A new type of electrodynamic balance was designed, constructed and applied to the study of the chemistry of macerals and the chemical reaction between CaO sorbent particles and SO[sub 2]. The single-particle device was coupled to a Raman spectrometer. With this balance a single electrically charged microparticle is suspended in visible and infrared laser beams by means of superposed ac and dc electrical fields. The apparatus was designed to permit gas flow through the chamber so that gas-solid and gas-liquid chemical reactions can be carried out. A visible laser beam was used to illuminate the particle for Raman and fluorescence measurements, and an infrared laser beam was used to heat the particle. An overview of the experimental system is presented in Figure 1. The levitated particles were heated from two sides using a CO[sub 2] laser operating at the infrared wavelength of 10.6 [mu]m. The optical system used to direct the heating laser beam to the target is shown in Figure 2. Infrared detectors indicated in Figure 1 were used to measure the particle temperature by two-color pyrometery. A new technique was explored to independently determine the particle temperature; the method involves measuring the ratio of the intensities of Stokes …

A new type of electrodynamic balance was designed, constructed and applied to the study of the chemistry of macerals and the chemical reaction between CaO sorbent particles and SO{sub 2}. The single-particle device was coupled to a Raman spectrometer. With this balance a single electrically charged microparticle is suspended in visible and infrared laser beams by means of superposed ac and dc electrical fields. The apparatus was designed to permit gas flow through the chamber so that gas-solid and gas-liquid chemical reactions can be carried out. A visible laser beam was used to illuminate the particle for Raman and fluorescence measurements, and an infrared laser beam was used to heat the particle. An overview of the experimental system is presented in Figure 1. The levitated particles were heated from two sides using a CO{sub 2} laser operating at the infrared wavelength of 10.6 {mu}m. The optical system used to direct the heating laser beam to the target is shown in Figure 2. Infrared detectors indicated in Figure 1 were used to measure the particle temperature by two-color pyrometery. A new technique was explored to independently determine the particle temperature; the method involves measuring the ratio of the intensities of Stokes …

During this period work has encompassed: (a) development of electropotential drop techniques to monitor the growth of cracks in steel specimens for a variety of specimen geometries; (b) micromechanical modeling of fracture using finite element calculations of crack and notch-tip stress and strain fields; (3) examining helium effects on radiation damage in austenitic and ferritic stainless steels; (4) analysis of the degradation of the mechanical properties of austenitic stainless steels for the purpose of assessing the feasibility of using these steels in ITER; (5) development of an integrated approach to integrity assessment; and (6) development of advanced methods of measuring fracture properties.

During this period work has encompassed: (a) development of electropotential drop techniques to monitor the growth of cracks in steel specimens for a variety of specimen geometries; (b) micromechanical modeling of fracture using finite element calculations of crack and notch-tip stress and strain fields; (3) examining helium effects on radiation damage in austenitic and ferritic stainless steels; (4) analysis of the degradation of the mechanical properties of austenitic stainless steels for the purpose of assessing the feasibility of using these steels in ITER; (5) development of an integrated approach to integrity assessment; and (6) development of advanced methods of measuring fracture properties.

Gamma-induced volatility of simulated DWPF high-level nuclear waste glasses is highly dependent upon the redox state of the glass. For oxidized glasses with an Fe{sup 2+}/(Fe{sup 2+} + Fe{sup 3+}) ratio < 0.1, no volatility was detected after gamma irradiation. Since the projected DWPF high-level radioactive waste glasses will be oxidized, no significant gamma-induced volatility is expected for these glasses upto the glass transition temperature. For larger pieces of highly-reduced DWPF simulated waste glass, no volatility was observed (using {approximately}100 mg pieces in the TGA) after gamma irradiation. However, for powdered samples of this reduced glass, volatility changes upon gamma radiation were detected at 350 and 475{degree}C. The volatility at 350{degree}C was due to changes at the glass surface whereas the change in volatility at 475{degree}C were due to interactions of gamma irradiation within the bulk of the glass. The glass transition temperatures of both oxidized and reduced glasses were unaffected by gamma irradiation but did increase upon a second heat cycle. Results are also presented which reveal that no significant change in redox level within the glass occurred as a result of gamma irradiation.

Gamma-induced volatility of simulated DWPF high-level nuclear waste glasses is highly dependent upon the redox state of the glass. For oxidized glasses with an Fe[sup 2+]/(Fe[sup 2+] + Fe[sup 3+]) ratio < 0.1, no volatility was detected after gamma irradiation. Since the projected DWPF high-level radioactive waste glasses will be oxidized, no significant gamma-induced volatility is expected for these glasses upto the glass transition temperature. For larger pieces of highly-reduced DWPF simulated waste glass, no volatility was observed (using [approximately]100 mg pieces in the TGA) after gamma irradiation. However, for powdered samples of this reduced glass, volatility changes upon gamma radiation were detected at 350 and 475[degree]C. The volatility at 350[degree]C was due to changes at the glass surface whereas the change in volatility at 475[degree]C were due to interactions of gamma irradiation within the bulk of the glass. The glass transition temperatures of both oxidized and reduced glasses were unaffected by gamma irradiation but did increase upon a second heat cycle. Results are also presented which reveal that no significant change in redox level within the glass occurred as a result of gamma irradiation.

A model has been developed that accounts for grain growth during, superplastic flow and its subsequent influence on stress-strain-strain rate behavior. These studies are experimentally based and have involved two different types of superplastic materials -- a quasi-single phase metal (Coronze 638) and a microduplex metal (ultrahigh-carbon steel - UHCS). In both materials the kinetics of strain-enhanced grain growth have been studied as a function of strain, strain rate and temperature. An equation for the rate of grain growth has been developed that incorporates the influence of temperature. The evolution of the grain size distribution during superplastic deformation has also been investigated. Our model integrates grain growth laws derived from these studies with two mechanism based, rate dependent constitutive laws to predict the stress-strainstrain rate behavior of materials during superplastic deformation. The influence of crain size distribution and its evolution with strain and strain rate on the stress-strain-strain rate behavior has been represented through the use of distributed parameters. The model can capture the stress-strain-strain rate behavior over a wide range of strains and strain rates with a single set of parameters. Many subtle features of the mechanical response of these materials can be adequately predicted.

The overall objective is to study the mechanisms and the energy dependence of heavy ion fragmentation by studying the reactions of heavy ion projectiles (e.g. [sup 4]He, [sup 16]O, [sup 20]Ne, [sup 28]Si, [sup 56]Fe) in a variety of targets (H, He, C, Si, Cu, Pb) and at a number of beam energies exceeding 0.1 GeV/nucleon. The results have application to questions in high-energy nuclear astrophysics. Most of the discussion is on low-energy [sup 16]O,[sup 28]Si data analysis. The description includes analysis procedures and techniques, detector calibrations, data selections and normalizations. Cross section results for the analysis are also presented. 83 figs., 6 tabs., 73 refs.

The overall objective is to study the mechanisms and the energy dependence of heavy ion fragmentation by studying the reactions of heavy ion projectiles (e.g. {sup 4}He, {sup 16}O, {sup 20}Ne, {sup 28}Si, {sup 56}Fe) in a variety of targets (H, He, C, Si, Cu, Pb) and at a number of beam energies exceeding 0.1 GeV/nucleon. The results have application to questions in high-energy nuclear astrophysics. Most of the discussion is on low-energy {sup 16}O,{sup 28}Si data analysis. The description includes analysis procedures and techniques, detector calibrations, data selections and normalizations. Cross section results for the analysis are also presented. 83 figs., 6 tabs., 73 refs.

The Department of Energy has established specifications for the DWPF product, which require that the DWPF provide estimates of the service life of the canister label, provide assurance that the DWPF canister will be leaktight when shipped, demonstrate that the contents of the canistered waste form will not lead to internal corrosion of the canister. The DWPF has elected to meet these requirements, in part, by characterizing canisters produced in the facility during the Startup Test Program. This includes canisters filled on the pour turntable (normal conditions) and canisters filled on the drain turntable (credible upset conditions expected to be more severe due to higher temperatures). This document identifies the requirements for characterization of the canister fabrication welds and canister labels (characterization of canister closure welds is being performed by Equipment Engineering Section), and for estimation of their service life in DWPF's Glass Waste Storage Building.

The Department of Energy has established specifications for the DWPF product, which require that the DWPF provide estimates of the service life of the canister label, provide assurance that the DWPF canister will be leaktight when shipped, demonstrate that the contents of the canistered waste form will not lead to internal corrosion of the canister. The DWPF has elected to meet these requirements, in part, by characterizing canisters produced in the facility during the Startup Test Program. This includes canisters filled on the pour turntable (normal conditions) and canisters filled on the drain turntable (credible upset conditions expected to be more severe due to higher temperatures). This document identifies the requirements for characterization of the canister fabrication welds and canister labels (characterization of canister closure welds is being performed by Equipment Engineering Section), and for estimation of their service life in DWPF`s Glass Waste Storage Building.

Letter opinion issued by the Office of the Attorney General of Texas in Austin, Texas, providing an interpretation of Texas law. It provides the opinion of the Texas Attorney General, Dan Morales, regarding a legal question submitted for clarification: Whether section 6 of article 42.131 of the Code of Criminal Procedure extends the benefits of attorney general legal representation to community supervision and corrections departments (ID# 17346)

Newsletter of the Texas Bureau of Disease Control and Epidemiology discussing the news, activities, and events of the organization and other information related to health in Texas.

In the US, the transportation sector consumes over one quarter of the entire energy used, almost in its entirety as petroleum products, and in quantities greater than the total US domestic oil production. The transportation sector is responsible for a significant fraction of all emissions that either prevent US cities from achieving compliance with EPA air quality standards or have serious global change implications. Finally, the GDP (Gross Domestic Product) and employment due to the sector are low and incommensurate with the high fraction of energy that the transportation sector consumes. We examine below this situation in some detail and make recommendations for improvements.

Hybrid technologies for the reduction of NO[sub x] emissions from coal-fired utility boilers have shown the potential to offer greater levels of NO[sub x] control than the sum of the individual technologies, leading to more cost effective emissions control strategies. Energy and Environmental Research Corporation (EER) has developed a hybrid NO[sub x] control strategy involving two proprietary concepts which has the potential to meet the US Department of Energy's NO[sub x] reduction goal at a significant reduction in cost compared to existing technology. The process has been named CombiNO[sub x]. CombiNO[sub x] is an integration of three technologies: modified reburning, promoted selective noncatalytic reduction (SNCR) and methanol injection. These technologies are combined to achieve high levels of NO[sub x] emission reduction from coal-fired power plants equipped with S0[sub x] scrubbers. The first two steps, modified reburning and promoted SNCR are linked. It has been shown that performance of the SNCR agent is dependent upon local oxidation of CO. Reburning is used to generate the optimum amount of CO to promote the SNCR agent. Approximately 10 percent reburning is required, this represents half of that required for conventional reburning. If the reburn fuel is natural gas, the combination of reburning and …

Hybrid technologies for the reduction of NO{sub x} emissions from coal-fired utility boilers have shown the potential to offer greater levels of NO{sub x} control than the sum of the individual technologies, leading to more cost effective emissions control strategies. Energy and Environmental Research Corporation (EER) has developed a hybrid NO{sub x} control strategy involving two proprietary concepts which has the potential to meet the US Department of Energy`s NO{sub x} reduction goal at a significant reduction in cost compared to existing technology. The process has been named CombiNO{sub x}. CombiNO{sub x} is an integration of three technologies: modified reburning, promoted selective noncatalytic reduction (SNCR) and methanol injection. These technologies are combined to achieve high levels of NO{sub x} emission reduction from coal-fired power plants equipped with S0{sub x} scrubbers. The first two steps, modified reburning and promoted SNCR are linked. It has been shown that performance of the SNCR agent is dependent upon local oxidation of CO. Reburning is used to generate the optimum amount of CO to promote the SNCR agent. Approximately 10 percent reburning is required, this represents half of that required for conventional reburning. If the reburn fuel is natural gas, the combination of reburning and …

The Electronic Systems Contract Administration Payment And Invoicing Database (ESCAPAID) project is a cooperative effort to simplify and automate the contracting and billing of services between Digital Equipment Corporation (Digital) and Los Alamos National Laboratory (LANL).The ESCAPAID project is intended to improve productivity in both organizations by reducing the inaccuracies and the amount of manual effort in the current system. Within LANL, the project is intended to streamline operations for purchasing (N4AT Division), finance (FIN Division), and Laboratory personnel requesting maintenance contract services from Digital. In October 1992, Digital and LANL released a jointly developed Program Definition, which provides an overview of the proposed system and an eight-step strategy for implementing a preliminary model.The second step of this strategy calls for the development of a model plan, including a description of afl high-level tasks that need to be completed and a series of Gantt and PERT charts. In order to accomplish this step, representatives from Digital and LANL participated in a Joint Application Development (JAD) workshop on January 19 and 20, 1993. The results of the workshop are reflected in this document.

The Electronic Systems Contract Administration Payment And Invoicing Database (ESCAPAID) project is a cooperative effort to simplify and automate the contracting and billing of services between Digital Equipment Corporation (Digital) and Los Alamos National Laboratory (LANL).The ESCAPAID project is intended to improve productivity in both organizations by reducing the inaccuracies and the amount of manual effort in the current system. Within LANL, the project is intended to streamline operations for purchasing (N4AT Division), finance (FIN Division), and Laboratory personnel requesting maintenance contract services from Digital. In October 1992, Digital and LANL released a jointly developed Program Definition, which provides an overview of the proposed system and an eight-step strategy for implementing a preliminary model.The second step of this strategy calls for the development of a model plan, including a description of afl high-level tasks that need to be completed and a series of Gantt and PERT charts. In order to accomplish this step, representatives from Digital and LANL participated in a Joint Application Development (JAD) workshop on January 19 and 20, 1993. The results of the workshop are reflected in this document.

Despite the apparent simplicity of controlled fusion, there are many phenomena which have prevented its achievement. One phenomenon is laser-plasma instabilities. An investigation of one such instability, stimulated Brillouin scattering (SBS), is reported here. SBS is a parametric process whereby an electromagnetic wave (the parent wave) decays into another electromagnetic wave and an ion acoustic wave (the daughter waves). SBS impedes controlled fusion since it can scatter much or all of the incident laser light, resulting in poor drive symmetry and inefficient laser-plasma coupling. It is widely believed that SBS becomes convectively unstable--that is, it grows as it traverses the plasma. Though it has yet to be definitively tested, convective theory is often invoked to explain experimental observations, even when one or more of the theory`s assumptions are violated. In contrast, the experiments reported here not only obeyed the assumptions of the theory, but were also conducted in plasmas with peak densities well below quarter-critical density. This prevented other competing or coexisting phenomena from occurring, thereby providing clearly interpretable results. These are the first SBS experiments that were designed to be both a clear test of linear convective theory and pertinent to controlled fusion research. A crucial part of this …

We investigate the effects of secondary interactions in nucleus- nucleus and proton-nucleus collisions using a modified HIJET Monte Carlo generator. The effects of N[sup *] production is explored and it is found that the numbers of kaons can almost be explained by their inclusion. However the transverse momentum spectrum of the kaons is not explained, since their production in HIJET is a soft secondary scattering process and not a hot thermal process like the data.

We investigate the effects of secondary interactions in nucleus- nucleus and proton-nucleus collisions using a modified HIJET Monte Carlo generator. The effects of N{sup *} production is explored and it is found that the numbers of kaons can almost be explained by their inclusion. However the transverse momentum spectrum of the kaons is not explained, since their production in HIJET is a soft secondary scattering process and not a hot thermal process like the data.

In 1979, a K-edge densitometer (KED) was installed by the Safeguards Assay group from Los Alamos National Laboratory in the PNC reprocessing plant at Tokai-mura, Japan. It uses an active nondestructive assay technique, KED, to measure the plutonium concentration of the product solution. The measurement uncertainty of an assay depends on the count time chosen, but can be 0.5% or better. The computer hardware and software were upgraded in 1992. This manual describes the operation of the instrument, with an emphasis on the user interface to the software.

In 1979, a K-edge densitometer (KED) was installed by the Safeguards Assay group from Los Alamos National Laboratory in the PNC reprocessing plant at Tokai-mura, Japan. It uses an active nondestructive assay technique, KED, to measure the plutonium concentration of the product solution. The measurement uncertainty of an assay depends on the count time chosen, but can be 0.5% or better. The computer hardware and software were upgraded in 1992. This manual describes the operation of the instrument, with an emphasis on the user interface to the software.

We present the results of [Lambda] and K[sub s[sup o]] production from Si and Pb targets with 14.6[times][Lambda] Gev/c Si beams. The measured rapidity distributions and the transverse mass exponential slopes are presented and compared with models.