An aerial radiological survey was conducted over the Superconducting Super Collider Laboratory (SSCL) site from July 22 through August 20,1991. Parallel lines were flown at intervals of 305 meters over a 1,036-square-kilometer (400-square-mile) area surrounding Waxahachie, Texas. The 70,000 terrestrial gamma energy spectra obtained were reduced to an exposure rate contour map overlaid on a United States Geological Survey (USGS) map of the area. The mean terrestrial exposure rate measured was 5.4 {mu}R/h at 1 meter above ground level. Comparison to ground-based measurements shows good agreement. No anomalous or man-made isotopes were detected.

This Baseline Risk Assessment of Groundwater Contamination at the Uranium Mill Tailings Site Near Gunnison, Colorado evaluates potential impacts to public health or the environment resulting from groundwater contamination at the former uranium mill processing site. The tailings and other contaminated material at this site are being placed in an off-site disposal cell by the US Department of Energy`s (DOE) Uranium Mill Tailings Remedial Action (UMTRA) Project. Currently, the UMTRA Project is evaluating groundwater contamination. This is the second risk assessment of groundwater contamination at this site. The first risk assessment was performed primarily to evaluate existing domestic wells. This risk assessment evaluates the most contaminated monitor wells at the processing site. It will be used to assist in determining what remedial action is needed for contaminated groundwater at the site after the tailings are relocated. This risk assessment follows an approach outlined by the US Environmental Protection Agency (EPA). The first step is to evaluate groundwater data collected from monitor wells at the site. Evaluation of these data showed that the main contaminants in the groundwater are cadmium, cobalt, iron, manganese, sulfate, uranium, and some of the products of radioactive decay of uranium.

Fish communities in two upper Little Tennessee River tributaries, Rabbit Creek and Middle Creek, both located in Macon County, North Carolina, were monitored using IBI methods in 1990 and again in 1992. A single site, each on the lower reaches of its respective creek, was chosen to reflect the influence of conditions throughout the watershed and to provide a measure of water quality exiting the watershed. The Rabbit Creek watershed (Holly Springs community) has a long history of settlement and agricultural use. Dominant land uses today are pasture in the bottom lands and residential development at higher elevations. Much of the upper portion of the Middle Creek watershed on the slopes of Scaly Mountain is devoted to cabbage farming, often on steep slopes and highly erodible soils. From the cabbage growing area, the creek drops 400 feet to the lower valley. Other common land uses include residential, livestock, and forest. Both streams are characterized by heavy sedimentation and frequent high turbidity. Both streams showed marked improvement between 1990 and 1992. In 1990, Rabbit Creek`s IBI score was 31.0, for a bioclass rating of ``poor.`` In 1992, the IBI score was 42.1 for a bioclass rating of ``fair.`` For Middle Creek, …

The objective of this work is to investigate, in the laboratory, the parameters associated with a chemically assisted in situ recovery procedure, using hydrogen chloride (HCI), carbon dioxide (CO{sub 2}), and steam (H{sub 2}0), to obtain data useful to develop a process more economic than existing processes and to report all findings. The technical progress of the project is reported. The project status is that the progress is being made towards being able to run meaningful experiments.

This report is divided into 5 sections: Ru[sub 4]/Fe complexes of tetra(4[prime]-methyl-2,2[prime]-bipyridine)porphyrin--catalytic epoxidation of olefins; water oxidation catalysis by doubly linked [mu]-oxo ruthenium complexes; polymer films formed by oxidation of transition metal electrodes into solutions of bisbipyridinealkane ligands; polymer films containing [CpMo([mu]-S)][sub 2]S[sub 2]CHR dinuclear clusters;and conducting polymer films for catalyst incorporation.

This report is divided into 5 sections: Ru{sub 4}/Fe complexes of tetra(4{prime}-methyl-2,2{prime}-bipyridine)porphyrin--catalytic epoxidation of olefins; water oxidation catalysis by doubly linked {mu}-oxo ruthenium complexes; polymer films formed by oxidation of transition metal electrodes into solutions of bisbipyridinealkane ligands; polymer films containing [CpMo({mu}-S)]{sub 2}S{sub 2}CHR dinuclear clusters;and conducting polymer films for catalyst incorporation.

The design of a fiber optic communication network for monitoring and control in power systems is discussed. It is shown that by appropriate choice of protocols, a fault-tolerant system can be built that operates in any arbitrary configuration. Since the network is based on fiber optics, it can be made fast enough for substation monitoring and control. In this application, a relatively small number of cables is required to implement a high reliability system. The network can also be used for distribution automation. In this application the network is required to reach all parts of the power system, and the fiber cable itself becomes a significant fraction of the cost of communications. However, since many applications can be supported at once, the cost per function can be reasonable.

A fully-parameterized model for the formation and growth of aerosols via gas-to-particle conversion has been developed and tested. A particularly significant contribution is a new method for the prediction of numbers of particles nucleated using information on the vapor source rate, relative humidity, and preexisting aerosol alone, thus eliminating the need to solve a system of coupled ODEs. Preliminary tests indicate substantial reduction in computational costs, but it is recommended that the BIMODAM model be incorporated into a large-scale model of the sulfur cycle in order to more fully test its computational feasibility.

The report is divided into: vibrational models for surface ethylidenes (on catalyst surfaces); alpha vs beta hydrogen elimination in formation of propene from an osmacyclobutane; mechanism of formation and fragmentation of diosmacyclobutanes; reaction of dienes and allenes with diosmacyclobutanes; structure of Os(CO)[sub 4](C[sub 2]H[sub 4]), an osmacyclopropane; and reaction of [mu]-oxobis [(trifluoromethanesulfanato) (phenyl)iodine(III)] with Group 14 propargyl derivatives and a propargyl ether. 16 refs, figs.

The report is divided into: vibrational models for surface ethylidenes (on catalyst surfaces); alpha vs beta hydrogen elimination in formation of propene from an osmacyclobutane; mechanism of formation and fragmentation of diosmacyclobutanes; reaction of dienes and allenes with diosmacyclobutanes; structure of Os(CO){sub 4}(C{sub 2}H{sub 4}), an osmacyclopropane; and reaction of {mu}-oxobis [(trifluoromethanesulfanato) (phenyl)iodine(III)] with Group 14 propargyl derivatives and a propargyl ether. 16 refs, figs.

We proposed to demonstrate the effectiveness of a catalytic membrane reactor (a ceramic membrane combined with a catalyst) to selectively produce methanol by partial oxidation of methane. Methanol is used as a chemical feedstock, gasoline additive, and turbine fuel. Methane partial oxidation using a catalytic membrane reactor has been determined as one of the promising approaches for methanol synthesis from methane. In the original proposal, the membrane was used to selectively remove methanol from the reaction zone before carbon oxides form, thus increasing the methanol yield. Methanol synthesis and separation in one step would also make methane more valuable for producing chemicals and fuels. The cooling tube inserted inside the membrane reactor has created a low temperature zone that rapidly quenches the product stream. This system has proved effective for increasing methanol selectivity during CH{sub 4} oxidation. The membranes broke during experiments, however, apparently because of the large radial thermal gradient and axial thermal expansion difference. Our efforts concentrated on improving the membrane lifetime by modifying this non-isothermal membrane reactor.

The Colorado economic impact study summarizes employment and economic benefits to the state from activities associated with the Uranium Mill Tailings Remedial Action (UMTRA) Project during Colorado state fiscal year 1993 (July 1, 1992, through June 30, 1993). To capture employment benefits, a questionnaire was distributed to subcontractor employees at the active UMTRA Project sites of Grand Junction, Rifle, and Gunnison, Colorado. An estimated 52 percent of the employees working on the UMTRA Project responded to this information request. Economic data were requested from each site prime subcontractor, as well as from the Remedial Action Contractor. The most significant benefits associated with the UMTRA Project in Colorado are summarized.

Meteorologic data from the Pantex Plant and from the nearby National Weather Service (NWS) station at the Amarillo, Texas, International Airport were evaluated to determine if the NWS data adequately represented meteorologic conditions at the Pantex Plant. Annual site environmental dose calculations for the Pantex Plant have previously used the NWS data; information from this data comparison helped determine if future environmental dose calculations should use site-specific Pantex meteorologic data. The meteorologic data evaluated were wind speed, wind direction, and atmospheric stability class. Atmospheric stability class data were compared for years 1990 and 1991 and found to be very similar. Stability class designations were identical and one class different in 63% and 30%, respectively, of the paired hourly data. An unexpected finding was the preponderance of Class D stability, which occurred approximately 62% of the time in both data sets. The overall effect of meteorological differences between the two locations was evaluated by performing environmental dose assessments using the GENII dose assessment computer code. Acute and chronic releases of {sup 3}H and {sup 239}Pu were evaluated. Results using the NWS Amarillo meteorologic data were approximately one-half of those generated using Pantex meteorologic data. The two-fold difference in dose results is …

Report that summarizes the goals and objectives of the report in regards to increasing development of the captioning associate program for Amarillo College.

The objectives of the study were: to evaluate the response of grassland ecosystems to atmospheric change at regional and site scales, and to develop multiscaled modeling systems to relate ecological and atmospheric models with different spatial and temporal resolutions. A menu-driven shell was developed to facilitate use of models at different temporal scales and to facilitate exchange information between models at different temporal scales. A detailed ecosystem model predicted that C{sub 3} temperate grasslands wig respond more strongly to elevated CO{sub 2} than temperate C{sub 4} grasslands in the short-term while a large positive N-PP response was predicted for a C{sub 4} Kenyan grassland. Long-term climate change scenarios produced either decreases or increases in Colorado plant productivity (NPP) depending on rainfall, but uniform increases in N-PP were predicted in Kenya. Elevated CO{sub 2} is likely to have little effect on ecosystem carbon storage in Colorado while it will increase carbon storage in Kenya. A synoptic climate classification processor (SCP) was developed to evaluate results of GCM climate sensitivity experiments. Roughly 80% agreement was achieved with manual classifications. Comparison of lx and 2xCO{sub 2} GCM Simulations revealed relatively small differences.

The NIPER Reservoir Assessment and Characterization Research Program incorporates elements of the near-term, mid-term and long-term objectives of the National Energy Strategy-Advanced Oil Recovery Program. The interdisciplinary NIPER team focuses on barrier island reservoirs, a high priority class of reservoirs, that contains large amounts of remaining oil in place located in mature fields with a high number of shut-in and abandoned wells. The project objectives are to: (1) identify heterogeneities that influence the movement and trapping of reservoir fluids in two examples of shoreline barrier reservoirs (Patrick Draw Field, WY and Bell Creek Field, MT); (2) develop geological and engineering reservoir characterization methods to quantify reservoir architecture and predict mobile oil saturation distribution for application of targeted infill drilling and enhanced oil recovery (EOR) processes; and (3) summarize reservoir and production characteristics of shoreline barrier reservoirs to determine similarities and differences. The major findings of the research include: (1) hydrogeochemical analytical techniques were demonstrated to be an inexpensive reservoir characterization tool that provides information on reservoir architecture and compartmentalization; (2) the formation water salinity in Patrick Draw Field varies widely across the field and can result in a 5 to 12% error in saturation values calculated from wireline logs if …

This long-term surveillance plan (LTSP) for the Lakeview, Oregon, Uranium Mill Tailings Remedial Action (UMTRA) Project disposal site describes the surveillance activities for the Lakeview (Collins Ranch) disposal cell, which will be referred to as the Collins Ranch disposal cell throughout this document. The US Department of Energy (DOE) will carry out these activities to ensure that the disposal cell continues to function as designed. This final LTSP was prepared as a requirement for acceptance under the US Nuclear Regulatory Commission (NRC) general license for custody and long-term care of residual radioactive materials. This LTSP documents whether the land and interests are owned by the United States or an Indian tribe, and details how the long-term care of the disposal site will be carried out. It is based on the DOE`s Guidance for Implementing the UMTRA Project Long-term Surveillance Program (DOE, 1992a).

The long-term surveillance plan (LTSP) for the Shiprock, New Mexico, Uranium Mill Tailings Remedial Action (UMTRA) Project disposal site describes the surveillance activities for the Shiprock disposal cell. The US Department of Energy (DOE) will carry out these activities to ensure that the disposal cell continues to function as designed. This final LTSP is being submitted to the US Nuclear Regulatory Commission (NRC) as a requirement for issuance of a general license for custody and long-term care for the disposal site. The general license requires that the disposal cell be cared for in accordance with the provisions of this LTSP. This Shiprock, New Mexico, LTSP documents whether the land and interests are owned by the US or an Indian tribe and describes in detail the long-term care program through the UMTRA Project Office.

This field conference was designed to assemble a group of Quaternary researchers to examine the possibility of using the Zuni-Bandera volcanic field in western New Mexico as a test area for evaluating and calibrating various Quaternary dating techniques. The Zuni-Bandera volcanic-field is comprised of a large number of basaltic lava flows ranging in age from about 700 to 3 ka. Older basalts are present in the Mount Taylor volcanic field to the north. Geologic mapping has been completed for a large portion of the Zuni-Bandera volcanic field and a number of geochronological investigations have been initiated in the area. While amending this conference, please consider how you might bring your expertise and capabilities to bear on solving the many problem in Quaternary geochronology.

Focus has been mainly on preparation and characterization of triply bridged dinuclear complexes containing a tris-2-2'- bipyridineruthenium chromophore and a second tris-bipyridine metal complex which is to serve as electron donor or acceptor, and of linked RuL[sub 3]-containing D-C-A complexes where D is a phenothiazine donor and A is a diquat type acceptor. (DLC)

Focus has been mainly on preparation and characterization of triply bridged dinuclear complexes containing a tris-2-2`- bipyridineruthenium chromophore and a second tris-bipyridine metal complex which is to serve as electron donor or acceptor, and of linked RuL{sub 3}-containing D-C-A complexes where D is a phenothiazine donor and A is a diquat type acceptor. (DLC)

As asked by the U. S. Department of Energy/Office of Special Applications, and in support of the Environmental Impact Statement for the Cassini mission, The Johns Hopkins University/Applied Physics Laboratory (JHU/APL) has conducted preliminary one-dimensional ablation and thermal analyses of the General Purpose Heat Source (GPHS). The predicted earth entry conditions provided by the Jet Propulsion Laboratory (JPL) for a Cassini Venus-Venus-Earth-Jupiter Gravity Assist (VVEJGA) trajectory were used as initial conditions. The results of this study which constitute the initial reentry analysis assessment leading to the Cassini Updated Safety, Analysis Report (USAR) are discussed in this document.

Progress reports are presented for the following tasks: overview and progress of waste package project and container design; waste container design considerations (criticality analysis, experimental drift model); waste container alternate design considerations; thermal simulation of high level nuclear waste canister emplacement; structural analysis and design of nuclear waste package canister; robotic manipulation of the nuclear waste container; investigation of stress in a circular tunnel due to overburden & thermal loading of horizontally placed 21PWR multi-purpose canisters; investigation of faulted tunnel models by combined photoelasticity and finite element analysis; and transport phenomena in the near field.

Compilation of monthly reports from departments in the city of San Antonio, Texas providing statistics, project updates, and other information about services and activities.