Catalyst Additives to Enhance Mercury Oxidation and Capture Quarterly Report: March - June 2004 (open access)

Catalyst Additives to Enhance Mercury Oxidation and Capture Quarterly Report: March - June 2004

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Date: July 2004
Creator: Gale, Thomas K.
System: The UNT Digital Library
Catalyst Additives to Enhance Mercury Oxidation and Capture Quarterly Report: April - June 2005 (open access)

Catalyst Additives to Enhance Mercury Oxidation and Capture Quarterly Report: April - June 2005

Preliminary research has shown that SCR catalysts employed for nitrogen-oxide reduction can effectively oxidize mercury. This report discusses initial results from fundamental investigations into the behavior of mercury species in the presence of SCR catalysts at Southern Research Institute. The testing was performed at Southern Research's Catalyst Test Facility, a bench-scale reactor capable of simulating gas-phase reactions occurring in coal-fired utility pollution-control equipment. Three different SCR catalysts are currently being studied in this project--honeycomb-type, plate-type, and a hybrid-type catalyst. The catalysts were manufactured and supplied by Cormetech Inc., Hitachi America Ltd., and Haldor-Topsoe Inc., respectively. Parametric testing was performed to investigate the contribution of flue-gas chemistry on mercury oxidation via SCR catalysts. Methods and procedures for experimental testing continue to be developed to produce the highest quality mercury-oxidation data. During this past quarter, it was discovered that long periods (12 - 24 hours) are required to equilibrate the catalysts in the system. In addition, after the system has been equilibrated, operational changes to temperature, gas concentration, or flow rate shifts the equilibrium, and steady-state must be reestablished, which can require as much as twelve additional hours per condition change. In the last quarter of testing, it was shown that the …
Date: July 2005
Creator: Cannon, Jared W. & Gale, Thomas K.
System: The UNT Digital Library