Rare earths and copper systems were studied using X-ray absorption spectroscopy (XAS) and resonant inelastic X-ray scattering (RIXS). The use of monochromased synchotron radiation and improved energy resolution for RIXS made possible to obtain valuable information on the electronic structure in 4f, 5f and 3d systems. Experimental results for rare-earths (Ho, Gd, Cm, U, Np, Pu) were analyzed by atomic multiplet theory based on the Hartree-Fock calculations. The inelastic scattering structures in RIXS spectra at 5d edge of actinides found to be sensitive to actinide oxidation states in different systems. Comparison of experimental and calculated Cm 5d RIXS spectra gave direct information about valency of the 248-curium isotope in oxide. Scientific understanding of processes that control chemical changes of radioactive species from spent fuel is improved by studying interactions of actinide ions (U, Np, Pu) with corroded iron surfaces. RIXS measurements at the actinide 5d edge found to be sensitive to actinide oxidation states in different systems. Comparison of experimental and calculated Cm 5d RIXS spectra gave direct information about valency of the 248 curium isotope in oxide. Scientific understanding of processes that control chemical changes of radioactive species from spent fuel is improved by studying interactions of actinide ions …

The problem of the bimolecular rate constant, alpha , for the mutual charge neutralization reaction (ion-ion recombination) for ions formed by the vacuum ultraviolet photolysis of nitric oxide is considered. The pressure dependence of alpha over a pressure range of 10 to 600 torr for mixtures of a few hundred microns of NO with He, Ar, Kr, Xe, H/sub 2/, D/sub 2/, and N/sub 2/ was measured. From the low-pressure limit of alpha , the rate constant for charge neutralization in the absence of a third body was found to be k/sub o/ = 2.1 plus or minus 0.4 x 10/sup -7/ cm/sup 3// sec. The high-pressure limit of alpha was estimated to be 2.0 plus or minus 0.5 x 10/sup -6/ cm/sup 3//sec. The third-body efficiencies for promoting the charge-neutralization reaction were measured. The results, relative to He as the third-body gas, are H/sub 2/= 1.4 plus or minus 0.4, D/sub 2/= 1.5 plus or minus 0.4, Ar =3.6 plus or minus 0.8, Kr =4.3 plus or min11.0, N/sub 2/ = 5.2 plus or minus 1.1, and Xe = 6.8 plus or minus 1.5. The average ionic mobility in the gas mixtures is estimated, and the mobilities indicate that …

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