From introduction: "This report presents the apparent viscosities of supernate-sludge slurries prepared synthetically to simulate the conditions known to exist in the waste storage tanks, but with fission products and plutonium absent."

From statement of objectives: The purposes of the work described in this report are to provide data useful for designing and operating the dissolver solution clarification equipment to be installed in the Redox production plant.

Zirflex cladding waste is to be neutralized to pH 10 before transfer to waste storage tanks. This treatment causes the precipitation of zirconium oxide or hydroxide, which may lead to flow difficulties during transfer. The purpose of this investigation was to determine the physical properties and flow characteristics of the neutralized slurry to assist in the selectin of satisfactory transfer equipment and storage conditions.

This report describes the work carried out in 321 Building semiworks equipment, to define the factors contributing to high corrosion-product contamination and presents recommendations for reducing the impurity level to meet current specifications (maximum of 200 parts total metals per million parts U).

The purpose of the Analytical Laboratory Manual is to assemble the basic procedures to be used for the analyses of materials employed within the Fuels Preparation Department. The methods appear in detailed steps suitable for laboratory use. This document replaces the "Essential Material Analytical Manual, " HW-25375 and "Metal Preparation Analytical Manual," HW-30862.

Abstract: "The sensitivity to fast neutrons of a CP Meter ionization chamber of the type used for health physics beta and gamma survey measurements has been investigated."

Report discussing changes in parameters regarding Sutton's diffusion hypothesis, which is used in calculations of plant stacks' atmospheric pollutant distribution. An explanation of the computation and results are given.

Three types of stainless steel (309 SCB, Carpenter 20, 304-L) were exposed to both the liquid and vapor phase of each of three types of solutions. The time of exposure totaled ten days during which the specimens were cleaned and weighed periodically. The three synthetic D-12 waste solutions contained respectively chrome-high chloride, chrome-low chloride and high chloride sans chromium. The solutions were renewed at each weighing.

Report describing the thermal hydraulics facilities at Hanford Laboratories as well as its operation, equipment, and systems.

Series of isothermal transformation studies for improvement in fabrication and reactor performance of uranium fuel elements.

In answer to the question, "How well do we know the composition of the fuel material for the PRTR start-up tests?", the analytical data on the PRTR fuel elements and other fuel elements which were fabricated by similar processes was gathered and analyzed. The results of this analysis are presented.

The wrist badge provides a dosimeter that is useful in estimating the radiation dose to the hands and forearms. Its new shield system gives good gamma and slow neutron dose discrimination with duPont 552 film packets. The film can be evaluated using the present technique and equipment. Several attempts to develop hand dosimeters have been made. Finger rings using film have been used routinely but have not been entirely satisfactory for all situations. The wrist badge was developed to provide improved gamma and slow neutron dose measurement of the upper extremities under certain appropriate conditions. The wrist badge dosimeter is not a substitute or alternate for finger ring dosimeters but is a necessary dosimeter for some extremity exposure situations.

Report reviewing a study regarding the chemical properties, appearance, texture, homogeneity and slurrying ability of waste metal sludge. The settling rates of sludge-supernatant slurries is also discussed.

Abstract: "A method has been established for the estimation of volatile organic acids in aqueous process solutions containing UNH, nitric acid, ANN, sodium dichromate and small amounts of hexone. The practice is to distill a 400 ul or 500 ul sample in the presence of an excess of phosphoric acid and ferrous sulfate under a high vacuum; a special apparatus utilizing a receiver cooled with a dry ice-isopropanol mixture is employed. The distillate is taken up in isopropanol and then titrated potentiometrically with standard potassium hydroxide solution. Since nitric acid and organic acids are present, two end points are observed. The potassium hydroxide added between these end points is equivalent to the organic acids. In the titration, CO2 from the atmosphere or in the potassium hydroxide is a source of error. The former was avoided and correction was made for the latter."

Abstract: "A new method of determining 8-hydroxyquinoline by titration with electrolytucally-generated bromine has been developed. Results show good precision in the range 0.4 mg. to 1.6 mg. total 8-hydroxyquinoline, with 99% confidence limits of less than +/- 2%. An electronically-regulated constant current source, required by the method, is described. A new indicator system with high sensitivity to free bromine is discussed."

The uranium recovery processes which are in operation or under construction at the present time--TBP, Redox and Purex--yield an aqueous uranyl nitrate solution as the recovered uranium product. For conversion of this recovered uranium to UF6 for feed to the gaseous diffusion plants, the uranyl nitrate in the solution is concentrated with or without prior organic stripping, calcined to UC3, reduced to UO2 with hydrogen, hydro-fluorinated to UF4 with RF, and finally fluorinated to UF6 with elemental fluorine.

The following document describes data collected from a 14-month period of analyzing crustaceans containing radioactivity. Provided is information based on the change of radioactivity through seasonal changes.

For some time, the need has been recognized for an X-ray diffraction unit applicable to studies concerning the crystallographic characteristics of pile irradiated materials. Except for studies involving specimens of low activity, it has been impossible in the past to investigate materials which emit intense beta and gamma radiations. The exact type and degree of irradiation damage to high activity materials has been largely a matter of theoretical conjecture. The object of this report is to describe an X-ray diffraction spectrometer that can be used to collect crystallographic data from irradiated materials.

One of the primary reasons for operating the high pressure KER loops is to obtain information concerning water quality control characteristics for recirculating water cooled reactors. The KER-1 loop is predominantly carbon steel and approximates the water quality conditions specified for the New Production Reactor (NPR).

Introduction: "Evidence of masonite deterioration in test hole plugs was interpreted to mean that a previous estimate of the minimum lifetime of the masonite in a Hanford biological shield might be somewhat optimistic. The importance of understanding the effects of radiations on masonite for both present and future pile shields dictated that masonite be sampled from an operating pile shield and studied. The results and techniques are discussed in the following sections of this report."

The first of two general methods are discussed based on the removal of the thin layer of aluminum to which graphite adheres. Two electro-polishing techniques, an electrolytic etch, an anodization-deanodication cycle and two chemical etches are described.

In the Sulfex process, stainless steel cladding, generally 304-L, is removed from fuel elements by dissolution in boiling four to six molar sulfuric acid. When cladding removal is complete, the decladding solution is removed is removed to waste. The exposed fuel cores are rinsed and dissolved in nitric acid.

The transfer or circulation of raw dissolver solutions containing gross particulate matter presents many problems not easily overcome by standard pumping equipment. In April of 1956 the HAPO concept of a modified Archimedes screw pump was developed. Two basic models, externally powered and driven through extended shafts, were constructed and tested. Operation of these preliminary models was so satisfactory that a third unit, integrally formed into drive motor, was built and placed in extended life test. This report describes construction and testing of the third and final model.

The following report examines a rapid method used to eliminate the possibility of explosive perchlorate-organic mixtures in a control laboratory in order to determine radiocesium. These methods include the usage of chloroplatinic acid as a precipitate of radocesium.