonneville Power Administration. End-Use Research Section.
Object Type: Report
System: The UNT Digital Library
The 1992 Pacific Northwest Residential Energy Survey - Phase 1.  Book 12: Non-Respondent Survey, Volume AG: Study of Non-Respondents (open access)

The 1992 Pacific Northwest Residential Energy Survey - Phase 1. Book 12: Non-Respondent Survey, Volume AG: Study of Non-Respondents

This book constitutes a portion of the primary documentation for the 1992 Pacific Northwest Residential Energy Survey, Phase I. The complete 33-volume set of primary documentation provides information needed by energy analysts and interpreters with respect to planning, execution, data collection, and data management of the PNWRES92-I process. Thirty of these volumes are devoted to different ``views`` of the data themselves, with each view having a special purpose or interest as its focus. Analyses and interpretations of these data will be the subjects of forthcoming publications. Conducted during the late summer and fall months of 1992, PNWRES92-I had the over-arching goal of satisfying basic requirements for a variety of information about the stock of residential units in Bonneville`s service region. Surveys with a similar goal were conducted in 1979 and 1983. This volume contains a follow-up study of non-respondents to the original survey. The information is cross tabulated. ``Selected crosstabulations`` refers to a set of nine survey items of wide interest (Dwelling Type, Ownership Type, Year-of-Construction, Dwelling Size, Primary Space-Heating Fuel, Primary Water-Heating Fuel, Household Income for 1991, Utility Type, and Space-Heating Fuels: Systems and Equipment) that were crosstabulated among themselves.
Date: August 1, 1993
Creator: United States. Bonneville Power Administration. End-Use Research Section.
Object Type: Report
System: The UNT Digital Library
The 1992 Pacific Northwest Residential Energy Survey : Phase 1 (PNWRES92-I) : Executive Summary, Concordance, Glossary. (open access)

The 1992 Pacific Northwest Residential Energy Survey : Phase 1 (PNWRES92-I) : Executive Summary, Concordance, Glossary.

The general processes employed in and the major findings from the conduct of Phase I of the Pacific Northwest Residential Energy Survey (PNWRES92-I) during the last quarter of 1992 are outlined. This was Bonneville's third comprehensive residential survey of the region, conducted to provide data on energy usage, conservation awareness and behaviors, and associated consumer characteristics for use in forecasting and planning. The summary is divided into four sections: Background sets the stage with respect to the need for the survey, relates it to previous work, outlines the implementation processes, and summarizes the data products. Profiling the respondents summarizes the survey results under these six categories: Demographics, Housing Units, Room Inventory, Appliance Inventory, Air-Conditioning/Heating/Water-Heating, and Opinion. Reports and Cross-tabulations describes the various individual documents. Bonneville Power Pulse provides a short description of an Excel-spreadsheet-based software program that contains all of the tabulated material in a format that encourages browsing among the tables and charts, with special feature that they can be copied directly into other Windows-based documents.
Date: August 1, 1993
Creator: United States. Bonneville Power Administration. End-Use Research Section.
Object Type: Report
System: The UNT Digital Library
1993 RCRA Part B permit renewal application, Savannah River Site: Volume 10, Consolidated Incineration Facility, Section C, Revision 1 (open access)

1993 RCRA Part B permit renewal application, Savannah River Site: Volume 10, Consolidated Incineration Facility, Section C, Revision 1

This section describes the chemical and physical nature of the RCRA regulated hazardous wastes to be handled, stored, and incinerated at the Consolidated Incineration Facility (CIF) at the Savannah River Site. It is in accordance with requirements of South Carolina Hazardous Waste Management Regulations R.61-79.264.13(a) and(b), and 270.14(b)(2). This application is for permit to store and teat these hazardous wastes as required for the operation of CIF. The permit is to cover the storage of hazardous waste in containers and of waste in six hazardous waste storage tanks. Treatment processes include incineration, solidification of ash, and neutralization of scrubber blowdown.
Date: August 1, 1993
Creator: Molen, G.
Object Type: Report
System: The UNT Digital Library
1993 Solid Waste Reference Forecast Summary (open access)

1993 Solid Waste Reference Forecast Summary

This report, which updates WHC-EP-0567, 1992 Solid Waste Reference Forecast Summary, (WHC 1992) forecasts the volumes of solid wastes to be generated or received at the US Department of Energy Hanford Site during the 30-year period from FY 1993 through FY 2022. The data used in this document were collected from Westinghouse Hanford Company forecasts as well as from surveys of waste generators at other US Department of Energy sites who are now shipping or plan to ship solid wastes to the Hanford Site for disposal. These wastes include low-level and low-level mixed waste, transuranic and transuranic mixed waste, and nonradioactive hazardous waste.
Date: August 1, 1993
Creator: Valero, O. J.; Blackburn, C. L.; Kaae, P. S.; Armacost, L. L. & Garrett, S. M. K.
Object Type: Report
System: The UNT Digital Library
Accessibility and Integrity of Networked Information Collections (open access)

Accessibility and Integrity of Networked Information Collections

The paper begins with a survey of recent developments in networked information resources and tools to identify, navigate, and use such resources. The paper then discusses the changing legal framework that governs use of electronic information as contract law rather than simple sale within the context of copyright law becomes the dominant model for acquiring access to electronic information.
Date: August 1993
Creator: United States. Congress. Office of Technology Assessment.
Object Type: Report
System: The UNT Digital Library
Acoustic, fiber optic, and silicon microelectronic microsensors research and development activities at Sandia National Laboratories (open access)

Acoustic, fiber optic, and silicon microelectronic microsensors research and development activities at Sandia National Laboratories

Sandia National Laboratories, an 8500+ person, multiprogram research and development facility operated for the US Department of Energy, has over 400 research, development and applications scientists and engineers working on sensor technologies. Sandia`s 20 person Microsensors Research and Development Department has invented, developed and fielded sensor systems based on acoustic, fiber optic, and silicon microelectronic technologies. These sensors have been used for diverse applications inducting the monitoring of cleaning chemical concentrations in industrial process effluent streams, detection of explosive gas concentrations in aging industrial equipment, real-time measurements of fluid viscosity in equipment lubricants, and monitoring of contaminant concentration levels in ultrapure process gases. Representative sensor technologies available for technology transfer will be described including bulk acoustic wave resonators, surface acoustic wave devices, fiber optic micromirror sensors, and silicon microelectronic sensors.
Date: August 1, 1993
Creator: Wiczer, J. J.
Object Type: Article
System: The UNT Digital Library
Acoustic resonance spectroscopy in nuclear safeguards (open access)

Acoustic resonance spectroscopy in nuclear safeguards

Objects resonate at specific frequencies when mechanically excited. The specific resonance frequencies are a function of shape, size, material of construction, and contents of the object. This paper discusses the use of acoustic resonance spectroscopy (ARS) to monitor containers and detect tampering. Evaluation of this technique is based on simulated storage simulations. Although these simulations show promise for this application of ARS, final evaluation will require actual field testing.
Date: August 1, 1993
Creator: Olinger, C. T.; Lyon, M. J.; Stanbro, W. D.; Mullen, M. F. & Sinha, D. N.
Object Type: Article
System: The UNT Digital Library
Active probing of plasma edge turbulence and feedback studies on the Texas Experimental Tokamak (TEXT) (open access)

Active probing of plasma edge turbulence and feedback studies on the Texas Experimental Tokamak (TEXT)

A novel experiment is under way on the Texas Experimental Tokamak (TEXT) to actively modify the turbulence at the plasma edge by launching waves using electrostatic probes in the shadow of the limiter. The experiments are carried out with a wave launching system consisting of two Langmuir probes, which are about 1.8 cm apart in the poloidal direction, with respect to the magnetic field. These probes are operated in the electron side of the (I,V) characteristic. The probe tips are fed separately by independent ac power supplies. Measurements indicate that the wave, launched with a typical frequency image of 15--50 kHz from the edge of the machine top, is received by sensing probes located halfway around the torus. The detected signal strength depends on the frequency of the wave, the plasma current, and the phasing of the applied ac signal between the launching probes. Modifications to the spectra of the density and potential fluctuations are observed. These experiments have been extended to control of the edge plasma fluctuation level using feedback to explore its effects on confinement. When the launcher is driven by the floating potential of the fluctuating plasma at the location of the launching probes, then the fluctuations …
Date: August 1, 1993
Creator: Uckan, T.; Richards, B. & Bengtson, R. D.
Object Type: Report
System: The UNT Digital Library
The adjustable phase planar helical undulator (open access)

The adjustable phase planar helical undulator

The study of magnetic and biological materials which exhibit magnetic circular dichroism has created a demand for circularly polarized x-rays whose helicity may be switched between the right and left hand senses. At present, circularly polarized x-rays are obtained from storage ring bending magnets by accepting radiation from above and below the axis, but insertion device sources are desired for greater intensity. Planar helical undulators are magnetic insertion devices that generate helical magnetic fields. The charged particle beam executes a helical trajectory in the device, and produces elliptically polarized x-rays. The special case of circularly polarized x-rays is most in demand. We present here the design description of a new type of planar helical undulator, which we are constructing for the SPEAR storage ring at the Stanford Synchrotron Radiation Laboratory (SSRL). It comprises four rows of pure permanent magnet blocks, one row in each quadrant about the axis defined by the electron beam. Rows may be translated longitudinally with respect to each other to change the helicity of the magnetic field they create at the position of the beam. They may also be translated longitudinally to vary the energy of the x-rays emitted, unlike designs where this function is performed …
Date: August 1, 1993
Creator: Carr, R. & Lidia, S.
Object Type: Article
System: The UNT Digital Library
Adsorption analysis of ammonia in an aqueous solution (open access)

Adsorption analysis of ammonia in an aqueous solution

An analysis is carried out to determine the effects of the diffusional resistance on the rate of the adsorption of ammonia in an aqueous solution. A performance prediction model is developed to calculate the local rate of heat and mass transfer, including physical and thermodynamic property calculations of the mixture. An algorithm is developed for calculating the interfacial conditions. The local heat- and mass-transfer calculation is then incorporated into the performance prediction method for adsorption for a given geometry.
Date: August 1, 1993
Creator: Arman, B. & Panchal, C. B.
Object Type: Article
System: The UNT Digital Library
Advanced batteries for electric vehicle applications (open access)

Advanced batteries for electric vehicle applications

A technology assessment is given for electric batteries with potential for use in electric powered vehicles. Parameters considered include: specific energy, specific power, energy density, power density, cycle life, service life, recharge time, and selling price. Near term batteries include: nickel/cadmium and lead-acid batteries. Mid term batteries include: sodium/sulfur, sodium/nickel chloride, nickel/metal hydride, zinc/air, zinc/bromine, and nickel/iron systems. Long term batteries include: lithium/iron disulfide and lithium- polymer systems. Performance and life testing data for these systems are discussed. (GHH)
Date: August 1, 1993
Creator: Henriksen, G.L.
Object Type: Report
System: The UNT Digital Library
Advanced coal-fueled gas turbine systems. Final report (open access)

Advanced coal-fueled gas turbine systems. Final report

The configuration of the subscale combustor has evolved during the six years of this program from a system using only an impact separator to remove particulates to a system which also included a slagging cyclone separator before the lean-quench combustor. The system also now includes active slag tapping after the impact separator rather than a bucket to collect the slag. The subscale 12 MM Btu/hr (higher heating value, HHV) slagging combustor has demonstrated excellent coal-fired operation at 6 atm. The combustor has fired both coal-water mixtures (CWM) and pulverized coal (PC). Three Wyoming subbituminous coals and two bituminous coals have been successfully fired in the TVC. As a result of this active testing, the following conclusions may be drawn: (1) it was possible to achieve the full design thermal capacity of 12 MM Btu/hr with the subscale slagging combustor, while burning 100% pulverized coal and operating at the design pressure of 6 atm; (2) because of the separate-chamber, rich-lean design of the subscale slagging combustor, NO{sub x} emissions that easily meet the New Source Performance Standards (NSPS) limits were achieved; (3) carbon burnout efficiency was in excess of 99% when 100% coal-fired; (4) ninety percent of the ash can be …
Date: August 1, 1993
Creator: unknown
Object Type: Report
System: The UNT Digital Library
Advanced direct liquefaction concepts for PETC generic units. Quarterly technical progress report, April 1993--June 1993 (open access)

Advanced direct liquefaction concepts for PETC generic units. Quarterly technical progress report, April 1993--June 1993

Section 1 contains a report of the progress by the University of Kentucky Center for Applied Energy Research on the following tasks: laboratory support (liquefaction in dewaxed and hydrotreated dewaxed solvent); CO pretreatment (effect of process variables on CO pretreatment, CO-pretreated product characterization, and liquefaction results); and iron based dispersed catalysts (production, characterization and testing of sulfated hematites and reaction model development). Section 2 contains a progress report by CONSOL, Inc. on the following tasks: laboratory support; pretreatment work on dewaxing; pretreatment work on agglomeration; and economic evaluation. Progress by Sandia National Laboratories is reported in Section 3 on the following: laboratory support (TGA methods) and solvent pretreatment (coker tar hydrogenation and coal liquefaction results). Section 4 gives a preliminary technical assessment by LDP Associates on the following: baseline economic assessment; assessment of improved coal conversion; and fluid coking.
Date: August 1, 1993
Creator: unknown
Object Type: Report
System: The UNT Digital Library
Advanced failure analysis laboratory equipment networking (open access)

Advanced failure analysis laboratory equipment networking

Today`s integrated circuits are so complex that it is often necessary to have access to the layouts and schematics when performing voltage contrast, cross sectioning, light emission, mechanical probing, optical beam induced current, and even simple SEM and Optical Examination. To deal with these issues, Sandia National Laboratories is developing an advanced failure analysis laboratory networking scheme to provide computer control, layout navigation, schematic navigation, and report generation on each of the major pieces of failure analysis equipment. This concept is known as an Integrated Diagnostic Environment or IDE. An integrated diagnostic environment is an environment where failure analysis equipment is computer-controlled and linked by a high speed network. The network allows CAD databases to be shared between instruments, improving the failure analyst`s productivity on each analysis task. At Sandia, we are implementing this concept using SUN Sparcstation computers running Schlumberger`s IDE software. To date, we have incorporated our electron beam prober and light emission system into the environment. We will soon add our scanning optical microscope and focused ion beam system and eventually add our optical microscope and microprobe station into the network. There are a number of issues to consider when implementing an Integrated Diagnostic Environment; these are …
Date: August 1, 1993
Creator: Henderson, C. L. & Barton, D. L.
Object Type: Article
System: The UNT Digital Library
Advanced ground-penetrating, imaging radar for bridge inspection (open access)

Advanced ground-penetrating, imaging radar for bridge inspection

Inspecting high-value structures, like bridges and buildings using Ground Penetrating Radar (GPR) is an application of the technology that is growing in importance. In a typical inspection application, inspectors use GPR to locate structural components, like reinforcing bars embedded in concrete, to avoid weakening the structure while collecting core samples for detailed inspection. Advanced GPR, integrated with imaging technologies for use as an NDE tool, can provide the capability to locate and characterize construction flaws and wear- or age-induced damage in these structures without the need for destructive techniques like coring. In the following sections, we discuss an important inspection application, namely, concrete bridge deck inspection. We describe an advanced bridge deck inspection system concept and provide an overview of a program aimed at developing such a system. Examples of modeling, image reconstruction, and experimental results are presented.
Date: August 1, 1993
Creator: Warhus, J. P.; Mast, J. E.; Johansson, E. M.; Nelson, S. E. & Lee, Hua
Object Type: Article
System: The UNT Digital Library
Advanced Hybrid Gasification Facility (open access)

Advanced Hybrid Gasification Facility

The objective of this procurement is to provide a test facility to support early commercialization of advanced fixed-bed coal gasification technology for electric power generation applications. The proprietary CRS Sirrine Engineers, Inc. PyGas{trademark} staged gasifier has been selected as the initial gasifier to be developed under this program. The gasifier is expected to avoid agglomeration when used on caking coals. It is also being designed to crack tar vapors and ammonia, and to provide an environment in which volatilized alkali may react with aluminosilicates in the coal ash thereby minimizing their concentration in the hot raw coal gas passing through the system to the gas turbine. This paper describes a novel, staged, airblown, fixed-bed gasifier designed to solve both through the incorporation of pyrolysis (carbonization) with gasification. It employs a pyrolyzer (carbonizer) to avoid sticky coal agglomeration which occurs in a fixed-bed process when coal is gradually heated through the 400{degrees}F to 900{degrees}F range. In a pyrolyzer, the coal is rapidly heated such that coal tar is immediately vaporized. Gaseous tars are then thermally cracked prior to the completion of the gasification process. During the subsequent endothermic gasification reactions, volatilized alkali can be chemically bound to aluminosilicates in (or added …
Date: August 1, 1993
Creator: Sadowski, R. S.; Skinner, W. H.; Johnson, S. A. & Dixit, V. B.
Object Type: Article
System: The UNT Digital Library
Advanced in Macrostatistical Hydrodynamics (open access)

Advanced in Macrostatistical Hydrodynamics

An overview is presented of research that focuses on slow flows of suspensions in which colloidal and inertial effects are negligibly small (Macrostatistical Hydrodynamics). First, we describe nuclear magnetic resonance imaging experiments to quantitatively measure particle migration occurring in concentrated suspensions undergoing a flow with a nonuniform shear rate. These experiments address the issue of how the flow field affects the microstructure of suspensions. In order to understand the local viscosity in a suspension with such a flow-induced, spatially varying concentration, one must know how the viscosity of a homogeneous suspension depends on such variables as solids concentration and particle orientation. We suggest the technique of falling ball viscometry, using small balls, as a method to determine the effective viscosity of a suspension without affecting the original microstructure significantly. We also describe data from experiments in which the detailed fluctuations of a falling ball`s velocity indicate the noncontinuum nature of the suspension and may lead to more insights into the effects of suspension microstructure on macroscopic properties. Finally, we briefly describe other experiments that can be performed in quiescent suspensions (in contrast to the use of conventional shear rotational viscometers) in order to learn more about the microstructure and boundary …
Date: August 1, 1993
Creator: Graham, A. L.; Tetlow, N.; Abbott, J. R.; Mondy, L. S. & Brenner, H.
Object Type: Article
System: The UNT Digital Library
The Advanced Light Source (ALS) Radiation Safety System. Revised (open access)

The Advanced Light Source (ALS) Radiation Safety System. Revised

The Advanced Light Source (ALS) at the Lawrence Berkeley Laboratory (LBL) is a 1.5 Gev synchrotron light source facility consisting of a 120 kev electron gun, 50 Mev linear accelerator, 1.5 Gev booster synchrotron, 200 meter circumference electron storage ring, and many photon beamline transport systems for research. Figure 1. ALS floor plan. Pairs of neutron and gamma radiation monitors are shown as dots numbered from 1 to 12. The Radiation Safety System for the ALS has been designed and built with a primary goal of providing protection against inadvertent personnel exposure to gamma and neutron radiation and, secondarily, to enhance the electrical safety of select magnet power supplies.
Date: August 1, 1993
Creator: Ritchie, A. L.; Oldfather, D. E. & Lindner, A. F.
Object Type: Article
System: The UNT Digital Library
Advanced NMR-based techniques for pore structure analysis of coal. Quarterly report No. 6, January 1, 1993--March 31, 1993 (open access)

Advanced NMR-based techniques for pore structure analysis of coal. Quarterly report No. 6, January 1, 1993--March 31, 1993

One of the main problems in coal utilization is the inability to properly characterize its complex pore structure. Coals typically have micro/ultra-micro pores but they also exhibit meso and macroporosity. Conventional pore size techniques (adsorption/condensation, mercury porosimetry) are limited because of this broad pore size range, microporosity, reactive nature of coal, samples must be completely dried, and network/percolation effects. Small angle scattering is limited because it probes both open and closed pores. Although one would not expect any single technique to provide a satisfactory description of a coal`s structure, it is apparent that better techniques are necessary. Small angle scattering could be improved by combining scattering and adsorption measurements. Also, the measurement of NMR parameters of various gas phase and adsorbed phase NMR active probes can provide pore structure information. We will investigate the dependence of the common NMR parameters such as chemical shifts and relaxation times of several different nuclei and compounds on the pore structure of model microporous solids, carbons, and coals. In particular, we will study the interaction between several small molecules ({sup 129}Xe, {sup 3}He, {sup 2}H{sub 2}, {sup 14}N{sub 2},{sup 14}NH{sub 3}, {sup 15}N{sup 2}, {sup 13}CH{sub 4}, {sup 13}CO{sub 2}) and the pore surfaces …
Date: August 1, 1993
Creator: Smith, D. M.
Object Type: Report
System: The UNT Digital Library