Biological Conversion of Synthesis Gas (open access)

Biological Conversion of Synthesis Gas

Syngas is known to contain approximately 1 percent H[sub 2]S, along with CO[sub 2], C0[sub 2], H[sub 2] and CH[sub 4]. Similarly, the syngas may become contaminated with oxygen, particularly during reactor start-up and during maintenance. Previous studies with the water-gas shift bacterium Rhodospirillum rubrum have shown that the bacterium is tolerant of small quantities of oxygen, but the effects of oxygen on CO-consumption are unknown. Similarly, R. rubrum is known to be tolerant of H[sub 2]S, with high concentrations of H[sub 2]S negatively affecting CO-uptake. Batch experiments were thus carried out to determine the effects of H[sub 2]S and O[sub 2] on CO-uptake by R. rubrum. The results of these experiments were quantified by using Monod equations modified by adding terms for CO, H[sub 2]S and O[sub 2] inhibition. The techniques used in determining kinetic expressions previously shown for other gas-phase substrate bacterial systems including R. rubrum were utilized.
Date: January 5, 1993
Creator: Ackerson, M. D.; Clausen, E. C. & Gaddy, J. L.
Object Type: Report
System: The UNT Digital Library
Biological Conversion of Synthesis Gas. Project Status Report, October 1, 1992--December 31, 1992 (open access)

Biological Conversion of Synthesis Gas. Project Status Report, October 1, 1992--December 31, 1992

Syngas is known to contain approximately 1 percent H{sub 2}S, along with CO{sub 2}, C0{sub 2}, H{sub 2} and CH{sub 4}. Similarly, the syngas may become contaminated with oxygen, particularly during reactor start-up and during maintenance. Previous studies with the water-gas shift bacterium Rhodospirillum rubrum have shown that the bacterium is tolerant of small quantities of oxygen, but the effects of oxygen on CO-consumption are unknown. Similarly, R. rubrum is known to be tolerant of H{sub 2}S, with high concentrations of H{sub 2}S negatively affecting CO-uptake. Batch experiments were thus carried out to determine the effects of H{sub 2}S and O{sub 2} on CO-uptake by R. rubrum. The results of these experiments were quantified by using Monod equations modified by adding terms for CO, H{sub 2}S and O{sub 2} inhibition. The techniques used in determining kinetic expressions previously shown for other gas-phase substrate bacterial systems including R. rubrum were utilized.
Date: January 5, 1993
Creator: Ackerson, M. D.; Clausen, E. C. & Gaddy, J. L.
Object Type: Report
System: The UNT Digital Library
Excise Tax Financing of Federal Trust Funds (open access)

Excise Tax Financing of Federal Trust Funds

Dedicated excise taxes finance only a small number of the many activities undertaken by the Federal Government. The fourteen trust funds and special funds currently financed by excise taxes can be grouped under four programmatic purposes: nature conservation and recreation, transportation, environmental cleanup, and health damage compensation. In close parallel, the products currently subject to taxation on behalf of trust and special funds can be classified under the categories of hunting and fishing equipment; cargo transport and air passenger transportation; motor fuels; and materials potentially hazardous to the environment or human health.
Date: January 5, 1993
Creator: Noto, Nonna A. & Talley, Louis Alan
Object Type: Report
System: The UNT Digital Library
Implementation of the hazardous debris rule (open access)

Implementation of the hazardous debris rule

Hazardous debris includes objects contaminated with hazardous waste. Examples of debris include tree stumps, timbers, boulders, tanks, piping, crushed drums, personal protective clothing, etc. Most of the hazardous debris encountered comes from Superfund sites and other facility remediation, although generators and treaters of hazardous waste also generate hazardous debris. Major problems associated with disposal of debris includes: Inappropriateness of many waste treatments to debris; Difficulties in obtaining representative samples; Costs associated with applying waste specific treatments to debris; Subtitle C landfill space was being used for many low hazard debris types. These factors brought about the need for debris treatment technologies and regulations that addressed these issues. The goal of such regulation was to provide treatment to destroy or remove the contamination if possible and, if this is achieved, to dispose of the cleaned debris as a nonhazardous waste. EPA has accomplished this goal through promulgation of the Hazardous Debris Rule, August 18, 1992.
Date: January 5, 1993
Creator: Sailer, J. E.
Object Type: Article
System: The UNT Digital Library
Malignant melanoma slide review project: Patients from non-Kaiser hospitals in the San Francisco Bay Area. Final report (open access)

Malignant melanoma slide review project: Patients from non-Kaiser hospitals in the San Francisco Bay Area. Final report

This project was initiated, in response to concerns that the observed excess of malignant melanoma among employees of Lawrence Livermore National Laboratory (LLNL) might reflect the incidence of disease diagnostically different than that observed in the general population. LLNL sponsored a slide review project, inviting leading dermatopathology experts to independently evaluate pathology slides from LLNL employees diagnosed with melanoma and those from a matched sample of Bay Area melanoma patients who did not work at the LLNL. The study objectives were to: Identify all 1969--1984 newly diagnosed cases of malignant melanoma among LLNL employees resident in the San Francisco-Oakland Metropolitan Statistical Area, and diagnosed at facilities other than Kaiser Permanente; identify a comparison series of melanoma cases also diagnosed between 1969--1984 in non-Kaiser facilities, and matched as closely as possible to the LLNL case series by gender, race, age at diagnosis, year of diagnosis, and hospital of diagnosis; obtain pathology slides for the identified (LLNL) case and (non-LLNL) comparison patients for review by the LLNL-invited panel of dermatopathology experts; and to compare the pathologic characteristics of the case and comparison melanoma patients, as recorded by the dermatopathology panel.
Date: January 5, 1993
Creator: Reynolds, P.
Object Type: Report
System: The UNT Digital Library
Methods for testing transport models. [Departments of Nuclear Engineering and Statistics, Univ. of Illinois at Urbana[endash]Champaign] (open access)

Methods for testing transport models. [Departments of Nuclear Engineering and Statistics, Univ. of Illinois at Urbana[endash]Champaign]

This report documents progress to date under a three-year contract for developing Methods for Testing Transport Models.'' The work described includes (1) choice of best methods for producing code emulators'' for analysis of very large global energy confinement databases, (2) recent applications of stratified regressions for treating individual measurement errors as well as calibration/modeling errors randomly distributed across various tokamaks, (3) Bayesian methods for utilizing prior information due to previous empirical and/or theoretical analyses, (4) extension of code emulator methodology to profile data, (5) application of nonlinear least squares estimators to simulation of profile data, (6) development of more sophisticated statistical methods for handling profile data, (7) acquisition of a much larger experimental database, and (8) extensive exploratory simulation work on a large variety of discharges using recently improved models for transport theories and boundary conditions. From all of this work, it has been possible to define a complete methodology for testing new sets of reference transport models against much larger multi-institutional databases.
Date: January 5, 1993
Creator: Singer, C. & Cox, D.
Object Type: Report
System: The UNT Digital Library
Methods for testing transport models. Third year annual report (open access)

Methods for testing transport models. Third year annual report

This report documents progress to date under a three-year contract for developing ``Methods for Testing Transport Models.`` The work described includes (1) choice of best methods for producing ``code emulators`` for analysis of very large global energy confinement databases, (2) recent applications of stratified regressions for treating individual measurement errors as well as calibration/modeling errors randomly distributed across various tokamaks, (3) Bayesian methods for utilizing prior information due to previous empirical and/or theoretical analyses, (4) extension of code emulator methodology to profile data, (5) application of nonlinear least squares estimators to simulation of profile data, (6) development of more sophisticated statistical methods for handling profile data, (7) acquisition of a much larger experimental database, and (8) extensive exploratory simulation work on a large variety of discharges using recently improved models for transport theories and boundary conditions. From all of this work, it has been possible to define a complete methodology for testing new sets of reference transport models against much larger multi-institutional databases.
Date: January 5, 1993
Creator: Singer, C. & Cox, D.
Object Type: Report
System: The UNT Digital Library
Texas Attorney General Opinion: DM-195 (open access)

Texas Attorney General Opinion: DM-195

Document issued by the Office of the Attorney General of Texas in Austin, Texas, providing an interpretation of Texas law. It provides the opinion of the Texas Attorney General, Dan Morales, regarding a legal question submitted for clarification: Whether a proceeding to recover excess proceeds after a tax lien foreclosure requires a separate cause of action, and related question (RQ-456)
Date: January 5, 1993
Creator: Texas. Attorney-General's Office.
Object Type: Text
System: The Portal to Texas History
Texas Register, Volume 18, Number 2, Pages 90-185, January 5, 1993 (open access)

Texas Register, Volume 18, Number 2, Pages 90-185, January 5, 1993

A weekly publication, the Texas Register serves as the journal of state agency rulemaking for Texas. Information published in the Texas Register includes proposed, adopted, withdrawn and emergency rule actions, notices of state agency review of agency rules, governor's appointments, attorney general opinions, and miscellaneous documents such as requests for proposals. After adoption, these rulemaking actions are codified into the Texas Administrative Code.
Date: January 5, 1993
Creator: Texas. Secretary of State.
Object Type: Journal/Magazine/Newsletter
System: The Portal to Texas History
Longitudinal information and radiation damage in EM calorimetry (open access)

Longitudinal information and radiation damage in EM calorimetry

The SCC radiation field is higher than that encountered by previous hadron collider detectors. In particular, the electromagnetic (EM) calorimeter compartment sees the highest radiation dose. Since an EM calorimeter also makes the most precise energy measurement, special care must be lavished on this part of a calorimeter. Previous studies have concentrated on Monte Carlo examinations of 2 longitudinal compartments within the EM which can alleviate radiation damage. Recently, it was realized that a ``shower maximum`` detector, such as exists in CDF, also contains information of the conversion point of an electromagnetic shower. As such, it can potentially be used in a fashion analogous to the longitudinal compartments, although it is not designed to be optimized for this role.
Date: February 5, 1993
Creator: Green, D.
Object Type: Report
System: The UNT Digital Library
Longitudinal information and radiation damage in EM calorimetry (open access)

Longitudinal information and radiation damage in EM calorimetry

The SCC radiation field is higher than that encountered by previous hadron collider detectors. In particular, the electromagnetic (EM) calorimeter compartment sees the highest radiation dose. Since an EM calorimeter also makes the most precise energy measurement, special care must be lavished on this part of a calorimeter. Previous studies have concentrated on Monte Carlo examinations of 2 longitudinal compartments within the EM which can alleviate radiation damage. Recently, it was realized that a shower maximum'' detector, such as exists in CDF, also contains information of the conversion point of an electromagnetic shower. As such, it can potentially be used in a fashion analogous to the longitudinal compartments, although it is not designed to be optimized for this role.
Date: February 5, 1993
Creator: Green, D.
Object Type: Report
System: The UNT Digital Library
Monolithic Solid Oxide Fuel Cell Technology Advancement for Coal-Based Power Generation. Quarterly Technical Progress Report, October--December 1992 (open access)

Monolithic Solid Oxide Fuel Cell Technology Advancement for Coal-Based Power Generation. Quarterly Technical Progress Report, October--December 1992

The program focuses on materials research and development, fabrication process development, cell/stack performance testing and characterization, cost and system analysis, and quality development.
Date: February 5, 1993
Creator: unknown
Object Type: Report
System: The UNT Digital Library
Tennessee Valley Authority Eagle Bend 161-kV delivery point environmental assessment (open access)

Tennessee Valley Authority Eagle Bend 161-kV delivery point environmental assessment

Eagle Bend is an area located in a bend of the Clinch River about one mile southeast of Clinton, Tennessee, in Anderson County. This area, including an industrial park, is supplied electric power by the Clinton Utilities Board (UB) through its 69-kV system, which is in turn supplied by TVA over a 69-kV transmission line from Norris Hydro Plant. Studies of the power supply in the area indicate that there will likely be significant load growth both in the Clinton area in general and the industrial park in particular. Studies further show that if this new load is supplied at 69-kV, the TVA transformer at Norris Hydro which supplies this load will be overloaded by the summer of 1993 and no feasible alternate source which would maintain the quality and reliability of the power delivered to the Clinton system exists to accept this load. Clinton UB also needs to transfer load from its Clinton substation in the same time period to prevent overloading. Additional studies and consultation between TVA and Clinton UB have indicated that the best solution to this problem is to supply this load at 161-kV at a new delivery point for Clinton UB. This would require the …
Date: February 5, 1993
Creator: unknown
Object Type: Report
System: The UNT Digital Library
Texas Parks & Wildlife News, February 5, 1993 (open access)

Texas Parks & Wildlife News, February 5, 1993

Weekly newsletter discussing natural resources, parks, hunting and fishing, and other information related to the outdoors in Texas.
Date: February 5, 1993
Creator: Texas. Parks and Wildlife Department.
Object Type: Journal/Magazine/Newsletter
System: The Portal to Texas History
Texas Register, Volume 18, Number 10, Pages 721-776, February [5], 1993 (open access)

Texas Register, Volume 18, Number 10, Pages 721-776, February [5], 1993

A weekly publication, the Texas Register serves as the journal of state agency rulemaking for Texas. Information published in the Texas Register includes proposed, adopted, withdrawn and emergency rule actions, notices of state agency review of agency rules, governor's appointments, attorney general opinions, and miscellaneous documents such as requests for proposals. After adoption, these rulemaking actions are codified into the Texas Administrative Code.
Date: February 5, 1993
Creator: Texas. Secretary of State.
Object Type: Journal/Magazine/Newsletter
System: The Portal to Texas History
In situ, subsurface monitoring of vapor-phase TCE using fiber optics (open access)

In situ, subsurface monitoring of vapor-phase TCE using fiber optics

A vapor-phase, reagent-based, fiber optic trichloroethylene (TCE) sensor developed by Lawrence Livermore National Laboratory (LLNL) was demonstrated at the Savannah River Site (SRS) in two configurations. The first incorporated the sensor into a down-well instrument bounded by two inflatable packers capable of sealing an area for discrete depth analysis. The second involved an integration of the sensor into the probe tip of the Army Corps of Engineers Waterways Experiment Station (WES) cone penetrometry system. Discrete depth measurements of vapor-phase concentrations of TCE in the vadose zone were successfully made using both configurations. These measurements demonstrate the first successful in situ sensing (as opposed to sampling) of TCE at a field site.
Date: March 5, 1993
Creator: Rossabi, J.; Colston, B. Jr.; Brown, S.; Milanovich, F. & Lee, L. T. Jr.
Object Type: Article
System: The UNT Digital Library
The influence of naturally-occurring organic acids on model estimates of lakewater acidification using the model of acidification of groundwater in catchments (MAGIC) (open access)

The influence of naturally-occurring organic acids on model estimates of lakewater acidification using the model of acidification of groundwater in catchments (MAGIC)

A project for the US Department of Energy, entitled Incorporation of an organic acid representation into MAGIC (Model of Acidification of Groundwater in Catchments) and Testing of the Revised Model UsingIndependent Data Sources'' was initiated by E S Environmental Chemistry, Inc. in March, 1992. Major components of the project include: improving the MAGIC model by incorporating a rigorous organic acid representation, based on empirical data and geochemical considerations, and testing the revised model using data from paleolimnological hindcasts of preindustrial chemistry for 33 Adirondack Mountain lakes, and the results of whole-catchment artificial acidification projects in Maine and Norway. The ongoing research in this project involves development of an organic acid representation to be incorporated into the MAGIC modeland testing of the improved model using three independent data sources. The research during Year 1 has included conducting two workshops to agree on an approach for the organic acid modeling, developing the organic subroutine and incorporating it into MAGIC (Task 1), conducing MAGIC hindcasts for Adirondack lakes and comparing the results with paleolimnological reconstructions (Task 2), and conducting site visits to the manipulation project sites in Maine and Norway. The purpose of this report is to provide a summary of the work …
Date: March 5, 1993
Creator: Sullivan, T.J.; Eilers, J.M. (E and S Environmental Chemistry, Inc., Corvallis, OR (United States)); Cosby, B.J. (Virginia Univ., Charlottesville, VA (United States). Dept. of Environmental Sciences); Driscoll, C.T. (Syracuse Univ., NY (United States). Dept. of Civil Engineering); Hemond, H.F. (Massachusetts Inst. of Tech., Cambridge, MA (United States). Dept. of Civil Engineering) & Charles, D.F.
Object Type: Report
System: The UNT Digital Library
The influence of naturally-occurring organic acids on model estimates of lakewater acidification using the model of acidification of groundwater in catchments (MAGIC). Summary of research conducted during year 1 (open access)

The influence of naturally-occurring organic acids on model estimates of lakewater acidification using the model of acidification of groundwater in catchments (MAGIC). Summary of research conducted during year 1

A project for the US Department of Energy, entitled ``Incorporation of an organic acid representation into MAGIC (Model of Acidification of Groundwater in Catchments) and Testing of the Revised Model UsingIndependent Data Sources`` was initiated by E&S Environmental Chemistry, Inc. in March, 1992. Major components of the project include: improving the MAGIC model by incorporating a rigorous organic acid representation, based on empirical data and geochemical considerations, and testing the revised model using data from paleolimnological hindcasts of preindustrial chemistry for 33 Adirondack Mountain lakes, and the results of whole-catchment artificial acidification projects in Maine and Norway. The ongoing research in this project involves development of an organic acid representation to be incorporated into the MAGIC modeland testing of the improved model using three independent data sources. The research during Year 1 has included conducting two workshops to agree on an approach for the organic acid modeling, developing the organic subroutine and incorporating it into MAGIC (Task 1), conducing MAGIC hindcasts for Adirondack lakes and comparing the results with paleolimnological reconstructions (Task 2), and conducting site visits to the manipulation project sites in Maine and Norway. The purpose of this report is to provide a summary of the work that …
Date: March 5, 1993
Creator: Sullivan, T. J.; Eilers, J. M.; Cosby, B. J.; Driscoll, C. T.; Hemond, H. F.; Charles, D. F. et al.
Object Type: Report
System: The UNT Digital Library
The Savannah River Technology Center environmental monitoring field test platform (open access)

The Savannah River Technology Center environmental monitoring field test platform

Nearly all industrial facilities have been responsible for introducing synthetic chemicals into the environment. The Savannah River Site is no exception. Several areas at the site have been contaminated by chlorinated volatile organic chemicals. Because of the persistence and refractory nature of these contaminants, a complete clean up of the site will take many years. A major focus of the mission of the Environmental Sciences Section of the Savannah River Technology Center is to develop better, faster, and less expensive methods for characterizing, monitoring, and remediating the subsurface. These new methods can then be applied directly at the Savannah River Site and at other contaminated areas in the United States and throughout the world. The Environmental Sciences Section has hosted field testing of many different monitoring technologies over the past two years primarily as a result of the Integrated Demonstration Program sponsored by the Department of Energy`s Office of Technology Development. This paper provides an overview of some of the technologies that have been demonstrated at the site and briefly discusses the applicability of these techniques.
Date: March 5, 1993
Creator: Rossabi, J.
Object Type: Article
System: The UNT Digital Library
Shemya Air Force Base, Alaska No Further Action Decision document for Hg-1 (open access)

Shemya Air Force Base, Alaska No Further Action Decision document for Hg-1

This document is being prepared to document that a No Further Action Decision (NFAD) document is appropriate for the Hg-1 site at Shemya Air Force Base (AFB), Alaska, under the Air Force Installation Restoration Program (IRP). The IRP is a Department of Defense (DOD) program established to identify and remediate hazardous waste problems on DOD property that result from past practices. The Alaska Department of Environmental Conservation (ADEC) draft document [open quotes]No Further Action Criteria for DOD Military/FUD Sites[close quotes] has been used as a guide in preparing this document. Air Force personnel have stated that the Hg-1 site may have been used to store mercury and PCB-contaminated material. The site was added to the IRP in 1987, and later that year a field investigation was conducted at the site. Soil samples were collected and analyzed for mercury, EP toxicity, polychlorinated biphenyls (PCBs), and dioxin. All concentrations of contaminants found in Area Hg-1 are below regulatory action levels for PCBs (40 CFR 761) and mercury (55 FR 30798) or below detection levels for dioxin/furans. Therefore, leaving these soils in place is acceptable.
Date: March 5, 1993
Creator: unknown
Object Type: Report
System: The UNT Digital Library
Shemya Air Force Base, Alaska No Further Action Decision document for Hg-1. Final report (open access)

Shemya Air Force Base, Alaska No Further Action Decision document for Hg-1. Final report

This document is being prepared to document that a No Further Action Decision (NFAD) document is appropriate for the Hg-1 site at Shemya Air Force Base (AFB), Alaska, under the Air Force Installation Restoration Program (IRP). The IRP is a Department of Defense (DOD) program established to identify and remediate hazardous waste problems on DOD property that result from past practices. The Alaska Department of Environmental Conservation (ADEC) draft document {open_quotes}No Further Action Criteria for DOD Military/FUD Sites{close_quotes} has been used as a guide in preparing this document. Air Force personnel have stated that the Hg-1 site may have been used to store mercury and PCB-contaminated material. The site was added to the IRP in 1987, and later that year a field investigation was conducted at the site. Soil samples were collected and analyzed for mercury, EP toxicity, polychlorinated biphenyls (PCBs), and dioxin. All concentrations of contaminants found in Area Hg-1 are below regulatory action levels for PCBs (40 CFR 761) and mercury (55 FR 30798) or below detection levels for dioxin/furans. Therefore, leaving these soils in place is acceptable.
Date: March 5, 1993
Creator: unknown
Object Type: Report
System: The UNT Digital Library
Texas Parks & Wildlife News, March 5, 1993 (open access)

Texas Parks & Wildlife News, March 5, 1993

Weekly newsletter discussing natural resources, parks, hunting and fishing, and other information related to the outdoors in Texas.
Date: March 5, 1993
Creator: Texas. Parks and Wildlife Department.
Object Type: Journal/Magazine/Newsletter
System: The Portal to Texas History
Texas Register, Volume 18, Number 18, Pages 1383-1462, March 5, 1993 (open access)

Texas Register, Volume 18, Number 18, Pages 1383-1462, March 5, 1993

A weekly publication, the Texas Register serves as the journal of state agency rulemaking for Texas. Information published in the Texas Register includes proposed, adopted, withdrawn and emergency rule actions, notices of state agency review of agency rules, governor's appointments, attorney general opinions, and miscellaneous documents such as requests for proposals. After adoption, these rulemaking actions are codified into the Texas Administrative Code.
Date: March 5, 1993
Creator: Texas. Secretary of State.
Object Type: Journal/Magazine/Newsletter
System: The Portal to Texas History
The use of post detonation analysis of stable isotope ratios to determine the type and production process of the explosive involved (open access)

The use of post detonation analysis of stable isotope ratios to determine the type and production process of the explosive involved

The detonation of a series of explosives was performed in a controlled manner to collect the resulting, solid residue or {open_quotes}soot.{close_quotes} This residue was examined to determine the ratios of the stable carbon, hydrogen, and nitrogen isotopes. The goal of the experiment was to determine if these ratios could be used to indicate, from the post detonation residues, the type and origin of the detonated explosive. The ratios of the stated stable isotopes in the undetonated explosive were also determined. Despite some reservations in the quality of the data resulting from contamination by nonexplosive components, certain trends can be discerned. (1) Carbon isotopes allow aromatic explosives to be distinguished from nonaromatic explosives. This trend seems to carry through the detonation so that the distinction might be made after the fact. (2) The amination process for TATB can be detected through the hydrogen and, to some extent, the nitrogen isotope ratios. Unfortunately, the data are not sufficiently good to determine if this differential carries through the detonation. (3) The relative magnitude and sign of the nitrogen isotope ratio seems to carry through the detonation: some exchange with atmospheric nitrogen is probable. Even though this set of experiments must also be viewed …
Date: March 5, 1993
Creator: McGuire, R. R.; Velsko, C. A.; Lee, C. G. & Raber, E.
Object Type: Report
System: The UNT Digital Library