The Equation of State of Solids at Low Temperature (open access)

The Equation of State of Solids at Low Temperature

Technical report describing and evaluating the the three experimental methods for obtaining equation of state data at low temperatures; (1) approximate measurement of the PVT relationship by a piston-displacement technique, (2) the measurement of a heat capacity at constant volume as a function of molar volume and temperature, and (3) direct measurement of the pressure variation of the elastic constants using ultrasonic techniques. X-ray methods also might be applicable.
Date: October 13, 1961
Creator: Bernardes, N. (Newton), 1931- & Swenson, C. A.
System: The UNT Digital Library
Boiling Points and Surface Tensions of Mixtures of Benzyl Acetate With Dioxan, Aniline and Meta-Cresol (open access)

Boiling Points and Surface Tensions of Mixtures of Benzyl Acetate With Dioxan, Aniline and Meta-Cresol

Technical report. From Abstract : "Accurate measurements on boiling points and surface tensions of mixtures of benzyl acetate with dioxan, aniline and meta-cresol over the entire range of concentration are reported. The results have been analysed in terms of quasi-crystalline model which is partially successful in representing the composition dependence of heats of mixing, boiling points and surface tension except for composition dependence of boiling points of benzyl acetate and meta-cresol."
Date: September 13, 1962
Creator: Katti, P. K. & Chaudhri, M. M.
System: The UNT Digital Library
The Weighting of Intensities (open access)

The Weighting of Intensities

Technical report. From report : "The method of least squares refinement is based on the prediction of the theory of errors that, if the errors of the observed structure factors follow the Gaussian distribution, the most nearly correct atomic parameters will be those which result in the minimization of the residual R = Σi [√wi(|Fo| - |Fc|)i]2."
Date: December 13, 1962
Creator: Hershaft, Alex & Corbett, John D.
System: The UNT Digital Library
The Crystal Structure of Bis(Meta-Chlorobenzoyl) Methane (open access)

The Crystal Structure of Bis(Meta-Chlorobenzoyl) Methane

Technical report. From Abstract : "The crystal structure of bis(meta-chlorobenzoyl) methane has been determined by three dimensional anisotropic least squares refinement of scintillation counter data. The molecule was found to be nearly planar with a maximum deviation from the least squares molecular plane of 0.068Å and an average deviation of 0.023Å. Fourier transform techniques to locate phenyl rings provided the key to the structure determination. The intramolecular bond distances and thermal parameters of the oxygen atoms support a resonant, enol ring with a symmetric, intramolecular hydrogen bond. The structure confirms conslusions from the structure of bis(meta-bromobenzoyl) methane where the symmetry of the molecule was forced by the crystal symmetry."
Date: December 13, 1962
Creator: Engebretson, Gordon R. & Rundle, R. E.
System: The UNT Digital Library
Formation Constants of the Complex Species Formed by Interaction of Rare-Earth Nitrilotriacetate Complexes with an Equivalent Amount of Base (open access)

Formation Constants of the Complex Species Formed by Interaction of Rare-Earth Nitrilotriacetate Complexes with an Equivalent Amount of Base

From abstract: "The formation constants of the RChOH- species, formed by interaction of individual rare-earth nitrilotriacetate species and KOH at 25°C and an ionic strength of 0.1, have been determined by the potentiometric method, i.e., computed from the pH values of equilibrium mixtures containing varying proportions of rare-earth complex and base. The relationship of these constants to the ion-exchange separation of rare earths at high pH has been discussed."
Date: April 13, 1962
Creator: Guptak, Asim K. & Powell, Jack E.
System: The UNT Digital Library