Technical report describing two experiments performed to compare the amounts of fission gases swept out of UNH solution with those amounts swept out of PU solution under idential condiditons. The charge wire technique was used. The essential date and the results are given in tables in the report.

Report outlining a study that tested the use of colorimetric methods with high concentration phosphoric acid as a solvent for rapid analysis of mixtures of T^+4 and T^+6.

Abstract. to estimate the oxygen picked up by thorium in casting a rapid method of running the acid insoluble content was developed. the quickest procedure consists of reacting with mixed acids, fuming with perchloric and filtration to separate the "free" thorium from the "combined". The precipitate is ignited and weighed as thorium dioxide.

Introduction. the conventional procedures of analysis for uranium and manganese can be employed in the analysis of alloys of these metals. The alloys are reacted with perchloric acid and hydrogen peroxide, fumed to remove any chloride ions, diluted to volume and aliquots analyzed by redoximetry.

Introduction. It has been known for a long time that thorium is precipitated by oxalic acid in acid solutions, but a survey of the literature showed no study of the limits of the acidity and oxalic acid excess which yield quantitative results. V. I. Spitzin reports on the solubility of thorium oxalate in varying concentrations of several acids, but the effect of an excess oxalic acid is not included. Since solutions are sometimes presented for analysis that contain more than the recommended two per cent mineral acid, it would be advantageous to be able to quantitatively remove the thorium without otherwise altering the solutions. This was especially of interest in solutions containing bismuth, since it was hoped that some amounts of thorium could be precipitated in nitric acid solutions containing large quantities of bismuth. In removing the bismuth, first by a bismuth oxychloride precipitation, thee is every opportunity for carrying of the thorium.

Summary: A set of conditions is described for a ten minute determination of water in TO₃ by ignition and absorption of the evolved water in magnesium perchlorate. Complete conversion to T₃O₃ is obtained under these conditions, so that total loss on ignition and total T (plus non-volatile impurity) content may also be obtained. It has been found unnecessary to employ Cu foil to prevent interference by nitrates, which may be present with a nitrate/water ratio as high as 5, and in an amount that does not exceed 100 mg.

Abstract: The velocity of sound at the time of 100-ton shot at Trinity was measured to be 1116.1 ft/sec. Values of blast pressure computed from the excess velocity are given, but are not considered as reliable.

Summary: "Carbides of Th, Ta, Be, and Zr have been prepared from the oxides of these metals by reaction with graphite in the induction furnace. Methods for the analysis of these compounds are given."

Abstract. A summary of the effect of metal, carbon, silicon, and oxygen impurities upon the various sulfide refractories is given and the proper procedures for elimination of the impurities are discussed. CeS which is properly prepared can be handled in air without danger of catching fire or appreciable oxidation. 650 satisfactory crucibles have been made to date using sulfides which were screened and pressed in air with less than 0.5% oxygen pickup. The other cerium and thorium sulfides are even more inert to oxidation than is CeS. Phase diagram possibilities are discussed for the cerium and thorium sulfide and oxy-sulfide systems. Further study of the ThS has shown that ThS crucibles are the highest melting and least volatile of the sulfide crucibles and ThS may be used for remelting of some metals up to 2000 degrees C. ThS crucibles appear to be the most suitable containers for metal reductions.

This paper reports work carried out to determine the factors necessary to give a filterable precipitation and determine the effects of these factors on the quantitativeness of the precipitation, and how any tendency to increase the tuballoy solubility may be overcome.

Abstract: "In the low temperature precipitation of tubanyl peroxide from Beta gunks, process modifications are described which minimize the effect of iron on decompisition of H2O2. These include the addition of excess H2O2 to the slurry only after attaining a reduced temperature, the use of malonic and acetic acid complexing when the H2O2 is added at room temperature, and the use of wetting agents when the entire process is carried out at 2 C."

The following report presents data from the investigations on discovering factors affecting the precipitation of tubanyl peroxide from Alpha and Beta gunk solutions at reduced temperatures.

From abstract: "A chamber was constructed with three electrodes dividing the space into two regions of 800 c.c. The surfaces of one of these were coated with boron carbide. With opposite potentials on two electrodes, ion currents to the collecting electrode due to gamma rays were practically cancelled and ion currents due to alpha rays induced by slow neutrons were measured."

Technical report with short reports on (1) Effect of radiation on water and aqueous systems; (2) Gas evolution from uranyl solutions; (3) Effect of radiation on solid compounds; (4) Instruments; and (5) Scattering.

Technical report with short reports covering (1) Effect of radiation on water and aqueous systems; (2) Effect of neutrons on graphite; (3) Effect of radiation on solid compounds; and (4) Scattering, stopping-power, ion-pair production, etc.

Abstract. thorium can be precipitated as a salt of p-dimethylaminoazophenylarsonic acid at a pH of about 1.5. the precipitate, collected on a sintered glass filter is washed with dilute ammonium hydroxide to dissolve the dye. the amount of thorium is determined by measuring the concentration of the dye spectrophotometrically at a wavelength of 450 millimicrons. Zirconium, which interferes, can be separated and determined using the same reagent in strong hydrochloric. the behavior of thorium metal upon treatment with various acids and upon fusion withKHSO4 is described. three satisfactory procedures are given for dissolving the metal with sulfuric acid, phosphoric acid, and by a potassium hydrogen sulfate fusion. The laboratory was presented with the problem of analyzing for a large number of elements in O2 metal. the results of a systematic study of methods for effecting solution of the metal are offered here since they may be of some interest and use to other laboratories. The four methods which effected complete solution of the metal are (1) Sulfuric acid method; (2) Fusion method; (3) Phosphoric acid method; and (4) Nitric acid-hydrofluoric acid method.

This report discusses the production of ceramic ware through the process of slip-casting. The report separately describes the processes of creating zirconia ware, beryllia ware, alundum ware, thoria ware, and specially shaped ceramic ware.

The following report provides a general summary of some methods that could be used to convert hexafluoride into tetrafluoride, but is mainly devoted to the work done on the conversion of tetrafluoride to tetrachloride.

"In order to determine low concentrations of vanadium in TF₄ spectrographically, an investigation was conducted to ascertain conditions necessary for a reproducible procedure. The study was made to find a method of direct analysis of TF₄ to eliminate the time factor of any error introduced by the conversion of TF₄ to T₃O₈. All available methods of excitation were investigated."

Abstract. Fluorides and other halides are hydrolyzed completely by passing a rapid stream of superheated steam over the sample near 1000 degrees C in a specially designed platinum reaction tube. The steam and hydrogen halide are condensed by cooling, and the resulting distillate titrated with standard sodium hydroxide solution. The fluorides and chlorides of the light metals, hitherto thought of as very difficult to hydrolyze, are mixed with U3O8, or other metallic oxides, which reacts with the products of hydrolysis, thus shifting the equilibrium so that the reaction is complete in a comparatively short time. A description of the apparatus, including photographs, the recommended method of procedure, hydrolysis rate graphs, and suggestions for further applications of the method are given.

From introduction: The present report is a summary of the experimental work on a laboratory scale to date involving the ammonia reduction and the one step TF4 processes.

Report discussing a study on the effect of several ions on the fluorescence on uranium. At the time this report was published, the study was incomplete.

Apparatus, field layout, miscellaneous testing, and the method of analysis of a 100-ton test at Trinity.

This paper is based off of an operation of a recording tape scaler, which records pulses from a counter or scaler upon a tape as a function of time. With the recording tape scaler, the interval between pulses of counter or scaler is measured in this report.