Certifying Industrial Energy Efficiency Performance: AligningManagement, Measurement, and Practice to Create Market Value (open access)

Certifying Industrial Energy Efficiency Performance: AligningManagement, Measurement, and Practice to Create Market Value

More than fifteen years after the launch of programs in theU.K. and U.S., industry still offers one of the largest opportunities forenergy savings worldwide. The International Energy Agency (IEA) estimatesthe savings potential from cost-optimization of industrial motor-drivensystems alone at 7 percent of global electricity use. The U.S. Departmentof Energy (USDOE) Industrial Technologies Program estimates 7 percentsavings potential in total US industrial energy use through theapplication of proven best practice. Simple paybacks for these types ofprojects are frequently two years or less. The technology required toachieve these savings is widely available; the technical skills requiredto identify energy saving opportunities are known and transferable.Although programs like USDOE's Best Practices have been highlysuccessful, most plants, as supported by 2002 MECS data, remain eitherunaware or unmotivated to improve their energy efficiency--as evidencedby the 98 percent of US industrial facilities reporting to MECS say thatthey lack a full-time energy manager. With the renewed interest in energyefficiency worldwide and the emergence of carbon trading and newfinancial instruments such as white certificates1, there is a need tointroduce greater transparency into the way that industrial facilitiesidentify, develop, and document energy efficiency projects. Historically,industrial energy efficiency projects have been developed by plantengineers, frequently with assistance from consultants and/or supplierswith …
Date: July 1, 2007
Creator: McKane, Aimee; Scheihing, Paul & Williams, Robert
Object Type: Article
System: The UNT Digital Library
Quench performance of Nb3Sn cos-theta coils made of 108/127 RRP strands (open access)

Quench performance of Nb3Sn cos-theta coils made of 108/127 RRP strands

A series of 1-m long Nb{sub 3}Sn dipole models has been built at Fermilab in an attempt to refine the wind-and-react technology for Nb3Sn accelerator magnets. Three models made with Powder-in-Tube Nb{sub 3}Sn strand reached their design field of 10 T demonstrating a good reproducibility of magnet quench performance and field quality. Recently a new dipole 'mirror' model based on Nb{sub 3}Sn coil made of improved Restack Rod Process strand was constructed and tested reaching the maximum field above 11 T. This paper describes the parameters of the RRP strand and cable used as well as the design, fabrication and test results of this magnet.
Date: July 1, 2007
Creator: Zlobin, A.V.; Ambrosio, G.; Andreev, N.; Barzi, E.; Bossert, R.; Carcagno, R. et al.
Object Type: Article
System: The UNT Digital Library
Multizone Age-of-Air Analysis (open access)

Multizone Age-of-Air Analysis

Age of air is a technique for evaluating ventilation that has been actively used for over 20 years. Age of air quantifies the time it takes for outdoor air to reach a particular location or zone within then indoor environment. Age of air is often also used to quantify the ventilation effectiveness with respect to indoor air quality. In a purely single zone situation this use of age of air is straightforward, but application of age of air techniques in the general multizone environment has not been fully developed. This article looks at expanding those single-zone techniques to the more complicated environment of multizone buildings and in doing so develops further the general concept of age of air. The results of this analysis shows that the nominal age of air as often used cannot be directly used for determining ventilation effectiveness unless specific assumptions are made regarding source distributions.
Date: July 1, 2007
Creator: Sherman, Max H.
Object Type: Article
System: The UNT Digital Library
Test definitions for the evaluation of digital waveform recorders. (open access)

Test definitions for the evaluation of digital waveform recorders.

This Test Definition for the Evaluation of Digitizing Waveform Recorders (DWR) defines the process that can be performed as part of the evaluation and testing of geophysical sensors, digitizers, sensor subsystems and geophysical station/array systems. The objectives are to (1) evaluate the overall technical performance of the DWR, measure the distortions introduced by the high resolution digitizers and provide a performance check of the internal calibrator if provided and (2) evaluate the technical performance of the DWR for a specific sensor application. The results of these evaluations can be compared to the manufacturer's specifications and any relevant application requirements or specifications.
Date: July 1, 2007
Creator: Kromer, Richard Paul (R.P. Kromer Consulting, Albuquerque, NM); Hart, Darren M. & Harris, James Mark
Object Type: Report
System: The UNT Digital Library
Statistical Studies on Sequential Probability Ratio Test for Radiation Detection (open access)

Statistical Studies on Sequential Probability Ratio Test for Radiation Detection

A Sequential Probability Ratio Test (SPRT) algorithm helps to increase the reliability and speed of radiation detection. This algorithm is further improved to reduce spatial gap and false alarm. SPRT, using Last-in-First-Elected-Last-Out (LIFELO) technique, reduces the error between the radiation measured and resultant alarm. Statistical analysis determines the reduction of spatial error and false alarm.
Date: July 1, 2007
Creator: Warnick Kernan, Ding Yuan, et al.
Object Type: Article
System: The UNT Digital Library
Development and Validation of a One-Dimensional Co-Electrolysis Model for Use in Large-Scale Process Modeling Analysis (open access)

Development and Validation of a One-Dimensional Co-Electrolysis Model for Use in Large-Scale Process Modeling Analysis

A one-dimensional chemical equilibrium model has been developed for analysis of simultaneous high-temperature electrolysis of steam and carbon dioxide (coelectrolysis) for the direct production of syngas, a mixture of hydrogen and carbon monoxide. The model assumes local chemical equilibrium among the four process-gas species via the shift reaction. For adiabatic or specified-heat-transfer conditions, the electrolyzer model allows for the determination of coelectrolysis outlet temperature, composition (anode and cathode sides), mean Nernst potential, operating voltage and electrolyzer power based on specified inlet gas flow rates, heat loss or gain, current density, and cell area-specific resistance. Alternately, for isothermal operation, it allows for determination of outlet composition, mean Nernst potential, operating voltage, electrolyzer power, and the isothermal heat requirement for specified inlet gas flow rates, operating temperature, current density and area-specific resistance. This model has been developed for incorporation into a system-analysis code from which the overall performance of large-scale coelectrolysis plants can be evaluated. The one-dimensional co-electrolysis model has been validated by comparison with results obtained from a 3-D computational fluid dynamics model and by comparison with experimental results.
Date: July 1, 2007
Creator: O'Brien, J. E.; McKellar, M. G.; Hawkes, G. L. & Stoots, C. M.
Object Type: Article
System: The UNT Digital Library
The Future of U.S. Chemistry Research: Benchmarks and Challenges (open access)

The Future of U.S. Chemistry Research: Benchmarks and Challenges

None
Date: July 1, 2007
Creator: Chemistry, Committee on Benchmarking the Research Competitiveness of the United States in
Object Type: Report
System: The UNT Digital Library
Neutral current interactions in MINOS (open access)

Neutral current interactions in MINOS

The Main Injector Neutrino Oscillation Search (MINOS) long-baseline experiment has been actively collecting beam data since 2005, having already accumulated 3 x 10{sup 20} protons-on-target (POT). The several million neutrinos per year observed at the Near detector may improve the existing body of knowledge of neutrino cross-sections and the Near-Far comparison of the observed energy spectrum neutral current events constrains oscillations into sterile neutrinos. MINOS capabilities of observing neutral current neutrino events are described and the employed methodology for event selection is discussed, along with preliminary results obtained. An outlook on the expected neutral current related contributions from MINOS is also presented.
Date: July 1, 2007
Creator: Sousa, Alexandre
Object Type: Article
System: The UNT Digital Library
The Laminin 511/521 Binding Site on the Lutheran Blood Group Glycoprotein is Located at theFlexible Junction of Ig Domains 2 and 3 (open access)

The Laminin 511/521 Binding Site on the Lutheran Blood Group Glycoprotein is Located at theFlexible Junction of Ig Domains 2 and 3

The Lutheran blood group glycoprotein, first discovered on erythrocytes, is widely expressed in human tissues. It is a ligand for the {alpha}5 subunit of Laminin 511/521, an extracellular matrix protein. This interaction may contribute to vasocclusive events that are an important cause of morbidity in sickle cell disease. Using X-ray crystallography, small angle X-ray scattering and site directed mutagenesis we show that the extracellular region of Lutheran forms an extended structure with a distinctive bend between the second and third immunoglobulin-like domains. The linker between domains 2 and 3 appears to be flexible and is a critical determinant in maintaining an overall conformation for Lutheran that is capable of binding to Laminin. Mutagenesis studies indicate that Asp312 of Lutheran and the surrounding cluster of negatively charged residues in this linker region form the Laminin binding site. Unusually, receptor binding is therefore not a function of the domains expected to be furthermost from the plasma membrane. These studies imply that structural flexibility of Lutheran may be essential for its interaction with Laminin and present a novel opportunity for the development of therapeutics for sickle cell disease.
Date: July 1, 2007
Creator: Mankelow, Tosti J.; Burton, Nicholas; Stedansdottir, Fanney O.; Spring, Frances A.; Parsons, Stephen F.; Pesersen, Jan S. et al.
Object Type: Report
System: The UNT Digital Library
Recent Major Improvements to the ALS Sector 5 MacromolecularCrystallography Beamlines (open access)

Recent Major Improvements to the ALS Sector 5 MacromolecularCrystallography Beamlines

Although the Advanced Light Source (ALS) was initially conceived primarily as a low energy (1.9GeV) 3rd generation source of VUV and soft x-ray radiation it was realized very early in the development of the facility that a multipole wiggler source coupled with high quality, (brightness preserving), optics would result in a beamline whose performance across the optimal energy range (5-15keV) for macromolecular crystallography (MX) would be comparable to, or even exceed, that of many existing crystallography beamlines at higher energy facilities. Hence, starting in 1996, a suite of three beamlines, branching off a single wiggler source, was constructed, which together formed the ALS Macromolecular Crystallography Facility. From the outset this facility was designed to cater equally to the needs of both academic and industrial users with a heavy emphasis placed on the development and introduction of high throughput crystallographic tools, techniques, and facilities--such as large area CCD detectors, robotic sample handling and automounting facilities, a service crystallography program, and a tightly integrated, centralized, and highly automated beamline control environment for users. This facility was immediately successful, with the primary Multiwavelength Anomalous Diffraction beamline (5.0.2) in particular rapidly becoming one of the foremost crystallographic facilities in the US--responsible for structures such …
Date: July 1, 2007
Creator: Morton, Simon A.; Glossinger, James; Smith-Baumann, Alexis; McKean, John P.; Trame, Christine; Dickert, Jeff et al.
Object Type: Article
System: The UNT Digital Library
Electron cloud effects on an intense ion beam in a four solenoid lattice (open access)

Electron cloud effects on an intense ion beam in a four solenoid lattice

The Solenoid Transport Experiment (STX) at LBNL successfully demonstrated the transport of a space-charge dominated ion beam in a two-solenoid lattice. Initial experiments showed a strong dependence of electron cloud effects on solenoid field strength. A current-reducing aperture, two solenoids and in-bore diagnostics were added to the two-solenoid lattice in order to study electron cloud effects more closely. Experiments were conducted with a 10 {micro}s, singly charged potassium ion bunch at an ion energy of 0.3 MeV and currents of 26 mA and 45 mA. A qualitative comparison of experimental and calculated results are presented, including a comparison of the effects of manipulating electrons on the beam dynamics, quantifying beam-induced gas desorption, ionization, and electron effects.
Date: July 1, 2007
Creator: Department of Nuclear Engineering, University of California at Berkeley,; 4155 Etcheverry Hall, MC 1730, Berkeley, CA 94720, USA.; Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, CA-94720, USA.; University of Maryland, College Park, MD 20742-3511, USA.; Lawrence Liveremore National Laboratory, Livermore, California 94550, USA.; Voss Scientific, Albuquerque, NM 87108, USA. et al.
Object Type: Article
System: The UNT Digital Library
Control of Surface Mounted Permanent Magnet Motors with Special Application to Fractional-Slot Motors with Concentrated Windings (open access)

Control of Surface Mounted Permanent Magnet Motors with Special Application to Fractional-Slot Motors with Concentrated Windings

A 30 pole, 6 kW, and 6000 maximum revolutions per minute (rpm) prototype of the permanent magnet synchronous motor (PMSM) with fractional-slot concentrated windings (FSCW) has been designed, built, and tested at the University of Wisconsin at Madison (UWM). This machine has significantly more inductance than that of regular PMSMs. The prototype was delivered in April 2006 to the Oak Ridge National Laboratory (ORNL) for testing and development of a controller that will achieve maximum efficiency. In advance of the test/control development effort, ORNL has used the PMSM models developed over a number of previous studies to study how steady state performance of high inductance PMSM machines relates to control issues. This report documents the results of this research. The amount of inductance that enables the motor to achieve infinite constant power speed ratio (CPSR) is given by L{sub {infinity}} = E{sub b}/{Omega}{sub b}I{sub R}, where E{sub b} is the root-mean square (rms) magnitude of the line-to-neutral back-electromotive force (emf) at base speed, {Omega}{sub b} is the base speed in electrical radians per second, and I{sub R} is the rms current rating of the motor windings. The prototype machine that was delivered to ORNL has about 1.5 times as much …
Date: July 1, 2007
Creator: McKeever, John W; Patil, Niranjan & Lawler, Jack
Object Type: Report
System: The UNT Digital Library
Opportunities for Saving Energy and Improving Air Quality in Urban Heat Islands (open access)

Opportunities for Saving Energy and Improving Air Quality in Urban Heat Islands

World energy use is the main contributor to atmospheric CO2. In 2002, about 7.0 giga metric tons of carbon (GtC) were emitted internationally by combustion of gas, liquid, and solid fuels (CDIAC, 2006), 2 to 5 times the amount contributed by deforestation (Brown et al., 1988). The share of atmospheric carbon emissions for the United States from fossil fuel combustion was 1.6 GtC. Increasing use of fossil fuel and deforestation together have raised atmospheric CO{sub 2} concentration some 25% over the last 150 years. According to global climate models and preliminary measurements, these changes in the composition of the atmosphere have already begun raising the Earth's average temperature. If current energy trends continue, these changes could drastically alter the Earth's temperature, with unknown but potentially catastrophic physical and political consequences. During the last three decades, increased energy awareness has led to conservation efforts and leveling of energy consumption in the industrialized countries. An important byproduct of this reduced energy use is the lowering of CO{sub 2} emissions. Of all electricity generated in the United States, about one-sixth is used to air-condition buildings. The air-conditioning use is about 400 tera-watt-hours (TWh), equivalent to about 80 million metric tons of carbon (MtC) …
Date: July 1, 2007
Creator: Akbari, Hashem
Object Type: Book
System: The UNT Digital Library
Test definitions for the evaluation of seismic sensors. (open access)

Test definitions for the evaluation of seismic sensors.

Most test methodologies referenced in this Test Definition and Test Procedures were designed by Sandia specifically for geophysical instrumentation evaluation. When appropriate, test instrumentation calibration is traceable to the National Institute for Standards Technology (NIST).
Date: July 1, 2007
Creator: Kromer, Richard Paul (R.P. Kromer Consulting, Albuquerque, NM); Hart, Darren M. & Harris, James Mark
Object Type: Report
System: The UNT Digital Library
Diffractive Z/gamma* --> mu+mu- boson production in proton - antiproton collisions (open access)

Diffractive Z/gamma* --> mu+mu- boson production in proton - antiproton collisions

Measurements of the inclusive diffractive Z {yields} {mu}{sup +}{mu}{sup -} cross section with gap requirement for M{sub {mu}}{sub {mu}} > 40 GeV at {radical} s = 1.96 TeV and fraction of Z bosons produced diffractively with gap requirement from Z inclusive production are presented. The measurements are performed using a data sample corresponding to an integrated luminosity of 820 pb{sup -1}, collected with the D0 detector at the Tevatron, between 2002 to 2005. A total of 39945 di-muons events are selected and final results of: {sigma}{sub Diff}{sup gap} x Br(Z/{gamma}* {yields} {mu}{sup +}{mu}{sup -}) = 4.09 {+-} 0.64(stat.) {+-} 0.88(syst.) {+-} 0.27(lumi.) pb and, R{sub Diff}{sup gap} = 1.92 {+-} 0.30(stat.) {+-} 0.41(syst.) {+-} 0.12(lumi) % are obtained. In addition, d{sigma}/d{zeta} and d{sigma}/dy distributions are presented and they are compared with diffractive montecarlo (POMWIG). A reasonable agreement is obtained in this comparation. Finally, comparison of fraction of Z bosons produced diffractively with gap requirement (gap fraction) as measured with D0 during Run I of the Tevatron is compared. A good agreement is found for gap fraction results.
Date: July 1, 2007
Creator: Mendoza Navas, Luis Miguel
Object Type: Thesis or Dissertation
System: The UNT Digital Library
Current Outlook for 99mTc Distribution Based on Electron Accelerator Production (open access)

Current Outlook for 99mTc Distribution Based on Electron Accelerator Production

In 1999 a practical example illustrating the economical and reliable production of 99mTc from an accelerator was developed. It included the realistic costs involved in establishing and operating the accelerator facility and the distribution of the 99mTc to regions in Florida. However, the technology was never commercialized. Recent political and economic developments prompted this second look at accelerator produced 99mTc. The practicality of this system in 2007 dollars was established to account for inflation and current demand. The same distribution model and production schedule from the Global ‘99 study were used. Numbers were found using current rates and costs where possible and indexed estimations when necessary. Though several of the costs increased significantly and the sale price remains at approximately 35¢/mCi, the unit cost of 99mTc throughput only increased from 12.8¢/mCi to 15.0¢/mCi or approximately 17.2% from 1999 to 2007 thus continuing to be economically viable. This study provides ground work for creating business development models at additional locations within the U.S.
Date: July 1, 2007
Creator: Nelson, Benjamin L.; Bence, W. David & Snyder, John R.
Object Type: Article
System: The UNT Digital Library
Data Center Energy Benchmarking: Part 3 - Case Study on an ITEquipment-testing Center (No. 20) (open access)

Data Center Energy Benchmarking: Part 3 - Case Study on an ITEquipment-testing Center (No. 20)

The data center in this study had a total floor area of 3,024 square feet (ft{sup 2}) with one-foot raised-floors. It was a rack lab with 147 racks, and was located in a 96,000 ft{sup 2} multi-story office building in San Jose, California. Since the data center was used only for testing equipment, it was not configured as a critical facility in terms of electrical and cooling supply. It did not have a dedicated chiller system but was served by the main building chiller plant and make-up air system. Additionally it was served by only a single electrical supply with no provision for backup power in the event of a power outage. The Data Center operated on a 24 hour per day, year-round cycle, and users had full-hour access to the data center facility. The study found that data center computer load accounted for 15% of the overall building electrical load, while the total power consumption attributable to the data center including allocated cooling load and lighting was 22% of the total facility load. The density of installed computer loads (rack load) in the data center was 61 W/ft{sup 2}. Power consumption density for all data center allocated load (including …
Date: July 1, 2007
Creator: Xu, Tengfang & Greenberg, Steve
Object Type: Report
System: The UNT Digital Library
Stressed glass technology for actuators and removable barrier applications. (open access)

Stressed glass technology for actuators and removable barrier applications.

There are commercial and military applications in which a material needs to serve as a barrier that must subsequently be removed. In many cases it is desirable that once the barrier has served its function that it then be reduced to small pieces. For example, in pipelines and in downhole drilling applications, valves are needed to function as barriers that can sustain high pressures. Later the valves must be removed and essentially disappear or be rendered to such a small size that they do not interfere with the functioning of other equipment. Military applications include covers on missile silos or launch vehicles. Other applications might require that a component be used once as an actuator or for passive energy storage, and then be irreversibly removed, again so as not to interfere with the function or motion of other parts of the device. Brittle materials, especially those that are very strong, or are pre-stressed, are ideal candidates for these applications. Stressed glass can be produced in different sizes and shapes and the level of strength and pre-stress, both of which control the fragmentation, can be manipulated by varying the processing. Stressed glass can be engineered to fracture predictably at a specific …
Date: July 1, 2007
Creator: Schwing, Kamilla, J.; Warren, Mial E.; Glass, Sarah Jill & Tappan, Alexander Smith
Object Type: Report
System: The UNT Digital Library
Determining physical constraints in transcriptional initiationcomplexes using DNA sequence analysis (open access)

Determining physical constraints in transcriptional initiationcomplexes using DNA sequence analysis

Eukaryotic gene expression is often under the control ofcooperatively acting transcription factors whose binding is limited bystructural constraints. By determining these structural constraints, wecan understand the "rules" that define functional cooperativity.Conversely, by understanding the rules of binding, we can inferstructural characteristics. We have developed an information theory basedmethod for approximating the physical limitations of cooperativeinteractions by comparing sequence analysis to microarray expressiondata. When applied to the coordinated binding of the sulfur amino acidregulatory protein Met4 by Cbf1 and Met31, we were able to create acombinatorial model that can correctly identify Met4 regulatedgenes.
Date: July 1, 2007
Creator: Shultzaberger, Ryan K.; Chiang, Derek Y.; Moses, Alan M. & Eisen,Michael B.
Object Type: Article
System: The UNT Digital Library
A measurement of the lambda_b lifetime at the D0 experiment (open access)

A measurement of the lambda_b lifetime at the D0 experiment

This thesis describes a measurement of the lifetime of the {Lambda}{sub b}{sup 0} baryon, performed using data from proton-antiproton collisions at a centre of mass energy of 1.96 TeV. The decay {Lambda}{sub b}{sup 0} {yields} {Lambda}{sub c}{sup +}{mu}{sup -}{ovr P{nu}}{sub {mu}}X was reconstructed in approximately 1.3 fb{sup -1} of data recorded by the D0 detector in 2002-2006 during Run II of the Fermilab Tevatron collider. A signal of 4437 {+-} 329 {Lambda}{sub c}{sup +}{mu}{sup -} pairs was obtained, and the {Lambda}{sub b}{sup 0} lifetime was measured using a binned {chi}{sup 2} fit, which gives a value {tau}({Lambda}{sub b}{sup 0}) = 1.290{sub -0.110}{sup +0.119}(stat){sub -0.091}{sup +0.085}(syst) ps. This result is consistent with the world average and is one of the most precise measurements of this quantity.
Date: July 1, 2007
Creator: Lewin, Marcus Philip
Object Type: Thesis or Dissertation
System: The UNT Digital Library
Integrated Analysis of Environment-driven Operational Effects in Sensor Networks (open access)

Integrated Analysis of Environment-driven Operational Effects in Sensor Networks

There is a rapidly growing need to evaluate sensor network functionality and performance in the context of the larger environment of infrastructure and applications in which the sensor network is organically embedded. This need, which is motivated by complex applications related to national security operations, leads to a paradigm fundamentally different from that of traditional data networks. In the sensor networks of interest to us, the network dynamics depend strongly on sensor activity, which in turn is triggered by events in the environment. Because the behavior of sensor networks is sensitive to these driving phenomena, the integrity of the sensed observations, measurements and resource usage by the network can widely vary. It is therefore imperative to accurately capture the environmental phenomena, and drive the simulation of the sensor network operation by accounting fully for the environment effects. In this paper, we illustrate the strong, intimate coupling between the sensor network operation and the driving phenomena in their applications with an example sensor network designed to detect and track gaseous plumes.
Date: July 1, 2007
Creator: Park, Alfred J & Perumalla, Kalyan S
Object Type: Report
System: The UNT Digital Library
MASS2, Modular Aquatic Simulation System in Two Dimensions, Theory and Numerical Methods (open access)

MASS2, Modular Aquatic Simulation System in Two Dimensions, Theory and Numerical Methods

The Modular Aquatic Simulation System in Two Dimensions (MASS2) is a two-dimensional, depth-averaged hydrodynamics and transport model. The model simulates time varying distributions of depth-averaged velocities, water surface elevations, and water quality constituents. MASS2 uses a structured, multi-block, boundary-fitted, curvilinear computational mesh, which allows the simulation of very complex riverine or estuarine networks. The blocks may be of varying resolution, which allows high resolution to be used only where needed. MASS2 can simulate a wide variety of hydrodynamic conditions, including supercritical flow and hydraulic jumps. It can also simulate a wide variety of water quality conditions, including sediment, conservative or decaying contaminants, sediment-sorbed contaminants, water temperature, and total dissolved gas. Any number of these constituents may be simulated simultaneously. In addition, transport simulations may be performed using pre-calculated hydrodynamic conditions, allowing long-term transport simulations unencumbered by the more intensive hydrodynamic calculations, or repeated transport simulations without re-simulating hydrodynamics. This report documents the theory and numerical methods used in MASS2. In addition, the results are presented from several of hydrodynamic and transport validation tests to which MASS2 was subjected. The companion user manual documents the application of MASS2.
Date: July 1, 2007
Creator: Perkins, William A. & Richmond, Marshall C.
Object Type: Report
System: The UNT Digital Library
Optimization of Acetylene Black Conductive Additive andPolyvinylidene Difluoride Composition for High Power RechargeableLithium-Ion Cells (open access)

Optimization of Acetylene Black Conductive Additive andPolyvinylidene Difluoride Composition for High Power RechargeableLithium-Ion Cells

Fundamental electrochemical methods were applied to study the effect of the acetylene black (AB) and the polyvinylidene difluoride (PVDF) polymer binder on the performance of high-power designed rechargeable lithium ion cells. A systematic study of the AB/PVDF long-range electronic conductivity at different weight ratios is performed using four-probe direct current tests and the results reported. There is a wide range of AB/PVDF ratios that satisfy the long-range electronic conductivity requirement of the lithium-ion cathode electrode; however, a significant cell power performance improvement is observed at small AB/PVDF composition ratios that are far from the long-range conductivity optimum of 1 to 1.25. Electrochemical impedance spectroscopy (EIS) tests indicate that the interfacial impedance decreases significantly with increase in binder content. The hybrid power pulse characterization results agree with the EIS tests and also show improvement for cells with a high PVDF content. The AB to PVDF composition plays a significant role in the interfacial resistance. We believe the higher binder contents lead to a more cohesive conductive carbon particle network that results in better overall all local electronic conductivity on the active material surface and hence reduced charge transfer impedance.
Date: July 1, 2007
Creator: Liu, G.; Zheng, H.; Battaglia, V.S.; Simens, A.S.; Minor, A.M. & Song, X.
Object Type: Article
System: The UNT Digital Library
RH-TRU Waste Content Codes (open access)

RH-TRU Waste Content Codes

The Remote-Handled Transuranic (RH-TRU) Content Codes (RH-TRUCON) document describes the inventory of RH-TRU waste within the transportation parameters specified by the Remote-Handled Transuranic Waste Authorized Methods for Payload Control (RH-TRAMPAC).1 The RH-TRAMPAC defines the allowable payload for the RH-TRU 72-B. This document is a catalog of RH-TRU 72-B authorized contents by site. A content code is defined by the following components: • A two-letter site abbreviation that designates the physical location of the generated/stored waste (e.g., ID for Idaho National Laboratory [INL]). The site-specific letter designations for each of the sites are provided in Table 1. • A three-digit code that designates the physical and chemical form of the waste (e.g., content code 317 denotes TRU Metal Waste). For RH-TRU waste to be transported in the RH-TRU 72-B, the first number of this three-digit code is “3.” The second and third numbers of the three-digit code describe the physical and chemical form of the waste. Table 2 provides a brief description of each generic code. Content codes are further defined as subcodes by an alpha trailer after the three-digit code to allow segregation of wastes that differ in one or more parameter(s). For example, the alpha trailers of the subcodes …
Date: July 1, 2007
Creator: Solutions, Washington TRU
Object Type: Report
System: The UNT Digital Library