The goal of this project is to build and test a Time Series Submersible Incubation Device (TS-SID) capable of the autonomous in situ measurement of phytoplankton production and other rate processes for a period of up at least three months. The instrument is conceptually based on a recently constructed Submersible Incubation Device (SID). The TS-SID is to possess the ability to periodically incubate samples in the presence of an appropriate tracer, and to store 94 chemically fixed subsamples for later analysis. The TS-SID has been designed to accurately simulate the natural environment, and to avoid trace metal contamination and physical damage to cells. Devices for biofouling control of internal and external surfaces are to be incorporated into the instrument. After the time series capabilities of the instrument have been successfully evaluated by medium-term coastal time series studies (up to one month), longer-term coastal time series studies (2-3 months) will be conducted to evaluate the biofouling prevention measures that have been used with the instrument.

We performed a wide variety of laboratory analyses during the past quarter. As with most of the work we performed during the previous quarter, our recent efforts were primarily directed toward the determination of the effects of adsorbed water on the cohesivity and tensile strength of powders. We also continued our analyses of dust cake ashes that have had the soluble compounds leached from their particle surfaces by repeated washings with water. Our analyses of leached and unleached dust cake ashes continued to provide some interesting insights into effects that compounds adsorbed on surfaces of ash particles can have on bulk ash behavior. As suggested by our literature review, our data indicate that water adsorption depends on particle morphology and on surface chemistry. Our measurements of tensile strength show, that for many of the samples we have analyzed a relative minimum in tensile strength exists for samples conditioned and tested at about 30% relative humidity. In our examinations of the effects of water conditioning on sample cohesivity, we determined that in the absence of absorption of water into the interior of the particles, cohesivity usually increases sharply when environments having relative humidities above 75% are used to condition and test …

The {eta}{sub 6} is a {open_quotes}heavy axion{close_quotes} remnant of dynamical electroweak symmetry breaking by a color sextet quark condensate. Electroweak scale color instanton interactions allow it to be both very massive and yet be responsible for Strong CP conservation in the color triplet quark sector. It may have been seen at LEP via its two-photon decay mode and at TRISTAN via its hadronic decay modes.

We performed a wide variety of laboratory analyses during the past quarter. As with most of the work we performed during the previous quarter, our recent efforts were primarily directed toward the determination of the effects of adsorbed water on the cohesivity and tensile strength of powders. We also continued our analyses of dust cake ashes that have had the soluble compounds leached from their particle surfaces by repeated washings with water. Our analyses of leached and unleached dust cake ashes continued to provide some interesting insights into effects that compounds adsorbed on surfaces of ash particles can have on bulk ash behavior. As suggested by our literature review, our data indicate that water adsorption depends on particle morphology and on surface chemistry. Our measurements of tensile strength show, that for many of the samples we have analyzed a relative minimum in tensile strength exists for samples conditioned and tested at about 30% relative humidity. In our examinations of the effects of water conditioning on sample cohesivity, we determined that in the absence of absorption of water into the interior of the particles, cohesivity usually increases sharply when environments having relative humidities above 75% are used to condition and test …

The goal of this project is to build and test a Time Series Submersible Incubation Device (TS-SID) capable of the autonomous in situ measurement of phytoplankton production and other rate processes for a period of up at least three months. The instrument is conceptually based on a recently constructed Submersible Incubation Device (SID). The TS-SID is to possess the ability to periodically incubate samples in the presence of an appropriate tracer, and to store 94 chemically fixed subsamples for later analysis. The TS-SID has been designed to accurately simulate the natural environment, and to avoid trace metal contamination and physical damage to cells. Devices for biofouling control of internal and external surfaces are to be incorporated into the instrument. After the time series capabilities of the instrument have been successfully evaluated by medium-term coastal time series studies (up to one month), longer-term coastal time series studies (2-3 months) will be conducted to evaluate the biofouling prevention measures that have been used with the instrument.

Baseline testing at the ``base`` site. Tampa Electric Company`s (TECo`s) Big Bend Station, commenced on September 28 and was completed on October 2. Initial results from this testing were presented in the previous Technical Progress Report, but a more complete discussion is provided in this report. Parametric testing was conducted at the Big Bend site during this quarter to evaluate the effects of dibasic acid (DBA) addition on system SO{sub 2} removal performance. The parametric tests were conducted from November 2 through 19. A DBA consumption rate test was also conducted, after the parametric tests were completed. The DBA consumption test was conducted from November 21 through 25. Options I and II to the base program were exercised by DOE/PETC at the end of the previous quarter. These options involve testing at Hoosier Energy Rural Electric Cooperative Inc.`s Merom Station and Southwestern Electric Power Company`s Pirkey Station, respectively. Testing was conducted at Merom Station during November. Previously, Radian Corporation was the test contractor for EPRI-funded performance additive testing at this site. This EPRI-funded testing involved the equivalent of baseline testing, parametric testing with both DBA and sodium formate performance additives, and an additive consumption test with the DBA additive. The …

Laboratory flotation tests were carried out on three coals and on coal pyrite. Floatability measurements included natural floatability, flotation with a xanthate collector and salt flotation. The ranking of the floatability of the three coals were: Upper Freeport > Pittsburgh > Illinois. The floatability of mineral pyrite and coal pyrite increased markedly with xanthate concentration, but decreased with increased pH. In general, coal pyrite was more difficult to float than mineral pyrite. This was attributed to the presence of surface carbonaceous and mineral matter, since floatability of coal pyrite improved by acid pretreatment. Flotation tests demonstrated that the floatability of coal and mineral pyrite was greatly enhanced by the presence of an electrolyte. Flotation was also enhanced by the addition of modifiers such as CuSO{sub 4}, Na{sub 2}S, CO{sub 2} and EDTA. Lime additions markedly reduced the floatability of coal pyrite. Enhanced floatability of coal pyrite resulted when the pyrite was anodically oxidized in a specially constructed electrochemical flotation cell Pretreatment in potential ranges previously observed for polysulfide and sulfur film formation resulted in the enhanced floatability. While interesting trends and influences, both chemical and electrochemical, markedly improved the floatability of coal, there is little hope for reverse flotation as …

Magnetic Resonance Imaging (MRI) was used to measure granular-flow in a partially filled, steadily rotating, long, horizontal cylinder. This non-invasive technique can yield statistically averaged two-dimensional concentrations and velocity profiles anywhere in the flow of suitable granular materials. First, rigid body motion of a cylinder fill with granular material was studied to confirm the validity of this method. Then, the density variation of the flowing layer where particles collide and dilate, and the depth of the flowing layer and the flow velocity profile were obtained as a function of the cylinder rotation rate.

The current shortage of {sup 18}O has revived interest in using one step UV photodissociation of formaldehyde to enrich {sup 13}C, {sup 17}O and {sup 18}O. The frequency doubled output of the copper laser pumped dye laser system currently in operation at LLNL can be used to drive this dissociation. The authors use a simple kinetics model and their experience with Atomic Vapor Laser Isotope Separation (AVLIS) process design to examine the relative merits of different designs for a formaldehyde photodissociation process. Given values for the molecular photoabsorption cross section, partition function, spectroscopic selectivity, collisional exchange and quenching cross sections (all as parameters), they perform a partial optimization in the space of illuminated area, formaldehyde pressure in each stage, and formaldehyde residence time in each stage. They examine the effect of cascade design (heads and tails staging) on molecule and photon utilization for each of the three isotope separation missions, and look in one case at the system`s response to different ratios of laser to formaldehyde costs. Finally, they examine the relative cost of enrichment as a function of isotope and product assay. Emphasis is as much on the process design methodology, which is general, as on the specific application …

Axial symmetry is a very desirable property of the mirror devices both for fusion and neutron source applications. The main obstacle to be circumvented in the development of such systems, is the flute instability of axisymmetric mirrors. In recent years there appeared a number of proposals, devoted to the stabilization of the flute perturbations in the framework of axisymmetric magnetic configurations, which are based on the combining of the MHD unstable central cell with various types of end-cell stabilizers. In the present paper we concentrate ourselves just on this scheme, including long solenoid with a uniform field, conjugated with the end stabilizing anchor, intended to provide MHD stability of the system as a whole. The attractive feature of such a configuration is that it allows to exploit finite larmor radius (FLR) effects for the stabilization of the flute perturbations. As is well known, FLR effects, being strong, stabilize all flute modes, except the one with azimuthal number m = 1, corresponding to the ``rigid`` displacement of the plasma column (the ``global`` mode). Consequently, in the conditions when FLR effects dominate, the anchor has to stabilize the ``global` mode only. Bearing in mind a favorable influence of FLR effects we, however, …

Glass frit will be a major raw material for the operation of the Defense Waste Processing Facility. The frit will be controlled by certificate of conformance and a confirmatory analysis from a commercial analytical laboratory. The following effort provides additional quantitative information on the variability of frit chemical analyses at two commercial laboratories. Identical samples of IDMS Frit 202 were chemically analyzed at two commercial laboratories and at three different times over a period of four months. The SRL-ADS analyses, after correction with the reference standard and normalization, provided confirmatory information, but did not detect the low silica level in one of the frit samples. A methodology utilizing elliptical limits for confirming the certificate of conformance or confirmatory analysis was introduced and recommended for use when the analysis values are close but not within the specification limits. It was also suggested that the lithia specification limits might be reduced as long as CELS is used to confirm the analysis.

This project is sponsored by the United States Department of Energy (DOE) for the ``Engineering Design and Analysis of Advanced Physical Fine Coal Cleaning Technologies: The major goal is to provide the simulation tools for modeling both conventional and advanced coal cleaning technologies. This DOE project is part of a major research initiative by the Pittsburgh Energy Technology Center (PETC) aimed at advancing three advanced coal cleaning technologies-heavy-liquid cycloning, selective agglomeration, and advanced froth flotation through the proof-of-concept (POC) level. The commercially available ASPEN PLUS process simulation package will be extended to handle coal cleaning applications. Algorithms for predicting the process performance, equipment size, and flowsheet economics of commercial coal cleaning devices and related ancillary equipment will be incorporated into the coal cleaning simulator. This report is submitted to document the progress of Aspen Technology, Inc. (AspenTech), its contractor, ICF Kaiser Engineers, Inc.,(ICF KE) and CQ Inc., a subcontractor to ICF KE, for the period of October through December 1992. ICF KE is providing coal preparation consulting and processing engineering services in this work and they are responsible for recommending the design of models to represent conventional coal cleaning equipment and costing of these models. CQ Inc. is a subcontractor …

A cyclic voltammetry technique was used to study the interactions of pyrite during bioleaching with the bacterium Thiobacillus ferrooxidans. Potential effects of heavy metals (silver and mercury) and varying the pH on the iron oxidizing ability of the bacterium are reported. Redox potential techniques were used to study effect of ferrous sulfate concentration and pH on bacterial growth.

Magnetic Resonance Imaging (MRI) was used to measure granular-flow in a partially filled, steadily rotating, long, horizontal cylinder. This non-invasive technique can yield statistically averaged two-dimensional concentrations and velocity profiles anywhere in the flow of suitable granular materials. First, rigid body motion of a cylinder fill with granular material was studied to confirm the validity of this method. Then, the density variation of the flowing layer where particles collide and dilate, and the depth of the flowing layer and the flow velocity profile were obtained as a function of the cylinder rotation rate.

This project is sponsored by the United States Department of Energy (DOE) for the Engineering Design and Analysis of Advanced Physical Fine Coal Cleaning Technologies: The major goal is to provide the simulation tools for modeling both conventional and advanced coal cleaning technologies. This DOE project is part of a major research initiative by the Pittsburgh Energy Technology Center (PETC) aimed at advancing three advanced coal cleaning technologies-heavy-liquid cycloning, selective agglomeration, and advanced froth flotation through the proof-of-concept (POC) level. The commercially available ASPEN PLUS process simulation package will be extended to handle coal cleaning applications. Algorithms for predicting the process performance, equipment size, and flowsheet economics of commercial coal cleaning devices and related ancillary equipment will be incorporated into the coal cleaning simulator. This report is submitted to document the progress of Aspen Technology, Inc. (AspenTech), its contractor, ICF Kaiser Engineers, Inc.,(ICF KE) and CQ Inc., a subcontractor to ICF KE, for the period of October through December 1992. ICF KE is providing coal preparation consulting and processing engineering services in this work and they are responsible for recommending the design of models to represent conventional coal cleaning equipment and costing of these models. CQ Inc. is a subcontractor …

Baseline testing at the base'' site. Tampa Electric Company's (TECo's) Big Bend Station, commenced on September 28 and was completed on October 2. Initial results from this testing were presented in the previous Technical Progress Report, but a more complete discussion is provided in this report. Parametric testing was conducted at the Big Bend site during this quarter to evaluate the effects of dibasic acid (DBA) addition on system SQ removal performance. The parametric tests were conducted from November 2 through 19. A DBA consumption rate test was also conducted, after the parametric tests were completed. The DBA consumption test was conducted from November 21 through 25. Options I and II to the base program were exercised by DOE/PETC at the end of the previous quarter. These options involve testing at Hoosier Energy Rural Electric Cooperative Inc.'s Merom Station and Southwestern Electric Power Company's Pirkey Station, respectively. Testing was conducted at Merom Station during November. Previously, Radian Corporation was the test contractor for EPRI-funded performance additive testing at this site. This EPRI-funded testing involved the equivalent of baseline testing, parametric testing with both DBA and sodium formate performance additives, and an additive consumption test with the DBA additive. The results …

A cyclic voltammetry technique was used to study the interactions of pyrite during bioleaching with the bacterium Thiobacillus ferrooxidans. Potential effects of heavy metals (silver and mercury) and varying the pH on the iron oxidizing ability of the bacterium are reported. Redox potential techniques were used to study effect of ferrous sulfate concentration and pH on bacterial growth.

In this paper we consider the problem of interprocessor communication on a Completely Connected Optical Communication Parallel Computer (OCPC). The particular problem we study is that of realizing an h-relation. In this problem, each processor has at most h messages to send and at most h messages to receive. It is clear that any 1-relation can be realized in one communication step on an OCPC. However, the best known p-processor OCPC algorithm for realizing an arbitrary h-relation for h > 1 requires {Theta}(h + log p) expected communication steps. (This algorithm is due to Valiant and is based on earlier work of Anderson and Miller.) Valiant`s algorithm is optimal only for h = {Omega}(log p) and it is an open question of Gereb-Graus and Tsantilas whether there is a faster algorithm for h = o(log p). In this paper we answer this question in the affirmative by presenting a {Theta} (h + log log p) communication step algorithm that realizes an arbitrary h-relation on a p-processor OCPC. We show that if h {le} log p then the failure probability can be made as small as p{sup -{alpha}} for any positive constant {alpha}.

Glass frit will be a major raw material for the operation of the Defense Waste Processing Facility. The frit will be controlled by certificate of conformance and a confirmatory analysis from a commercial analytical laboratory. The following effort provides additional quantitative information on the variability of frit chemical analyses at two commercial laboratories. Identical samples of IDMS Frit 202 were chemically analyzed at two commercial laboratories and at three different times over a period of four months. The SRL-ADS analyses, after correction with the reference standard and normalization, provided confirmatory information, but did not detect the low silica level in one of the frit samples. A methodology utilizing elliptical limits for confirming the certificate of conformance or confirmatory analysis was introduced and recommended for use when the analysis values are close but not within the specification limits. It was also suggested that the lithia specification limits might be reduced as long as CELS is used to confirm the analysis.

Monthly report providing tabular statistical information about motor vehicle accidents in rural areas of Texas during 1992, with data broken out by various criteria including number of persons, locations, types of accidents, time of day, and other factors.

Monthly report providing tabular statistical information about motor vehicle accidents in Texas during 1992, with data broken out by various criteria including number of persons, locations, types of accidents, time of day, and other factors.