Design criteria are described, and test results are presented, for prototype ALS undulator beam position monitors. The design is based on monitors presently in use at NSLS, with modifications to account for the widely varying and large K values of the undulators to be installed at the ALS. In particular, we have modified the design to simplify the thermal engineering and we have explored techniques to suppress the response of the monitors to soft photons, so that the beam position can be determined by measuring the higher energy photons which are better collimated. 4 refs., 8 figs.

This document discusses burnout risk (BOR) power limits which are designed to protect the reactor from a significant release of fission products, due to critical heat flux (CHF) burnout of fuel and target assemblies. At expected operating power levels for the reactor restart, approximately 50% of historical full power, the risk of CHF and attendant burnout is negligible. Flow instability power limits will restrict reactor operation, and flow instability will always occur before CHF. BOR power limits must nevertheless be calculated because they are required by the reactor control computer, (2) Bounding BOR limits have been calculated for the K-14 cycle, to fulfill this requirement, and they are presented in this document. Two sets of BOR limits have been calculated: one applicable for the first subcycle, zero to 30% fuel burnup, and the other for the second subcycle, 30% to 55% fuel burnup.

From 1985 to the present we have studied the behavior of selenium in various habitats and environments at Kesterson reservoir, shifting emphasis as remedial actions altered the physical setting. Investigations have evaluated the efficacy of several remedial alternatives, from innovative techniques relying on the complex geochemical behavior of selenium alternatives, from innovative techniques relying on the complex geochemical behavior of selenium in aquatic environments to conventional excavation schemes. Results of these studies supported two cost-effective remedial measures; drain water deliveries were terminated in 1986 and, in 1988, 1 million cubic yards of soil were imported and used to fill the low lying areas of the former Kesterson Reservoir. To date, these two actions appear to have eliminated the aquatic habitat that caused waterfowl death and deformity at Kesterson from the early 1980's to 1987. Biological, surface water and groundwater monitoring data collected by the USBR indicate that Kesterson is now a much safer environment than in past years when drainage water containing 300{mu}g/l of selenium was delivered to the Reservoir. The continued presence of a large inventory of selenium within the upper portions of unfilled areas of Kesterson Reservoir and immediately below the fill material requires that a continued awareness …

In the project status report for 4/9/90--7/8/90, Table 2 presented update results of a comparative study of coal sample deterioration in several container types including foil laminate bags. This table contained an erroneous entry (foil laminate bag {minus}20 mesh, alkali extraction 65.4% transmittance). The alkali extraction test on {minus}20 mesh coal stored in foil laminate bags for 52 weeks was repeated in duplicate on another bag (after 64 weeks total storage) resulting in a measurement of 96.2% transmittance. This value has been substituted for the erroneous 65.4% value in the corrected copy of Table 2 enclosed with this report. All values of the alkali extraction and Gieseler fluidity tests indicate that the state of preservation of sample in foil laminate bags is excellent. The samples stored by other methods for comparison purposes all showed significant loss in fluid characteristics. One new whole-seam channel sample of the hvAb Pittsburgh seam coal, DECS-12, was collected July 25, 1990 in Greene County, PA. This sample was placed in 30-gallon steel barrels with high-density lid gaskets and purged with argon at the mine. Upon return to Penn State it was promptly processed so that Gieseler fluidity and other routine analyses could be performed.

Considerable amounts of tedious labor are required to manually scan high-resolution 1D slices of two dimensional {gamma}-{gamma} coincident matrices for relevant and exciting structures. This is particularly true when the interesting structures are of weak intensity. We are working on automated search methods for the detection of rotational band structures in the full 2D space using pattern recognition techniques. For nominal sized data sets (1024{times}1024), however, these techniques only become computationally feasible through the use of Fourier Transform methods. Furthermore the presentation of data matrices as images rather than series of 1D spectra has been shown to be useful. In this paper we will present the data manipulation techniques we have developed.

The objective of proposed research is development of catalysts with enhanced slurry phase activity and better selectivity to fuel range products, through a more detailed understanding and systematic studies of the effects of pretreatment procedures and promoters/binders (silica) on catalyst performance.

This document discusses a turbulator which utilizes a heated chemical bath to reduce smearable contamination from small parts and tools. It is comprised of two agitators programmed to automatically alternate the flow of the cleaning solution within the tank in four separate and distinct high velocity flow patterns allowing access to the entire surface area of the part or tool being decontaminated. The turbulator is being evaluated to determine if agitation increases the effectiveness of waste minimization. Testing of the turbulator consisted of evaluation of the Sludgetrap Containment, Tool Cleaning Demonstration, and Coupon Testing. Results so far are that the sludgetrap is effective in containing particles the size of sand, agitation increases the effectiveness of the turbulator, abrasives can replace detergents for waste minimization, and Inconel 625 is more difficult to clean than Type 3041 Stainless Steel.

ASHRAE Standard 62-1989 (Standard 62-89) Ventilation for Acceptable Indoor Air Quality'' is the new heating, ventilating, and air-conditioning (HVAC) industry consensus for ventilation air in commercial buildings. Bonneville Power Administration (Bonneville) references ASHRAE Standard 62-81 (the predecessor to Standard 62-89) in their current environmental documents for required ventilation rates. Through its use, it had become evident to Bonneville that Standard 62-81 needed interpretation. Now that the revised Standard (Standard 62-89) is available, its usefulness needs to be evaluated. Based on current information and public comment, the American Society of Heating, Refrigeration, and Air-Conditioning Engineers (ASHRAE) revised Standard 62-1981 to Standard 62-89. Bonneville's study estimated the energy and cost implications of ASHRAE Standard 62-89 using simulations based on DOE-2.1D, a computer simulation program which estimates building use hourly as a function of building characteristics and climatic location. Ten types of prototypical commercial buildings used by Bonneville for load forecasting purposes were examined: Large and Small Office, Large and Small Retail, Restaurant, Warehouse, Hospital, Hotel, School, and Grocery. These building characterizations are based on survey and energy metering data and represent average or typical construction and operation practices and mechanical system types. Prototypical building ventilation rates were varied in five steps to …

The window industry's commercialization of low-emissivity coatings and low-conductivity gas-filling over the past few years has helped to drastically reduce heat transfer rates through the glazed areas of windows. However, few changes have taken place in the design and construction of window frames and edges, leaving these elements to account for most of the heat transfer through today's state-of-the-art windows. This paper presents design and material requirements for the manufacture of low-conductivity window frames obtained through the use of finite element computer modeling. Such frames will compliment and not degrade today's most energy-efficient insulated glass units. 7 refs., 2 figs., 5 tabs.

Progress report of the Argonne National Laboratory's Nuclear Technology Programs, including R&D in three areas: applied physical chemistry, separation science and technology, and nuclear waste management.

This paper is the final report on DOE-OSS Task ANLE88002 Fast Air Chamber Calorimetry.'' The task objective was to design, construct, and test an isothermal air chamber calorimeter for plutonium assay of bulk samples that would meet the following requirements for sample power measurement: average sample measurement time less than 20 minutes. Measurement of samples with power output up to 10 W. Precision of better than 1% RSD for sample power greater than 1 W. Precision better than 0.010 watt SD, for sample power less than 1 W. This report gives a description of the calorimeter hardware and software and discusses the test results. The instrument operating procedure, included as an appendix, gives examples of typical input/output and explains the menu driven software.

Annual report for the superconductor program at Argonne National Laboratory discussing the group's activities and research. This report describes technical progress of research and development efforts aimed at producing superconducting components based on the Y-Ba--Cu, Bi-Sr-Ca-Cu, Bi-Pb-Sr-Ca-Cu, and TI-Ba-Ca-Cu oxide systems including: synthesis and heat treatment of high-Ta superconductors, formation of monolithic and composite wires and tapes, superconductor/metal connectors, characterization of structures and superconducting and mechanical properties, and fabrication and properties of thin films.

The interfacial area concentration is one of the most important parameters in a thermal-hydraulic analysis of two-phase flow systems based on the two-fluid model. A theoretical foundation of the measurement method for the time averaged local interfacial area using a double sensor probe is presented. Based on this theory, the double sensor resistivity probe was employed for the measurement of local properties of two-phase flow such as the interfacial velocity, local interfacial area concentration and void fraction in vertical air-water bubbly flow. Experimental data are presented on the radial profiles of the void fraction, bubble velocity, bubble chord length and interfacial area concentration at various gas flow rates. In addition to these, some statistical information on turbulent motions of bubbles are presented. Each of the double sensors are checked against the global void measurement using a differential pressure. The result is very satisfactory. Furthermore, the area averaged void fraction, and the interfacial area concentration obtained from the double sensor probe measurement compared very well with the photographic measurements. The results show that the double sensor probe method is accurate and reliable for the local measurements of interfacial area and void fraction in bubbly two-phase flow. Results of the measurement of …

A method of fabricating an electrode for use in a metal chloride battery and an electrode are provided. The electrode has relatively larger and more uniform pores than those found in typical electrodes. The fabrication method includes the steps of mixing sodium chloride particles selected from a predetermined size range with metal particles selected from a predetermined size range, and then rigidifying the mixture. The electrode exhibits lower resistivity values of approximately 0.5 {Omega}cm{sup 2} than those resistivity values of approximately 1.0--1.5 {Omega}cm{sup 2} exhibited by currently available electrodes.

The effectiveness of water sprays to absorb HF releases has been recently demonstrated by extended laboratory and field tests. In this paper computer simulations are presented of the Hawk, Nevada Test Site, series of field tests, along with parametric studies of several cases which have not been studied in the field. The model used in these simulations, HFSPRAY, treats the gas-phase as an Eulerean fluid whereas the spray is described according to the Lagrangian approach by a finite number of drops of varying size and trajectory. HFSPRAY simulates the momentum, mass and energy interactions between a water spray and a turbulent plume of HF in air; it is capable of predicting the flow velocities, temperature, water vapor and HF concentration fields in two-dimensional large-geometries, for spraying in any direction, (i.e., down-flow, inclined-down-flow, up-flow, and co-current horizontal flow). 15 refs., 21 figs.

We discuss the physics of matter that is relevant to the structure of compact stars. This includes nuclear, neutron star matter and quark matter and phase transitions between them. Many aspects of neutron star structure and its dependance on a number of physical assumptions about nuclear matter properties and hyperon couplings are investigated. We also discuss the prospects for obtaining constraints on the equation of state from astrophysical sources. Neuron star masses although few are known at present, provide a very direct constraint in as much as the connection to the equation of state involves only the assumption that Einstein's general of theory of relativity is correct at the macroscopic scale. Supernovae simulations involve such a plethora of physical processes including those involved in the evolution of the precollapse configuration, not all of them known or understood, that they provide no constraint at the present time. Indeed the prompt explosion, from which a constraint had been thought to follow, is now believed not to be mechanism by which most, if any stars, explode. In any case the nuclear equation of state is but one of a multitude on uncertain factors, and possibly one of the least important. The rapid rotation …

Regions of incomplete charge collection, or dead layers'', are compared for Si(Li) detectors fabricated with Au and Pd entrance window electrodes. The dead layers were measured by characterizing the detector spectral response to x-ray energies above and below the Si K{alpha} absorption edge. It was found that Si(Li) detectors with Pd electrodes exhibit consistently thinner effective Si dead layers than those with Au electrodes. Furthermore, it is demonstrated that the minimum thickness required for low resistivity Pd electrodes is thinner than that required for low resistivity Au electrodes, which further reduces the signal attenuation in Pd/Si(Li) detectors. A model, based on Pd compensation of oxygen vacancies in the SiO{sub 2} at the entrance window Si(Li) surface, is proposed to explain the observed differences in detector dead layer thickness. Electrode structures for optimum Si(Li) detector performance at low x-ray energies are discussed. 18 refs., 8 figs., 1 tab.

It is argued that quantum measurements do pose a problem, within the context created by the fundamental aim of science, which is identified as the construction of a cohesive, comprehensive, and rationally coherent idea of the nature of the world in which we live. Models of nature are divided into two classes: (1), those in which there is a selection process that, for any possible measurement, would, if that measurement were to be performed, pick out one single outcome, and, (2), all others. It is proved that any model of class that reproduces the predictions of quantum theory must violate the condition that there be no faster-than-light influences of any kind. This result is used to motivate the study of models in which unitary evolution is maintained and there is no selection of unique outcomes. A consideration of ontic probabilities, historical records, and the form of the mind-brain connection leads to an elaboration of the Everett many-worlds interpretation that appears to provide the basis of satisfactory solution of the measurement problem. 18 refs.

A series of picosecond experiments and computer simulations will be presented that test collisional and hydrodynamic models for vibrational relaxation in liquids. The relationships between isolated binary collision models (IBC) and stochastic dynamics will be presented. The appropriateness of IBC theory in describing vibrational relaxation in liquids will also be discussed.

Semiclassical and quantum mechanical transition state theory is reviewed and two new approaches described. One is general implementation of a semiclassical rate expression that involves the good'' action-angle variables associated with the saddle point (i.e., transition state) of a potential energy surface. The other is an evaluation of a formally exact quantum expression for the rate in terms of Siegert eigenvalues associated with the transition state. Siegert eigenvalues are usually associated with scattering resonances, so their identification with the saddle point of a potential surface, and the expression for the reaction rate in terms of them, is quite an unexpected and novel development. 14 refs.

The production of hydrogen from synthesis gas made by gasification of coal is expensive. The separation of hydrogen from synthesis gas is a major cost element in the total process. In this report we describe the results of a program aimed at the development of membranes and membrane modules for the separation and purification of hydrogen from synthesis gas. The performance properties of the developed membranes were used in an economic evaluation of membrane gas separation systems in the coal gasification process. Membranes tested were polyetherimide and a polyamide copolymer. The work began with an examination of the chemical separations required to produce hydrogen from synthesis gas, identification of three specific separations where membranes might be applicable. A range of membrane fabrication techniques and module configurations were investigated to optimize the separation properties of the membrane materials. Parametric data obtained were used to develop the economic comparison of processes incorporating membranes with a base-case system without membranes. The computer calculations for the economic analysis were designed and executed. Finally, we briefly investigated alternative methods of performing the three separations in the production of hydrogen from synthesis gas. The three potential opportunities for membranes in the production of hydrogen from synthesis …

The ultimate objective of the tasks described in the research agreement was to identify resources primarily, but not exclusively, within New York State that are available for the development of a Center for Advanced Microelectronics Processing (CAMP). Identification of those resources would enable Brookhaven National Laboratory to prepare a program plan for the CAMP. In order to achieve the stated goal, the principal investigators undertook to meet the key personnel in relevant NYS industrial and academic organizations to discuss the potential for economic development that could accompany such a Center and to gauge the extent of participation that could be expected from each interested party. Integrated of these discussions was to be achieved through a workshop convened in the summer of 1990. The culmination of this workshop was to be a report (the final report) outlining a plan for implementing a Center in the state. As events unfolded, it became possible to identify the elements of a major center for x-ray lithography on Lone Island at Brookhaven National Laboratory. The principal investigators were than advised to substitute a working document based upon that concept in place of a report based upon the more general CAMP workshop originally envisioned. Following that …

This report summarizes the Savannah River Site (SRS) groundwater monitoring program conducted in the first quarter of 1990. It includes the analytical data, field data, well activity data, and the other documentation for this program and provides a record of the program's activities and rationale and an official document of the analytical results. The groundwater monitoring program includes the following activities: installation, maintenance, and abandonment of monitoring wells, environmental soil borings, development of the sampling and analytical schedule, collection and analyses of groundwater samples, review of the analytical data and other data, maintenance of the databases containing groundwater monitoring data and related data, quality assurance (QA) evaluations of laboratory performance, and reports of results to waste-site facility custodians and to the Environmental Protection Section (EPS) of EPD.

Its high radiation resistivity and large-area capability are the expected advantages of this material together with its ability to provide a front-end readout electronics in the vicinity of the sensor element. Electrons and holes created by incoming charged particles, X-rays, {gamma} rays, are drifted by the electric field inside a-Si:H diodes and this carrier movement induces signal charges on electrodes. Charge collection and signal generation process are analyzed in terms of carrier mobilities, lifetimes and electric field. Charge collection in thick a-Si:H diodes is often limited by deep-level trapping of carriers during transit and a finite charge integration time required for single particle counting in some applications and sometimes by volume recombination of carriers for detecting heavily-ionizing particles such as {alpha} particles. The charge collection process is also strongly affected by the non-uniform electric field profiles in a-Si:H diodes caused by the fixed space charges inside the material under reverse-bias. Signal generation due to a weak light pulse irradiating each end of a thick diode is measured as a function of a reverse-bias and it gives a valuable information about the fixed space charges. Field profiles can be manipulated by either doping, electrode geometry, or combination of both to improve …