Niobium-Tin-Aluminum Alloy Studies (open access)

Niobium-Tin-Aluminum Alloy Studies

From Abstract : "A proposed constitutional diagram was developed from equilibrium data obtained for the niobium-tin binary alloy system. ... Alloying Nb3Sn with Nb3Al appears to raise the zero field superconducting transformation temperature of Nb3Sn slightly."
Date: February 1963
Creator: Ellis, Thomas Gordon & Wilhelm, Harley A.
System: The UNT Digital Library
Least Structure Solution of Photonuclear Yield Functions (open access)

Least Structure Solution of Photonuclear Yield Functions

From Abstract : "A new method for the solution of experimental photonuclear yield functions for cross sections is presented. ... The resulting cross sections are compared to the assumed cross sections used to derive the trial yield function."
Date: 1963
Creator: Cook, B. C.
System: The UNT Digital Library
Spectrophotometric Determination of Scandium with Arsenazo (open access)

Spectrophotometric Determination of Scandium with Arsenazo

From Introduction : "After a study on the determination of rare earths with arsenazo, it was thought worthwhile to attempt a spectrophotometric determination of scandium with the same reagent."
Date: 1963
Creator: Onishi, Hiroshi & Banks, Charles V.
System: The UNT Digital Library
Crystalline Field Splittings in Holmium and Dysprosium Ethylsulfates (open access)

Crystalline Field Splittings in Holmium and Dysprosium Ethylsulfates

From report : "It has become apparent that pragmatic resonance data alone are insufficient to correctly evaluate crystal field parameters for rare-earth ethylsulfates, and that heat capacity data above 20°K are a useful aid in determining whether low lying levels obtained by absorption spectroscopy have been correctly identified."
Date: March 1963
Creator: Spedding, F. H.; Gerstein, B. C.; Haas, W. J.; Phillips, E. & Sutherland, W. L.
System: The UNT Digital Library
Magnetostriction in Dy and Ho (open access)

Magnetostriction in Dy and Ho

From Abstract : "Phenomenal magnetostriction has been observed in Dy and Ho single crystals. ... [The} magnetostriction curve showed three slightly developed knees which agree well with the knees observed in the magnetization data for Ho previously reported."
Date: 1963
Creator: Legvold, S.; Alstad, J. & Rhyne, J.
System: The UNT Digital Library
The Inference of Adsorption from Differential Double Layer Capacitance Measurements (open access)

The Inference of Adsorption from Differential Double Layer Capacitance Measurements

From Abstract : "Dependence of boundary tension and capacitance at the mercury-aqueous 0.1 N HClO4 interface on polarization and organic solute concentration were determined for the colutes n-amyl alcohol and phenol. ... An earlier treatment proposed by this Laboratory based on a (non-thermodynamic) assumption of linear variation of surface charge density with coverage appears adequately justified for inference of fractional surface coverages near the electrocapillary maximum, but must be considered approximate for evaluation of molar area at full coverage in cases where linear variation of charge with coverage has not been demonstrated."
Date: April 26, 1963
Creator: Hansen, Robert S.; Kelsh, Dennis J. & Grantham, D. H.
System: The UNT Digital Library
Mass Spectrometric Evidence for the Pyridoxal-Leucine Reaction Mechanism (open access)

Mass Spectrometric Evidence for the Pyridoxal-Leucine Reaction Mechanism

From Abstract : "The mass spectrum of leucine-dn, prepared by the reaction of pyridoxal with excess leucine in D2O medium, has been established using the crucible source techniques. ... The reaction can be used for the selective α, β-deuteration of amino acids other than leucine.
Date: May 3, 1963
Creator: Junk, G. A. & Svec, H. J.
System: The UNT Digital Library
Reinvestigation of the CC Stretching and CH3 Rocking Assignments In Isopropyl and tert-Butyl Halides (open access)

Reinvestigation of the CC Stretching and CH3 Rocking Assignments In Isopropyl and tert-Butyl Halides

From report: "In a series of paper (1-3) Sheppard has analyzed the vibrational spectra of simple alkyl halides. During the course of an investigation of the spectra of similar alkyl thiocyanates certain anomalies appeared in the assignments of the CC stretching and methyl rocking vibrations in isopropyl and tert.-butyl halides."
Date: May 3, 1963
Creator: Hirschmann, R. P. & Kniseley, R. N.
System: The UNT Digital Library
Isotopic Composition of Vanadium From Organic Sources (open access)

Isotopic Composition of Vanadium From Organic Sources

From Abstract : "The V50/V51 ratios of vanadium from the ascidians, Ciona intestinalis and Ascidia ceratodes were measured, on an absolute basis, by comparison with a reference using a CEC Model 21-220 180° mass spectrometer."
Date: 1963
Creator: Calellen, Jennings; Flesch, Gerald D. & Svec, Harry J.
System: The UNT Digital Library
Thermal Conductivity of Silicon and Iron From 300 to 1400°K (open access)

Thermal Conductivity of Silicon and Iron From 300 to 1400°K

From Abstract : "The thermal diffusivities of pure silicon and of Armco iron have been measures from 300 to 1400°K. The specific heats of the same materials have been measured over the same temperature range."
Date: January 1, 1963
Creator: Klein, A. H.; Shanks, H. R. & Danielson, G. C.
System: The UNT Digital Library
The Uranium-Rhenium Alloy System (open access)

The Uranium-Rhenium Alloy System

Abstract The phase diagram of the uranium-rhenium alloy system is presented along with a discussion on transformation kinetics of the uranium solid solutions. The phase diagram is of the double eutectic type with the intermediate phase having the composition URe2. This phase exhibits allotropy at 180°C and melts congruently at 2200°C. URe2 reacts sluggishly with the uranium solid solutions below 750°C to form the peritectoid compound U2Re. Eutectic reactions occur at 1105° and 2105°C at respective compositions of 10.5 and 65.5 wt. % Re. Eutectoid reactions occur at 643° and 681°C at compositions of 1.4 and 6 wt. % Re, respectively. The maximum solubility of rhenium in α uranium is about 0.4 wt. % at 643°C and in β uranium is 1.9 wt. % at 681°C. The solubility of rhenium in γ uranium is 6 wt. % at 681°C and increases to about 7 wt. % at 975°C. The solubility of uranium in rhenium is 0.6 wt. % at room temperature with little variation up to 2000°C. Alloys of β and γ uranium containing more than about 1.2 and 7 wt. % Re respectively, can be readily supercooled to room temperature. Rapid cooling of γ alloys containing less than about …
Date: January 14, 1963
Creator: Jackson, R. J. (Robert James), 1929-; Williams, D. E. & Larsen, W. L.
System: The UNT Digital Library
Thermodynamics of Formation of ThMg2 (open access)

Thermodynamics of Formation of ThMg2

Literature review on the discovery, experiments on, and applications of the compound ThMg2.
Date: January 1963
Creator: Novotny, D. B. & Smith, J. F.
System: The UNT Digital Library
The Solubility of Holmium in Copper, Silver, and Gold (open access)

The Solubility of Holmium in Copper, Silver, and Gold

From Abstract: "The solid solubility of holmium in copper, silver, and gold was determined using metallographic techniques. The composition of the first intermetallic compound in these systems was found to be Cu4Ho, Ag7Ho2, and Au3Ho. These compounds form eutectics with the solvent metals which melt at 868, 787, and 778°C respectively."
Date: January 1963
Creator: Wunderlin, W. J.; Beaudry, B. J. & Daane, A. H.
System: The UNT Digital Library
Propagation Characteristics of Capillary Ripples II. Instrumentation for Measurement of Ripple Velocity and Amplitude (open access)

Propagation Characteristics of Capillary Ripples II. Instrumentation for Measurement of Ripple Velocity and Amplitude

Technical report. From Abstract : "An instrument for measuring the propagation velocity of capillary ripples to within 0.3% and for measuring the amplitude of such ripples to within 1 to 10% (depending upon amplitude) was designed and constructed. The principle components of the instrument were a Teflon Langmuir trough (with provision for automatic recording of compression data); generating and receiving probes consisting of a thin rod and a razor blade respectively mounted so that the rod and razor edge were parallel and accurately placed in the surface to be studied."
Date: January 1963
Creator: Mann, J. Adin, Jr. & Hansen, R. S.
System: The UNT Digital Library
Indicator Transition Ranges in Tertiary Butyl Alcohol (open access)

Indicator Transition Ranges in Tertiary Butyl Alcohol

Technical report. From Abstract : "The approximate transition ranges of a number of common indicators in tertiary butyl alcohol are given in terms of potentials measured with a glass-two phase salt bridge-SCE electrode system. Potential control was obtained by the addition of a sulfuric acid-malonic acid mixture and titration with tetrabutylammonium hydroxide. In general, the sulfonphthaleins are recommended for the titration of strong to medium strength acids, and Azo Violet, o-nitroaniline, and a p-nitro-p-aminoazobenzene for very weak acids."
Date: 1963
Creator: Marple, Leland W. & Fritz, James S.
System: The UNT Digital Library
The Crystal Structure of Bismuth Subchloride (open access)

The Crystal Structure of Bismuth Subchloride

Technical report. From Abstract : "The stoichiometric formula of the lower chloride in the BiCl3-Bi system has been established as Bi12Cl14 (BiCl1.167) through a dingle crystal, X-ray determination of its structure. ... Previous studies of the Bi-Cl3-Bi system are re-examined in the light of the structural results."
Date: January 10, 1963
Creator: Hershaft, Alex & Corbett, John D.
System: The UNT Digital Library
Solution of Metals in Their Molten Salts. Some Manganese, Chromium, Uranium and Antimony Systems (open access)

Solution of Metals in Their Molten Salts. Some Manganese, Chromium, Uranium and Antimony Systems

Technical report. From Abstract : "Preparations of high purity MnCl2, CrCl2, CrI2, UBr4, UI3 and Sb4S3 are described; the melting points obtained for CrI2 (868°) and Sb2S3 (559.5°) are significantly higher than previously reported. The small solubilities of manganese and chromium in the respective halides studied were characterized primarily by the depression of the freezing points of the salts by excess metal."
Date: January 1963
Creator: Corbett, John D.; Clark, Ronald J. & Munday, Theodore F.
System: The UNT Digital Library
Acid-Base Reactions in Fused Salts. Dichromate-Bromate Reaction (open access)

Acid-Base Reactions in Fused Salts. Dichromate-Bromate Reaction

Technical report. From Abstract : "The reaction of Lewis acid and base, Cr2O7= and BrO3_, in fused KNO3 - NaNO3 mixtures has been shown to involve an equilibrium followed by a slow decomposition to gaseous products."
Date: February 1963
Creator: Duke, F. R. & Schlegel, James
System: The UNT Digital Library
The Strontium-Strontium Hydride Phase System (open access)

The Strontium-Strontium Hydride Phase System

Technical report. From Abstract : "The Sr-SrH2 phase diagram was studied by thermal analysis, chemical analysis of equilibrated phases and X-ray diffraction. The maximum solubility of SrH2 in strontium metal is 38 mole % at the peritectic temperature of 880°C. Strontium metal undergoes an allotropic transformation at 555°C and melts at 768°C. A second transformation was found, at about 240°C, in samples containing hydrogen. Strontium hydride was found to have an allotropic transformation at 855°C."
Date: February 20, 1963
Creator: Peterson, D. T. & Colburn, R. P.
System: The UNT Digital Library
High Pressure Research at Low Temperatures (open access)

High Pressure Research at Low Temperatures

Two principle reasons exist for the extension of high pressure research to temperatures near absolute zero. First, the comparison of certain data with theory (such as the pressure-volume relationship) is more meaningful if the effects of thermal vibrations can be ignored. Second, there are phenomena which can be studied only at low temperatures. These include superconductivity, the properties of solid helium and other inert gases, some electronic phenomena, etc.
Date: February 24, 1963
Creator: Swenson, C. A.
System: The UNT Digital Library
A Study of the Rare Earth Metal Propionate Complexes (open access)

A Study of the Rare Earth Metal Propionate Complexes

Technical report. From Abstract : "The first two successive formation constants of the trivalent rare earth metals with the proportionate ligand were determined by a potentiometric method. A comparison was made of the trends in the stability constants of the proportionate ligand as one proceeds through the rare earth series with the trends observed for several other ligands. Attempts to explain some of the trends have been summarized."
Date: January 1963
Creator: Paul, George Stephen & Powell, Jack E.
System: The UNT Digital Library
High Purity Calcium (open access)

High Purity Calcium

Technical report. From Introduction : "For more than a century, methods employed in preparing calcium were based largely on electrowinning and the most successful were based on [Sir Humphrey] Davy's process. ... In general, the metal was of adequate quality for the industrial applications of the time, and although by 1940 some strides had been made in the purification of calcium, interests in the better grades of the metal were limited essentially to experimental work of academic concern."
Date: April 3, 1963
Creator: Wilhelm, H. A. & Carlson, O. N.
System: The UNT Digital Library
Design and Test of a Diaphragm Pump for Liquid Metals (open access)

Design and Test of a Diaphragm Pump for Liquid Metals

Technical report. From Abstract : "Details are provided on the construction and operation of a two-stage diaphragm pump successfully used for the first time in liquid metal service. From the results of 5,376 hr. test of the pump it was concluded that it is well suited to the pumping of liquid metals at low flow rates where pulsating flow can be tolerated and also where remote operation is required. Operating temperatures and pressures are limited only by the availability of suitable materials of construction."
Date: April 12, 1963
Creator: Westerheide, D. E. & Clifford, J. C.
System: The UNT Digital Library
Measurement of Thermal Properties by the Arc Image Furnace (open access)

Measurement of Thermal Properties by the Arc Image Furnace

Technical report. From Abstract : "A number of imaging furnace systems and sources are discussed with emphasis on the carbon arc image furnace. Several potential applications of the carbon arc image furnace in high temperature research are described and a new method of heat capacity determination is discussed."
Date: April 16, 1963
Creator: McMahon, W. R. & Wilder, D. R.
System: The UNT Digital Library