Advanced separation technology for flue gas cleanup. Quarterly technical report No. 1 (open access)

Advanced separation technology for flue gas cleanup. Quarterly technical report No. 1

The objective of this work is to develop a novel system for regenerable SO{sub 2} and NO{sub x} scrubbing of flue gas that focuses on (a) a novel method for regeneration of spent SO{sub 2} scrubbing liquor and (b) novel chemistry for reversible absorption of NO{sub x}. In addition, high efficiency hollow fiber contactors (HFC) are proposed as the devices for scrubbing the SO{sub 2} and NO{sub x} from the flue gas. The major cost item in existing technology is capital investment. Therefore, our approach is to reduce the capital cost by using high efficiency hollow fiber devices for absorbing and desorbing the SO{sub 2} and NO{sub x}. Our novel chemistry for scrubbing NO{sub x} win consist of water soluble phthalocyanine compounds invented by SRI and also of polymeric forms of Fe{sup ++} complexes similar to traditional NO{sub x} scrubbing media described in the open literature. Our past work with the phthalocyanine compounds, used as sensors for NO and NO{sub 2} in flue gases, shows that these compounds bind NO and NO{sub 2} reversibly and with no interference from O{sub 2}, CO{sub 2}, SO{sub 2}, or other components of flue gas. The final novelty of our approach is the arrangement …
Date: July 1, 1992
Creator: unknown
System: The UNT Digital Library