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Catalytic hydrocarbon reactions over supported metals (open access)

Catalytic hydrocarbon reactions over supported metals

During the past year we have completed our characterization of the factors that control the structure of fully oxidized W and Mo on silica and have established that support hydroxyl groups play a central role in dispersing and attaching cations to the support oxide. Work with M[sub 2](CO)[sub 4]Cp[sub 2](M[sub 2]=MoMo, WW, MoW) system has been very encouraging and continues to support the notion that it may be possible to control the structure of adsorbed catalysts (in this case generate metal dimers) by use of organometallic precursors. Techniques are being developed necessary to employ XPS as a means to characterize the attachment process and the oxidation state of the cations after various thermal and photolytic reduction steps.
Date: March 29, 1993
Creator: Ekerdt, J. G.
Object Type: Report
System: The UNT Digital Library
Catalytic hydrocarbon reactions over supported metals. Progress report, February 1, 1992--March 31, 1993 (open access)

Catalytic hydrocarbon reactions over supported metals. Progress report, February 1, 1992--March 31, 1993

During the past year we have completed our characterization of the factors that control the structure of fully oxidized W and Mo on silica and have established that support hydroxyl groups play a central role in dispersing and attaching cations to the support oxide. Work with M{sub 2}(CO){sub 4}Cp{sub 2}(M{sub 2}=MoMo, WW, MoW) system has been very encouraging and continues to support the notion that it may be possible to control the structure of adsorbed catalysts (in this case generate metal dimers) by use of organometallic precursors. Techniques are being developed necessary to employ XPS as a means to characterize the attachment process and the oxidation state of the cations after various thermal and photolytic reduction steps.
Date: March 29, 1993
Creator: Ekerdt, J. G.
Object Type: Report
System: The UNT Digital Library
Comparison of INMARSAT and ATS3 satellite communication (open access)

Comparison of INMARSAT and ATS3 satellite communication

There exists a need to provide communication through a satellite- based network which allows a user to communicate from a remote site to a fixed site. This discussion provides a comparison, both technical and financial, between the existing ATS3 satellite system and the commercial INMARSAT system. This comparison identified the limitations of each system to provide various types of communication.
Date: March 29, 1993
Creator: unknown
Object Type: Report
System: The UNT Digital Library
Composition dependence of fluid thermophysical properties: Theory and modeling (open access)

Composition dependence of fluid thermophysical properties: Theory and modeling

Objectives are studies of equilibrium/nonequilibrium properties of asymmetric fluid mixtures through computer simulation (CS), development of predictive theories of mixture equilibrium properties, development and application of selection algorithm methodology for mixture equations of state, and use of theory to develop new engineering design models for fluid mixtures. Kirwood charging method CS of Lennard-Jones mixtures with large size ratios verified the Kirkwood-Buff/Baxter method of calculating chemical potentials. CS of n-butane showed that the rheology is not a function of system size. A modified stepwise regression algorithm was developed and applied to HFC R134a. An analytical expression was developed for conformal solution size correction for mixtures. The extended corresponding states theory (ECST) can be applied to systems having large polarity differences; an accurate representation was developed of bulk phase properties of water-hydrocarbon systems. It was found how to force ECST to reach the correct virial limit.
Date: March 29, 1993
Creator: Ely, J.F.
Object Type: Report
System: The UNT Digital Library
Composition dependence of fluid thermophysical properties: Theory and modeling. Progress report (open access)

Composition dependence of fluid thermophysical properties: Theory and modeling. Progress report

Objectives are studies of equilibrium/nonequilibrium properties of asymmetric fluid mixtures through computer simulation (CS), development of predictive theories of mixture equilibrium properties, development and application of selection algorithm methodology for mixture equations of state, and use of theory to develop new engineering design models for fluid mixtures. Kirwood charging method CS of Lennard-Jones mixtures with large size ratios verified the Kirkwood-Buff/Baxter method of calculating chemical potentials. CS of n-butane showed that the rheology is not a function of system size. A modified stepwise regression algorithm was developed and applied to HFC R134a. An analytical expression was developed for conformal solution size correction for mixtures. The extended corresponding states theory (ECST) can be applied to systems having large polarity differences; an accurate representation was developed of bulk phase properties of water-hydrocarbon systems. It was found how to force ECST to reach the correct virial limit.
Date: March 29, 1993
Creator: Ely, J. F.
Object Type: Report
System: The UNT Digital Library
A parallel hashed oct-tree N-body algorithm (open access)

A parallel hashed oct-tree N-body algorithm

We report on an efficient adaptive N-body method which we have recently designed and implemented. The algorithm computers the forces on an arbitrary distribution of bodies in a time which scales as N log N with particle number. The accuracy of the force calculations is analytically bounded, and can be adjusted via a user defined parameter between a few percent relative accuracy, down to machine arithmetic accuracy. Instead of using pointers to indicate the topology of the tree, we identify each possible cell with a key. The mapping of keys into memory locations is achieved via a hash table. This allows us to access data in an efficient manner across multiple processors using a virtual shared memory model. Performance of the parallel program is measured on the 512 processor Intel Touchstone Delta system. We also comment on a number of wide-ranging applications which can benefit from application of this type of algorithm.
Date: March 29, 1993
Creator: Warren, M. S. & Salmon, J. K.
Object Type: Article
System: The UNT Digital Library
Plant Closings, Mass Layoffs, and Worker Dislocations: Data Issues (open access)

Plant Closings, Mass Layoffs, and Worker Dislocations: Data Issues

For at least 15 years Members of Congress have continued to ask: How many U.S. manufacturing plants have closed? For at least 15 years they have continued to ask: How many U.S. manufacturing plants have relocated abroad, and where have they gone? For at least 15 years the answer has been: For the most part, those questions can't be answered, based on Government data. How many plants are moving to Mexico? What industries and what States are the plants from? How many U.S. workers are losing their jobs as a result? It appears that still, after two legislative attempts to mandate collection of these data, the Government publishes no counts of U.S. plant closings, and almost no information on plant relocations. Options for strengthening the data systems include addressing three main weaknesses: inadequate data program design, a plant closing definition that misses its mark, and publication of partial instead of complete survey results.
Date: March 29, 1993
Creator: Bolle, Mary Jane
Object Type: Report
System: The UNT Digital Library
President Bush's Judicial Nominations During the 101st and 102nd Congresses (open access)

President Bush's Judicial Nominations During the 101st and 102nd Congresses

There are ten categories of courts (including the local courts of the District of Columbia) to which the President nominates judges. The report provides background and statistics concerning President Bush's judicial nominations in each court category as well as actions taken on those nominations by the United States Senate. Each of the report's ten sections discusses the composition and jurisdiction of the court in question and notes the committee to which nominations to this court were referred when received by the Senate. Also, statistics on judicial nominations received by the Senate during the four years of the Bush Presidency are presented.
Date: March 29, 1993
Creator: Rutkus, Denis Steven
Object Type: Report
System: The UNT Digital Library
Silicon microelectronic field-emissive devices for advanced display technology (open access)

Silicon microelectronic field-emissive devices for advanced display technology

Field-emission displays (FEDS) offer potential advantages of high luminous efficiency, low power consumption, and low cost compared to AMLCD or CRT technologies. An LLNL team has developed silicon-point field emitters for vacuum triode structures and has also used thin-film processing techniques to demonstrate planar edge-emitter configurations. LLNL is interested in contributing its experience in this and other FED-related technologies to collaborations for commercial FED development. At LLNL, FED development is supported by computational capabilities in charge transport and surface/interface modeling in order to develop smaller, low-work-function field emitters using a variety of materials and coatings. Thin-film processing, microfabrication, and diagnostic/test labs permit experimental exploration of emitter and resistor structures. High field standoff technology is an area of long-standing expertise that guides development of low-cost spacers for FEDS. Vacuum sealing facilities are available to complete the FED production engineering process. Drivers constitute a significant fraction of the cost of any flat-panel display. LINL has an advanced packaging group that can provide chip-on-glass technologies and three-dimensional interconnect generation permitting driver placement on either the front or the back of the display substrate.
Date: March 29, 1993
Creator: Morse, J. D.
Object Type: Article
System: The UNT Digital Library
The Steel Jaw Leghold Trap: Issues and Concerns (open access)

The Steel Jaw Leghold Trap: Issues and Concerns

Steel jaw leghold traps are used in 47 States in the United States to capture furbearing animals (Florida and Rhode Island have prohibited use except with special permit for nuisance animals, and New Jersey has banned all uses). In addition to use by the fur industry, these traps are employed by State agencies in game management (e.g., to control predators and diseases). The leghold trap issue pits animal welfare groups opposed to the pain and suffering of trapped animals against supporters of the trap who maintain that alternatives are not cost effective and/or efficient.
Date: March 29, 1993
Creator: Corn, M. Lynne
Object Type: Report
System: The UNT Digital Library
Texas Attorney General Opinion: DM-211 (open access)

Texas Attorney General Opinion: DM-211

Document issued by the Office of the Attorney General of Texas in Austin, Texas, providing an interpretation of Texas law. It provides the opinion of the Texas Attorney General, Dan Morales, regarding a legal question submitted for clarification: Authority of Texas Racing Commission pursuant to sections 6.09 and 10.05 of the Texas Racing Act, article 179e, V.T.C.S., to receive and regulate the use of breakage generated by pari-mutuel wagering on greyhounds (RQ-230)
Date: March 29, 1993
Creator: Texas. Attorney-General's Office.
Object Type: Text
System: The Portal to Texas History
Texas Attorney General Opinion: DM-212 (open access)

Texas Attorney General Opinion: DM-212

Document issued by the Office of the Attorney General of Texas in Austin, Texas, providing an interpretation of Texas law. It provides the opinion of the Texas Attorney General, Dan Morales, regarding a legal question submitted for clarification: Whether a school district may contract with off-duty police officers and deputy sheriffs for security services, and related questions (RQ-427)
Date: March 29, 1993
Creator: Texas. Attorney-General's Office.
Object Type: Text
System: The Portal to Texas History
Texas Attorney General Opinion: LO93-024 (open access)

Texas Attorney General Opinion: LO93-024

Letter opinion issued by the Office of the Attorney General of Texas in Austin, Texas, providing an interpretation of Texas law. It provides the opinion of the Texas Attorney General, Dan Morales, regarding a legal question submitted for clarification: Whether a teacher performing an internship under section 13.0321 of the Education Code to obtain an additional certification in speech and hearing therapy is violating V.T.C.S. article 4512j (ID# 16797)
Date: March 29, 1993
Creator: Texas. Attorney-General's Office.
Object Type: Text
System: The Portal to Texas History
Thick-target yields of iodine isotopes from proton interactions in Te, and the double-[beta] decay of [sup 128,130]Te (open access)

Thick-target yields of iodine isotopes from proton interactions in Te, and the double-[beta] decay of [sup 128,130]Te

We report thick-target yields of [sup 126,128,130]I from the bombardment of natural Te targets with 15-, 30-, 45- and 50-MeV protons, together with the iodine production cross sections for 1.85- and 5.0-GeV protons. With these data, we have estimated the relative cosmic-ray induced production of [sup 126]Xe, [sup 128]Xe and [sup 13O]Xe in Te ores. These quantities affect the ratio of double-[beta] decay half-lives of [sup 13O]Te and [sup 128]Te. A revised correction of cosmic-ray induced xenon can change the half-life ratio by as much as 10%, from (3.52[plus minus]0.11) [times] 10[sup [minus]4] to (3.88[plus minus]0.14) [times] 10[sup [minus]4].
Date: March 29, 1993
Creator: da Cruz, M.T.F.; Chan, Y.D.; Garcia, A.; Larimer, R.M.; Lesko, K.T.; Norman, E.B. et al.
Object Type: Article
System: The UNT Digital Library
Thick-target yields of iodine isotopes from proton interactions in Te, and the double-{beta} decay of {sup 128,130}Te (open access)

Thick-target yields of iodine isotopes from proton interactions in Te, and the double-{beta} decay of {sup 128,130}Te

We report thick-target yields of {sup 126,128,130}I from the bombardment of natural Te targets with 15-, 30-, 45- and 50-MeV protons, together with the iodine production cross sections for 1.85- and 5.0-GeV protons. With these data, we have estimated the relative cosmic-ray induced production of {sup 126}Xe, {sup 128}Xe and {sup 13O}Xe in Te ores. These quantities affect the ratio of double-{beta} decay half-lives of {sup 13O}Te and {sup 128}Te. A revised correction of cosmic-ray induced xenon can change the half-life ratio by as much as 10%, from (3.52{plus_minus}0.11) {times} 10{sup {minus}4} to (3.88{plus_minus}0.14) {times} 10{sup {minus}4}.
Date: March 29, 1993
Creator: da Cruz, M. T. F.; Chan, Y. D.; Garcia, A.; Larimer, R. M.; Lesko, K. T.; Norman, E. B. et al.
Object Type: Article
System: The UNT Digital Library
Summary of Pick-Up [Truck] Involved Accidents in the State of Texas for Calendar Year 1992 (open access)

Summary of Pick-Up [Truck] Involved Accidents in the State of Texas for Calendar Year 1992

Annual report providing tabular statistical information about motor vehicle accidents that involved pickup trucks in Texas during calendar year 1992, with data broken out by various criteria including number of persons, locations, types of accidents, time of day, and other factors.
Date: February 29, 1993
Creator: Texas. Department of Public Safety. Statistical Services.
Object Type: Report
System: The Portal to Texas History
Bench-scale testing of the multi-gravity separator in combination with Microcel (open access)

Bench-scale testing of the multi-gravity separator in combination with Microcel

The primary objective of the proposed work is to design, install and operate an advanced fine coal processing circuit combining Microcel and MGS technologies. Both of these processes have specific advantages as stand-alone units. For example, the Microcel column is effective in removing ash-bearing mineral matter, while the MGS is capable of efficiently removing coal-pyrite composites. Therefore, by combining both of these unit operations into a single processing circuit, synergistic advantages can be gained. As a result, this circuit arrangement has the potential of improving coal quality beyond that which could be achieved using either one of the technologies individually. In addition to the primary objective, secondary objectives of the proposed test program will include: (1) Circuit Optimization: The performance of each unit operation, individually and combined, will be optimized by conducting parametric studies as a function of key operating variables. The goal of this work will be to maximize the rejections of pyritic sulfur and ash while maintaining a high energy recovery; and (2) Process Variability: The steady-state performance of the optimized processing circuit will be studied (i) by conducting several long-duration test runs over a period of several days and (ii) by testing coal samples from other sources …
Date: January 29, 1993
Creator: unknown
Object Type: Report
System: The UNT Digital Library
Bench-scale testing of the multi-gravity separator in combination with Microcel. First quarterly report, September 29, 1992--December 31, 1992 (open access)

Bench-scale testing of the multi-gravity separator in combination with Microcel. First quarterly report, September 29, 1992--December 31, 1992

The primary objective of the proposed work is to design, install and operate an advanced fine coal processing circuit combining Microcel and MGS technologies. Both of these processes have specific advantages as stand-alone units. For example, the Microcel column is effective in removing ash-bearing mineral matter, while the MGS is capable of efficiently removing coal-pyrite composites. Therefore, by combining both of these unit operations into a single processing circuit, synergistic advantages can be gained. As a result, this circuit arrangement has the potential of improving coal quality beyond that which could be achieved using either one of the technologies individually. In addition to the primary objective, secondary objectives of the proposed test program will include: (1) Circuit Optimization: The performance of each unit operation, individually and combined, will be optimized by conducting parametric studies as a function of key operating variables. The goal of this work will be to maximize the rejections of pyritic sulfur and ash while maintaining a high energy recovery; and (2) Process Variability: The steady-state performance of the optimized processing circuit will be studied (i) by conducting several long-duration test runs over a period of several days and (ii) by testing coal samples from other sources …
Date: January 29, 1993
Creator: unknown
Object Type: Report
System: The UNT Digital Library
Characterization of mixed CH-TRU waste at Argonne-West. A WIPP project update (open access)

Characterization of mixed CH-TRU waste at Argonne-West. A WIPP project update

Argonne National Laboratory is participating in the Department of Energy`s Waste Isolation Pilot Plant (WIPP) Experimental Test Program by characterizing and repackaging mixed contact-handled transuranic waste. Argonne`s initial activities in the Program were described last year at Waste Management `92. Since then, additional waste has been characterized and repackaged, resulting in six bins ready for shipment to WIPP upon the initiation of the bin tests. Lessons learned from these operations are being factored in the design and installation of a new characterization facility, the Enhanced Waste Characterization Facility (EWCF). The objectives of the WIPP Experimental Test Program have also undergone change since last year leading to an accelerated effort to factor sludge sampling capability into the EWCF. Consequently, the initiation of non-sludge operations in the waste characterization chamber has been delayed to Summer 1993 while the sludge sampling modifications are incorporated into the facility. Benefits in operational flexibility, effectiveness, and efficiency and reductions in potential facility and personnel contamination and exposure are expected from the enhanced waste characterization facility within the Hot Fuel Examination Facility at Argonne-West. This paper summarizes results and lessons learned from recent characterization and repackaging efforts and future plans for characterization. It also describes design features …
Date: January 29, 1993
Creator: Dwight, C. C.; Guay, K. P.; Courtney, J. C.; Connolly, M. J. & Higgins, P. J.
Object Type: Report
System: The UNT Digital Library
A coal-fired combustion system for industrial process heating applications (open access)

A coal-fired combustion system for industrial process heating applications

This advanced combustion system research program is for the development of innovative coal-fired process heaters which can be used for high temperature melting, smelting and waste vitrification processes. The process heater concepts to be developed are based on advanced glass melting and ore smelting furnaces developed and patented by Vortec Corporation. The process heater systems to be developed have multiple use applications; however, the Phase III research effort is being focused on the development of a process heater system to be used for producing value added vitrified glass products from boiler/incinerator ashesand industrial wastes. The primary objective of the Phase III project is to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order to evaluate its potential marketability. During the current reporting period, a majority of the effort was spent relining the separator/reservoir and the cyclone melter. The relinings were completed, the cyclonemelter was reinstalled, and the test system was returned to operational status. The wet ESP was delivered and placed on its foundation. The focus during the upcoming months will be completing the integration ofthe wet ESP and conducting the first industrial proof-of-concept test. The other system …
Date: January 29, 1993
Creator: unknown
Object Type: Report
System: The UNT Digital Library
A coal-fired combustion system for industrial process heating applications. Quarterly technical progress report, October 1992--December 1992 (open access)

A coal-fired combustion system for industrial process heating applications. Quarterly technical progress report, October 1992--December 1992

This advanced combustion system research program is for the development of innovative coal-fired process heaters which can be used for high temperature melting, smelting and waste vitrification processes. The process heater concepts to be developed are based on advanced glass melting and ore smelting furnaces developed and patented by Vortec Corporation. The process heater systems to be developed have multiple use applications; however, the Phase III research effort is being focused on the development of a process heater system to be used for producing value added vitrified glass products from boiler/incinerator ashesand industrial wastes. The primary objective of the Phase III project is to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order to evaluate its potential marketability. During the current reporting period, a majority of the effort was spent relining the separator/reservoir and the cyclone melter. The relinings were completed, the cyclonemelter was reinstalled, and the test system was returned to operational status. The wet ESP was delivered and placed on its foundation. The focus during the upcoming months will be completing the integration ofthe wet ESP and conducting the first industrial proof-of-concept test. The other system …
Date: January 29, 1993
Creator: unknown
Object Type: Report
System: The UNT Digital Library
Experimental study of interactions of highly charged ions with atoms at keV energies. Progress report, August 15, 1990--February 15, 1993 (open access)

Experimental study of interactions of highly charged ions with atoms at keV energies. Progress report, August 15, 1990--February 15, 1993

This final progress report summarizes the work carried out during the 29 month period from August 15, 1990 to February 15, 1993 under grant DE-FG02-86ER13519. The following experiments were done. We measured the absolute total and one- and two- electron transfer cross sections for Ar{sup q+} (8{le} q {le} 16) on He and H{sub 2} at 2.3 qkeV, the angular distributions of the scattered projectiles in Ar{sup 8+,9+} collisions, with Ar and Kr at 2.3 qkeV, the electron emissions in low energy Ar{sup q+} on Ar collisions, the recoil ion charge state distributions in low energy Ar{sup q+} -Ar collisions, the absolute total and one-and two-electron transfer cross sections for Ar{sup 8+} on Ar at 2.3 qkeV, and the absolute total and one- and two-electron transfer cross sections for Ar{sup 8+} on Ar as a function of energy. We also used energy gain spectroscopy to study Ar{sup q+} on Ar collisions at 40 and 30 qeV, and time of flight spectroscopy to investigate ionization and dissociation of CO and N{sub 2} in collisions with low energy, highly charged argon ions. In addition, we applied the Goldberger and Watson transition theory to derive transition rates and cross sections for atomic radiative …
Date: January 29, 1993
Creator: Kostroun, V. O.
Object Type: Report
System: The UNT Digital Library
Heterogeneity in c-jun gene expression in normal and malignant cells exposed to either ionizing radiation or hydrogen peroxide (open access)

Heterogeneity in c-jun gene expression in normal and malignant cells exposed to either ionizing radiation or hydrogen peroxide

None
Date: January 29, 1993
Creator: Horio, M.; Collart, F. R. & Huberman, E.
Object Type: Report
System: The UNT Digital Library
PHENIX Conceptual Design Report (open access)

PHENIX Conceptual Design Report

The PHENIX Conceptual Design Report (CDR) describes the detector design of the PHENIX experiment for Day-1 operation at the Relativistic Heavy Ion Collider (RHIC). The CDR presents the physics capabilities, technical details, cost estimate, construction schedule, funding profile, management structure, and possible upgrade paths of the PHENIX experiment. The primary goals of the PHENIX experiment are to detect the quark-gluon plasma (QGP) and to measure its properties. Many of the potential signatures for the QGP are measured as a function of a well-defined common variable to see if any or all of these signatures show a simultaneous anomaly due to the formation of the QGP. In addition, basic quantum chromodynamics phenomena, collision dynamics, and thermodynamic features of the initial states of the collision are studied. To achieve these goals, the PHENIX experiment measures lepton pairs (dielectrons and dimuons) to study various properties of vector mesons, such as the mass, the width, and the degree of yield suppression due to the formation of the QGP. The effect of thermal radiation on the continuum is studied in different regions of rapidity and mass. The e[mu] coincidence is measured to study charm production, and aids in understanding the shape of the continuum dilepton …
Date: January 29, 1993
Creator: unknown
Object Type: Report
System: The UNT Digital Library