Knowledge of the rheological properties of saturated solutions containing solid particles is very important in nuclear waste management technology. For example, the nuclear waste in the Hanford Site high-level radioactive waste tanks contains strong electrolyte solutions with a high concentration of solids. Previous attempt using rotational viscometers to determine the rheology has shown unusual thixotropic and shear thinning behaviors with a lack of reproducibility. Using falling-ball rheometry, the rheology of the undisturbed simulant may be determined with much better reproducibility. In this study, a well-mixed simulant which has similar chemical composition to the actual waste will be tested. Falling-ball size and density will be varied to get data in a wide range of shear rates. To determine the rheogram, several methods will be tried to match the observed data. Based on these tests, a rheogram can be determined from the model and its best-fit parameters. The simulant shows shear-thinning behavior and a yield stress. This would suggest a H-B model. But when fitting to one of the simulants which showed a very low yield stress, the predictions assuming no yield and assuming yield resulted in no improvement in the fit when assuming yield.

The Russian-American Gallium solar neutrino Experiment (SAGE) began the second phase of operation (SAGE II) in September of 1992. Monthly measurements of the integral flux of solar neutrinos have been made with 55 tonnes of gallium. The K-peak results of the first five runs of SAGE II give a capture rate of 76{sub {minus}18}{sup +21} (stat) {sub {minus}7}{sup +5} (sys) SNU. combined with the SAGE I result, the capture rate is 74{sub {minus}12}{sup +13} (stat) {sub {minus}7}{sup +5} (sys) SNU. This represents only 56%--60% of the capture rate predicted by different Standard Solar Models.

This project investigates the roles of various aqueous soluble catalyst precursors containing various anions, specifically acetate (CH{sub 3}COO{sup {minus}}), chloride (Cl{sup {minus}}), nitrate (NO{sub 3}{sup {minus}}), sulfate (SO{sub 4}{sup 2{minus}}) and carbonate (CO{sub 3}{sup 2{minus}}) on the surface electrical properties of coal and seeks to understand the effects of these salts on the adsorption, dispersion and activities of calcium and potassium. The current report discusses the reactivities the lignite derived char catalyzed by {approximately}0.05 - 0.07 %wt. potassium. The catalytic compounds used were potassium acetate, potassium carbonate, potassium chloride, potassium nitrate, and potassium sulfate. The initial concentration of each salt solution from which potassium was ion-exchanged onto the coal was 0.001 mol/L and the metal was ion-exchanged onto the coal at the approximate pHs of 2, 6 and 9. Although the potassium contents in the chars were similar ({approximately}0.05 - 0.07 %wt.), a wide spread of char reactivities were observed. Char gasification ranged from > 90 %wt. to < 20 %wt. At this time, no general correlation between char reactivities, catalyst type, catalyst precursor anions or catalyst loading pH is obvious. However, the data are currently being analyzed in terms of zeta potentials to determine the effect, if any, of …

This report discusses the following topics related to the Superconducting Super Collider: Cryogenic system -- general requirements; cryogenic system components; heat load budgets and refrigeration plant capacities; flow and thermal characteristics; process descriptions; cryogenic control instrumentation and value engineering trade-offs.

This paper shows an analysis of the applicability of an adsorption system for electric vehicle (EV) air conditioning. Adsorption systems are designed and optimized to provide the required cooling for four combinations of vehicle characteristics and driving cycles. The resulting adsorption systems are compared with vapor compression air conditioners that can satisfy the cooling load. The objective function is the overall system weight, which includes the cooling system weight and the weight of the battery necessary to provide energy for air conditioner operation. The system with the minimum overall weight is considered to be the best. The results show the optimum values of all the variables, as well as temperatures and amounts adsorbed, for the adsorption and desorption processes. The results indicate that, for the conditions analyzed in this paper, vapor compression air conditioners are superior to adsorption systems, not only because they are lighter, but also because they have a higher COP and are more compact.

This report describes a hybrid vehicle simulation model, which can be applied to many of the vehicles currently being considered for low pollution and high fuel economy. The code operates interactively, with all the vehicle information stored in data files. The code calculates fuel economy for three driving schedules, time for 0-96 km/h at maximum acceleration, hill climbing performance, power train dimensions, and pollution generation rates. This report also documents the application of the code to a hybrid vehicle that operates with a hydrogen internal combustion engine. The simulation model is used for parametric studies of the vehicle. The results show the fuel economy of the vehicle as a function of vehicle mass, aerodynamic drag, engine-generator efficiency, flywheel efficiency, and flywheel energy and power capacities.

This paper shows an analysis of the applicability of an adsorption system for electric vehicle (EV) air conditioning. Adsorption systems are designed and optimized to provide the required cooling for four combinations of vehicle characteristics and driving cycles. The resulting adsorption systems are compared with vapor compression air conditioners that can satisfy the cooling load. The objective function is the overall system weight, which includes the cooling system weight and the weight of the battery necessary to provide energy for air conditioner operation. The system with the minimum overall weight is considered to be the best, because a lower weight results in an increased vehicle range. The results indicate that, for the conditions analyzed in this paper, vapor compression air conditioners are superior to adsorption systems not only because they are lighter, but also because they have a higher COP and are more compact.

As part of the Fuel Cycle Facility (FCF) of Argonne National Laboratory`s Integral Fast Reactor (IFR) demonstration, a computer-based Mass-Tracking (MTG) System has been developed. The MTG System collects, stores, retrieves and processes data on all operations which directly affect the flow of process material through FCF and supports such activities as process modeling, compliance with operating limits (e.g., criticality safety), material control and accountability and operational information services. Its architecture is client/server, with input and output connections to operator`s equipment-control stations on the floor of FCF as well as to terminal sessions. Its heterogeneous database includes a relational-database manager as well as both binary and ASCII data files. The design of the database, and the software that supports it, is based on a model of discrete accountable items distributed in space and time and constitutes a complete historical record of the material processed in FCF. Although still under development, much of the MTG System has been qualified and is in production use.

A statistical design of experiments approach has been employed to evaluate the particle removal efficacy of the SC-1/megasonic clean for sub-0.15 {mu}m inorganic particles. The effects of megasonic input power, solution chemistry, bath temperature, and immersion time have been investigated. Immersion time was not observed to be a statistically significant factor. The NH{sub 4}OH/H{sub 2}O{sub 2} ratio was significant, but varying the molar H{sub 2}O{sub 2} concentration had no effect on inorganic particle removal. Substantially diluted chemistries, performed with high megasonic input power and moderate-to-elevated temperatures, was shown to be very effective for small particle removal. Bath composition data show extended lifetimes can be obtained when high purity chemicals are used at moderate (eg., 45{degrees}C) temperature. Transition metal surface concentrations and surface roughness have been measured after dilute SC-1 processing and compared to metallic contamination following traditional SC-1.

Weatherable, low cost, front surface, solar reflectors on flexible substrates would be highly desirable for lamination to solar concentrator panels. The method to be described in this paper may permit such reflector material to be fabricated for less than 50 cents per square foot. Vacuum deposited Polymer/Silver/Polymer reflectors and Fabry-Perot interference filters were fabricated in a vacuum web coating operation on polyester substrates. Reflectivities were measured in the wavelength range from .4 {mu}m to .8 {mu}m. It is hoped that a low cost substrate can be used with the substrate laminated to the concentrator and the weatherable acrylic polymer coating facing the sun. This technique should be capable of deposition line speeds approaching 1500 linear feet/minute. Central to this technique is a new vacuum deposition process for the high rate deposition of polymer films. This polymer process involves the flash evaporation of an acrylic monomer onto a moving substrate. The monomer is subsequently cured by an electron beam or ultraviolet light. This high speed polymer film deposition process has been named the PML process - for Polymer Multi-Layer.

Low Level radioactive Waste (LLW) at the Savannah River Site at Aiken, South Carolina, has traditionally been disposed of using engineered trenches in accordance with the guidelines and technology existing at the time. Recently, subgrade concrete vaults known as E-Area Vaults (EAV) have been constructed at SRS. The EAV project is a comprehensive effort for upgrading LLW disposal at SRS based on meeting the requirements of current Department of Energy (DOE) Orders, and addressing more stringent federal and state regulations. The EAV is a first of its kind state-of-the-art facility designed and built in the United States to receive LLW. Westinghouse Savannah River Company (WSRC) conducted an Operational Readiness Review (ORR) of the vaults prior to startup. The objective of the EAV ORR was to perform a comprehensive review of the operational readiness of the facilities per DOE guidelines including Defense Nuclear Facilities Safety Board (DNFSB) recommendations. This review included assessing construction of the vaults as per design, adequate approved procedures, and training of all the personnel associated with the facility operations. EAV ORR incorporated the lessons learned from other DOE ORRs, included DNFSB recommendations, used a graded approach, and utilized subject matter experts for each functional area of assessment.

Simultaneous removal of SO{sub 2} and NO{sub x} using a regenerable solid sorbent will constitute an important improvement over the use of separate processes for the removal of these two pollutants from stack gases and possibly eliminate several shortcomings of the individual SO{sub 2} and NO{sub x} removal operations. This process will allow simple and reliable cleanup of large volumes of stack gases at a competitive cost; produce a concentrated stream of SO{sub 2} which an easily be converted into valuable by-products; be compatible with existing power generation plants; and essentially eliminate the waste materials generated in some other sulfur removal processes. Department of Energy`s Pittsburgh Energy Technology Center (PETC) and UOP/Shell have developed processes which both employ copper oxide-based sorbents in different reactor configurations, namely, former uses a regenerative fluidized bed while the latter employs a cyclic fixed bed contactor. More recent studies at PETC considered cerium oxide as an alternate sorbent to CuO{sup (1,2)}. Ceria improves the resistance of the alumina support to thermal sintering and produces a regeneration off-gas stream that can be easily converted to elemental sulfur. It has potentially higher sulfur capture capacity than copper. The objective of this research is to determine the effects …

This progress report describes new experimental results and interpretations for data collected from October 1, 1992, through September 30, 1993, as part of the Characterization Task of the Uranium in Soils Integrated Demonstration of the Office of Technology Development, Office of Environmental Restoration and Waste Management of the US Department of Energy. X-ray absorption, optical luminescence, and Raman vibrational spectroscopies were used to determine uranium speciation in contaminated soils from the US DOE`s former uranium production facility at Fernald, Ohio. These analyses were carried out both before and after application of one of the various decontamination technologies being developed within the Integrated Demonstration. This year the program focused on characterization of the uranium speciation remaining in the soils after decontamination treatment. X-ray absorption and optical luminescence spectroscopic data were collected for approximately 40 Fernald soil samples, which were treated by one or more of the decontamination technologies.

We have used experiments and modeling to develop a new radiative divertor configuration for DIII-D. Gas puffing experiments with the existing open divertor have shown the creation of a localized ({approximately}10 cm diameter) radiation zone which results in substantial reduction (3--10) in the divertor heat flux while {delta}{sub E} remains {approximately}2 times ITER-89P scaling. However, ne increases with D{sub 2} puffing, and Z{sub eff} increases with neon puffing. Divertor structures are required to minimize the effects on the core plasma. The UEDGE fluid code, benchmarked with DIII-D data, and the DEGAS neutrals transport code are used to estimate the effectiveness of divertor configurations; slots reduce the core ionization more than baffles. The overall divertor shape is set by confinement studies which indicate that high triangularity ({delta} {approximately}0.8) is important for high {tau}{sub E} VH-modes. Results from engineering feasibility studies, including diagnostic access, will be presented.

Traffic management can be thought of as a stochastic queuing process where the serving time at one of its control points is dynamically linked to the global traffic pattern, which is, in turn, dynamically linked to the control point. For this closed-loop system to be effective, the traffic management system must sense and interpret large spatial projections of data originating from multiple sensor suites. The intent of the Wide-Area Surveillance (WAS) Project is to build upon this concept and define the operational specifications and characteristics of a Traffic Flow Wide-Area Surveillance (TFWAS) system in terms of traffic management and control. In doing so, the functional capabilities of a TFWAS will be mapped onto an operational profile that is consistent with the Federal Highway Administration`s Intelligent Vehicle Highway System. This document provides the underlying foundation of this work by offering a concept definition for the TFWAS system. It concentrates on answering the question: ``What is the system?`` In doing so, the report develops a hierarchy of specialized definitions.

The N-body problem is to simulate the motion of N particles under the influence of mutual force fields based on an inverse square law. The problem has applications in several domains including astrophysics, molecular dynamics, fluid dynamics, radiosity methods in computer graphics and numerical complex analysis. Research efforts have focused on reducing the O(N{sup 2}) time per iteration required by the naive algorithm of computing each pairwise interaction. Widely respected among these are the Barnes-Hut and Greengard methods. Greengard claims his algorithm reduces the complexity to O(N) time per iteration. Throughout this thesis, we concentrate on rigorous, distribution-independent, worst-case analysis of the N-body methods. We show that Greengard`s algorithm is not O(N), as claimed. Both Barnes-Hut and Greengard`s methods depend on the same data structure, which we show is distribution-dependent. For the distribution that results in the smallest running time, we show that Greengard`s algorithm is {Omega}(N log{sup 2} N) in two dimensions and {Omega}(N log{sup 4} N) in three dimensions. We have designed a hierarchical data structure whose size depends entirely upon the number of particles and is independent of the distribution of the particles. We show that both Greengard`s and Barnes-Hut algorithms can be used in conjunction with …

Report submitted by Amarillo College to the Texas 73rd regular legislature requesting appropriations to fund programming and activities. It includes an overview of the institution's goals, summaries of appropriations requests for fiscal years 1996 and 1997, and supporting documentation.

For the 1994 Tevatron collider run, CDF has upgraded the electron and photo trigger hardware to make use of shower position and size information from the central shower maximum detector. For electrons, the upgrade has resulted in a 50% reduction in backgrounds while retaining approximately 90% of the signal. The new trigger also eliminates the background to photon triggers from single-phototube spikes.

The retained dose of ions can be increased by Plasma Immersion Ion Implantation and Deposition (PIIID). A substrate is immersed in a metal or carbon plasma and a negative repetitively pulsed bias voltage is applied. During the pulses, an electric sheath is formed around the substrate and ions are accelerated through the sheath and implanted into the substrate. Direct and recoil ion implantation and sputtering take place during the pulses whereas low-energy deposition occurs between the pulses. The condensable plasma can be produced using a cathodic arc plasma source combined with a magnetic macroparticle filter. PIIID can be applied to perform fast high-dose implantations or to deposit thin films with broad intermixing at the film-substrate interface. The bias voltage duty cycle can be tuned to sputter away the film deposited during pulse off-time (similar to the method of sacrificial layer). We have simulated the PIIID process using the Monte Carlo code T-DYN 4.0. This code allows a calculation of the dose-dependent depth profile for a process with deposition and implantation phases, taking sputtering into account. Predicted retained doses and experimentally obtained retained doses measured by Rutherford backscattering spectrometry are compared.

Global Basins Research Network will perform a field demonstration of their ``Dynamic Enhanced Recovery Technology`` to test the concept that the growth of faults in Eugene Island Block 330 (EI-330 field) are conduits through which producing reservoirs are charged and that enhanced production can be developed by producing directly from the fault zone. The site, operated by Penzoil, is located in 250 feet of water and the productive depth intervals include 4000 to 9000 feet. The field demonstration will be accomplished by drilling and production testing of growth fault systems associated with the EI-330 field. The project utilizes advanced 3-D seismic analysis, geochemical studies, structural and stratigraphic reservoir characterization, reservoir simulation, and compact visualization systems. In this quarterly report, progress reports are presented for the following tasks: Task one--management start-up; Task two--database management; Task three--field demonstration experiment; Task four--reservoir characterization; Task five--modeling; Task six--geochemistry; and Task seven--data integration.

Regulatory Facility Guides (RFGS) are being developed to provide the US. Department of Energy (DOE) and DOE contractor facilities with the understanding of the exact applicability of specific transportation regulations to DOE shippers. These detailed state-specific compilations of federal, state, tribal, local, and international transportation regulations should lead to enhanced compliance, fewer efforts, and less confusion. To date, RFGs for three states have been developed. The RFGs for Tennessee and Ohio were finalized in February 1994 and have been distributed under a controlled distribution. The RFG for New Meidco is in final draft form and is undergoing DOE review. Two additional RFGs, for the states of Idaho and California, are expected to be completed by September 1994.

Pulse power can be used to generate high energy density conditions in convergent hollow cylindrical geometry through the use of appropriate electrode configuration and cylindrical loads. Cylindrically symmetric experiments are conducted with the Pegasus-H inductive store, capacitor energized pulse power facility at Los Alamos using both precision machined cylindrical liner loads and low mass vapor deposited cylindrical foil loads. The liner experiments investigate solid density hydrodynamic topics. Foil loads vaporize from Joule heating to generate an imploding cylindrical plasma which can be used to simulate some fluxes associated with fusion energy processes. Similar experiments are conducted with {open_quotes}Procyon{close_quotes} inductive store pulse power assemblies energized by explosively driven magnetic flux compression.

Thermal losses from duct systems have been shown to be a significant fraction of the heat or cooling energy delivered by the space-conditioning equipment. However, when the ducts are located in a partially conditioned buffer space such as a basement, a portion of these losses are effectively regained through system interactions with the building. This paper presents two methods of measuring this regain effect. One is based on the relative thermal resistances between the conditioned space and the buffer space, on the one hand, and between the buffer space and the outside, on the other. The second method is based on a measured drop in the buffer-space temperature when steps are taken to reduce the duct losses. The second method is compared with results of an extensive research project that are published in a major professional society handbook. The thermal regain fraction using the drop in basement temperature was found to be 0.68, while that obtained from an analysis of the system performance data, without using the basement temperature, was 0.59.

The theoretical research activity at the University of Maryland supported by the Department of Energy focusses on two major tasks. They are: A. Transport, generation of shear flow and L-H transitions in Tokamaks; and B. MHD stability of Tokamaks. Titles of specific research projects under these fields carried out in this period include: Poloidal rotation of tokamak plasmas at super-poloidal-sonic speeds; Rotation of plasmas in neoclassical regimes; New unstable branch of drift resistive ballooning modes in tokamaks; 3D fluid simulations of the drift resistive ballooning modes - twisted coordinate system; Disintegration of ion banana orbits in tokamak edge plamsas; Fast reconnection in high temperature plasmas; Dynamics of sawtooth collapse in tokamak plasmas; Effect of trapped particles on MHD modes; MHD stability of high beta toroidal equilibria.